As one of the regions most affected by global cli-mate warming,the Tianshan mountains has experienced sev-eral ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is c...As one of the regions most affected by global cli-mate warming,the Tianshan mountains has experienced sev-eral ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Moun-tains was used to reconstruct the summer(June-August)maximum temperature(T_(max6-8))variations from 1718 to 2017.The reconstruction explained 53.1% of the variance in the observed T_(max6-8).Over the past 300 years,the T_(max6-8)reconstruction showed clear interannual and decadal vari-abilities.There was a significant warming trend(0.18°C/decade)after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The T_(max6-8) variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the sum-mer North Atlantic Oscillation.This study reveals that cli-mate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mech-anisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.展开更多
As one of the regions most affected by global climate warming,the Tianshan mountains has experienced several ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is con...As one of the regions most affected by global climate warming,the Tianshan mountains has experienced several ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Mountains was used to reconstruct the summer(June-August)maximum temperature(Tmax6-8) variations from 1718 to2017.The reconstruction explained 53.1% of the variance in the observed Tmax6-8.Over the past 300 years,the Tmax6-8reconstruction showed clear interannual and decadal variabilities.There was a significant warming trend(0.18 ℃/decade) after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The Tmax6-8variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the summer North Atlantic Oscillation.This study reveals that climate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mechanisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.展开更多
By the end of 2020,83 silver deposits(or ore occurrences),including four super-large-scale deposits,nine large-scale deposits,33 medium-scale deposits and 37 small-scale deposits or ore occurrences,have been proved.Th...By the end of 2020,83 silver deposits(or ore occurrences),including four super-large-scale deposits,nine large-scale deposits,33 medium-scale deposits and 37 small-scale deposits or ore occurrences,have been proved.The amount of silver metal exceeds 86000 t with average grade of 100 g/t,which makes Daxing’anling region one of the the most important silver ore belt in China.However,the metallogenic characteristics and metallogenesis need to be clarified.The silver deposits in the study area are classified into three main types,which are magmatic hydrothermal vein type,continental volcano-subvolcanic type and skarn type,respectively.The supergiant deposits include the Shuangjianzishan deposit(silver metal amount of 15214 t with average grade of 138 g/t),the Baiyinchagandongshan deposit(silver metal amount of 9446 t with average grade of 187 g/t),the Huaobaote deposit(silver metal amount of 6852 t with average grade of 170 g/t),and the Fuxingtun deposit(silver metal amount of 5240 t with average grade of 196 g/t).The silver deposits are mainly distributed in the central and south of the Daxing’anling area,and mainly formed in the Yanshanian period.The silver polymetallic deposits in the Daxinganling area are significantly controlled by regional faults and the junction zone of volcanic rock basins and their margins.The north-east trending deep faults are the most important ore-controlling structures in this area.The distribution of silver polymetallic deposits along the main faults is obvious,and the intersection area of multiple groups of faults often form important mine catchments.The Permian is the most important ore-bearing formation in this area,but some important silver polymetallic deposits occur in Mesozoic volcanic basins or pre-Mesozoic strata.The magmatic rocks related to mineralization are mainly intermediate acidic or acidic intrusions,intermediate acidic lavas,pyroclastic rocks,and small intrusions of ultra-shallow or shallow facies of the Yanshanian Period.The mineralization element combination is mainly determined by the elemental geochemical background of surrounding rocks or source layers.In addition,the type of deposit,the distance from the mineralization center,and the degree of differentiation of ore-forming rock mass are also important influence factors.The article analyzes the prospecting prospects of each silver deposit type in the study area,discusses the relationship between mineralization center and deep prospecting,and proposes that porphyry silver deposits should be paid attention to.In the prospecting and exploration of silver deposits,comprehensive evaluation and multi-target prospecting need to be strengthened because silver can coexist or be associated with a variety of metals.展开更多
Background,aim,and scope Certain physicochemical indexes of topsoil are closely related to climatic factors including temperature,and precipitation.Understanding the relationship between modern topsoil properties and ...Background,aim,and scope Certain physicochemical indexes of topsoil are closely related to climatic factors including temperature,and precipitation.Understanding the relationship between modern topsoil properties and climatic factors is essential for quantitative paleoclimate reconstruction.Motuo located in the eastern Himalayas,exhibits a significant elevation gradient of over 7000 m from Nnamjagbarwa Peak(7782 m a.s.l.)to the Baxika(150 m a.s.l.).This region features a complete vertical zonation of vegetation,from alpine meadow to tropical forest,presenting an ideal place to investigate the relationships among vegetation,soil and climate conditions across altitudinal gradients.This study aims to explore the vertical variations in the physicochemical composition of topsoil and its relationship with temperature and precipitation.Materials and methods Twenty-seven topsoil samples were collected at 100 m intervals from 800 m to 3600 m a.s.l.along the southern slope of the Himalayas.Grain size,magnetic susceptibility and geochemical elements were measured to discuss the vertical variation characteristics of topsoil composition and their correlation with climatic factors.Results(1)The grain size of topsoil at different altitudes in Motuo is mainly composed of sand accounting for an averaged 53.2%,followed by silt and clay.(2)In the mixed forest zone,frequency dependent magnetic susceptibility(χfd%)shows a clear relationship with altitude,and clay is positively correlated with both altitude and climatic factors.(3)The oxides of topsoil in this area mainly consist of SiO_(2),Al_(2)O_(3) and Fe_(2)O_(3),followed by MgO,CaO,Na_(2)O and K_(2)O,with slight variations in the primary components at different altitudes.The sensitivity of elements to climate varies across different altitudes and vegetation zone,likely due to the region’s complex topography and vegetation.(4)Physical and biological weathering dominates in the broad-leaved forest zone of Motuo,while chemical weathering is more prominent in the coniferous forest zone,with the mixed forest zone falling in between.Discussion The formation of topsoil across the three vegetation zones is influenced by various factors,including parent material,vegetation,and climate.In the broad-leaved forest zone,physical weathering(precipitation,root wedging etc.)and pedogenesis dominate,resulting in finer grain size.The χ_(fd)% increases with altitude likely due to the high temperature and abundant precipitation in this zone,which facilitate the transformation of strong magnetic miners into weaker ones,particularly when the soil is oversaturated.Zirconium(Zr),primarily found in zircon,is depleted at lower altitudes by strong current erosion.Barium(Ba)is similarly reduced at low altitudes in this zone.In mixed forest zone,clay content is the lowest,indicating weaker physical weathering conditions than broad-leaved forest zone.The coarser grain size may result from the combined effects of topography and vegetation coverage.Magnetic susceptibility and organic matter show a positive correlation with altitude.Zr concentration is higher than that in the broad-leaved forest zone,likely resulting from decreased precipitation.In the coniferous zone,the clay content shows considerable fluctuations,with grain size generally becoming finer as altitude increases.This trend may be explained by intensified soil disintegration from seasonal freeze-thaw cycles.The χ_(fd)% values lack a clear trend or pattern,possibly due to soil erosion causing the migration of magnetic minerals or insufficient iron precipitation,which reduces the concentration of magnetic minerals in the soil.Additionally,a positive correlation is observed between altitude and organic matter content,with higher altitudes associated with greater organic matter accumulation.This may be attributed to lower microbial activity in colder conditions,which slows the decomposition and transformation of organic matter.Conclusions The variations in grain size,magnetic susceptibility,and geochemical elements differ across altitudes and vegetation zones,closely connected to the complex interplay of terrain,vegetation,and climate in Motuo.In the mixed forest,altitude has a significant impact onχfd%,and the clay component is particularly sensitive to changes in altitude,mean annual temperature,and precipitation.Zr shows a strong correlation with altitude and climate factors,making it a valuable indicator for assessing changes in atmospheric precipitation within specific altitude ranges.Recommendations and perspectives This study enhances our understanding of the relationships between the physicochemical properties of topsoil and climate conditions,offering valuable insights for paleoclimate reconstruction in Motuo.展开更多
