Gas-phase Ca^＋-dipropylamine complex has been subjected to photodissociation （400-690 nm）. One reactive product, Ca^＋-NHC3H7, is detected only in the region of 450-528 nm, besides the evaporation fragment of Ca^＋...Gas-phase Ca^＋-dipropylamine complex has been subjected to photodissociation （400-690 nm）. One reactive product, Ca^＋-NHC3H7, is detected only in the region of 450-528 nm, besides the evaporation fragment of Ca^＋, which is dominant throughout the whole spectral region we have studied. The photoreaction channel may be explained in terms of a metal insertion mechanism. The calculated results are in good agreement with the experimental observations.展开更多
基金supported by the National Natural Science Foundation of China (20129001)the Research Grants Council of Hong Kong, China(CA05/06.SC02)R/D Fund of Shenzhen University, China (200824)~~
基金supported by the National Science Fund for Distinguished Young Scholars,China(21425627)National Natural Science Foundation of China(21461162003,21476271)Natural Science Foundation of Guangdong Province,China(2014KTSCX004,2014A030308012)~~
文摘Gas-phase Ca^＋-dipropylamine complex has been subjected to photodissociation （400-690 nm）. One reactive product, Ca^＋-NHC3H7, is detected only in the region of 450-528 nm, besides the evaporation fragment of Ca^＋, which is dominant throughout the whole spectral region we have studied. The photoreaction channel may be explained in terms of a metal insertion mechanism. The calculated results are in good agreement with the experimental observations.
基金supprt from National Science Foundation of China (Nos.21033008,21073169,21103157)National Basic Research Program of China(No.2010CB923300 and No.2011CB921400)+2 种基金Fundamental Research Funds for the Central Universities of China (No.2340000034)Innovation Funds for Young Researchers of USTC(No.2340000025)Hong Kong UGC(No.AoE/P-04/08-2)
