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Reattachment of the Osteotomized Greater Trochanter in Hip Surgery Using an Ultrahigh Molecular Weight Polyethylene Fiber Cable: A Multi-Institutional Study 被引量:1
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作者 Seiya Jingushi Tsutomu Kawano +8 位作者 Hirokazu Iida Kenichi Oe Kenji Ohzono Yoshihide Nakamura Makoto Osaki Hidetsugu Ohara Seung Bak Lee Toshihiko Hara Naohide Tomita 《Open Journal of Orthopedics》 2013年第6期283-289,共7页
The purpose of this multicenter study was to evaluate the clinical performance of an ultrahigh molecular weight polyethylene (UHMWPE) fiber cable for re-attachment of the osteotomized greater trochanter in hip surgery... The purpose of this multicenter study was to evaluate the clinical performance of an ultrahigh molecular weight polyethylene (UHMWPE) fiber cable for re-attachment of the osteotomized greater trochanter in hip surgery. Included in the study were 85 hips that had undergone surgery with greater trochanter osteotomy, including 50 hip arthroplasty procedures and 35 hip osteotomies. The osteotomized greater trochanter was reattached using one or more UHMWPE fiber cables. The bone union and displacement of the greater trochanter were assessed in radiographs for up to 12 months after surgery. Non-union of the osteotomy site occurred in 4.7% of the cases. In approximately 90% of the cases, displacement was less than 2 mm at up to 12 months after surgery. The UHMWPE fiber cable was a good biomaterial for reattaching the osteotomized greater trochanter and may also be an option for osteosynthesis procedures. 展开更多
关键词 ultrahigh molecular weight polyethylene fiber CABLE Biomaterials OSTEOSYNTHESIS Greater Trochanter OSTEOTOMY Hip Operations ARTHROPLASTY
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Manufacturing of Ultra-high Molecular Weight Polyethylene Fiber Reinforced Tape and the Loss of Strength
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作者 胡祖明 刘兆峰 《Journal of China Textile University(English Edition)》 EI CAS 1999年第4期92-94,共3页
Due to the low density and excellent mechanical proper-ties,high performance fiber reinforced materials have aconsiderable application in the area of high technologyand dally usage.In this paper,the Ultra-high Molecu-... Due to the low density and excellent mechanical proper-ties,high performance fiber reinforced materials have aconsiderable application in the area of high technologyand dally usage.In this paper,the Ultra-high Molecu-lar Weight Polyethylene(UHMWPE)fiber reinforcedPE tape prepared with the method of powder impregnat-ion was studied.The effect of impregnate length and thetensile force of the yarn on the fiber content as well as on the strength and modulus of the tape were discussed.Calculation shows that the strength and the modulus ofthe ULMWPE fiber can keep about 85% after it undergothe process. 展开更多
关键词 ultra - high molecular weight polyethylene fiber REINFORCED material TAPE IMPREGNATION
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PREPARATION OF MICROPOROUS ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE (UHMWPE) BY THERMALLY INDUCED PHASE SEPARATION OF A UHMWPE/LIQUID PARAFFIN MIXTURE 被引量:8
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作者 沈烈 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2008年第6期653-657,共5页
Ultra-high molecular weight polyethylene (UHMWPE) with a microporous structure was prepared via thermally induced phase separation (TIPS).Liquid paraffin (LP) was used as a diluent in the preparation of microporous UH... Ultra-high molecular weight polyethylene (UHMWPE) with a microporous structure was prepared via thermally induced phase separation (TIPS).Liquid paraffin (LP) was used as a diluent in the preparation of microporous UHMWPE. Small angle laser light scattering (SALLS) and differential scanning calorimetry (DSC) were used to determine the phase separation temperatures,i.e.the cloud points and the dynamic crystallization temperatures,respectively.It was found that the cloudI points were coincident with the cryst... 展开更多
关键词 ultra high molecular weight polyethylene Thermally induced phase separation Liquid paraffin.