Background,aim,and scope Soil microbes are important drivers of nutrient transformation and energy f low.Reclaiming forest land for agricultural use may have profound effects on soil properties and microbial communiti...Background,aim,and scope Soil microbes are important drivers of nutrient transformation and energy f low.Reclaiming forest land for agricultural use may have profound effects on soil properties and microbial communities.However,the response of soil microbial communities to soil reclamation in the dryland agroecosystem is less understood.Therefore,it is necessary to investigate the changes of soil microbial communities driven by land use conversion to promote nutrient cycling in reclaimed farmland.Materials and methods Based on the metagenomic technique,we evaluated the microbial composition and function of the newly created farmland(NF)after reclamation with two types of traditional farmland(slope farmland(SF),checkdam farmland(CF))on the Loess Plateau,and explored the response of nutrient cycling function to dominant genera and soil properties.Results The results showed that Proteobacteria,Actinobacteria,and Acidobacteria were prevalent in the three types of farmlands.Compared with SF and CF,NF increased the relative abundance of Actinobacteria and Nocardioides,as well as genes related to amino acid metabolism and carbohydrate metabolism.The relative abundance of functional genes related to carbon and nitrogen cycling in the NF was higher than that in the traditional farmland(SF and CF).The relative abundance of nutrient cycling functional genes was positively correlated with dominant genera in the three types of farmlands.Except for pH,soil physicochemical factors were negatively correlated with genes related to amino acid metabolism and carbon cycle.Discussion Previous studies have shown that the nutrient conditions of the soil may intensify the competition between the eutrophic and oligotrophic microbial populations.After long-term cultivation and fertilization,the soil properties of traditional farmland were significantly different from those of NF,leading to the differentiation of dominant microbial groups.Microbes usually have functional redundancy to cope with changing environments.Soil microbes in traditional farmland may contain more genes related to replication and repair,cell growth and death,and environmental adaptation in response to disturbances caused by agricultural practices.On the contrary,the NF was less disturbed by agricultural activities,and the soil properties were more similar to forest land,so the carbon and nitrogen cycle function genes were more abundant.The nutrient cycling function was affected by the abundance of microbial dominant groups and soil properties,which may be related to the availability of soil nutrients and agricultural disturbance in different farmlands.Aspects of soil microbial-driven nutrient cycling in agriculture could be regulated in sustainable method.Conclusions The change from forest land to farmland kept more carbon and nitrogen cycling function in the newly created farmland,while long-term agricultural activities have drastically changed the functional structure of traditional farmland,resulting in the nutrient cycling function more concentrated to meet the needs of crop growth.Recommendations and perspectives Hence,it is necessary to apply sustainable agricultural method to regulate microbial-driven nutrient cycling.The insights are meaningful for sustainable agricultural development and land management in arid areas.展开更多
Background,aim,and scope The tectonic uplift of the Cenozoic Tibetan Plateau has produced a chain effect,which is an excellent location for Earth system science research,and its uplift process,mechanism and environmen...Background,aim,and scope The tectonic uplift of the Cenozoic Tibetan Plateau has produced a chain effect,which is an excellent location for Earth system science research,and its uplift process,mechanism and environmental effects are the hot spot and frontier of the current research.The“Tibetan Plateau uplift-weathering-CO_(2) concentration-global climate change”model was put forward by Raymo and Ruddiman to interpret the Late Cenozoic climate change.However,there are still some questions suspended,such as does the weathering of the Tibetan Plateau have the ability to control the global climate?How to explain the modern-like global CO_(2) concentration starting at about 24 Ma?Here,a short space was taken to present a brainstorm about the above questions on account of existing geological pieces of evidence.Materials and methods In this paper,we integrate the formation and evolution of the Yangtze River and Pearl River,the origin and development of the Asian inland aridification-monsoon system,the Cenozoic tectonic uplift process of the Tibetan Plateau,and the westerly winds to discuss and analyze the relationship between the Cenozoic CO_(2) concentration changes and the uplift of the Tibetan Plateau and why the CO_(2) concentration similar to the present was formed at about 24 Ma.Results Similar correspondence of the surface uplift history of Xizang,other global mountains,and the declining CO_(2) concentration could support the theory Tibetan Plateau weathering inf luences CO_(2) concentration.Starting from 24 Ma,the most important character was the uplift and erosion of Xizang and Himalaya,collaborating with Ocean Iron Fertilization(OIF)together as an entity to control the atmospheric CO_(2) concentration because the great Asian rivers,Asian monsoons,and westerlies connected Xizang and surrounded seas together through materials transportation.Discussion Paleogeographic reconstructions from 40 Ma to 20 Ma illustrate that the main topographic change occurred in the Andes,Cordillera orogenic belt,and Xizang.We comprise a comprehensive set of evidence from independent data,which correspond temporally with the tipping point(about 24 Ma)of the atmospheric CO_(2) and we noticed that modern-like Asia monsoon,inland aridity,Asian great rivers,and climate zone formed at about 24 Ma and also there are tectonic activities for the Andes and Rockies.We raised the possibility that the modern-like atmospheric CO_(2) concentration at about 24 Ma was caused by the above geological factors.Here the rivers,monsoon,and westerlies are termed as“connectors”.In addition,these Asian rivers originated from Xizang,the monsoon,and inner Asian aridification are strongly a function of the uplift and growth of Xizang,thus,Xizang here is named as“trigger”.The distinct character of“trigger-connectors”model is that this not only takes the monsoon,westerlies,and the global great rivers into consideration but also expands the range which inf luences atmospheric CO_(2) concentration,from local points to a vast area since about 24 Ma,such as from Tibetan Plateau to Asia,including surrounded seas,after about 24 Ma.However,because the opening of the Late Oligocene-Early Miocene Antarctic periphery straits is highly coincident with the onset of modern-like global atmospheric CO_(2) concentration,we are forced to consider that they also had a significant impact on the reduction of atmospheric CO_(2) concentrations at this time.Conclusions“Trigger-connectors”was put forward to explain the Cenozoic CO_(2) variation,especially modern-like global CO_(2) concentration since about 24 Ma.Recommendations and perspectives Here we use the“trigger-connectors”model to explain the formation of modern-like CO_(2) concentrations starting at about 24 Ma,but there are still some problems.The most important premise for the“trigger-connectors”model is the constructed Cenozoic CO_(2) concentration record is reliable,which is the foundation of our hypothesis.In the future,potential improvements should focus on topographic reconstructions of Xizang and the global mountains.Here we have concentrated on Xizang in the considered timeslices but still,pay less attention to other global orogenic belts.Collaborations with geologist experts in those regions could provide valuable feedback to evaluate their potential role of them in CO_(2) evolution.What is more,considerable progress may be achieved with the addition and consideration of more and new geological data.展开更多
