摘要
合成了壳聚糖-g-水杨酸,用1H NMR, IR和热重分析等对结构进行了表征.接枝反应的最佳条件为:壳聚糖12.5 mmol, n(水杨酸) : n(壳聚糖)=0.75,于55 ℃～65 ℃反应1 h,水杨酸接枝率为20%.
Chitosan-g-（ salicylic acid） was prepared in nonaqueous solution. The structure was characterized by 1^H NMR, IR and thermal analysis. The optimal reaction conditions were as follows： chitosan was 12.5 mmol, n（ salicylic acid） ：n（chitosan） = 0.75, reaction temperature was 55 ℃- 65℃C, reaction time was 1 h. Under the optimal reaction conditions the graft ratio of salicylic acid was 20%.
出处
《合成化学》
CAS
CSCD
2005年第5期461-463,485,共4页
Chinese Journal of Synthetic Chemistry
基金
河南省科技厅资助项目(0424410105)
河南省教育厅资助项目(2004360005)
关键词
水杨酸
壳聚糖
接枝
合成
salicylic acid
chitosan
grafts
synthesis
