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聚丙烯纤维接枝丙烯酸反应条件优化 被引量:11

Optimum conditions of grafting copolymerization ofpolypropylene fiber with acrylic acid
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摘要 The optimum conditions of grafting copolymerization reaction of acrylic acid(AA) onto polypropylene(PP) fiber was studied by using benzoyl peroxide(BPO) as initiator.The primary and secondary sequences of the grafting copolymerization reaction conditions was analysed. The results showed that grafting copolymerization reaction was greatly influenced by the temperature,reaction time, concentration of BPO and that of AA in the primary and secondary role as the above sequence. The optimum reaction conditions of gaining higher exchange capacity for the weak acidic cation-exchange fiber are as follows: the grafting temperature 80 ℃, the reaction time 7 h, the concentration of BPO 2% and AA 80%. The optimum conditions of grafting copolymerization reaction of acrylic acid (AA) onto polypropylene (PP) fiber was studied by using benzoyl peroxide (BPO) as initiator. The primary and secondary sequences of the grafting copolymerization reaction conditions was analysed. The results showed that grafting copolymerization reaction was greatly influenced by the temperature, reaction time, concentration of BPO and that of AA in the primary and secondary role as the above sequence. The optimum reaction conditions of gaining higher exchange capacity for the weak acidic cation-exchange fiber are as follows: the grafting temperature 80°C, the reaction time 7 h, the concentration of BPO 2% and AA 80%.
出处 《化工学报》 EI CAS CSCD 北大核心 2005年第3期555-559,共5页 CIESC Journal
关键词 聚丙烯纤维 丙烯酸 弱酸性阳离子交换纤维 接枝共聚反应 Acrylics Fourier transform infrared spectroscopy Graft copolymers Grafting (chemical) Ion exchange resins
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