Characterization of transport pathways and depositional changes in Mercury(Hg)and their connection to climatic and environmental changes on various time scales are crucial for better understanding the anthropogenic im...Characterization of transport pathways and depositional changes in Mercury(Hg)and their connection to climatic and environmental changes on various time scales are crucial for better understanding the anthropogenic impacts on the global Hg cycle in the Anthropocene epoch.In this study,we examined Hg variations recorded in a stalagmite from central China,covering the period from 25.5 to 10.9 thousand years ago.Our data show a marked increase in Hg concentrations during the late Last Glacial Maximum,which coincided with the period of highest dust deposition on the Chinese Loess Plateau.Hg concentrations were lower during Heinrich events 1 and 2 and the Younger Dryas but higher during the BùllingAllerùd and the early Holocene.We suggest that regional dust load,which enhances atmospheric dry deposition of Hg,is the primary factor influencing Hg deposition in central China on glacialinterglacial timescales.On millennial-to-centennial timescales,climate also plays a significant role.Warmer and wetter conditions increase vegetation,litterfall,and soil/rock weathering,which in turn boost mineral dissolution and soil erosion in the vadose zone.These processes collectively result in higher Hg concentrations in the stalagmite.展开更多
Reconstruction of the paleoaltitude history of the Tibetan Plateau is critical for understanding the linkage between tectonics and its effect on regional and global climate change.Presently,most of the paleoaltitude s...Reconstruction of the paleoaltitude history of the Tibetan Plateau is critical for understanding the linkage between tectonics and its effect on regional and global climate change.Presently,most of the paleoaltitude studies are concentrated on the southern and southeastern part of the Tibetan Plateau,and few studies have been conducted in the central-northern part.In this paper we focused on the Wudaoliang Formation in the Tuotuohe Basin,central to northern Tibetan Plateau,to reconstruct paleoaltitude based on carbonate oxygen isotopes.The carbonate samples are primary or have experienced an early stage of digenesis.Based on the thermodynamic and empirical model results,the paleoaltitude of the Wudaoliang Formation is found to be around 2700–3260 m(average of 2980±280 m)in the early Miocene(~24 Ma).Integrating paleoaltitude results from Wudaoliang Basin and our results,we conclude that crustal shortening and tectonic activity were strong during the late Eocene to late Oligocene-early Miocene and relatively weak during the early Miocene in the central-northern Tibetan Plateau.展开更多
Intensive measurements were conducted in Xi’an,China before and during a COVID-19 lockdown period to investigate how changes in anthropogenic emissions affected the optical properties and radiative effects of brown c...Intensive measurements were conducted in Xi’an,China before and during a COVID-19 lockdown period to investigate how changes in anthropogenic emissions affected the optical properties and radiative effects of brown carbon(BrC)aerosol.The contribution of BrC to total aerosol light absorption during the lockdown(13%-49%)was higher compared with the normal period(4%-29%).Mass absorption cross-sections(MACs)of specific organic aerosol(OA)factors were calculated from a ridge regression model.Of the primary OA(POA),coal combustion OA(CCOA)had the largest MACs at all tested wave-lengths during both periods due to high molecular-weight BrC chromophores;that was followed by biomass burning OA(BBOA)and hydrocarbon-like OA(HOA).For secondary OA(SOA),the MACs of the lessoxidized oxygenated OA(OOA)species(LO-OOA)atλ=370-590 nm were higher than those of more-oxidized OOA(MO-OOA)during both periods,presumably due to chromophore bleaching.The largest contributor to BrC absorption at the short wavelengths was CCOA during both periods,but BrC absorption by LO-OOA and MO-OOA became dominant at longer wavelengths during the lockdown.The estimated radiation forcing efficiency of BrC over 370-600 nm increased from 37.5 W·gduring the normal period to 50.2 W·gduring the lockdown,and that enhancement was mainly caused by higher MACs for both LO-OOA and MO-OOA.This study provides insights into the optical properties and radiative effects of source-specific BrC aerosol when pollution emissions are reduced.展开更多
In this study,online water-soluble inorganic ions were detected to deduce the formation mechanism of secondary inorganic aerosol in Xianyang,China during wintertime.The dominant inorganic ions of sulfate(SO_(4)^(2-)),...In this study,online water-soluble inorganic ions were detected to deduce the formation mechanism of secondary inorganic aerosol in Xianyang,China during wintertime.The dominant inorganic ions of sulfate(SO_(4)^(2-)),nitrate(NO_(3)^(-)),and ammonium(NH_(4)^(+))(the sum of those is abbreviated as SNA)accounted for 17%,21%,and 12% of PM_(2.5)mass,respectively.While the air quality deteriorated from excellent to poor grades,the precursor gas sulfur dioxide(SO_(2))of SO_(4)^(2-)increased and then decreased with a fluctuation,while nitrogen dioxide(NO_(2))and ammonia(NH_(3)),precursors of NO_(3)^(-)and NH_(4)^(+),and SNA show increasing trends.Meteorological factors including boundary layer height(BLH),temperature,and wind speed also show decline trends,except relative humidity(RH).Meanwhile,the secondary conversion ratio shows a remarkable increasing trend,indicating that there was a strong secondary transformation.From the perspective of chemical mechanisms,RH is positively correlated with sulfur oxidation ratios(SOR),nitrogen oxidation ratios(NOR),and ammonia conversion ratios,representing that the increase of humidity could promote the generation of SNA.Notably,SOR and NOR were also positively related to the ammonia.On the one hand,the low wind speed and BLH led to the accumulation of pollutants.On the other hand,the increases of RH and ammonia promoted more formations of SNA and PM_(2.5).The results advance our identification of the contributors to the haze episodes and assist to establish more efficient emission controls in Xianyang,in addition to other cities with similar emission and geographical characteristics.展开更多
A"once-in-a-millennium"super rainstorm battered Zhengzhou,central China,from 07/17/2021 to 07/22/2021(named"7.20"Zhengzhou rainstorm).It killed 398 people and caused billions of dollars in damage.A...A"once-in-a-millennium"super rainstorm battered Zhengzhou,central China,from 07/17/2021 to 07/22/2021(named"7.20"Zhengzhou rainstorm).It killed 398 people and caused billions of dollars in damage.A pressing question is whether rainstorms of this intensity can be effectively documented by geological archives to understand better their historical variabilities beyond the range of meteorological data.Here,four land snail shells were collected from Zhengzhou,and weekly to daily resolved snail shellδ^(18)O records from June to September of 2021 were obtained by gas-source mass spectrometry and secondary ion mass spectrometry.The daily resolved records show a dramatic negative shift between 06/18/2021 and 09/18/2021,which has been attributed to the"7.20"Zhengzhou rainstorm.Moreover,the measured amplitude of this shift is consistent with the theoretical value estimated from the flux balance model and instrumental data for the"7.20"Zhengzhou rainstorm.Our results suggest that the ultra-high resolutionδ^(18)O of land snail shells have the potential to reconstruct local synoptic scale rainstorms quantitatively,and thus fossil snail shells in sedimentary strata can be valuable material for investigating the historical variability of local rainstorms under different climate backgrounds.展开更多