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Structure and Properties of Self-reinforced Material Made from Ultra-high Molecular Weight Polyethylene-montmorillonite Nanocomposite 被引量:3
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作者 WANGQing-zhao LIAOXian-ling LIUZong-lin 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第4期504-510,共7页
High-strength and high-modulus ultra-high molecular weight polyethylene(UHMWPE), named self-reinforced material, was obtained by the elongation of UHMWPE-montmorillonite nanocomposite at melting temperature. According... High-strength and high-modulus ultra-high molecular weight polyethylene(UHMWPE), named self-reinforced material, was obtained by the elongation of UHMWPE-montmorillonite nanocomposite at melting temperature. According to the scanning electron microscope(SEM) analysis, a great deal of fibrillar texture formed in the direction of elongation, and the tensile fractured surface was similar to that of highly oriented fiber. The transmission electron microscope(TEM) and selective area electron diffraction(SAED) analyses reveal that the reinforced phase of the self-reinforced material is an extended chain crystal and its size is about 50_200 nm wide and several microns long, and the montmorillonite layers are broken up to pieces in the size from 100 to 10 nm. The broken layers which have a huge surface area interacting strongly with macromolecules reduces the entanglement density of UHMWPE and induces the chain orientation in flow field. It is supposed that the astriction of montmorillonite layers to polyethylene chains is not only end-tethered but also side-tethered. The differential scan calorimetry(DSC) analysis shows that there are two endothermal peaks for the self-reinforced material, of which the peak at a higher temperature(136.4 ℃) is ascribed to the melting of the reinforced phase. 展开更多
关键词 ultra-high molecular weight polyethylene-montmorillonite nanocomposite ELONGATION Self-reinforced material Properties Structure
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Ultra-High Molecular Weight Polyethylene Tape Applied for Distal Humeral Condyle Fracture around Total Elbow Arthroplasty in Patients with Rheumatoid Arthritis: Report of Two Cases 被引量:1
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作者 Norio Yamamoto Mitsuhiko Takahashi +1 位作者 Naohito Hibino Koichi Sairyo 《Open Journal of Orthopedics》 2015年第9期283-287,共5页
Managing fractures of distal humerus in patients with rheumatoid arthritis (RA) is technically challenging. Total elbow arthroplasty (TEA) is one of the treatment options for these fractures. While elbow motion is lar... Managing fractures of distal humerus in patients with rheumatoid arthritis (RA) is technically challenging. Total elbow arthroplasty (TEA) is one of the treatment options for these fractures. While elbow motion is largely regained by TEA, comminuted condyle fragments are often ignored. Although numerous approaches for repair of condylar fragments around TEA are described, any universal fixation strategy for these fractures has not been established. This report describes, for the first time, application of an ultra-high molecular weight polyethylene (UHMWPE) tape for the treatment of distal humerus fracture in 2 patients with rheumatic elbow arthropathy. The post-operative clinical courses were good. Radiographs showed bony union of the condylar fragments without loosening in two cases. Because of its flat configuration, softness, and flexibility, UHMWPE tape is a promising material for stabilizing fracture of the distal humerus associated with TEA. 展开更多
关键词 Total Elbow ARTHROPLASTY DISTAL HUMERUS ultra-high molecular weight polyethylene RHEUMATOID Arthritis
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PREPARATION AND CHARACTERIZATION OF ULTRA-HIGH MOLECULAR WEIGHT POLY(ETHYLENE TEREPHTHALATE)(PET)FIBER
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作者 章谭莉 胡学超 +1 位作者 谢又乐 严建华 《Journal of China Textile University(English Edition)》 EI CAS 1997年第4期7-12,共6页
