The molar extinction coefficients at the absorption maximum of the solvated electron spectrum have been evaluated to be 900,970,and 1000 mol^(-1).m^2 for 1,2-ethanediol (12ED),1,2-propanediol (12PD),and 1,3-propanedio...The molar extinction coefficients at the absorption maximum of the solvated electron spectrum have been evaluated to be 900,970,and 1000 mol^(-1).m^2 for 1,2-ethanediol (12ED),1,2-propanediol (12PD),and 1,3-propanediol (13PD),respectively.These values are two-third or three-fourth of the value usually reported in the published report. Picosecond pulse radiolysis studies have aided in depicting the radiolytic yield of the solvated electron in these sol- vents as a function of time from picosecond to microsecond.The radiolytic yield in these viscous solvents is found to be strongly different from that of the water solution.The temperature dependent absorption spectra of the solvated electron in 12ED,12PD,and 13PD have been also investigated.In all the three solvents,the optical spectra shift to the red with increasing temperature.While the shape of the spectra does not change in 13PD,a widening on the blue side of the absorption band is observed in 12ED and 12PD at elevated temperatures.展开更多
This paper investigates long-term energy strategy compatible with significant reduction of world carbon dioxide （CO2） emissions, employing a long-term global energy model, Dynamic New Earth 21 （called DNE21）. The ...This paper investigates long-term energy strategy compatible with significant reduction of world carbon dioxide （CO2） emissions, employing a long-term global energy model, Dynamic New Earth 21 （called DNE21）. The model seeks the optimal energy mix from 2000 to 2100 that minimizes the world total energy system cost under various kinds of energy and technological constraints, such as energy resource constraints, energy supply and demand balance constraints, and CO2 emissions constraints. This paper discusses the results of primary energy supply, power generation mix, CO2 emission, CCS （carbon capture and storage） and total system costs for six regions including world as a whole. To evaluate viable pathways forward for implementation of sustainable energy strategies, nuclear power generation is a viable source of clean and green energy to mitigate the CO2 emissions. Present research shows simulation results in two cases consisting of no CO2 regulation case （base case） and CO2 REG case （regulation case） which halves the world CO2 emissions by the year 2050. Main findings of this research describe that renewable and nuclear power generation will contribute significantly to mitigate the CO2 emission worldwide.展开更多
During the decommissioning of the Fukushima Daiichi nuclear power plant,it is important to consider the retrieval of resolidified debris both in air and underwater configurations.For the subsequent retrieval of debris...During the decommissioning of the Fukushima Daiichi nuclear power plant,it is important to consider the retrieval of resolidified debris both in air and underwater configurations.For the subsequent retrieval of debris from the reactor building,the resolidified debris must be cut into smaller pieces using various cutting methods.During the cutting process,aerosol particles are expected to be generated at the submicron scale.It has been noted that such aerosols sizing within the Greenfield gap(0.1-1μm)are difficult to remove effectively using traditional spraying methods.Therefore,to improve the aerosol removal efficiency of the spray system,a new aerosol agglomeration method was recently proposed,which involves injecting water mist to enlarge the sizes of the aerosol particles before removing them using water sprays.In this study,a series of experiments were performed to clarify the proper spray configurations for effective aerosol scavenging and to improve the performance of the water mist.The experimental results showed that the spray flow rate and droplet characteristics are important factors for the aerosol-scavenging efficiency and performance of the water mist.The results obtained from this study will be helpful for the optimization of the spray system design for effective aerosol scavenging during the decommissioning of the Fukushima Daiichi plant.展开更多
The effects of annealing and irradiation on the evolution of Cu clusters in a-Fe are investigated using object kinetic Monte Carlo simulations.In our model,vacancies act as carriers for chemical species via thermally ...The effects of annealing and irradiation on the evolution of Cu clusters in a-Fe are investigated using object kinetic Monte Carlo simulations.In our model,vacancies act as carriers for chemical species via thermally activated diffusion jumps,thus playing an important role in solute diffusion.At the end of the Cu cluster evolution,the simulations of the average radius and number density of the clusters are consistent with the experimental data,which indicates that the proposed simulation model is applicable and effective.For the simulation of the annealing process,it is found that the evolution of the cluster size roughly follows the 1/2 time power law with the increase in radius during the growth phase and the 1/3 time power law during the coarsening phase.In addition,the main difference between neutron and ion irradiation is the growth and evolution process of the copper-vacancy clusters.The aggregation of vacancy clusters under ion irradiation suppresses the migration and coarsening of the clusters,which ultimately leads to a smaller average radius of the copper clusters.Our proposed simulation model can supplement experimental analyses and provide a detailed evolution mechanism of vacancy-enhanced precipitation,thereby providing a foundation for other elemental precipitation research.展开更多