Covered by erodible loess and affected by significant seasonal climate variations,chemical weathering in the Chinese Loess Plateau(abbreviated as CLP)has important effects on the hydrochemistry of the Yellow River and...Covered by erodible loess and affected by significant seasonal climate variations,chemical weathering in the Chinese Loess Plateau(abbreviated as CLP)has important effects on the hydrochemistry of the Yellow River and the global carbon cycle.However,chemical weathering processes in the CLP are still unclear.Based on 296 river water samples in the CLP in the different seasons,hydrochemistry,weathering processes,and their controlling factors were revealed.River waters in the CLP exhibited slightly alkalinity(pH=8.4±0.5)with much high total dissolved solids(TDS)values(691±813 mg/L).The water types of river water in the CLP were primarily SO_(4)^(2-)-Cl^(-)-Na^(+),HCO_(3)^(-)-Ca^(2+)-Mg^(2+),and SO_(4)^(2-)-Cl^(-)-Ca^(2+)-Mg^(2+).According to the forward model,evaporite dissolution has the largest contribution(55.1%±0.2%)to riverine solutes in the CLP,then followed by carbonate weathering(35.6%±0.2%)and silicate weathering(6.5%±0.1%).For spatio-temporal variations,the contribution of evaporite dissolution in the CLP decreased from northwest to southeast with higher proportion in the dry season,carbonate weathering increased from northwest to southeast with a higher proportion in the wet season,and silicate weathering showed minor spatio-temporal variations.Ca^(2+)and Mg^(2+)were affected by carbonate precipitation and/or incongruent calcite dissolution,and about 50%of samples exhibited cation exchange reactions.The physical erosion rate in the CLP,which was 372±293 t·km^(-2)·yr^(-1),varied greatly and was greater than those of other worldwide rivers.Chemical weathering rates in the CLP showed an increasing trend southward.During the wet season,high runoff led to the release of evaporite and carbonate from loess,while the interfacial reaction kinetic limited the increase of the silicate weathering rates.The CO_(2)consumption budget by carbonate weathering(6.1×10^(10)mol/yr)and silicate weathering(1.6×10^(10)mol/yr)in the CLP accounted for 0.29%and 0.08%of the global carbon cycle,respectively.Meanwhile,the weathering proportion by sulfuric acids was relatively high with a CO_(2)release flux of 6.5×10^(9)mol/yr.By compiling the data,we propose that the interfacial reaction kinetic and runoff control CO_(2)consumption rate by silicate and carbonate weathering,respectively.These results contribute to the understanding of modern weathering processes of loess in the CLP,thus helping to deduce the environmental and climatic evolution of the basin.展开更多
Droughts are the most frequent natural disaster in regions at the margins of the East Asian summer monsoon(EASM),which pose threats to agriculture,the economy,and human lives.However,the limitations of only approximat...Droughts are the most frequent natural disaster in regions at the margins of the East Asian summer monsoon(EASM),which pose threats to agriculture,the economy,and human lives.However,the limitations of only approximately 60 years of meteorological observations hamper our understanding of the characteristics and mechanisms of local hydroclimate.Trees growing in the marginal region of the EASM are usually sensitive to moisture variations and have played important roles in past hydroclimatic reconstructions.Here,a 303-year tree-ring-width chronology of Pinus tabulaeformis from Mt.Lama,which is located in the junction of the Liaoning Province and Inner Mongolia,China,was used to reconstruct the May-August Palmer drought severity index(PDSI)in the marginal region of the EASM.The transfer function explains 48.0%(or 47.2%after adjusting for the loss of the degrees of freedom)of the variance over the calibration period from 1946 to 2012.A spatial correlation analysis demonstrates that our PDSI reconstruction can represent the drought variability on the northernmost margin of the EASM.The winter Asian polar vortex area index showed a delayed impact on the summer EASM precipitation in the following year.展开更多
Owing to uneven environmental monitoring site distribution,there are significant spatial data gaps for concentrations of ambientfine particles with diameters≤2.5µm(PM_(2.5))obtained using traditional monitoring ...Owing to uneven environmental monitoring site distribution,there are significant spatial data gaps for concentrations of ambientfine particles with diameters≤2.5µm(PM_(2.5))obtained using traditional monitoring methods.Satellite products are an alternative data source for locations where monitoring sites are unavailable.The Moderate Resolution Imaging Spectroradiometer(MODIS)aerosol optical depth(AOD)product has been widely used in PM_(2.5) assessment for years;however,it has obvious data gaps in winter.Here,the Visible Infrared Imaging Radiometer Suite(VIIRS)AOD was applied to supplement MODIS AOD data to obtain a fused AOD dataset.A three-stage model consisting of a corrected AOD model,mixed effects model,and geographically weighted regression model was developed and used with meteorological and vegetation factors to estimate PM_(2.5).Results showed overall modelfitting by cross-validation(CV)with an R^(2) of 0.92,mean absolute error of 5.72μg/m^(3),and root mean square error of 7.15μg/m^(3).The combination of MODIS AOD and VIIRS AOD was a suitable method for enhancing AOD coverage.The CV R^(2) value of the three-stage model(0.92)was higher than that of the two-stage model(0.9).Hence,the three-stage model could achieve a betterfit in estimating PM_(2.5) on a regional scale.展开更多
A key scientific approach to addressing the environmental radiation risks from Fukushima nuclear contaminated water(FNCW) discharge into the ocean is understanding and predicting the marine dispersion of radionuclides...A key scientific approach to addressing the environmental radiation risks from Fukushima nuclear contaminated water(FNCW) discharge into the ocean is understanding and predicting the marine dispersion of radionuclides.The dispersion of radiocesium(CsF:134Cs,137Cs) from the Fukushima nuclear accident in the North Pacific and its marginal seas post-2011 was systematically summarized,focusing on pathways,vertical distribution changes,and transit times.Our research examined CsFdispersion through the Kuroshio Extension and denser central mode water(D-CMW) to the eastern North Pacific,as well as through subtropical mode water(STMW),lighter central mode water(L-CMW),and D-CMW to the subtropical western North Pacific,China Seas,and Sea of Japan.We considered broader implications of CsFdispersion in light of ongoing FNCW discharge.Given this prolonged liquid discharge and Kuroshio Extension’s barrier effect,it is crucial to emphasize the role of CMW besides STMW in transporting FNCW to the subtropical western North Pacific and its marginal seas.Future research should focus on the key mechanism and longitude range of CMW crossing the Kuroshio Extension.Since short-lived134Cs decays rapidly during the storage and dispersion of FNCW,long-lived135Cs and135Cs/137Cs ratios can serve as valuable tracers for detecting and quantifying FNCW.Therefore,there is an urgent need for high-precision analysis of these key radionuclides and their characteristic ratios.To promptly detect,assess,and respond to FNCW intrusion,continuous monitoring and identification of nuclear pollution sources in key ocean currents and straits are critical.Furthermore,interdisciplinary research integrating monitoring with marginal sea circulation dynamics and high-resolution numerical simulations should be a priority.展开更多
The Northeast Plain in China ranks among the top five regions that have been significantly impacted by haze pollution.To effectively control pollution,it is crucial to accurately assess the effects of emission reducti...The Northeast Plain in China ranks among the top five regions that have been significantly impacted by haze pollution.To effectively control pollution,it is crucial to accurately assess the effects of emission reduction measures.In this study,we analyzed surveillance data and found substantial decreases(ranging from 19.0%to 50.1%)in average annual mass concentrations of key pollutants(such as CO,SO_(2),NO_(2),and PM_(2.5))in the Northeast Plain from 2016 to 2020.To precisely determine the contributions of meteorological conditions and emission reductions to the improvement of air quality in the Northeast Plain,we conducted three scenario simulations.By comparing source emissions in December 2016 and 2020 using the WRF-Chem model(except for SO_(2)),we observed significant reductions of 21.3%,8.8%,and 9.8%in mass concentrations of PM_(2.5),NO_(2),and CO,respectively,from 2016 to 2020.This highlights the essential role that meteorological conditions play in determining air quality in the Northeast Plain.Moreover,further reducing source emissions by 30%in December 2016 resulted in subsequent reductions of 25.3%,29.0%,4.5%,and 30.3%in mass concentrations of PM_(2.5),SO_(2),NO_(2),and CO,respectively,under the same meteorological conditions.Notably,source emission reduction was effective for PM_(2.5),SO_(2),and CO,but not for NO_(2).The improvement in air quality in the Northeast Plain from 2016 to 2020 can be attributed to the combined effects of improved meteorological conditions and reduced pollution sources.展开更多
基金This study was supported by the Second Tibetan Plateau Scientific Expedition and Research(2019QZKK0101)the China Desert Meteorological Science Research Foundation(Sqj2022012)+3 种基金the Natural Science Basic Research Program of Shaanxi Province(2023-JC-QN-0307)the National Natural Science Foundation of China(42361144712)the Chinese Academy of Sciences(XDB40010300)the State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS(SKLLQG2022).
