The Tarim Basin has revealed numerous tight sandstone oil and gas reservoirs.The tidal fl at zone in the Shunbei area is currently in the detailed exploration stage,requiring a comprehensive description of the sand bo...The Tarim Basin has revealed numerous tight sandstone oil and gas reservoirs.The tidal fl at zone in the Shunbei area is currently in the detailed exploration stage,requiring a comprehensive description of the sand body distribution characteristics for rational exploration well deployment.However,using a single method for sand body prediction has yielded poor results.Seismic facies analysis can eff ectively predict the macro-development characteristics of sedimentary sand bodies but lacks the resolution to capture fi ne details.In contrast,single-well sedimentary facies analysis can describe detailed sand body development but struggles to reveal broader trends.Therefore,this study proposes a method that combines seismic facies analysis with single-well sedimentary microfacies analysis,using the lower section of the Kepingtage Formation in the Shunbei area as a case study.First,seismic facies were obtained through unsupervised vector quantization to control the macro-distribution characteristics of sand bodies,while principal component analysis(PCA)was applied to improve the depiction of fi ne sand body details from seismic attributes.Based on 3D seismic data,well-logging data,and geological interpretation results,a detailed structural interpretation was performed to establish a high-precision stratigraphic framework,thereby enhancing the accuracy of sand body prediction.Seismic facies analysis was then conducted to obtain the macro-distribution characteristics of the sand bodies.Subsequently,core data and logging curves from individual wells were used to clarify the vertical development characteristics of tidal channels and sandbars.Next,PCA was employed to select the seismic attributes most sensitive to sand bodies in diff erent sedimentary facies.Results indicate that RMS amplitude in the subtidal zone and instantaneous phase in the intertidal zone are the most sensitive to sand bodies.A comparative analysis of individual seismic attributes for sand body characterization revealed that facies-based delineation improved the accuracy of sand body identifi cation,eff ectively capturing their contours and shapes.This method,which integrates seismic facies,single-well sedimentary microfacies,and machine learning techniques,enhances the precision of sand body characterization and off ers a novel approach to sand body prediction.展开更多
The preparation of a synthetic pitch from aromatic monomers could easily regulate structure orientation at the molecu-lar level,which would be useful in fabrication.An isotropic synthetic pitch was prepared by a chlor...The preparation of a synthetic pitch from aromatic monomers could easily regulate structure orientation at the molecu-lar level,which would be useful in fabrication.An isotropic synthetic pitch was prepared by a chlorine-and/or nitrogen-induced sub-stitution polymerization reaction method using aromatic hydrocarbon precursors containing Cl and N,which for this study were chloromethyl naphthalene and quinoline.This method was verified by investigating the structural changes under different synthesis conditions,and the synthesis mechanism induced by aromatics containing Cl was also probed.The result shows that the pyridinic N in quinoline contains a lone pair of electrons,and is an effective active site to induce the polymerization reaction by coupling with aromatic hydrocarbons containing Cl.The reaction between such free radicals causes strong homopolymerization and oligomeriza-tion.A higher reaction temperature and longer reaction time significantly increased the degree of polymerization and thus increased the softening point of the pitch.A linear molecular structure was formed by the Cl substitution reaction,which produced a highly spinnable pitch with a softening point of 258.6℃,and carbon fibers with a tensile strength of 1163.82 MPa were obtained.This study provides a relatively simple and safe method for the preparation of high-quality spinnable pitch.展开更多
Water splitting powered by clean electricity is a sustainable and promising approach to produce green hydrogen.Currently,noble metal(e.g.Iridium,Ruthenium,Platinum)-based catalysts are most widely used for water split...Water splitting powered by clean electricity is a sustainable and promising approach to produce green hydrogen.Currently,noble metal(e.g.Iridium,Ruthenium,Platinum)-based catalysts are most widely used for water splitting electrolysis.However,noble metal-based catalysts often suffer from multiple disadvantages,including high cost,low selectivity and poor durability.The emergence of metal-organic framework nanosheets(MOFNSs)attracts significant attention due to their unique advantages.Here,a concise,yet comprehensive and critical,review of recent advances in the field of MOFNSs is provided.This review explains the fundamental oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)catalytic mechanisms as well as key characterization techniques for the structure-activity relationship study are discussed.Moreover,it discusses efficient design strategies and the brief research advances of MOFNSs in HER,OER,and bifunctional electrocatalysis,along with some challenges and opportunities.展开更多
基金Collaborative Project Grant from the Exploration and Development Research Institute of SINOPEC Northwest Oilfi eld Company(Grant No.KY2021-S-104).
