This work is a simulation model with the LAMMPS calculation code of an electrode based on alkali metal oxides (lithium, sodium and potassium) using the Lennard Jones potential. For a multiplicity of 8*8*8, we studied ...This work is a simulation model with the LAMMPS calculation code of an electrode based on alkali metal oxides (lithium, sodium and potassium) using the Lennard Jones potential. For a multiplicity of 8*8*8, we studied a gap-free model using molecular dynamics. Physical quantities such as volume and pressure of the Na-O and Li-O systems exhibit similar behaviors around the thermodynamic ensembles NPT and NVE. However, for the Na2O system, at a minimum temperature value, we observe a range of total energy values;in contrast, for the Li2O system, a minimum energy corresponds to a range of temperatures. Finally, for physicochemical properties, we studied the diffusion coefficient and activation energy of lithium and potassium oxides around their melting temperatures. The order of magnitude of the diffusion coefficients is given by the relation Dli-O >DNa-O for the multiplicity 8*8*8, while for the activation energy, the order is well reversed EaNa-O > EaLi-O.展开更多
The concrete mixed to sugarcane bagasse fibers and polypropylene fibers prepared with varied conditions were presented. The aim of our study is to formulate a concrete mixed with sugarcane bagasse fibers, which will g...The concrete mixed to sugarcane bagasse fibers and polypropylene fibers prepared with varied conditions were presented. The aim of our study is to formulate a concrete mixed with sugarcane bagasse fibers, which will gradually replace the conventional polypropylene fibers often used. We formulated all our concretes using the dreux gorisse method. We used an oven calibrated at 105˚C to dry the washed fibers. We also carried out tensile splitting and compression tests, at 28 and 112 days of age. The reinforcement mechanisms of sugarcane bagasse fibers and polypropylene fibers concretes were subjected to tensile splitting and compression tests after total immersion of the specimens in tap water at 28 and 112 days. Porosity at 28 days, mass loss and drying shrinkage at 80 days were also studied. The curing processes of concretes containing 0.10, 0.15, 0.17, 0.23 and 0.25% bagasse fibers were compared with those of ordinary concretes containing no fiber. The results showed that the addition of bagasse fibers reduces mechanical strength and porosity. In summary, specimens SBC-0.15 and SBC-0.17 showed the best results for all fibers. We plan to do the same work, but this time with raffia or palm nut fibers.展开更多
The depositional environment of the sands of the cover formation is discussed. This study aims to determine the paleoenvironments of deposition of the sands of the cover formation in the Batéké Plateaus by s...The depositional environment of the sands of the cover formation is discussed. This study aims to determine the paleoenvironments of deposition of the sands of the cover formation in the Batéké Plateaus by studying sedimentary dynamics based on the description of lithological facies in the field and granulometric analyses in the laboratory. In the field, six (6) lithostratigraphic logs were surveyed and 42 sand samples were taken for laboratory analysis. In the laboratory, the samples underwent granulometric, sieving and sedimentometry analyses, after washing with running water using a 63 µm sieve. These analyses made it possible to determine the granulometric classes of the samples. The sieving results allowed to determine the granulometric parameters (mean, standard deviation, mode, median, skewness, flattening or kurtosis) using the method of moments with the software “Gradistat V.8”, granulometric parameters with which the granulometric facies, the mode of transport and the deposition environment were determined using the diagrams. Morphoscopy made it possible to determine the form and aspect of the surface of the quartz grains constituting these sands. Granulometric analyses show that these silty-clay or clayey-silty sands are fine sands and rarely medium sands, moderately to well sorted and rarely well sorted. The dominant granulometric facies is hyperbolic (sigmoid), with parabolic facies being rare. The primary mode of transport of these sands is saltation, which dominates rolling. The dispersion of points in the diagrams shows that these sands originate from two depositional environments: aeolian and fluvial. Morphoscopic analysis reveals the presence of clean rounded matt grains (RM), dirty rounded matt grains (RS), shiny blunt grains (EL) and shiny rounded grains (RL). The rounded matt grains exhibit several impact marks. The presence of dirty rounded grains with a ferruginous cement on their surface indicates that these sands have been reworked. These sands have undergone two types of transport, first by wind (aeolian environment) and then by water (fluvial environment).展开更多