文摘As one of the regions most affected by global cli-mate warming,the Tianshan mountains has experienced sev-eral ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Moun-tains was used to reconstruct the summer(June-August)maximum temperature(T_(max6-8))variations from 1718 to 2017.The reconstruction explained 53.1% of the variance in the observed T_(max6-8).Over the past 300 years,the T_(max6-8)reconstruction showed clear interannual and decadal vari-abilities.There was a significant warming trend(0.18°C/decade)after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The T_(max6-8) variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the sum-mer North Atlantic Oscillation.This study reveals that cli-mate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mech-anisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.
基金supported by the Second Tibetan Plateau Scientific Expedition and Research(2019QZKK0101)the China Desert Meteorological Science Research Foundation(Sqj2022012)+3 种基金the Natural Science Basic Research Program of Shaanxi Province(2023-JC-QN-0307)the National Natural Science Foundation of China(42361144712)the Chinese Academy of Sciences(XDB40010300)the State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS(SKLLQG2022).
文摘As one of the regions most affected by global climate warming,the Tianshan mountains has experienced several ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Mountains was used to reconstruct the summer(June-August)maximum temperature(Tmax6-8) variations from 1718 to2017.The reconstruction explained 53.1% of the variance in the observed Tmax6-8.Over the past 300 years,the Tmax6-8reconstruction showed clear interannual and decadal variabilities.There was a significant warming trend(0.18 ℃/decade) after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The Tmax6-8variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the summer North Atlantic Oscillation.This study reveals that climate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mechanisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.
基金financially supported by the projects of China Geological Survey(DD20221695,DD20160346 and DD20190379)the Fundamental Research Funds of the Central Public Welfare Scientific Research Institutes(JYYWF20183701 and JYYWF20183704)the Inner Mongolia Geological Exploration Fund Project(2020-YS03).
文摘By the end of 2020,83 silver deposits(or ore occurrences),including four super-large-scale deposits,nine large-scale deposits,33 medium-scale deposits and 37 small-scale deposits or ore occurrences,have been proved.The amount of silver metal exceeds 86000 t with average grade of 100 g/t,which makes Daxing’anling region one of the the most important silver ore belt in China.However,the metallogenic characteristics and metallogenesis need to be clarified.The silver deposits in the study area are classified into three main types,which are magmatic hydrothermal vein type,continental volcano-subvolcanic type and skarn type,respectively.The supergiant deposits include the Shuangjianzishan deposit(silver metal amount of 15214 t with average grade of 138 g/t),the Baiyinchagandongshan deposit(silver metal amount of 9446 t with average grade of 187 g/t),the Huaobaote deposit(silver metal amount of 6852 t with average grade of 170 g/t),and the Fuxingtun deposit(silver metal amount of 5240 t with average grade of 196 g/t).The silver deposits are mainly distributed in the central and south of the Daxing’anling area,and mainly formed in the Yanshanian period.The silver polymetallic deposits in the Daxinganling area are significantly controlled by regional faults and the junction zone of volcanic rock basins and their margins.The north-east trending deep faults are the most important ore-controlling structures in this area.The distribution of silver polymetallic deposits along the main faults is obvious,and the intersection area of multiple groups of faults often form important mine catchments.The Permian is the most important ore-bearing formation in this area,but some important silver polymetallic deposits occur in Mesozoic volcanic basins or pre-Mesozoic strata.The magmatic rocks related to mineralization are mainly intermediate acidic or acidic intrusions,intermediate acidic lavas,pyroclastic rocks,and small intrusions of ultra-shallow or shallow facies of the Yanshanian Period.The mineralization element combination is mainly determined by the elemental geochemical background of surrounding rocks or source layers.In addition,the type of deposit,the distance from the mineralization center,and the degree of differentiation of ore-forming rock mass are also important influence factors.The article analyzes the prospecting prospects of each silver deposit type in the study area,discusses the relationship between mineralization center and deep prospecting,and proposes that porphyry silver deposits should be paid attention to.In the prospecting and exploration of silver deposits,comprehensive evaluation and multi-target prospecting need to be strengthened because silver can coexist or be associated with a variety of metals.
文摘Background,aim,and scope Certain physicochemical indexes of topsoil are closely related to climatic factors including temperature,and precipitation.Understanding the relationship between modern topsoil properties and climatic factors is essential for quantitative paleoclimate reconstruction.Motuo located in the eastern Himalayas,exhibits a significant elevation gradient of over 7000 m from Nnamjagbarwa Peak(7782 m a.s.l.)to the Baxika(150 m a.s.l.).This region features a complete vertical zonation of vegetation,from alpine meadow to tropical forest,presenting an ideal place to investigate the relationships among vegetation,soil and climate conditions across altitudinal gradients.This study aims to explore the vertical variations in the physicochemical composition of topsoil and its relationship with temperature and precipitation.Materials and methods Twenty-seven topsoil samples were collected at 100 m intervals from 800 m to 3600 m a.s.l.along the southern slope of the Himalayas.Grain size,magnetic susceptibility and geochemical elements were measured to discuss the vertical variation characteristics of topsoil composition and their correlation with climatic factors.Results(1)The grain size of topsoil at different altitudes in Motuo is mainly composed of sand accounting for an averaged 53.2%,followed by silt and clay.(2)In the mixed forest zone,frequency dependent magnetic susceptibility(χfd%)shows a clear relationship with altitude,and clay is positively correlated with both altitude and climatic factors.(3)The oxides of topsoil in this area mainly consist of SiO_(2),Al_(2)O_(3) and Fe_(2)O_(3),followed by MgO,CaO,Na_(2)O and K_(2)O,with slight variations in the primary components at different altitudes.The sensitivity of elements to climate varies across different altitudes and vegetation zone,likely due to the region’s complex topography and vegetation.(4)Physical and biological weathering dominates in the broad-leaved forest zone of Motuo,while chemical weathering is more prominent in the coniferous forest zone,with the mixed forest zone falling in between.Discussion The formation of topsoil across the three vegetation zones is influenced by various factors,including parent material,vegetation,and climate.In the broad-leaved forest zone,physical weathering(precipitation,root wedging etc.)and pedogenesis dominate,resulting in finer grain size.The χ_(fd)% increases with altitude likely due to the high temperature and abundant precipitation in this zone,which facilitate the transformation of strong magnetic miners into weaker ones,particularly when the soil is oversaturated.Zirconium(Zr),primarily found in zircon,is depleted at lower altitudes by strong current erosion.Barium(Ba)is similarly reduced at low altitudes in this zone.In mixed forest zone,clay content is the lowest,indicating weaker physical weathering conditions than broad-leaved forest zone.The coarser grain size may result from the combined effects of topography and vegetation coverage.Magnetic susceptibility and organic matter show a positive correlation with altitude.Zr concentration is higher than that in the broad-leaved forest zone,likely resulting from decreased precipitation.In the coniferous zone,the clay content shows considerable fluctuations,with grain size generally becoming finer as altitude increases.This trend may be explained by intensified soil disintegration from seasonal freeze-thaw cycles.The χ_(fd)% values lack a clear trend or pattern,possibly due to soil erosion causing the migration of magnetic minerals or insufficient iron precipitation,which reduces the concentration of magnetic minerals in the soil.Additionally,a positive correlation is observed between altitude and organic matter content,with higher altitudes associated with greater organic matter accumulation.This may be attributed to lower microbial activity in colder conditions,which slows the decomposition and transformation of organic matter.Conclusions The variations in grain size,magnetic susceptibility,and geochemical elements differ across altitudes and vegetation zones,closely connected to the complex interplay of terrain,vegetation,and climate in Motuo.In the mixed forest,altitude has a significant impact onχfd%,and the clay component is particularly sensitive to changes in altitude,mean annual temperature,and precipitation.Zr shows a strong correlation with altitude and climate factors,making it a valuable indicator for assessing changes in atmospheric precipitation within specific altitude ranges.Recommendations and perspectives This study enhances our understanding of the relationships between the physicochemical properties of topsoil and climate conditions,offering valuable insights for paleoclimate reconstruction in Motuo.