This paper develops a high time-resolution optimal power generation mix model in its time resolution of 10 minutes on 365 days by linear programming technique. The model allows us to analyse the massive deployment of ...This paper develops a high time-resolution optimal power generation mix model in its time resolution of 10 minutes on 365 days by linear programming technique. The model allows us to analyse the massive deployment of photovoltaic system and wind power generation in power system explicitly considering those short-term output variation. PV （photovoltaic） and wind output are estimated, employing meteorological database. Simulation results reveal that variable fluctuation derived from a high penetration level of those renewables is controlled by quick load following operation of natural gas combined cycle power plant, pumped-storage hydro power, stationary NAS （sodium and sulfur） battery and the output suppression control of PV and wind. It additionally turns out that the operational configuration of those technologies for the renewable variability differs significantly depending on those renewable output variations in each season and solving the seasonal electricity imbalance as well as the daily imbalance is important if variable renewables are massively deployed.展开更多
Attosecondattosecond science;extreme ultraviolet;high-order harmonic generation;Ramsey-type spectroscopy Optical and Ramsey-Type Interferometry by Postgeneration Splitting of Harmonic PulseTime domain Ramsey-type inte...Attosecondattosecond science;extreme ultraviolet;high-order harmonic generation;Ramsey-type spectroscopy Optical and Ramsey-Type Interferometry by Postgeneration Splitting of Harmonic PulseTime domain Ramsey-type interferometry is useful for investigating spectroscopic information of quantum states in atoms and molecules.The energy range of the quantum states to be observed with this scheme has now reached more than 20 eV by resolving the interference fringes with a period of a few hundred attoseconds.This attosecond Ramsey-type interferometry requires the irradiation of a coherent pair of extreme ultraviolet(XUV)light pulses,while all the methods used to deliver the coherent XUV pulse pair until now have relied on the division of the source of an XUV pulse in two before the generation.In this paper,we report on a novel technique to perform attosecond Ramsey-type interferometry by splitting an XUV high-order harmonic(HH)pulse of a sub-20 fs laser pulse after its generation.By virtue of the postgeneration splitting of the HH pulse,we demonstrated that the optical interference emerging at the complete temporal overlap of the HH pulse pair seamlessly continued to the Ramsey-type electronic interference in a helium atom.This technique is applicable for studying the femtosecond dephasing dynamics of electronic wavepackets and exploring the ultrafast evolution of a cationic system entangled with an ionized electron with sub-20 fs resolution.展开更多
Cr-coated zirconium alloy was prepared by pulsed laser deposition(PLD)for the application of accident-tolerant fuel cladding in light water reactors.The microstructural characteristics of the Cr coating and its evolut...Cr-coated zirconium alloy was prepared by pulsed laser deposition(PLD)for the application of accident-tolerant fuel cladding in light water reactors.The microstructural characteristics of the Cr coating and its evolution with temperature were investigated using grazing incidence X-ray diff raction and in situ heating transmission electron microscopy(TEM).Results show that the microstructure of the laser-deposited Cr coatings consists mainly of fine and non-specific shaped nano-crystals in the inner layer and columnar crystals in the outer layer.The recrystallization of the Cr-coating layer starts at 300–400℃ to release the high strain introduced by PLD,and the grain coalescence starts at temperatures>400°C.Upon annealing,the(110)-texture gradually intensifi es because of its high reticular density and low close-packed energy.Additionally,in situ heating TEM observation shows the presence of cavities on the Cr–Zr interface,which may result from the interdiff usion and/or the transformation from amorphous to crystalline.展开更多