This study aims to characterize from a geotechnical point of view, the soils as well as the lateritic gravels along the Songololo-Lufu road route in the Kongo Central Province in the Democratic Republic of Congo (DRC)...This study aims to characterize from a geotechnical point of view, the soils as well as the lateritic gravels along the Songololo-Lufu road route in the Kongo Central Province in the Democratic Republic of Congo (DRC). Ten soil samples and eight lateritic gravel samples were analysed and tested in the laboratory. For each sample, identification parameters were determined such as particle size analysis, natural water content, Atterberg limits (plasticity index and consistency index), but also compaction and lift parameters such as optimal water content, maximum dry density and CBR lift index. All materials and soils have been classified according to the Congolese Road Standard (NRC) and according to the American HRB classification. The test results show us that clay soils almost always contain between 70% and 90% fine fraction;the grained fraction represents less than 30% in clay samples. For lateritic gravels soils, the percentage of fine elements varies between 35% and 15%;in sand around 20%;the gravelly fraction represents a little more than 50% of the soil. The majority of soil facies encountered define a plasticity index lower than 15. As for the consistency index, we obtained values greater than 1, both for clayey soils and for gravelly soils. The classification according to NRC defined for these soils the types Ae1 and Ae2 for the clayey facies and the types GL1 and GL2 for the gravelly soils, while that of the HRB identified the classes and subclasses A-6 and A-7-6 for clayey soils, and subclass A-2-6 for gravelly soils. The optimal water content values obtained range between 10.2% and 23.10%;the maximum dry densities are between 1.66 and 2.07 t/m<sup>3</sup> and the CBR index is between 6 and 26. As for the lateritic gravels materials of the Songololo region, the percentage of fine elements generally remains between 12% and 31%;the plasticity index is between 8 and 18;the optimal dry density is around 2 t/m<sup>3</sup>;the optimal water content is between 9.8% and 14.5% and the CBR index is between 27 and 82. The Songololo-Lufu lateritic gravels are characteristic of laterites in the savannah region, with a high gravel fraction at the expense of the fine fraction, but low parameters such as the liquid limit and plasticity index.展开更多
This work is the subject of the biostratigraphic and palaeoenvironmental study of the North Deep Sea area of the Congolese Miocene Atlantic Basin. This study is made from samples of lateral cores, drill cuttings and e...This work is the subject of the biostratigraphic and palaeoenvironmental study of the North Deep Sea area of the Congolese Miocene Atlantic Basin. This study is made from samples of lateral cores, drill cuttings and electrical logs. Lithology generally exhibits an irregular alternation of weakly indurated grey clay, light grey siltstones, and whitish, quartzitic sand, medium to coarse-grained, sub-angular to rounded. The presence of glaucony indicates that sediments have been deposited in a calm and reducing environment. The entire formation is fossiliferous. Micropaleontological analysis revealed 120 species of foraminifera including 98 planktonic (81.67%) and 22 benthic (18.33%) species used for biozonation, dating and interpretation of palaeoenvironments. Similarly, the bio-events of plankton foraminiferal, characterized by the level of the first appearance of certain species, have made it possible to identify fifteen biozones (<i>Globorotalia plesiotumida</i>,<i> Globorotalia merotumida</i>,<i> Globorotalia acostaensis</i>,<i> Globorotalia menardii</i>,<i> Globigerina nepenthes</i>,<i> Globorotalia siakensis</i>,<i> Globorotalia fohsi</i>,<i> Globorotalia praefohsi, Globorotalia peripheroacuta</i>,<i> Globorotalia peripheroronda</i>,<i> Praeorbulina sicana</i>,<i> Catapsydrax dissimilis</i>,<i> Globigerinatella insueta, Paragloborotalia kugleri </i>and<i> Globorotalia kugleri</i>) corresponding to age between Aquitanian and Lower Pliocene. Biofacies analysis of foraminifera has identified palaeoenvironments that vary from open marine environments, bathyal to abyssal. <p> <br /> </p>展开更多
Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has rem...Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has remained a witness to a stable zone not affected by the ancient erosion process. BIFs are most abundant and are dated to the Neoarchaean and Late Kibalian, hosted in the Upper Congo Granites Massifs of the DR. Congo. Zatua Hills consist of dolerite, phyllade, clay-rich sediment, poor itabirite, enriched BIFs, friable hematite, hard hematite, and mineralized and unmineralized breccias. Field study and geochemistry analysis by XRF, XRD, and ICP-MS are executed in order to know the geochemistry signature and paragenesis of Zatua Hills and the probably process could lead the BIFs to iron ore. The geochemistry analysis by XRF, XRD, and ICP-MS shows that Iron ore content has an iron rate between 57% and 69% with less deleterious elements such as Si, P, and Al. These deleterious elements are secondary and have silicium composition (probably quartz or chert, goethite, and Kaolinite), aluminum (probably gibbsite, variscite, cadwaladérite, goethite, and Kaolinite), phosphorous (probably variscite), and hydrated minerals, which are grown LOI in the samples. Hypogen and supergen processes are played in BIFs for iron ore conversion and, respectively, silica dissolution and leaching. Metamorphism was also impacted and marked by the Ti element (anatase) in samples, contributing to the crystallization of martite to hematite after magnetite oxidation.展开更多
Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area...Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area is identified by the high elevated zone which is remained the witness of stable zone, not affected by the ancienst erosion process. Zatua Hills are in the superior Kibalian formation dated to Neoarchaen, hosted in Upper Congo Granites Massifs of DRC covering a large central zone of NE of DRC, and consisting to dolerite, phyllade, clay rich sediment, poor Banded Iron Formations (BIFs), enriched BIFs, friable hematite, hard hematite, mineralized and unmineralized brechias. Magnetite, martite and hematite are associated to some secondary minerals such as goethite, gibbsite, kaolinite, strengite, variscite and others clay minerals present in BIFs. Petrographic analysis made from the samples collected in situ showed, as well as BIFs and iron ore associated, that magnetite was much abundant oxide mineral which is oxided to martite before to stabilize to hematite during the deposition time. Having about hundred meters of thickness, the rich iron ore of this area content, in the majority less deleterious elements which, are harmful in metallurgic process of iron. These secondary minerals were precipitated at various degrees in the leached cavities of rocks between martite and hematite aggregates to botryoidal texture and, are rich to Al, and are mainly consisting to gibbsite and solid solution series of variscite-strengite (AlPO<sub>4</sub>·2H<sub>2</sub>O and FePO<sub>4</sub>·2H<sub>2</sub>O). Low degree of metamorphism played when magnetite was converted to martite, with the presence of variscite and anatase like witnesses of this event in which, martite was crystalized to hematite.展开更多
A granulometric, mineralogical, morphoscopic and exoscopic study and Rock-Eval analysis carried out on samples taken in the Loango Bay and at Kivesso on the Congolese coast have made it possible to highlight the highl...A granulometric, mineralogical, morphoscopic and exoscopic study and Rock-Eval analysis carried out on samples taken in the Loango Bay and at Kivesso on the Congolese coast have made it possible to highlight the highly erosive character of the well-documented wet phases ca 9000 - 3000 years B.P. and ca 320 B.P. in the sub-region. Supported by carbon-14 dating, total organic carbon analyses highlight two major phases of peat deposit emplacement. The first, ca. 7000 years B.P., corresponds to the beginning of the deposition of the yellow formation in the entire Loango Bay;the second, ca. 320 years B.P., is contemporary with the deposition of peat in the Kivesso sector. The granulometric analysis of the sediments shows that they are essentially sandy-clay and very poor in silt, alternating with beds of silty clay sometimes rich in organic matter. These sands have a predominant mode of 0.200 mm and an average varying between 0.150 and 0.300 mm. They constitute the flood phase of the carrier current. They are associated with a population of mode 0.125 mm sometimes 0.050 mm with an average varying between 0.100 mm and 0.126 mm which corresponds to the settling phase. Morphoscopic examination showed several varieties of quartz that argue for a source of supply close to the depositional sites.展开更多