文摘Background,aim,and scope Soil microbes are important drivers of nutrient transformation and energy f low.Reclaiming forest land for agricultural use may have profound effects on soil properties and microbial communities.However,the response of soil microbial communities to soil reclamation in the dryland agroecosystem is less understood.Therefore,it is necessary to investigate the changes of soil microbial communities driven by land use conversion to promote nutrient cycling in reclaimed farmland.Materials and methods Based on the metagenomic technique,we evaluated the microbial composition and function of the newly created farmland(NF)after reclamation with two types of traditional farmland(slope farmland(SF),checkdam farmland(CF))on the Loess Plateau,and explored the response of nutrient cycling function to dominant genera and soil properties.Results The results showed that Proteobacteria,Actinobacteria,and Acidobacteria were prevalent in the three types of farmlands.Compared with SF and CF,NF increased the relative abundance of Actinobacteria and Nocardioides,as well as genes related to amino acid metabolism and carbohydrate metabolism.The relative abundance of functional genes related to carbon and nitrogen cycling in the NF was higher than that in the traditional farmland(SF and CF).The relative abundance of nutrient cycling functional genes was positively correlated with dominant genera in the three types of farmlands.Except for pH,soil physicochemical factors were negatively correlated with genes related to amino acid metabolism and carbon cycle.Discussion Previous studies have shown that the nutrient conditions of the soil may intensify the competition between the eutrophic and oligotrophic microbial populations.After long-term cultivation and fertilization,the soil properties of traditional farmland were significantly different from those of NF,leading to the differentiation of dominant microbial groups.Microbes usually have functional redundancy to cope with changing environments.Soil microbes in traditional farmland may contain more genes related to replication and repair,cell growth and death,and environmental adaptation in response to disturbances caused by agricultural practices.On the contrary,the NF was less disturbed by agricultural activities,and the soil properties were more similar to forest land,so the carbon and nitrogen cycle function genes were more abundant.The nutrient cycling function was affected by the abundance of microbial dominant groups and soil properties,which may be related to the availability of soil nutrients and agricultural disturbance in different farmlands.Aspects of soil microbial-driven nutrient cycling in agriculture could be regulated in sustainable method.Conclusions The change from forest land to farmland kept more carbon and nitrogen cycling function in the newly created farmland,while long-term agricultural activities have drastically changed the functional structure of traditional farmland,resulting in the nutrient cycling function more concentrated to meet the needs of crop growth.Recommendations and perspectives Hence,it is necessary to apply sustainable agricultural method to regulate microbial-driven nutrient cycling.The insights are meaningful for sustainable agricultural development and land management in arid areas.
文摘Background,aim,and scope The tectonic uplift of the Cenozoic Tibetan Plateau has produced a chain effect,which is an excellent location for Earth system science research,and its uplift process,mechanism and environmental effects are the hot spot and frontier of the current research.The“Tibetan Plateau uplift-weathering-CO_(2) concentration-global climate change”model was put forward by Raymo and Ruddiman to interpret the Late Cenozoic climate change.However,there are still some questions suspended,such as does the weathering of the Tibetan Plateau have the ability to control the global climate?How to explain the modern-like global CO_(2) concentration starting at about 24 Ma?Here,a short space was taken to present a brainstorm about the above questions on account of existing geological pieces of evidence.Materials and methods In this paper,we integrate the formation and evolution of the Yangtze River and Pearl River,the origin and development of the Asian inland aridification-monsoon system,the Cenozoic tectonic uplift process of the Tibetan Plateau,and the westerly winds to discuss and analyze the relationship between the Cenozoic CO_(2) concentration changes and the uplift of the Tibetan Plateau and why the CO_(2) concentration similar to the present was formed at about 24 Ma.Results Similar correspondence of the surface uplift history of Xizang,other global mountains,and the declining CO_(2) concentration could support the theory Tibetan Plateau weathering inf luences CO_(2) concentration.Starting from 24 Ma,the most important character was the uplift and erosion of Xizang and Himalaya,collaborating with Ocean Iron Fertilization(OIF)together as an entity to control the atmospheric CO_(2) concentration because the great Asian rivers,Asian monsoons,and westerlies connected Xizang and surrounded seas together through materials transportation.Discussion Paleogeographic reconstructions from 40 Ma to 20 Ma illustrate that the main topographic change occurred in the Andes,Cordillera orogenic belt,and Xizang.We comprise a comprehensive set of evidence from independent data,which correspond temporally with the tipping point(about 24 Ma)of the atmospheric CO_(2) and we noticed that modern-like Asia monsoon,inland aridity,Asian great rivers,and climate zone formed at about 24 Ma and also there are tectonic activities for the Andes and Rockies.We raised the possibility that the modern-like atmospheric CO_(2) concentration at about 24 Ma was caused by the above geological factors.Here the rivers,monsoon,and westerlies are termed as“connectors”.In addition,these Asian rivers originated from Xizang,the monsoon,and inner Asian aridification are strongly a function of the uplift and growth of Xizang,thus,Xizang here is named as“trigger”.The distinct character of“trigger-connectors”model is that this not only takes the monsoon,westerlies,and the global great rivers into consideration but also expands the range which inf luences atmospheric CO_(2) concentration,from local points to a vast area since about 24 Ma,such as from Tibetan Plateau to Asia,including surrounded seas,after about 24 Ma.However,because the opening of the Late Oligocene-Early Miocene Antarctic periphery straits is highly coincident with the onset of modern-like global atmospheric CO_(2) concentration,we are forced to consider that they also had a significant impact on the reduction of atmospheric CO_(2) concentrations at this time.Conclusions“Trigger-connectors”was put forward to explain the Cenozoic CO_(2) variation,especially modern-like global CO_(2) concentration since about 24 Ma.Recommendations and perspectives Here we use the“trigger-connectors”model to explain the formation of modern-like CO_(2) concentrations starting at about 24 Ma,but there are still some problems.The most important premise for the“trigger-connectors”model is the constructed Cenozoic CO_(2) concentration record is reliable,which is the foundation of our hypothesis.In the future,potential improvements should focus on topographic reconstructions of Xizang and the global mountains.Here we have concentrated on Xizang in the considered timeslices but still,pay less attention to other global orogenic belts.Collaborations with geologist experts in those regions could provide valuable feedback to evaluate their potential role of them in CO_(2) evolution.What is more,considerable progress may be achieved with the addition and consideration of more and new geological data.
基金supported by the National Natural Science Foundation of China(42325705 and 42230208)the Chinese Academy of Sciences(xbzg-zdsys-202217)。
文摘Characterization of transport pathways and depositional changes in Mercury(Hg)and their connection to climatic and environmental changes on various time scales are crucial for better understanding the anthropogenic impacts on the global Hg cycle in the Anthropocene epoch.In this study,we examined Hg variations recorded in a stalagmite from central China,covering the period from 25.5 to 10.9 thousand years ago.Our data show a marked increase in Hg concentrations during the late Last Glacial Maximum,which coincided with the period of highest dust deposition on the Chinese Loess Plateau.Hg concentrations were lower during Heinrich events 1 and 2 and the Younger Dryas but higher during the BùllingAllerùd and the early Holocene.We suggest that regional dust load,which enhances atmospheric dry deposition of Hg,is the primary factor influencing Hg deposition in central China on glacialinterglacial timescales.On millennial-to-centennial timescales,climate also plays a significant role.Warmer and wetter conditions increase vegetation,litterfall,and soil/rock weathering,which in turn boost mineral dissolution and soil erosion in the vadose zone.These processes collectively result in higher Hg concentrations in the stalagmite.
