The North China Craton(NCC) represents one of the oldest and largest cratons in the earth with a nearly complete record of Precambrian history. In the northern part of the NCC, the earliest phase of alkaline magmatism...The North China Craton(NCC) represents one of the oldest and largest cratons in the earth with a nearly complete record of Precambrian history. In the northern part of the NCC, the earliest phase of alkaline magmatism occurred in discrete pulses in the Early and Middle Devonian;whereas the next episode of alkaline magmatism took place in the early Mesozoic. The Gucheng pluton is exposed in the northern part of the NCC and forms a composite intrusion, consisting of K-feldspar–bearing clinopyroxenite, clinopyroxene–bearing syenite and alkali-feldspar syenite. Mineral phases in these lithologies include clinopyroxene(Wo43-48En19-35Fs18-38), sanidine(An0 Ab3-11Or89-97), and subordinate titanite, andradite and Na-feldspar. These rocks show homogeneous Sr but variable Nd isotopic compositions, and have relatively high zircon in-situ oxygen isotopes(δ18O=5.2–6.7). The Gucheng plutonic rocks formed through fractional crystallization and accumulation from ultrapotassic magmas, which were originated from partial melting of metasomatic vein systems in the subcontinental lithospheric mantle of the NCC. These vein networks developed as a result of the reactions of fluids derived from subducted pelitic sediments on the downgoing Palaeo-Asian ocean floor with the enriched, subcontinental lithospheric mantle peridotites. SHRIMP U-Pb zircon dating has revealed a crystallization age of 415 Ma for the timing of the emplacement of the Gucheng pluton that marks the early stages of alkaline magmatism associated with the Andean-type continental margin evolution along the northern edge of the NCC facing the Palaeo-Asian Ocean.展开更多
Farré-de-Pablo et al.(2018)report a new occurrence of in situ microdiamonds enclosed in chromite from ophiolitic chromitite pods hosted in the Tehuitzingo serpentinite of southern Mexico.The discovery enlarges th...Farré-de-Pablo et al.(2018)report a new occurrence of in situ microdiamonds enclosed in chromite from ophiolitic chromitite pods hosted in the Tehuitzingo serpentinite of southern Mexico.The discovery enlarges the number of occurrence of the ophiolite-hosted microdiamonds to 7 countries in the world,including India(Das,2015,2017),Albania(Xiong et al.,2017;Wu et al.,2017),Turkey(Lian et al.,2017),Myanmar(Chen et al.,2018),Russia(Yang et al.,2015),and China(Bai et al.,1993;Xu et al.,2009).The microdiamonds occur in ophiolitic podiform chromitites and peridotites,and are generally interpreted as UHP phases formed at pressures>4 GPa(Yang et al.,2014;Griffin et al.,2016;Das et al.,2017).However,Farré-de-Pablo et al.(2018)conclude that the Tehuitzingo diamonds were formed under low-temperature and low-pressure conditions during serpentinization,which challenges the current knowledge of diamond formation.Here,we discuss several lines of evidence that do not support the authors’conclusion.展开更多
Early Cretaceous magmatism suggested to be related with the Kerguelen mantle plume has been reported in both the eastern and western Tethyan Himalayan terrane.Coeval magmatism(133-138 Ma)recorded by hypabyssal intrusi...Early Cretaceous magmatism suggested to be related with the Kerguelen mantle plume has been reported in both the eastern and western Tethyan Himalayan terrane.Coeval magmatism(133-138 Ma)recorded by hypabyssal intrusive rocks have been recently discovered in the central Tethyan Himalaya(TH).The hypabyssal intrusions are dominated by OIB-like basaltic rocks intruded by later porphyritic/ophitic intermediate rocks and are characterized by strongly light rare earth element enrichment and prominent Na-Ta depletion and Pb enrichment.The basaltic rocks have low 143Nd/144Nd ratios ranging from 0.512365 to 0.512476 but relatively high 87Sr/86Sr ratios ranging from 0.708185 to 0.708966.TheεNd(t)ratios of the basaltic rocks are between-4.33 and-2.20 and initial 87Sr/86Sr ratios are 0.707807 to 0.708557.Geochemical data demonstrate that these rocks have experienced combined crustal assimilation and fractional crystallization processes.Magmatic zircons from the hypabyssal rocks exclusively have negativeεHf(t)values ranging from-0.7 to-12.7,suggestive of assimilation of crustal material.Zircons from these hypabyssal rocks have UPb ages ranging from 130 to 147 Ma.Inherited zircons have UPb ages from 397 to 2495 Ma.All the zircons are characterized by negativeεHf(t)values.The Jiding ocean island basalt(OIB)-like magmatism is geochemically and geochronologically comparable with that in the western and eastern Tethyan Himalaya,indicating widespread OIB-like magmatism in the northern margin of Greater India during the Cretaceous.Collectively,these rocks can be correlated with other early Cretaceous magmatism in western Australia and northern Antarctica.Considering the similarities,we suggest that the Jiding hypabyssal rocks are also genetically related to Kerguelen plume.Within the Yarlung Zangbo Suture Zone(YZSZ),there are also numerous occurrences of OIB-like rocks derived from mantle sources different from those of N-MORB-like magmas.The OIB-like magmatism in the YZSZ is nearly coeval with that in the TH,and the two are geochemically similar.We suggest that the OIB-like magmatism in the Neo-Tethyan ocean and the northern margin of Greater India may represent the dispersed fingerprints of the Kerguelen plume preserved in southern Tibet,China.展开更多