In this work, samples of titanium dental implants in salivary environment in the presence of certain foods were studied. 24 samples were prepared and subjected to the reactivity of certain foods for 6, 5, 6 and 7 week...In this work, samples of titanium dental implants in salivary environment in the presence of certain foods were studied. 24 samples were prepared and subjected to the reactivity of certain foods for 6, 5, 6 and 7 weeks. The ICP-MS technique was used to analyze the prepared samples. The results obtained showed no corrosion of the titanium alone in an artificial salivary medium. Significant corrosion was observed in the presence of food, which is manifested by the presence of traces of titanium in the samples.展开更多
文摘This work is a simulation model with the LAMMPS calculation code of an electrode based on alkali metal oxides (lithium, sodium and potassium) using the Lennard Jones potential. For a multiplicity of 8*8*8, we studied a gap-free model using molecular dynamics. Physical quantities such as volume and pressure of the Na-O and Li-O systems exhibit similar behaviors around the thermodynamic ensembles NPT and NVE. However, for the Na2O system, at a minimum temperature value, we observe a range of total energy values;in contrast, for the Li2O system, a minimum energy corresponds to a range of temperatures. Finally, for physicochemical properties, we studied the diffusion coefficient and activation energy of lithium and potassium oxides around their melting temperatures. The order of magnitude of the diffusion coefficients is given by the relation Dli-O >DNa-O for the multiplicity 8*8*8, while for the activation energy, the order is well reversed EaNa-O > EaLi-O.
文摘The concrete mixed to sugarcane bagasse fibers and polypropylene fibers prepared with varied conditions were presented. The aim of our study is to formulate a concrete mixed with sugarcane bagasse fibers, which will gradually replace the conventional polypropylene fibers often used. We formulated all our concretes using the dreux gorisse method. We used an oven calibrated at 105˚C to dry the washed fibers. We also carried out tensile splitting and compression tests, at 28 and 112 days of age. The reinforcement mechanisms of sugarcane bagasse fibers and polypropylene fibers concretes were subjected to tensile splitting and compression tests after total immersion of the specimens in tap water at 28 and 112 days. Porosity at 28 days, mass loss and drying shrinkage at 80 days were also studied. The curing processes of concretes containing 0.10, 0.15, 0.17, 0.23 and 0.25% bagasse fibers were compared with those of ordinary concretes containing no fiber. The results showed that the addition of bagasse fibers reduces mechanical strength and porosity. In summary, specimens SBC-0.15 and SBC-0.17 showed the best results for all fibers. We plan to do the same work, but this time with raffia or palm nut fibers.
文摘The depositional environment of the sands of the cover formation is discussed. This study aims to determine the paleoenvironments of deposition of the sands of the cover formation in the Batéké Plateaus by studying sedimentary dynamics based on the description of lithological facies in the field and granulometric analyses in the laboratory. In the field, six (6) lithostratigraphic logs were surveyed and 42 sand samples were taken for laboratory analysis. In the laboratory, the samples underwent granulometric, sieving and sedimentometry analyses, after washing with running water using a 63 µm sieve. These analyses made it possible to determine the granulometric classes of the samples. The sieving results allowed to determine the granulometric parameters (mean, standard deviation, mode, median, skewness, flattening or kurtosis) using the method of moments with the software “Gradistat V.8”, granulometric parameters with which the granulometric facies, the mode of transport and the deposition environment were determined using the diagrams. Morphoscopy made it possible to determine the form and aspect of the surface of the quartz grains constituting these sands. Granulometric analyses show that these silty-clay or clayey-silty sands are fine sands and rarely medium sands, moderately to well sorted and rarely well sorted. The dominant granulometric facies is hyperbolic (sigmoid), with parabolic facies being rare. The primary mode of transport of these sands is saltation, which dominates rolling. The dispersion of points in the diagrams shows that these sands originate from two depositional environments: aeolian and fluvial. Morphoscopic analysis reveals the presence of clean rounded matt grains (RM), dirty rounded matt grains (RS), shiny blunt grains (EL) and shiny rounded grains (RL). The rounded matt grains exhibit several impact marks. The presence of dirty rounded grains with a ferruginous cement on their surface indicates that these sands have been reworked. These sands have undergone two types of transport, first by wind (aeolian environment) and then by water (fluvial environment).