In a severe accident of a nuclear power reactor,coolant channel blockage by solidified molten core debris may significantly influence the core degradations that follow.The moving particle semi-implicit(MPS)method is o...In a severe accident of a nuclear power reactor,coolant channel blockage by solidified molten core debris may significantly influence the core degradations that follow.The moving particle semi-implicit(MPS)method is one of the Lagrangian-based particle methods for analyzing incompressible flows.In the study described in this paper,a novel solidification model for analyzing melt flowing channel blockage with the MPS method has been developed,which is suitable to attain a sufficient numerical accuracy with a reasonable calculation cost.The prompt velocity diffusion by viscosity is prioritized over the prompt velocity correction by the pressure term(for assuring incompressibility)within each time step over the“mushy zone”(between the solidus and liquidus temperature)for accurate modeling of solidification before fixing the coordinates of the completely solidified particles.To sustain the numerical accuracy and stability,the corrective matrix and particle shifting techniques have been applied to correct the discretization errors from irregular particle arrangements and to recover the regular particle arrangements,respectively.To validate the newly developed algorithm,2-D benchmark analyses are conducted for steady-state freezing of the water in a laminar flow between two parallel plates.Furthermore,3-D channel blockage analyses of a boiling water reactor(BWR)fuel support piece have been performed.The results show that a partial channel blockage develops from the vicinity of the speed limiter,which does not fully develop into a complete channel blockage,but still diverts the incoming melt flow that follows to the orifice region.展开更多
To retrieve the fuel debris in Fukushima Daiichi Nuclear Power Plants(1F),it is essential to infer the fuel debris distribution.In particular,the molten metal spreading behavior is one of the vital phenomena in nuclea...To retrieve the fuel debris in Fukushima Daiichi Nuclear Power Plants(1F),it is essential to infer the fuel debris distribution.In particular,the molten metal spreading behavior is one of the vital phenomena in nuclear severe accidents because it determines the initial condition for further accident scenarios such as molten core concrete interaction(MCCI).In this study,the fundamental molten metal spreading experiments were performed with different outlet diameters and sample amounts to investigate the effect of the outlet for spreading-solidification behavior.In the numerical analysis,the moving particle full-implicit method(MPFI),which is one of the particle methods,was applied to simulate the spreading experiments.In the MPFI framework,the melting-solidification model including heat transfer,radiation heat loss,phase change,and solid fraction-dependent viscosity was developed and implemented.In addition,the difference in the spreading and solidification behavior due to the outlet diameters was reproduced in the calculation.The simulation results reveal the detailed solidification procedure during the molten metal spreading.It is found that the viscosity change and the solid fraction change during the spreading are key factors for the free surface condition and solidified materials.Overall,it is suggested that the MPFI method has the potential to simulate the actual nuclear melt-down phenomena in the future.展开更多
Gas-solid flows are ubiquitous in industrial systems.The coupled model of the discrete element method(DEM)and computational fluid dynamics(CFD)is one of the techniques for the simulation of the gas-solid flows.To enha...Gas-solid flows are ubiquitous in industrial systems.The coupled model of the discrete element method(DEM)and computational fluid dynamics(CFD)is one of the techniques for the simulation of the gas-solid flows.To enhance the applicability of the DEM-CFD method,the coarse graining DEM has been developed to simulate large-scale powder systems.The coarse graining DEM is a scaling law model and hence can simulate large-scale systems using a smaller number of particles than the actual one.Although the coarse graining DEM enables to effectively simulate large-scale powder systems on a single PC,visualized image is lack of reality due to reduced spatial resolution.Here a novel visualization method is developed to produce realistic images.In the proposed technique,the virtual particles are located by considering the motion and location of the coarse grain particles.To show the adequacy of the proposed method,two types of visualization based on the computational results are made:a blow-up of powder due to injected gas flow and a spouted bed.In these systems,the visualized images are shown to be improved by the proposed visualization technique.The effectiveness of the proposed method is proved by the agreement of the images based on the calculation results between the standard DEM-CFD method and coarse graining DEM.展开更多
文摘The molar extinction coefficients at the absorption maximum of the solvated electron spectrum have been evaluated to be 900,970,and 1000 mol^(-1).m^2 for 1,2-ethanediol (12ED),1,2-propanediol (12PD),and 1,3-propanediol (13PD),respectively.These values are two-third or three-fourth of the value usually reported in the published report. Picosecond pulse radiolysis studies have aided in depicting the radiolytic yield of the solvated electron in these sol- vents as a function of time from picosecond to microsecond.The radiolytic yield in these viscous solvents is found to be strongly different from that of the water solution.The temperature dependent absorption spectra of the solvated electron in 12ED,12PD,and 13PD have been also investigated.In all the three solvents,the optical spectra shift to the red with increasing temperature.While the shape of the spectra does not change in 13PD,a widening on the blue side of the absorption band is observed in 12ED and 12PD at elevated temperatures.