The Pozanti-Karsanti ophiolite(PKO)in Turkey’s eastern Tauride belt comprises mantle peridotites,ultramafic to mafic cumulates,isotropic gabbros,sheeted dikes and pillow lavas.The mantle peridotites are dominated by ...The Pozanti-Karsanti ophiolite(PKO)in Turkey’s eastern Tauride belt comprises mantle peridotites,ultramafic to mafic cumulates,isotropic gabbros,sheeted dikes and pillow lavas.The mantle peridotites are dominated by spinel harzburgites with minor dunites.The harzburgites and dunites have quite depleted mineral and whole-rock chemical composition,suggesting high degrees of partial melting.Their PGEs vary from Pd-depleted to distinct Pd-enriched patterns,implying the crystallization of interstitial sulphides from sulphur-saturated melts(e.g.MORB-like forearc basalt).U-shaped or spoon-shaped REE patterns indicate that the PKO peridotites may have also been metasomatized by the LREE-enriched fluids released from a subducting slab in a suprasubduction zone.Based on the mineral and whole-rock chemical compositions,the PKO peridotites show affinities to forearc peridotites.Chromitites occur both in the mantle peridotites and the mantle-crust transition zone horizon(MTZ).Chromitites from the two different horizons have different textures but similar mineral compositions,consistent with typical high-Cr chromitites.Chromitites hosted by mantle harzburgites generally have higher total platinum-group element(PGE)contents than those of the MTZ chromitites.However,both chromitites show similar chondritenormalized PGE patterns characterized by clear IPGEs,Rh-enrichments relative to Pt and Pd.Such PGE patterns indicate no or only minor crystallization of Pt-and Pd enriched sulphides during formation of chromitites from a sulphur-undersaturated melt(e.g.boninitic or island arc tholeiitic melt).Dunite enveloping chromitite lenses in the ho*s ting harzburgite resulted from melt-rock reaction.We have performed mineral separation work on samples of podiform chromitite hosted by harzburgites.So far,more than200 grains of microdiamond and more than 100 grains of moissanite(Si C)have been separated from podiform chromitites.These minerals have been identified by EDX and Laser Raman analyses.The diamonds and moissanite are accompanied by large amounts of rutile.Additionally,zircon,monazite and sulphides are also common phases within the heavy mineral separates.Both diamond and moissanite have been analyzed for carbon and nitrogen isotopic composition using the CARMECA 1280-HR large geometry Secondary Ion Mass Spectrometer at the Helmholtz Zentrum Potsdam.In total,61δ13CPDB results for diamond were acquired,exhibiting a range from-28.4‰to-18.8‰.31δ13CPDB results for Moissanite vary between-30.5‰to-27.2‰,with a mean value of-29.0‰.Diamond has relatively large variation in nitrogen isotopic composition with 40δ15NAIR results ranging from-19.1‰to 16.6‰.The discovery of diamond,moissanite and the other unusual minerals from podiform chromitite of the Pozanti-Karsanti ophiolite provides new support for the genesis of ophiolitic peridotites and chromitites under high-pressure and ultra-high reducing conditions.Considering the unusual minerals,the high Mg#silicate inclusions,and the needle-shaped exsolutions in the PKO chromitites,the parental melts of these chromitites may have been mixed with deep asthenospheric basaltic melts that had assimilated materials of the descending slab when passing through the slab in a subduction zone environment.We suggest melt-rock reactions,magma mixing and assimilation may have triggered the oversaturation of chromites and the formation of PKO chromitites.展开更多
基金financially supported by grants from the Nature Science Foundation of China (Grant Nos. 416720634177302941302038 and 41720104009)
