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不对称催化烷基化反应中配体研究进展 被引量：6

Progress of Ligands in Asymmetric Catalytic Alkylation
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摘要 总结了用于不对称催化烷基化反应的氨基醇类配体、磺酰胺类配体、二茂铁类配体、吡啶醇类配体、手性磷类配体和固载的配体的最新研究成果,参考文献44篇。 The development of kinds of ligands including aminalcohol, sulfonamide, pyridyl alcohol, chiral phosphorus compound and supported ligand in asymmetric catalytic alkylation are reviewed with 44 references.
作者 周忠强 罗冬冬
机构地区 中南民族大学化学与材料科学学院催化材料科学湖北省重点实验室湖北
出处 《广州化学》 CAS 2005年第3期55-61,共7页 Guangzhou Chemistry
基金 湖北省自然科学基金资助课题(2003ABA070)
关键词 不对称 催化烷基化 配体 asymmetric, catalytic alkylation, ligand
分类号 O621.34 [理学—有机化学]
  • 相关文献

参考文献42

  • 1Dimitrov V, Dobrikov G, Genov M. Chiral β- and γ-aminoalcohols derived from (+)-camphor and (-)-fenchone as catalysts for the enantioselective addition of diethylzinc to benzaldehyde [J]. Tetrahedron Asymmetry, 2001, 12: 1323-1329.
  • 2Genov M, Kostova K, Dimitrov V. Highly diastereoselective synthesis of new optically active aminoalcohols in one step from (+)-camphor and (-)-fenchone [J]. Tetrahedron Asymmetry, 1997, 8: 1869-1876.
  • 3Philipova I, Dimitrov V, Simova S. Synthesis of new enantiopure aminodiols and their use as ligands for the addition ofdiethylzinc to benzaldehyde [J]. Tetrahedron Asymmetry, 1999, 10: 1381-1391.
  • 4Panev S, Linden A, Dimitrov V. Chiral aminoalcohols with a menthane skeleton as catalysts for the enantioselective addition of diethylzinc to benzaldehyde [J]. Tetrahedron Asymmetry, 2001, 12:1313-1321.
  • 5Hanyu N, Aoki T, Mino T, et al. New chiral 1,4-aminoalcohols derived from (+)-camphor and (-)-fenchone for the enantioselective addition of diethylzinc to aldehyde [J]. Tetrahedron Asymmetry, 2000, 11:4127-4136.
  • 6Hanyu N, Mino T, Sakamoto M, et al. Facile synthesis of amino bicyclo[2.2.1]heptyl alcohol and its application for enantioselective additions of diethylzinc to aldehydes [J]. Tetrahedron Letters, 2000, 41: 4587-4590.
  • 7Hanyu N, Aoki T, Mino T, et al. Enantioselective addition of diethylzinc to aldehydes catalyzed by optically active 1,4-aminoalcohols [J]. Tetrahedron Asymmetry, 2000, 11:2971-2979.
  • 8Kitamura M, Suga S, Kawai K, et al. Catalytic asymmetric induction, highly enantioselective addition of dialkylzincs to aldehydes [J]. JAm Chem Soc, 1986, 108: 6071-6072.
  • 9Kitarnura M, Oka H, Noyori R. Asymmetric addition of dialkylzincs to benzaldehyde derivatives catalyzed by chiral β-Amino alcohols, evidence for the monomeric alkylzinc aminoalkoxide as catalyst [ J]. Tetrahedron, 1999, 55:3605-3614.
  • 10Knollmuller M, Ferencic M, Gartner P. Enantioselective addition of organometallics to aldehydes using camphor derived chiral 1,4-aminoalcohols as ligands [J]. Tetrahedron Asymmetry, 1999, 10:3969-3975.

二级参考文献18

  • 1Dong C E，Tetrahedron:Asymmetry，2000年，11卷，2449_2454页
  • 2Hu Q S，J Am Chem Soc，1997年，119卷，12454页
  • 3Huang W S，J Am Chem Soc，1997年，119卷，4313_4314页
  • 4Ma L，Macromolecules，1997年，30卷，204页
  • 5Hu Q S，J Org Chem，1996年，61卷，8370_8377页
  • 6Kang J，J Chem Soc Chem Commun，1994年，17卷，2009页
  • 7Kang J，Syn Lett，1994年，10卷，842页
  • 8Gong B Q，J Org Chem，1991年，56卷，423页
  • 9a). Chaloner, P.A., Renuka Perera, S.A. Enantioselective addition of diethylzinc to benzaldehyde in the presence of ephedrine derivatives[J]. Tetrahedron Letters, 1987,28:3013～3014.b). Kitamura, M., Suga, S., Kawai, K., Noyori, R. Catalytic asymmetric induction highly enantioselective addition of diethylzinc to aldehydes[J]. J. Am. Chem. Soc., 1986, 108:6071～6072.
  • 10a). Hof, R.P., Polert, M.P., Peper, N.C.M.W., Kellogg, R.M. Sulfur derivatives of Ephedra alkaloids 1 new and highly efficient chiral catalyst[J]. Tetrahedron: Asymmetry., 1994,5:31～34.b). Kang, J., Kim, D.S., Kim, J.I. Enantioselective addition of diethylzinc to aldehydes catalyzed by drug-unrelated chiral amino thiol and the corresponding disulfide[J]. Synlett., 1994:842～844.c). Fitzpatrick, K., Hulst, R., Kellogg, R.M. Thiol and disulfide derivatives of Ephedra alkaloids. 2 A mechanistic study of their effect on the addition of diethylzinc to benzaldehyde[J]. Tetrahedron: Asymmetry., 1995, 6:1861～1864.

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广州化学
2005年 第3期

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