文摘The Tarim Basin has revealed numerous tight sandstone oil and gas reservoirs.The tidal fl at zone in the Shunbei area is currently in the detailed exploration stage,requiring a comprehensive description of the sand body distribution characteristics for rational exploration well deployment.However,using a single method for sand body prediction has yielded poor results.Seismic facies analysis can eff ectively predict the macro-development characteristics of sedimentary sand bodies but lacks the resolution to capture fi ne details.In contrast,single-well sedimentary facies analysis can describe detailed sand body development but struggles to reveal broader trends.Therefore,this study proposes a method that combines seismic facies analysis with single-well sedimentary microfacies analysis,using the lower section of the Kepingtage Formation in the Shunbei area as a case study.First,seismic facies were obtained through unsupervised vector quantization to control the macro-distribution characteristics of sand bodies,while principal component analysis(PCA)was applied to improve the depiction of fi ne sand body details from seismic attributes.Based on 3D seismic data,well-logging data,and geological interpretation results,a detailed structural interpretation was performed to establish a high-precision stratigraphic framework,thereby enhancing the accuracy of sand body prediction.Seismic facies analysis was then conducted to obtain the macro-distribution characteristics of the sand bodies.Subsequently,core data and logging curves from individual wells were used to clarify the vertical development characteristics of tidal channels and sandbars.Next,PCA was employed to select the seismic attributes most sensitive to sand bodies in diff erent sedimentary facies.Results indicate that RMS amplitude in the subtidal zone and instantaneous phase in the intertidal zone are the most sensitive to sand bodies.A comparative analysis of individual seismic attributes for sand body characterization revealed that facies-based delineation improved the accuracy of sand body identifi cation,eff ectively capturing their contours and shapes.This method,which integrates seismic facies,single-well sedimentary microfacies,and machine learning techniques,enhances the precision of sand body characterization and off ers a novel approach to sand body prediction.
文摘The preparation of a synthetic pitch from aromatic monomers could easily regulate structure orientation at the molecu-lar level,which would be useful in fabrication.An isotropic synthetic pitch was prepared by a chlorine-and/or nitrogen-induced sub-stitution polymerization reaction method using aromatic hydrocarbon precursors containing Cl and N,which for this study were chloromethyl naphthalene and quinoline.This method was verified by investigating the structural changes under different synthesis conditions,and the synthesis mechanism induced by aromatics containing Cl was also probed.The result shows that the pyridinic N in quinoline contains a lone pair of electrons,and is an effective active site to induce the polymerization reaction by coupling with aromatic hydrocarbons containing Cl.The reaction between such free radicals causes strong homopolymerization and oligomeriza-tion.A higher reaction temperature and longer reaction time significantly increased the degree of polymerization and thus increased the softening point of the pitch.A linear molecular structure was formed by the Cl substitution reaction,which produced a highly spinnable pitch with a softening point of 258.6℃,and carbon fibers with a tensile strength of 1163.82 MPa were obtained.This study provides a relatively simple and safe method for the preparation of high-quality spinnable pitch.
文摘Water splitting powered by clean electricity is a sustainable and promising approach to produce green hydrogen.Currently,noble metal(e.g.Iridium,Ruthenium,Platinum)-based catalysts are most widely used for water splitting electrolysis.However,noble metal-based catalysts often suffer from multiple disadvantages,including high cost,low selectivity and poor durability.The emergence of metal-organic framework nanosheets(MOFNSs)attracts significant attention due to their unique advantages.Here,a concise,yet comprehensive and critical,review of recent advances in the field of MOFNSs is provided.This review explains the fundamental oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)catalytic mechanisms as well as key characterization techniques for the structure-activity relationship study are discussed.Moreover,it discusses efficient design strategies and the brief research advances of MOFNSs in HER,OER,and bifunctional electrocatalysis,along with some challenges and opportunities.