文摘The North China Craton(NCC) represents one of the oldest and largest cratons in the earth with a nearly complete record of Precambrian history. In the northern part of the NCC, the earliest phase of alkaline magmatism occurred in discrete pulses in the Early and Middle Devonian;whereas the next episode of alkaline magmatism took place in the early Mesozoic. The Gucheng pluton is exposed in the northern part of the NCC and forms a composite intrusion, consisting of K-feldspar–bearing clinopyroxenite, clinopyroxene–bearing syenite and alkali-feldspar syenite. Mineral phases in these lithologies include clinopyroxene(Wo43-48En19-35Fs18-38), sanidine(An0 Ab3-11Or89-97), and subordinate titanite, andradite and Na-feldspar. These rocks show homogeneous Sr but variable Nd isotopic compositions, and have relatively high zircon in-situ oxygen isotopes(δ18O=5.2–6.7). The Gucheng plutonic rocks formed through fractional crystallization and accumulation from ultrapotassic magmas, which were originated from partial melting of metasomatic vein systems in the subcontinental lithospheric mantle of the NCC. These vein networks developed as a result of the reactions of fluids derived from subducted pelitic sediments on the downgoing Palaeo-Asian ocean floor with the enriched, subcontinental lithospheric mantle peridotites. SHRIMP U-Pb zircon dating has revealed a crystallization age of 415 Ma for the timing of the emplacement of the Gucheng pluton that marks the early stages of alkaline magmatism associated with the Andean-type continental margin evolution along the northern edge of the NCC facing the Palaeo-Asian Ocean.
基金financially supported by the Natural Science Foundation of China(41720104009,41802034 and 41802055)Natural Science Foundation of Jiangsu(BK20180349)
文摘Farré-de-Pablo et al.(2018)report a new occurrence of in situ microdiamonds enclosed in chromite from ophiolitic chromitite pods hosted in the Tehuitzingo serpentinite of southern Mexico.The discovery enlarges the number of occurrence of the ophiolite-hosted microdiamonds to 7 countries in the world,including India(Das,2015,2017),Albania(Xiong et al.,2017;Wu et al.,2017),Turkey(Lian et al.,2017),Myanmar(Chen et al.,2018),Russia(Yang et al.,2015),and China(Bai et al.,1993;Xu et al.,2009).The microdiamonds occur in ophiolitic podiform chromitites and peridotites,and are generally interpreted as UHP phases formed at pressures>4 GPa(Yang et al.,2014;Griffin et al.,2016;Das et al.,2017).However,Farré-de-Pablo et al.(2018)conclude that the Tehuitzingo diamonds were formed under low-temperature and low-pressure conditions during serpentinization,which challenges the current knowledge of diamond formation.Here,we discuss several lines of evidence that do not support the authors’conclusion.
基金supported by the National Natural Science Foundation of China(41802034,41720104009,41802055)the Natural Science Foundation of Jiangsu Province(BK20180349)the fund from the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources
文摘Early Cretaceous magmatism suggested to be related with the Kerguelen mantle plume has been reported in both the eastern and western Tethyan Himalayan terrane.Coeval magmatism(133-138 Ma)recorded by hypabyssal intrusive rocks have been recently discovered in the central Tethyan Himalaya(TH).The hypabyssal intrusions are dominated by OIB-like basaltic rocks intruded by later porphyritic/ophitic intermediate rocks and are characterized by strongly light rare earth element enrichment and prominent Na-Ta depletion and Pb enrichment.The basaltic rocks have low 143Nd/144Nd ratios ranging from 0.512365 to 0.512476 but relatively high 87Sr/86Sr ratios ranging from 0.708185 to 0.708966.TheεNd(t)ratios of the basaltic rocks are between-4.33 and-2.20 and initial 87Sr/86Sr ratios are 0.707807 to 0.708557.Geochemical data demonstrate that these rocks have experienced combined crustal assimilation and fractional crystallization processes.Magmatic zircons from the hypabyssal rocks exclusively have negativeεHf(t)values ranging from-0.7 to-12.7,suggestive of assimilation of crustal material.Zircons from these hypabyssal rocks have UPb ages ranging from 130 to 147 Ma.Inherited zircons have UPb ages from 397 to 2495 Ma.All the zircons are characterized by negativeεHf(t)values.The Jiding ocean island basalt(OIB)-like magmatism is geochemically and geochronologically comparable with that in the western and eastern Tethyan Himalaya,indicating widespread OIB-like magmatism in the northern margin of Greater India during the Cretaceous.Collectively,these rocks can be correlated with other early Cretaceous magmatism in western Australia and northern Antarctica.Considering the similarities,we suggest that the Jiding hypabyssal rocks are also genetically related to Kerguelen plume.Within the Yarlung Zangbo Suture Zone(YZSZ),there are also numerous occurrences of OIB-like rocks derived from mantle sources different from those of N-MORB-like magmas.The OIB-like magmatism in the YZSZ is nearly coeval with that in the TH,and the two are geochemically similar.We suggest that the OIB-like magmatism in the Neo-Tethyan ocean and the northern margin of Greater India may represent the dispersed fingerprints of the Kerguelen plume preserved in southern Tibet,China.