文摘This paper investigates long-term energy strategy compatible with significant reduction of world carbon dioxide （CO2） emissions, employing a long-term global energy model, Dynamic New Earth 21 （called DNE21）. The model seeks the optimal energy mix from 2000 to 2100 that minimizes the world total energy system cost under various kinds of energy and technological constraints, such as energy resource constraints, energy supply and demand balance constraints, and CO2 emissions constraints. This paper discusses the results of primary energy supply, power generation mix, CO2 emission, CCS （carbon capture and storage） and total system costs for six regions including world as a whole. To evaluate viable pathways forward for implementation of sustainable energy strategies, nuclear power generation is a viable source of clean and green energy to mitigate the CO2 emissions. Present research shows simulation results in two cases consisting of no CO2 regulation case （base case） and CO2 REG case （regulation case） which halves the world CO2 emissions by the year 2050. Main findings of this research describe that renewable and nuclear power generation will contribute significantly to mitigate the CO2 emission worldwide.
基金financially supported by the Nuclear Energy Science and Technology and Human Resource Development Project of the Japan Atomic Energy Agency/Collaborative Laboratories for Advanced Decommissioning Science(No.R04I034)Ruicong Xu appreciates the scholarship(financial support)from the Chinese Scholarship Council(CSC No.202106380073).
文摘During the decommissioning of the Fukushima Daiichi nuclear power plant,it is important to consider the retrieval of resolidified debris both in air and underwater configurations.For the subsequent retrieval of debris from the reactor building,the resolidified debris must be cut into smaller pieces using various cutting methods.During the cutting process,aerosol particles are expected to be generated at the submicron scale.It has been noted that such aerosols sizing within the Greenfield gap(0.1-1μm)are difficult to remove effectively using traditional spraying methods.Therefore,to improve the aerosol removal efficiency of the spray system,a new aerosol agglomeration method was recently proposed,which involves injecting water mist to enlarge the sizes of the aerosol particles before removing them using water sprays.In this study,a series of experiments were performed to clarify the proper spray configurations for effective aerosol scavenging and to improve the performance of the water mist.The experimental results showed that the spray flow rate and droplet characteristics are important factors for the aerosol-scavenging efficiency and performance of the water mist.The results obtained from this study will be helpful for the optimization of the spray system design for effective aerosol scavenging during the decommissioning of the Fukushima Daiichi plant.
基金supported by the National Natural Science Foundation of China (Nos.11975135 and 12005017)China Postdoctoral Science Foundation (No.2021M701829)
文摘The effects of annealing and irradiation on the evolution of Cu clusters in a-Fe are investigated using object kinetic Monte Carlo simulations.In our model,vacancies act as carriers for chemical species via thermally activated diffusion jumps,thus playing an important role in solute diffusion.At the end of the Cu cluster evolution,the simulations of the average radius and number density of the clusters are consistent with the experimental data,which indicates that the proposed simulation model is applicable and effective.For the simulation of the annealing process,it is found that the evolution of the cluster size roughly follows the 1/2 time power law with the increase in radius during the growth phase and the 1/3 time power law during the coarsening phase.In addition,the main difference between neutron and ion irradiation is the growth and evolution process of the copper-vacancy clusters.The aggregation of vacancy clusters under ion irradiation suppresses the migration and coarsening of the clusters,which ultimately leads to a smaller average radius of the copper clusters.Our proposed simulation model can supplement experimental analyses and provide a detailed evolution mechanism of vacancy-enhanced precipitation,thereby providing a foundation for other elemental precipitation research.
