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新型Ni-Cr-Co基高温合金在模拟煤燃烧环境中的高温腐蚀 被引量:15
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作者 赵双群 谢锡善 G.D.Smith 《中国有色金属学报》 EI CAS CSCD 北大核心 2004年第3期340-345,共6页
利用XRD,SEM和EDS等实验技术研究了一种新的超级超临界锅炉过热器管材Ni Cr Co基高温合金在模拟煤燃烧环境中的高温腐蚀行为。合金在700℃遭受的腐蚀过程分为2个阶段。在初始阶段,合金发生了氧化和硫化腐蚀,表面形成了保护性的Cr2O3膜,... 利用XRD,SEM和EDS等实验技术研究了一种新的超级超临界锅炉过热器管材Ni Cr Co基高温合金在模拟煤燃烧环境中的高温腐蚀行为。合金在700℃遭受的腐蚀过程分为2个阶段。在初始阶段,合金发生了氧化和硫化腐蚀,表面形成了保护性的Cr2O3膜,同时出现了内硫化现象。在加速腐蚀阶段,因CoSO4熔盐在合金表面的稳定存在使合金遭受严重的低温热腐蚀。当处于较高的SO3分压时,钴或氧化钴在合金表面熔盐中的溶解是造成合金抗腐蚀性能退化的原因。 展开更多
关键词 NI-CR-CO 高温合金 高温腐蚀 低温热腐蚀 合成煤灰/烟气 超级超临界锅炉 过热器
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粉煤燃烧环境中过热器管材的高温腐蚀 被引量:22
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作者 赵双群 谢锡善 Gaylord D Smith 《特殊钢》 北大核心 2003年第6期36-39,共4页
在分析粉煤燃烧环境对燃煤电厂锅炉蒸汽发生器的过热器 再热器腐蚀的影响的基础上 ,讨论了不锈钢和耐蚀合金在实验室模拟煤灰 烟气腐蚀试验及在锅炉燃煤环境中暴露后的耐蚀性 ,得出过热器 再热器管材用合金中的铬含量应在 2 5 %以上 。
关键词 过热器 再热器 煤灰 烟气 耐蚀合金 高温腐蚀 粉煤燃烧 燃煤电厂 锅炉
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新型镍基高温合金在模拟燃煤锅炉环境中的腐蚀 被引量:28
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作者 赵双群 谢锡善 Gaylord D.Smith 《金属学报》 SCIE EI CAS CSCD 北大核心 2004年第6期659-663,共5页
在人工合成的煤灰/烟气环境中研究了一种新型镍基高温合金550℃和700℃的腐蚀行为和腐蚀机理.结果表明,合金在550℃发生了不均匀的点蚀,表面形成了一层很薄的Cr_2O_3膜,腐蚀按照硫化机制发展.合金在700℃腐蚀时,初期发生了氧化和硫化腐... 在人工合成的煤灰/烟气环境中研究了一种新型镍基高温合金550℃和700℃的腐蚀行为和腐蚀机理.结果表明,合金在550℃发生了不均匀的点蚀,表面形成了一层很薄的Cr_2O_3膜,腐蚀按照硫化机制发展.合金在700℃腐蚀时,初期发生了氧化和硫化腐蚀,表面生成了保护性的氧化膜,并有内硫化物析出.由于合金表面生成CoO并在表面形成熔融态硫酸盐而逐渐进入加速腐蚀阶段,使合金遭受严重的低温热腐蚀.腐蚀产物外层为疏松的混合尖晶石化合物,内层为致密的氧化物层,在腐蚀层、腐蚀层与基体界面和Cr元素贫化区内分布着硫化物.合金耐腐蚀性能的迅速退化是合金表面Co及其氧化物在混合熔盐中的溶解所致. 展开更多
关键词 镍基高温合金 煤灰/烟气 低温热腐蚀 腐蚀机制
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INTRODUCTION TO INCONEL ALLOY 740: AN ALLOY DESIGNED FOR SUPERHEATER TUBING IN COAL-FIRED ULTRA SUPERCRITICAL BOILERS 被引量:19
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作者 S.J. Patel 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2005年第4期479-488,共10页
Chinese utilities as well as those worldwide are facing increased demand for additional electricity, reduced plant emissions and greater efficiency. To meet this challenge will require increasing boiler temperature, p... Chinese utilities as well as those worldwide are facing increased demand for additional electricity, reduced plant emissions and greater efficiency. To meet this challenge will require increasing boiler temperature, pressure and coal ash corrosion resistance of the materials of boiler construction of future coal-fired boilers. A new nickel-based tube alloy, INCONEL^R alloy 740, is described aiming at meeting this challenge. Emphasis will be on describing the alloy' s mechanical properties, coal-ash and steam corrosion resistance. Microstructural stability as a function of temperature and time is addressed as well as some of the early methodology em- ployed to arrive at the current chemical composition. 展开更多
关键词 ultrasupercritical BOILER tubing INCONEL coal-fired
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Nickel-base superalloys for USC power plants 被引量:1
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作者 John de BARBADILLO Brian BAKER 《Baosteel Technical Research》 CAS 2010年第S1期84-,共1页
The advanced ultra-supercritical power plants of the future will utilize steam pressures and temperatures that are too high for traditional ferritic steels,thus requiring austenitic materials.Older nickel-base superal... The advanced ultra-supercritical power plants of the future will utilize steam pressures and temperatures that are too high for traditional ferritic steels,thus requiring austenitic materials.Older nickel-base superalloys such as 263 and 617 were initially evaluated under the European THERMIE project beginning in the 1990s.An entirely new age-hardened alloy 740 which possesses exceptional fireside corrosion resistance and creep strength was also developed for boiler tubing capable of serving at 700C.Subsequently,interest in the USA considered other product forms such as steam header piping and steam turbine forgings for service as high as 760C.A more stable and weldable alloy version now called 740H was developed to meet these more demanding conditions.This paper summarizes the current status of work on alloys 740 and 740H. 展开更多
关键词 nickel-base alloys ultra-supercritical steam boiler creep-rupture WELDABILITY
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MICROSTRUCTURES AND THE STRUCTURE STABILITY OF INCONEL 725, A NEW AGE-HARDENABLE CORROSION RESISTANT SUPERALLOY
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作者 J.X.Dong M.C.Zhang S.K.Mannan 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2003年第2期145-150,共6页
INCONEL725 is a highly corrosion resistant nickel based alloy capable of being age-hardened to high strength levels. The micro structure observations and the phase identification after a standard heat treatment were i... INCONEL725 is a highly corrosion resistant nickel based alloy capable of being age-hardened to high strength levels. The micro structure observations and the phase identification after a standard heat treatment were investigated. The results show that the precipitation phases include the strengthening phasesγ', γ', and 8 phase, primary carbide phase TiC, as well as M6 C carbide and a little extent MC (mainly TiC) precipitates which nucleate mainly at grain boundaries. An isothermal aging study was carried out on this alloy for up to 10 000 hours at 593℃. This additional aging did not affect the tensile strength. However, micro structures show that the thermal exposure has a little additional effect. With increasing the exposure time, the size of γ' phase slightly increases, almost no change for γ' phase, while M6C carbides precipitated at grain boundaries have an increased and complex tendency on a few grain boundaries. The experimental results illustrate the excellent structure stability of the age-hardenable IN725 at 593℃. 展开更多
关键词 SUPERALLOY INCONEL725 micro structure long-term exposure
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