文摘The Pozanti-Karsanti ophiolite(PKO)in Turkey’s eastern Tauride belt comprises mantle peridotites,ultramafic to mafic cumulates,isotropic gabbros,sheeted dikes and pillow lavas.The mantle peridotites are dominated by spinel harzburgites with minor dunites.The harzburgites and dunites have quite depleted mineral and whole-rock chemical composition,suggesting high degrees of partial melting.Their PGEs vary from Pd-depleted to distinct Pd-enriched patterns,implying the crystallization of interstitial sulphides from sulphur-saturated melts(e.g.MORB-like forearc basalt).U-shaped or spoon-shaped REE patterns indicate that the PKO peridotites may have also been metasomatized by the LREE-enriched fluids released from a subducting slab in a suprasubduction zone.Based on the mineral and whole-rock chemical compositions,the PKO peridotites show affinities to forearc peridotites.Chromitites occur both in the mantle peridotites and the mantle-crust transition zone horizon(MTZ).Chromitites from the two different horizons have different textures but similar mineral compositions,consistent with typical high-Cr chromitites.Chromitites hosted by mantle harzburgites generally have higher total platinum-group element(PGE)contents than those of the MTZ chromitites.However,both chromitites show similar chondritenormalized PGE patterns characterized by clear IPGEs,Rh-enrichments relative to Pt and Pd.Such PGE patterns indicate no or only minor crystallization of Pt-and Pd enriched sulphides during formation of chromitites from a sulphur-undersaturated melt(e.g.boninitic or island arc tholeiitic melt).Dunite enveloping chromitite lenses in the ho*s ting harzburgite resulted from melt-rock reaction.We have performed mineral separation work on samples of podiform chromitite hosted by harzburgites.So far,more than200 grains of microdiamond and more than 100 grains of moissanite(Si C)have been separated from podiform chromitites.These minerals have been identified by EDX and Laser Raman analyses.The diamonds and moissanite are accompanied by large amounts of rutile.Additionally,zircon,monazite and sulphides are also common phases within the heavy mineral separates.Both diamond and moissanite have been analyzed for carbon and nitrogen isotopic composition using the CARMECA 1280-HR large geometry Secondary Ion Mass Spectrometer at the Helmholtz Zentrum Potsdam.In total,61δ13CPDB results for diamond were acquired,exhibiting a range from-28.4‰to-18.8‰.31δ13CPDB results for Moissanite vary between-30.5‰to-27.2‰,with a mean value of-29.0‰.Diamond has relatively large variation in nitrogen isotopic composition with 40δ15NAIR results ranging from-19.1‰to 16.6‰.The discovery of diamond,moissanite and the other unusual minerals from podiform chromitite of the Pozanti-Karsanti ophiolite provides new support for the genesis of ophiolitic peridotites and chromitites under high-pressure and ultra-high reducing conditions.Considering the unusual minerals,the high Mg#silicate inclusions,and the needle-shaped exsolutions in the PKO chromitites,the parental melts of these chromitites may have been mixed with deep asthenospheric basaltic melts that had assimilated materials of the descending slab when passing through the slab in a subduction zone environment.We suggest melt-rock reactions,magma mixing and assimilation may have triggered the oversaturation of chromites and the formation of PKO chromitites.