文摘This study aims to characterize from a geotechnical point of view, the soils as well as the lateritic gravels along the Songololo-Lufu road route in the Kongo Central Province in the Democratic Republic of Congo (DRC). Ten soil samples and eight lateritic gravel samples were analysed and tested in the laboratory. For each sample, identification parameters were determined such as particle size analysis, natural water content, Atterberg limits (plasticity index and consistency index), but also compaction and lift parameters such as optimal water content, maximum dry density and CBR lift index. All materials and soils have been classified according to the Congolese Road Standard (NRC) and according to the American HRB classification. The test results show us that clay soils almost always contain between 70% and 90% fine fraction;the grained fraction represents less than 30% in clay samples. For lateritic gravels soils, the percentage of fine elements varies between 35% and 15%;in sand around 20%;the gravelly fraction represents a little more than 50% of the soil. The majority of soil facies encountered define a plasticity index lower than 15. As for the consistency index, we obtained values greater than 1, both for clayey soils and for gravelly soils. The classification according to NRC defined for these soils the types Ae1 and Ae2 for the clayey facies and the types GL1 and GL2 for the gravelly soils, while that of the HRB identified the classes and subclasses A-6 and A-7-6 for clayey soils, and subclass A-2-6 for gravelly soils. The optimal water content values obtained range between 10.2% and 23.10%;the maximum dry densities are between 1.66 and 2.07 t/m<sup>3</sup> and the CBR index is between 6 and 26. As for the lateritic gravels materials of the Songololo region, the percentage of fine elements generally remains between 12% and 31%;the plasticity index is between 8 and 18;the optimal dry density is around 2 t/m<sup>3</sup>;the optimal water content is between 9.8% and 14.5% and the CBR index is between 27 and 82. The Songololo-Lufu lateritic gravels are characteristic of laterites in the savannah region, with a high gravel fraction at the expense of the fine fraction, but low parameters such as the liquid limit and plasticity index.
文摘This work is the subject of the biostratigraphic and palaeoenvironmental study of the North Deep Sea area of the Congolese Miocene Atlantic Basin. This study is made from samples of lateral cores, drill cuttings and electrical logs. Lithology generally exhibits an irregular alternation of weakly indurated grey clay, light grey siltstones, and whitish, quartzitic sand, medium to coarse-grained, sub-angular to rounded. The presence of glaucony indicates that sediments have been deposited in a calm and reducing environment. The entire formation is fossiliferous. Micropaleontological analysis revealed 120 species of foraminifera including 98 planktonic (81.67%) and 22 benthic (18.33%) species used for biozonation, dating and interpretation of palaeoenvironments. Similarly, the bio-events of plankton foraminiferal, characterized by the level of the first appearance of certain species, have made it possible to identify fifteen biozones (<i>Globorotalia plesiotumida</i>,<i> Globorotalia merotumida</i>,<i> Globorotalia acostaensis</i>,<i> Globorotalia menardii</i>,<i> Globigerina nepenthes</i>,<i> Globorotalia siakensis</i>,<i> Globorotalia fohsi</i>,<i> Globorotalia praefohsi, Globorotalia peripheroacuta</i>,<i> Globorotalia peripheroronda</i>,<i> Praeorbulina sicana</i>,<i> Catapsydrax dissimilis</i>,<i> Globigerinatella insueta, Paragloborotalia kugleri </i>and<i> Globorotalia kugleri</i>) corresponding to age between Aquitanian and Lower Pliocene. Biofacies analysis of foraminifera has identified palaeoenvironments that vary from open marine environments, bathyal to abyssal. <p> <br /> </p>
文摘Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has remained a witness to a stable zone not affected by the ancient erosion process. BIFs are most abundant and are dated to the Neoarchaean and Late Kibalian, hosted in the Upper Congo Granites Massifs of the DR. Congo. Zatua Hills consist of dolerite, phyllade, clay-rich sediment, poor itabirite, enriched BIFs, friable hematite, hard hematite, and mineralized and unmineralized breccias. Field study and geochemistry analysis by XRF, XRD, and ICP-MS are executed in order to know the geochemistry signature and paragenesis of Zatua Hills and the probably process could lead the BIFs to iron ore. The geochemistry analysis by XRF, XRD, and ICP-MS shows that Iron ore content has an iron rate between 57% and 69% with less deleterious elements such as Si, P, and Al. These deleterious elements are secondary and have silicium composition (probably quartz or chert, goethite, and Kaolinite), aluminum (probably gibbsite, variscite, cadwaladérite, goethite, and Kaolinite), phosphorous (probably variscite), and hydrated minerals, which are grown LOI in the samples. Hypogen and supergen processes are played in BIFs for iron ore conversion and, respectively, silica dissolution and leaching. Metamorphism was also impacted and marked by the Ti element (anatase) in samples, contributing to the crystallization of martite to hematite after magnetite oxidation.