文摘This paper develops a high time-resolution optimal power generation mix model in its time resolution of 10 minutes on 365 days by linear programming technique. The model allows us to analyse the massive deployment of photovoltaic system and wind power generation in power system explicitly considering those short-term output variation. PV （photovoltaic） and wind output are estimated, employing meteorological database. Simulation results reveal that variable fluctuation derived from a high penetration level of those renewables is controlled by quick load following operation of natural gas combined cycle power plant, pumped-storage hydro power, stationary NAS （sodium and sulfur） battery and the output suppression control of PV and wind. It additionally turns out that the operational configuration of those technologies for the renewable variability differs significantly depending on those renewable output variations in each season and solving the seasonal electricity imbalance as well as the daily imbalance is important if variable renewables are massively deployed.
基金supported by the Core Research for Evolutional Science and Technology(JPMJCR15N1)of JSTthe Center of Innovation Program(JPMJCE1313)of JST+2 种基金a Grant-in-Aid for Specially Promoted Research(JP15H05696)from MEXTGrants-in-Aid for Scientific Research(19H00869,19H05628,20H00371,26247068,20H05670)from MEXTthe Quantum Leap Flagship Program(JPMXS0118068681,JPMXS0118067246)of MEXT,Japan.
文摘Attosecondattosecond science;extreme ultraviolet;high-order harmonic generation;Ramsey-type spectroscopy Optical and Ramsey-Type Interferometry by Postgeneration Splitting of Harmonic PulseTime domain Ramsey-type interferometry is useful for investigating spectroscopic information of quantum states in atoms and molecules.The energy range of the quantum states to be observed with this scheme has now reached more than 20 eV by resolving the interference fringes with a period of a few hundred attoseconds.This attosecond Ramsey-type interferometry requires the irradiation of a coherent pair of extreme ultraviolet(XUV)light pulses,while all the methods used to deliver the coherent XUV pulse pair until now have relied on the division of the source of an XUV pulse in two before the generation.In this paper,we report on a novel technique to perform attosecond Ramsey-type interferometry by splitting an XUV high-order harmonic(HH)pulse of a sub-20 fs laser pulse after its generation.By virtue of the postgeneration splitting of the HH pulse,we demonstrated that the optical interference emerging at the complete temporal overlap of the HH pulse pair seamlessly continued to the Ramsey-type electronic interference in a helium atom.This technique is applicable for studying the femtosecond dephasing dynamics of electronic wavepackets and exploring the ultrafast evolution of a cationic system entangled with an ionized electron with sub-20 fs resolution.
基金supported by the Ministry of Education,Culture,Sport,Science and Technology of Japan(MEXT)Innovative Nuclear Research and Development Program(Grant No.JPMXD0220354500)Japan Atomic Energy Agency(JAEA)Nuclear Energy S&T and Human Resource Development Project through Concentrating Wisdom(Grant No.JPJA20P20337528)+1 种基金the Collaborative Research Project at the Nuclear Professional School,School of Engineering,the University of Tokyothe continuous support from the China Scholarship Council(CSC)。
文摘Cr-coated zirconium alloy was prepared by pulsed laser deposition(PLD)for the application of accident-tolerant fuel cladding in light water reactors.The microstructural characteristics of the Cr coating and its evolution with temperature were investigated using grazing incidence X-ray diff raction and in situ heating transmission electron microscopy(TEM).Results show that the microstructure of the laser-deposited Cr coatings consists mainly of fine and non-specific shaped nano-crystals in the inner layer and columnar crystals in the outer layer.The recrystallization of the Cr-coating layer starts at 300–400℃ to release the high strain introduced by PLD,and the grain coalescence starts at temperatures>400°C.Upon annealing,the(110)-texture gradually intensifi es because of its high reticular density and low close-packed energy.Additionally,in situ heating TEM observation shows the presence of cavities on the Cr–Zr interface,which may result from the interdiff usion and/or the transformation from amorphous to crystalline.
