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Na~+,K~+∥Cl~-,NO_3^-—H_2O体系25℃相图数据的预测及应用 被引量:1

The Prediction and the Application of Solubilities of Na ̄+,K ̄+∥Cl ̄-,NO -H_2O System at 25℃
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摘要 本文利用Pitzer电解质溶液理论.以盐的平衡常数作为平衡的判据,借助于计算机。对25℃时,Na~+,K~+∥Cl~-,NO-H_2O四元交互体系溶解度数据进行了计算,并举例展示了理论计算结果在工艺参数确定上的应用。 Based on Pitzers theory of the electrolyte solution,using equilibrium constants of salts as the conditions of dissociating equilibria and with the help of computers, thispaper has calculated the solubilities of quaternary reciprocal system Na ̄+,K ̄+∥Cl,NO H_2O at 25℃,and given an example to show the application of the results obtained in techno-logical parameter calculation.
出处 《山东轻工业学院学报(自然科学版)》 CAS 1994年第4期30-35,共6页 Journal of Shandong Polytechnic University
关键词 PITZER理论 水盐体系 溶解度 数据 预测 Pitzers theory,salt-water system,solubility
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同被引文献13

  • 1王建华,高瑞华.NaCl-KCl-NaNO_3-KNO_3-H_2O四元体系相平衡的计算[J].山东工业大学学报,1989,19(4):46-52. 被引量:1
  • 2黄雪莉,宋彭生.Na^+,K^+,Mg^(2+)/NO_3^-,Cl^-,SO_4^(2-)-H_2O体系25℃热力学模型和溶解度预测 Ⅰ:六元体系所需的Pitzer参数[J].盐湖研究,2005,13(4):21-28. 被引量:7
  • 3C.E.Harvie,N.Moller,J.H.Weare.The prediction of mineral solubilities in natural waters:The Na-K-Mg-Ca-H-Cl-SO4-OH-HCO3-CO3-CO2-H2O system to high ionic strengths at 25℃[J].Geochim.Cosmochim.Acta,1984,48(4):723-751.
  • 4K.S.Pitzer and J.J.Kim.Thermodynamics of electrolytes.IV.Activity and osmotic coefficients for mixed electrolytes.[J].J.A.C.S.1974,96(18):5701-5707.
  • 5Bezboruah,A.K.Covington,and R.A.Robinson.Excess Gibbs energies of aqueous mixtures of alkali metal chlorides and nitrates[J].J.Chem.Thermodynamics 1970(2):431-437.
  • 6R.A.Robinson and C.K.Lim[J].Trans.Faraday Soc.,1953(49):1144.
  • 7Platford R.F.Thermodynamics of mixed salts solutions:Excess Gibbs energies of mixing for the six ternary systems formed from aqueous MgCl2,Mg(NO3)2,CaCl2,and Ca(NO3)2 at 25℃[J].J.Chem.Thermodynamics,1971(3):319-324.
  • 8Manohar,S.,Ananthaswamy,J..J.Electrochem.Soc.,India,1988(37):299.
  • 9Manohar,S.,Ananthaswamy,J..Thermodynamic Properties of Electrolyte Solutions:An EMF Study of the Activity Coefficients of KCl in the System KCl-KNO3-H2O at 25,35 and 45℃[J].J.Solution Chem.,1990,19(11):1125-1135.
  • 10Kim Hee-Talk,Frederick W.J.Jr.,Evaluation of Pitzer Ion Interaction Parameters of Aqueous Mixed Electrolyte Solutions at 25 ℃,2.Ternary Mixing Parameters[J].J.Chem.Eng.Data,1988,38(3):278-283.

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