基金supported by the“Strategic Priority Research Program”of the Chinese Academy of Sciences(XDB26000000)the National Natural Science Foundation of China(No.42572166,41420104008)+3 种基金Open Fund of the State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS(SKLLQG1629,SKLLQG1708)Breeding programs of State Key Laboratory of Loess and Quaternary Geology(SKLLQGPY1804)the“The Second Tibetan Plateau Scientific Expedition and Research”a part of the“Belt&Road”project of IEECAS。
文摘Reconstruction of the paleoaltitude history of the Tibetan Plateau is critical for understanding the linkage between tectonics and its effect on regional and global climate change.Presently,most of the paleoaltitude studies are concentrated on the southern and southeastern part of the Tibetan Plateau,and few studies have been conducted in the central-northern part.In this paper we focused on the Wudaoliang Formation in the Tuotuohe Basin,central to northern Tibetan Plateau,to reconstruct paleoaltitude based on carbonate oxygen isotopes.The carbonate samples are primary or have experienced an early stage of digenesis.Based on the thermodynamic and empirical model results,the paleoaltitude of the Wudaoliang Formation is found to be around 2700–3260 m(average of 2980±280 m)in the early Miocene(~24 Ma).Integrating paleoaltitude results from Wudaoliang Basin and our results,we conclude that crustal shortening and tectonic activity were strong during the late Eocene to late Oligocene-early Miocene and relatively weak during the early Miocene in the central-northern Tibetan Plateau.
基金financially supported by the Key Research and Development Program of Shaanxi Province(2018-ZDXM3-01)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB40000000)+3 种基金the Sino-Swiss Cooperation on Air Pollution for Better Air(7F-09802.01.02)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(2019402)the Sino-Swiss Science and Technology Cooperation(SSSTC)project HAZECHINA(IZLCZ2_169986)the SDC Clean-Air-China Program(7F-09802.01.03)。
文摘Intensive measurements were conducted in Xi’an,China before and during a COVID-19 lockdown period to investigate how changes in anthropogenic emissions affected the optical properties and radiative effects of brown carbon(BrC)aerosol.The contribution of BrC to total aerosol light absorption during the lockdown(13%-49%)was higher compared with the normal period(4%-29%).Mass absorption cross-sections(MACs)of specific organic aerosol(OA)factors were calculated from a ridge regression model.Of the primary OA(POA),coal combustion OA(CCOA)had the largest MACs at all tested wave-lengths during both periods due to high molecular-weight BrC chromophores;that was followed by biomass burning OA(BBOA)and hydrocarbon-like OA(HOA).For secondary OA(SOA),the MACs of the lessoxidized oxygenated OA(OOA)species(LO-OOA)atλ=370-590 nm were higher than those of more-oxidized OOA(MO-OOA)during both periods,presumably due to chromophore bleaching.The largest contributor to BrC absorption at the short wavelengths was CCOA during both periods,but BrC absorption by LO-OOA and MO-OOA became dominant at longer wavelengths during the lockdown.The estimated radiation forcing efficiency of BrC over 370-600 nm increased from 37.5 W·gduring the normal period to 50.2 W·gduring the lockdown,and that enhancement was mainly caused by higher MACs for both LO-OOA and MO-OOA.This study provides insights into the optical properties and radiative effects of source-specific BrC aerosol when pollution emissions are reduced.
基金supported by the National Key R&D Program of China(No.2022YFF0802501)the Key Research and Development Program of Shaanxi Province(No.2018-ZDXM3-01)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2019402)。
文摘In this study,online water-soluble inorganic ions were detected to deduce the formation mechanism of secondary inorganic aerosol in Xianyang,China during wintertime.The dominant inorganic ions of sulfate(SO_(4)^(2-)),nitrate(NO_(3)^(-)),and ammonium(NH_(4)^(+))(the sum of those is abbreviated as SNA)accounted for 17%,21%,and 12% of PM_(2.5)mass,respectively.While the air quality deteriorated from excellent to poor grades,the precursor gas sulfur dioxide(SO_(2))of SO_(4)^(2-)increased and then decreased with a fluctuation,while nitrogen dioxide(NO_(2))and ammonia(NH_(3)),precursors of NO_(3)^(-)and NH_(4)^(+),and SNA show increasing trends.Meteorological factors including boundary layer height(BLH),temperature,and wind speed also show decline trends,except relative humidity(RH).Meanwhile,the secondary conversion ratio shows a remarkable increasing trend,indicating that there was a strong secondary transformation.From the perspective of chemical mechanisms,RH is positively correlated with sulfur oxidation ratios(SOR),nitrogen oxidation ratios(NOR),and ammonia conversion ratios,representing that the increase of humidity could promote the generation of SNA.Notably,SOR and NOR were also positively related to the ammonia.On the one hand,the low wind speed and BLH led to the accumulation of pollutants.On the other hand,the increases of RH and ammonia promoted more formations of SNA and PM_(2.5).The results advance our identification of the contributors to the haze episodes and assist to establish more efficient emission controls in Xianyang,in addition to other cities with similar emission and geographical characteristics.
基金supported by the National Natural Science Foundation of China(42221003,4202530442103084)the Research Projects from the Chinese Academy of Sciences(XDB40000000)+1 种基金the Science and Technology Innovation Project of Laoshan Laboratory(LSKJ202203300)the CAS Youth Interdisciplinary Team。
文摘A"once-in-a-millennium"super rainstorm battered Zhengzhou,central China,from 07/17/2021 to 07/22/2021(named"7.20"Zhengzhou rainstorm).It killed 398 people and caused billions of dollars in damage.A pressing question is whether rainstorms of this intensity can be effectively documented by geological archives to understand better their historical variabilities beyond the range of meteorological data.Here,four land snail shells were collected from Zhengzhou,and weekly to daily resolved snail shellδ^(18)O records from June to September of 2021 were obtained by gas-source mass spectrometry and secondary ion mass spectrometry.The daily resolved records show a dramatic negative shift between 06/18/2021 and 09/18/2021,which has been attributed to the"7.20"Zhengzhou rainstorm.Moreover,the measured amplitude of this shift is consistent with the theoretical value estimated from the flux balance model and instrumental data for the"7.20"Zhengzhou rainstorm.Our results suggest that the ultra-high resolutionδ^(18)O of land snail shells have the potential to reconstruct local synoptic scale rainstorms quantitatively,and thus fossil snail shells in sedimentary strata can be valuable material for investigating the historical variability of local rainstorms under different climate backgrounds.
基金supported by the Western Light-Key Laboratory Cooperative Research Cross-Team Project of Chinese Academy of Sciences(xbzg-zdsys-202309)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB40020502)the Shaanxi Science Fund for Distinguished Young Scholars(2020JC-030).
