In the present work,the interaction mechanism of specific polyelectrolyte multilayers(PEMs),fabricated by layer-by-layer deposition of polydiallyldimethylammonium chloride(PDDA)and poly(sodium 4-styrenesulfonate)(PSS)...In the present work,the interaction mechanism of specific polyelectrolyte multilayers(PEMs),fabricated by layer-by-layer deposition of polydiallyldimethylammonium chloride(PDDA)and poly(sodium 4-styrenesulfonate)(PSS),is studied using atomic force microscopy.The underwater oil-repellency of PS S-capped PEMs was further explored by measuring the interaction forces between tetradecane droplets and PEMs-coated silica substrates under various salinities.The force curves were analyzed following the Stokes-Reynolds-Young-Laplace theoretical model.Desirable consistency was achieved between the experimental and theoretical calculations at low NaCl concentrations(0.1 mM and 1 mM);however,underestimation of the attractive force was found as the NaCl concentration increases to moderate(10 mM)and high(100 mM)levels.Discrepancy analyses and incorporated features toward a reduced surface charge density were considered based on the previous findings of the orientation of anionic benzenesulfonate moieties(Liu et al.in Angew Chem Int Ed 54(16):4851-4856,2015.https://doi.org/10.1002/anie.201411992).Short-range steric hindrance interactions were further introduced to simulate"brush"effect stemming from nanoscale surface roughness.It is demonstrated in our work that the PSS-capped PEMs remains a stable underwater lipophobicity against high salinity,which renders it potential application in surface wetting modification and anti-fouling.展开更多
To assess the influence of the initial temperature field on ocean temperature and sea ice simulations,a climatological dataset(WOA18),a real-time varying dataset(SODA),and an analysis field obtained after applying the...To assess the influence of the initial temperature field on ocean temperature and sea ice simulations,a climatological dataset(WOA18),a real-time varying dataset(SODA),and an analysis field obtained after applying the“vertical projection”assimilation scheme were selected to obtain the initial temperature field(the initial moment was December 1,2015)for use in the sea ice simulation of the HAMSOM ice-ocean coupled model,considering the Bohai Sea in the 2015/2016 winter.In this study,after using this assimilation scheme,the analysis initial temperature field showed significant improvement.The simulated SST results showed that the initial temperature field had a considerable effect on the SST results in the first 45 days of the model run;after this period,the effect became negligible and the model internal dynamics and atmospheric forcing became dominant.The simulated sea ice results showed that the ice area and ice edge distance(i.e.,the distance between the intersection of the central axis and the ice edge line and axis apex)results obtained in experiment E3 which used the analysis initial temperature field were improved by~14%and~35%,respectively,and those obtained in experiment E2 which used the real-time varying initial temperature field were improved by~10%and~22%,respectively,compared to the results of experiment E1 which used the climatological initial temperature field.展开更多
基金the National Natural Science Foundation of China(51774303,51422406,51534007)the National Science and Technology Specific Project(2016ZX05028-004001)111 Project(B18054)for providing support for this research。
文摘In the present work,the interaction mechanism of specific polyelectrolyte multilayers(PEMs),fabricated by layer-by-layer deposition of polydiallyldimethylammonium chloride(PDDA)and poly(sodium 4-styrenesulfonate)(PSS),is studied using atomic force microscopy.The underwater oil-repellency of PS S-capped PEMs was further explored by measuring the interaction forces between tetradecane droplets and PEMs-coated silica substrates under various salinities.The force curves were analyzed following the Stokes-Reynolds-Young-Laplace theoretical model.Desirable consistency was achieved between the experimental and theoretical calculations at low NaCl concentrations(0.1 mM and 1 mM);however,underestimation of the attractive force was found as the NaCl concentration increases to moderate(10 mM)and high(100 mM)levels.Discrepancy analyses and incorporated features toward a reduced surface charge density were considered based on the previous findings of the orientation of anionic benzenesulfonate moieties(Liu et al.in Angew Chem Int Ed 54(16):4851-4856,2015.https://doi.org/10.1002/anie.201411992).Short-range steric hindrance interactions were further introduced to simulate"brush"effect stemming from nanoscale surface roughness.It is demonstrated in our work that the PSS-capped PEMs remains a stable underwater lipophobicity against high salinity,which renders it potential application in surface wetting modification and anti-fouling.
基金This research was jointly sponsored by the National Key R&D Program of China(2019YFC 1407800)National Natural Science Foundation of China(No.42006154).
文摘To assess the influence of the initial temperature field on ocean temperature and sea ice simulations,a climatological dataset(WOA18),a real-time varying dataset(SODA),and an analysis field obtained after applying the“vertical projection”assimilation scheme were selected to obtain the initial temperature field(the initial moment was December 1,2015)for use in the sea ice simulation of the HAMSOM ice-ocean coupled model,considering the Bohai Sea in the 2015/2016 winter.In this study,after using this assimilation scheme,the analysis initial temperature field showed significant improvement.The simulated SST results showed that the initial temperature field had a considerable effect on the SST results in the first 45 days of the model run;after this period,the effect became negligible and the model internal dynamics and atmospheric forcing became dominant.The simulated sea ice results showed that the ice area and ice edge distance(i.e.,the distance between the intersection of the central axis and the ice edge line and axis apex)results obtained in experiment E3 which used the analysis initial temperature field were improved by~14%and~35%,respectively,and those obtained in experiment E2 which used the real-time varying initial temperature field were improved by~10%and~22%,respectively,compared to the results of experiment E1 which used the climatological initial temperature field.
