摘要
介绍了微乳体系作为反应介质在有机反应中的应用,涉及亲电取代、亲核取代、亲核加成、酯水解、氧化、羰基化等反应,概述了微乳条件对于有机反应的强化或抑止作用。对其作用机理做出初步分析,提出今后微乳条件下有机反应应注意的几个关键性问题。
This is a general review on the applications of microemulsion for the media in organic reactions, which includes the reactions of electrophilic substitution, nucleophilic substitution,nucleophilic addition, hydrolysis of esters, oxidation and carbonylation, and the effects of intensification or restraint have been summarized. On the basis of the preliminary analysis of the mechanisms, several pivotal questions which should be solved in the future research have been mentioned.
出处
《化学工业与工程》
CAS
2004年第5期361-366,共6页
Chemical Industry and Engineering
基金
天津市自然科学基金资助项目(013605611)
关键词
微乳化
液液两相
有机反应
microemulsification
liquid-liquid diphase
organic reaction