文摘Covered by erodible loess and affected by significant seasonal climate variations,chemical weathering in the Chinese Loess Plateau(abbreviated as CLP)has important effects on the hydrochemistry of the Yellow River and the global carbon cycle.However,chemical weathering processes in the CLP are still unclear.Based on 296 river water samples in the CLP in the different seasons,hydrochemistry,weathering processes,and their controlling factors were revealed.River waters in the CLP exhibited slightly alkalinity(pH=8.4±0.5)with much high total dissolved solids(TDS)values(691±813 mg/L).The water types of river water in the CLP were primarily SO_(4)^(2-)-Cl^(-)-Na^(+),HCO_(3)^(-)-Ca^(2+)-Mg^(2+),and SO_(4)^(2-)-Cl^(-)-Ca^(2+)-Mg^(2+).According to the forward model,evaporite dissolution has the largest contribution(55.1%±0.2%)to riverine solutes in the CLP,then followed by carbonate weathering(35.6%±0.2%)and silicate weathering(6.5%±0.1%).For spatio-temporal variations,the contribution of evaporite dissolution in the CLP decreased from northwest to southeast with higher proportion in the dry season,carbonate weathering increased from northwest to southeast with a higher proportion in the wet season,and silicate weathering showed minor spatio-temporal variations.Ca^(2+)and Mg^(2+)were affected by carbonate precipitation and/or incongruent calcite dissolution,and about 50%of samples exhibited cation exchange reactions.The physical erosion rate in the CLP,which was 372±293 t·km^(-2)·yr^(-1),varied greatly and was greater than those of other worldwide rivers.Chemical weathering rates in the CLP showed an increasing trend southward.During the wet season,high runoff led to the release of evaporite and carbonate from loess,while the interfacial reaction kinetic limited the increase of the silicate weathering rates.The CO_(2)consumption budget by carbonate weathering(6.1×10^(10)mol/yr)and silicate weathering(1.6×10^(10)mol/yr)in the CLP accounted for 0.29%and 0.08%of the global carbon cycle,respectively.Meanwhile,the weathering proportion by sulfuric acids was relatively high with a CO_(2)release flux of 6.5×10^(9)mol/yr.By compiling the data,we propose that the interfacial reaction kinetic and runoff control CO_(2)consumption rate by silicate and carbonate weathering,respectively.These results contribute to the understanding of modern weathering processes of loess in the CLP,thus helping to deduce the environmental and climatic evolution of the basin.
基金The Strategic Priority Research Program of the Chinese Academy of Sciences,No.XDB40000000National Natural Science Foundation of China,No.41630531State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS,No.SKLLQG2041。
文摘Droughts are the most frequent natural disaster in regions at the margins of the East Asian summer monsoon(EASM),which pose threats to agriculture,the economy,and human lives.However,the limitations of only approximately 60 years of meteorological observations hamper our understanding of the characteristics and mechanisms of local hydroclimate.Trees growing in the marginal region of the EASM are usually sensitive to moisture variations and have played important roles in past hydroclimatic reconstructions.Here,a 303-year tree-ring-width chronology of Pinus tabulaeformis from Mt.Lama,which is located in the junction of the Liaoning Province and Inner Mongolia,China,was used to reconstruct the May-August Palmer drought severity index(PDSI)in the marginal region of the EASM.The transfer function explains 48.0%(or 47.2%after adjusting for the loss of the degrees of freedom)of the variance over the calibration period from 1946 to 2012.A spatial correlation analysis demonstrates that our PDSI reconstruction can represent the drought variability on the northernmost margin of the EASM.The winter Asian polar vortex area index showed a delayed impact on the summer EASM precipitation in the following year.
基金supported by National Key Research and Development Program[grants number 2016YFC0201700].
文摘Owing to uneven environmental monitoring site distribution,there are significant spatial data gaps for concentrations of ambientfine particles with diameters≤2.5µm(PM_(2.5))obtained using traditional monitoring methods.Satellite products are an alternative data source for locations where monitoring sites are unavailable.The Moderate Resolution Imaging Spectroradiometer(MODIS)aerosol optical depth(AOD)product has been widely used in PM_(2.5) assessment for years;however,it has obvious data gaps in winter.Here,the Visible Infrared Imaging Radiometer Suite(VIIRS)AOD was applied to supplement MODIS AOD data to obtain a fused AOD dataset.A three-stage model consisting of a corrected AOD model,mixed effects model,and geographically weighted regression model was developed and used with meteorological and vegetation factors to estimate PM_(2.5).Results showed overall modelfitting by cross-validation(CV)with an R^(2) of 0.92,mean absolute error of 5.72μg/m^(3),and root mean square error of 7.15μg/m^(3).The combination of MODIS AOD and VIIRS AOD was a suitable method for enhancing AOD coverage.The CV R^(2) value of the three-stage model(0.92)was higher than that of the two-stage model(0.9).Hence,the three-stage model could achieve a betterfit in estimating PM_(2.5) on a regional scale.
基金supported by the National Natural Science Foundation of China (Grant No. 22341603)the Key Deployment Project of the Chinese Academy of Sciences (CAS) (Grant No. ZDBS-SSW-DQC003)+2 种基金the Sinoforeign Joint Research Unit Project of the Bureau of International Cooperation, CAS (Grant No. 132B61ZYLH20230013)the Natural Science Basic Research Program of Shaanxi (Grant No. 2024JC-YBQN-0308)the Open Fund Project of the State Key Laboratory of Loess and Quaternary Geology (Grant No. SKLLQG2306)。
文摘A key scientific approach to addressing the environmental radiation risks from Fukushima nuclear contaminated water(FNCW) discharge into the ocean is understanding and predicting the marine dispersion of radionuclides.The dispersion of radiocesium(CsF:134Cs,137Cs) from the Fukushima nuclear accident in the North Pacific and its marginal seas post-2011 was systematically summarized,focusing on pathways,vertical distribution changes,and transit times.Our research examined CsFdispersion through the Kuroshio Extension and denser central mode water(D-CMW) to the eastern North Pacific,as well as through subtropical mode water(STMW),lighter central mode water(L-CMW),and D-CMW to the subtropical western North Pacific,China Seas,and Sea of Japan.We considered broader implications of CsFdispersion in light of ongoing FNCW discharge.Given this prolonged liquid discharge and Kuroshio Extension’s barrier effect,it is crucial to emphasize the role of CMW besides STMW in transporting FNCW to the subtropical western North Pacific and its marginal seas.Future research should focus on the key mechanism and longitude range of CMW crossing the Kuroshio Extension.Since short-lived134Cs decays rapidly during the storage and dispersion of FNCW,long-lived135Cs and135Cs/137Cs ratios can serve as valuable tracers for detecting and quantifying FNCW.Therefore,there is an urgent need for high-precision analysis of these key radionuclides and their characteristic ratios.To promptly detect,assess,and respond to FNCW intrusion,continuous monitoring and identification of nuclear pollution sources in key ocean currents and straits are critical.Furthermore,interdisciplinary research integrating monitoring with marginal sea circulation dynamics and high-resolution numerical simulations should be a priority.
基金supported by the National Key R&D Program of China(No.2022YFF0802501)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2022416)+1 种基金the Natural Science Basic Research Program of Shaanxi(No.2022JQ-267)the State Key Laboratory of Loess and Quaternary Geology(No.SKLLQG2335).
文摘The Northeast Plain in China ranks among the top five regions that have been significantly impacted by haze pollution.To effectively control pollution,it is crucial to accurately assess the effects of emission reduction measures.In this study,we analyzed surveillance data and found substantial decreases(ranging from 19.0%to 50.1%)in average annual mass concentrations of key pollutants(such as CO,SO_(2),NO_(2),and PM_(2.5))in the Northeast Plain from 2016 to 2020.To precisely determine the contributions of meteorological conditions and emission reductions to the improvement of air quality in the Northeast Plain,we conducted three scenario simulations.By comparing source emissions in December 2016 and 2020 using the WRF-Chem model(except for SO_(2)),we observed significant reductions of 21.3%,8.8%,and 9.8%in mass concentrations of PM_(2.5),NO_(2),and CO,respectively,from 2016 to 2020.This highlights the essential role that meteorological conditions play in determining air quality in the Northeast Plain.Moreover,further reducing source emissions by 30%in December 2016 resulted in subsequent reductions of 25.3%,29.0%,4.5%,and 30.3%in mass concentrations of PM_(2.5),SO_(2),NO_(2),and CO,respectively,under the same meteorological conditions.Notably,source emission reduction was effective for PM_(2.5),SO_(2),and CO,but not for NO_(2).The improvement in air quality in the Northeast Plain from 2016 to 2020 can be attributed to the combined effects of improved meteorological conditions and reduced pollution sources.
