摘要
在乙醇和水的混合体系中合成了锌配合物[Zn(SA)2(H2O)2](SA=水杨酸根),通过元素分析及X-射线单晶衍射对其进行了表征。结果表明该化合物属于单斜晶系,P21/c空间群,晶胞参数为a=1.55051(15)nm,b=0.53522(10)nm,c=0.91962(14)nm,α=90.00°,β=93.567(2)°,γ=90.00°,晶胞体积V=0.7617(2)nm3,Z=2,Dcalc=1.638 g.cm-3,F(000)=384,μ=1.652 cm-1,R=0.0298,wR=0.0710。
The complex [Zn(SA)2(H2O)2](SA= salicylic acid)have been synthesized from reactions of salicylic and zinc acetate in water-methanol,and characterized by elemental analysis and X-ray crystallography The results of structural analysis indicate that the complex crystallizes in the monoclinic system,space group P21/c with lattice parameters of compound:a=1.55051(15) nm,b=0.53522(10) nm,c=0.91962(14) nm,α=90.00°,β=93.567(2)°,γ=90.00°,V=0.7617(2) nm3,Z=2,Dcalc=1.638 g·cm-3,F(000)=384,μ=1.652 cm-1,R= 0.0.298,wR= 0.0710.
出处
《潍坊学院学报》
2007年第4期98-100,共3页
Journal of Weifang University
基金
国家自然科学基金资助项目(No.20671073)
关键词
水杨酸根
锌配合物
晶体结构
salicylic acid,zinc complex,crystal structure
