摘要
作为重要的催化材料,铑催化剂具有反应条件温和、反应选择性高等特点,已广泛应用于石油化工、医药化工、精细化工等领域。综述了铑作为加氢、氢甲酰化、羰基合成均相催化剂的工业应用情况的同时,还介绍了铑催化剂在新兴的不对称催化领域的选择催化性能和工业应用。指出了影响均相和手性铑催化剂工业化的因素,并对未来铑催化剂的工业应用进行了展望。
As significant catalyst materials ,rhodiumcat-alyst has soft reaction conditions and good selection,which widely used in petrochemical , medicine and finechemical fields .The industry applications in hydrogena-tion, hydroformylation and oxo-synthesis catalysis ofrhodiumwere reviewed,the important catalytic capabilityand applications of rhodiumin newasymmetric catalysisfields were introduced at the same time .The effect fac-tors in industrialization are also expounded.It providesan outlook of rhodiumcatalyst...
出处
《稀有金属》
EI
CAS
CSCD
北大核心
2005年第4期403-407,共5页
Chinese Journal of Rare Metals
关键词
铑
工业应用
均相催化
不对称催化
rhodium
industry application
homogeneous catalyst
asymmetric catalyst