文摘Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area is identified by the high elevated zone which is remained the witness of stable zone, not affected by the ancienst erosion process. Zatua Hills are in the superior Kibalian formation dated to Neoarchaen, hosted in Upper Congo Granites Massifs of DRC covering a large central zone of NE of DRC, and consisting to dolerite, phyllade, clay rich sediment, poor Banded Iron Formations (BIFs), enriched BIFs, friable hematite, hard hematite, mineralized and unmineralized brechias. Magnetite, martite and hematite are associated to some secondary minerals such as goethite, gibbsite, kaolinite, strengite, variscite and others clay minerals present in BIFs. Petrographic analysis made from the samples collected in situ showed, as well as BIFs and iron ore associated, that magnetite was much abundant oxide mineral which is oxided to martite before to stabilize to hematite during the deposition time. Having about hundred meters of thickness, the rich iron ore of this area content, in the majority less deleterious elements which, are harmful in metallurgic process of iron. These secondary minerals were precipitated at various degrees in the leached cavities of rocks between martite and hematite aggregates to botryoidal texture and, are rich to Al, and are mainly consisting to gibbsite and solid solution series of variscite-strengite (AlPO<sub>4</sub>·2H<sub>2</sub>O and FePO<sub>4</sub>·2H<sub>2</sub>O). Low degree of metamorphism played when magnetite was converted to martite, with the presence of variscite and anatase like witnesses of this event in which, martite was crystalized to hematite.
文摘A granulometric, mineralogical, morphoscopic and exoscopic study and Rock-Eval analysis carried out on samples taken in the Loango Bay and at Kivesso on the Congolese coast have made it possible to highlight the highly erosive character of the well-documented wet phases ca 9000 - 3000 years B.P. and ca 320 B.P. in the sub-region. Supported by carbon-14 dating, total organic carbon analyses highlight two major phases of peat deposit emplacement. The first, ca. 7000 years B.P., corresponds to the beginning of the deposition of the yellow formation in the entire Loango Bay;the second, ca. 320 years B.P., is contemporary with the deposition of peat in the Kivesso sector. The granulometric analysis of the sediments shows that they are essentially sandy-clay and very poor in silt, alternating with beds of silty clay sometimes rich in organic matter. These sands have a predominant mode of 0.200 mm and an average varying between 0.150 and 0.300 mm. They constitute the flood phase of the carrier current. They are associated with a population of mode 0.125 mm sometimes 0.050 mm with an average varying between 0.100 mm and 0.126 mm which corresponds to the settling phase. Morphoscopic examination showed several varieties of quartz that argue for a source of supply close to the depositional sites.
文摘In this work, samples of titanium dental implants in salivary environment in the presence of certain foods were studied. 24 samples were prepared and subjected to the reactivity of certain foods for 6, 5, 6 and 7 weeks. The ICP-MS technique was used to analyze the prepared samples. The results obtained showed no corrosion of the titanium alone in an artificial salivary medium. Significant corrosion was observed in the presence of food, which is manifested by the presence of traces of titanium in the samples.