基金the Nuclear EnergyScience & Technology and Human Resource Development Project (throughconcentrating wisdom)the Advanced Theoretical and Experimental Physics+1 种基金Waseda Universityand the TCU priority promotion research supported byTokyo City University。
文摘In a severe accident of a nuclear power reactor,coolant channel blockage by solidified molten core debris may significantly influence the core degradations that follow.The moving particle semi-implicit(MPS)method is one of the Lagrangian-based particle methods for analyzing incompressible flows.In the study described in this paper,a novel solidification model for analyzing melt flowing channel blockage with the MPS method has been developed,which is suitable to attain a sufficient numerical accuracy with a reasonable calculation cost.The prompt velocity diffusion by viscosity is prioritized over the prompt velocity correction by the pressure term(for assuring incompressibility)within each time step over the“mushy zone”(between the solidus and liquidus temperature)for accurate modeling of solidification before fixing the coordinates of the completely solidified particles.To sustain the numerical accuracy and stability,the corrective matrix and particle shifting techniques have been applied to correct the discretization errors from irregular particle arrangements and to recover the regular particle arrangements,respectively.To validate the newly developed algorithm,2-D benchmark analyses are conducted for steady-state freezing of the water in a laminar flow between two parallel plates.Furthermore,3-D channel blockage analyses of a boiling water reactor(BWR)fuel support piece have been performed.The results show that a partial channel blockage develops from the vicinity of the speed limiter,which does not fully develop into a complete channel blockage,but still diverts the incoming melt flow that follows to the orifice region.
文摘To retrieve the fuel debris in Fukushima Daiichi Nuclear Power Plants(1F),it is essential to infer the fuel debris distribution.In particular,the molten metal spreading behavior is one of the vital phenomena in nuclear severe accidents because it determines the initial condition for further accident scenarios such as molten core concrete interaction(MCCI).In this study,the fundamental molten metal spreading experiments were performed with different outlet diameters and sample amounts to investigate the effect of the outlet for spreading-solidification behavior.In the numerical analysis,the moving particle full-implicit method(MPFI),which is one of the particle methods,was applied to simulate the spreading experiments.In the MPFI framework,the melting-solidification model including heat transfer,radiation heat loss,phase change,and solid fraction-dependent viscosity was developed and implemented.In addition,the difference in the spreading and solidification behavior due to the outlet diameters was reproduced in the calculation.The simulation results reveal the detailed solidification procedure during the molten metal spreading.It is found that the viscosity change and the solid fraction change during the spreading are key factors for the free surface condition and solidified materials.Overall,it is suggested that the MPFI method has the potential to simulate the actual nuclear melt-down phenomena in the future.
基金supported by JSPS KAKENH1 Grant Number 19J22534.
文摘Gas-solid flows are ubiquitous in industrial systems.The coupled model of the discrete element method(DEM)and computational fluid dynamics(CFD)is one of the techniques for the simulation of the gas-solid flows.To enhance the applicability of the DEM-CFD method,the coarse graining DEM has been developed to simulate large-scale powder systems.The coarse graining DEM is a scaling law model and hence can simulate large-scale systems using a smaller number of particles than the actual one.Although the coarse graining DEM enables to effectively simulate large-scale powder systems on a single PC,visualized image is lack of reality due to reduced spatial resolution.Here a novel visualization method is developed to produce realistic images.In the proposed technique,the virtual particles are located by considering the motion and location of the coarse grain particles.To show the adequacy of the proposed method,two types of visualization based on the computational results are made:a blow-up of powder due to injected gas flow and a spouted bed.In these systems,the visualized images are shown to be improved by the proposed visualization technique.The effectiveness of the proposed method is proved by the agreement of the images based on the calculation results between the standard DEM-CFD method and coarse graining DEM.