This paper reports the spinning and drawing behavior of Ultra-high Molecular Weight polyethylene Terephthalate) (UHMW-PET) fibers. The as-spun fibers were produced by dry-jet wet spinning of a 15%-17% solution in 50:5... This paper reports the spinning and drawing behavior of Ultra-high Molecular Weight polyethylene Terephthalate) (UHMW-PET) fibers. The as-spun fibers were produced by dry-jet wet spinning of a 15%-17% solution in 50:50(v:v) trifluroroacetic acid and dichloromethane. Both molecular weight and polymer solution concentration have marked effect on the drawability of the as-spun-fibers. The maximum extension drawing ratio (EDRmax) of as-spun fiber increases with increasing molecular weight, whereas optimal concentration to achieve the EDRmax of as-spun fibers decreases with increasing molecular weight. Drawing speed and temperature during the first step have remarkable effect on the drawability of these fiber during the second step. Relatively lower drawing temperature and drawing speed (19 ℃ , 60 mm/min) during the first drawing step was beneficial to mechanical properties of ultimate fibers. At the range of 210 ℃ to 230 ℃, the draw ratio (DR) during the second step increases with increasing temperature. 展开更多
关键词 ultra-high molecular weight polyethylene TEREPHTHALATE DRAWING STRENGTH
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Determination and Temperature Dependence of Plateau Modulus for Polymerization of Propylene to Isotactic Polypropylene with Ultra-high Molecular Weight under Catalysis of Ziegler-Natta Catalyst 被引量:1
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作者 DINGJian DINGXue-jia XURi-wei YUDing-sheng 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2005年第2期227-231,共5页
The viscoelastic behavior of isotactic polypropylene with ultra-high molecular weight(UHPPH) and broad molecular weight distribution(MWD), produced in the presence of Ziegler-Natta catalyst, was investigated by means ... The viscoelastic behavior of isotactic polypropylene with ultra-high molecular weight(UHPPH) and broad molecular weight distribution(MWD), produced in the presence of Ziegler-Natta catalyst, was investigated by means of oscillatory rheometry at 180 and 200 ℃, whose loss modulus(G″) plots at 180 and 200 ℃ versus the natural logarithm of angular frequency(ω) present a pronounced maximum at 34.35 and 69.21 rad/s, respectively, and do not show a maximum peak at 0.01-100 rad/s for Ziegler-Natta catalyzing ethylene-propylene random copolymerization(PPR) with a conventional molecular weight and broad MWD. The fact indicates that the high molecular weight is responsible for a maximum peak of G″(ω) vs. lnω curves for UHPPH. This makes it possible to determine the plateau modulus(G 0_N) of UHPPH from a certain experimental temperature G″(ω) curve directly. For UHPPH, the G 0_N determined to be 4.28×10 5 and 3.62×10 5 Pa at 180 and 200 ℃, respectively, decreases with the increase of temperature and is independent of the molecular weight, which directly confirms reputation theoretical prediction that the G 0_N has no relation to the molecular weight. 展开更多
关键词 Isotactic polypropylene ultra-high molecular weight Broad molecular weight distribution Plateau modulus
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Influence of Molecular Weight of Ultra-high Molecular Weight Polyacrylonitrile on Its Rheological Behavior in Dimethylsulfoxide
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作者 沈新元 朱新远 刘永建 《Journal of Donghua University(English Edition)》 EI CAS 2001年第3期7-10,共4页
Ultra-high molecular weight polyacrylonitrile (UHMW PAN ) was prepared by aqueous suspension polymerization, and the effect of molecular weight on its rheological behaviors in dimethylsulfoxide (DMSO) and the spinning... Ultra-high molecular weight polyacrylonitrile (UHMW PAN ) was prepared by aqueous suspension polymerization, and the effect of molecular weight on its rheological behaviors in dimethylsulfoxide (DMSO) and the spinning stability were investigated. It shows that,compared with common polyacrylonitrile (C-PAN),UHMW- PAN/DMS0 solution has smaller non- Newtonian index, larger structural viscosity index, much longer maximum relaxation time, and no first- Newtonian region appears in the flow curves under the same experimental conditions. The explanations for these phenomena are given in the view of chain- entanglements. The optimal technology of preparing UHMW-PAN fibers and hollow fiber membranes could be obtained based on the theological study. 展开更多
关键词 ultra-high molecular weight POLYACRYLONITRILE rheological behavior spinnability.
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Synthesis and properties of ultrahigh molecular weight polyethylene/WS_2 nanoparticle fiber for bullet-proof materials 被引量:6
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作者 MA Tian ZHANG Tao +1 位作者 GAO PengGang ZHANG JianChun 《Chinese Science Bulletin》 SCIE EI CAS 2013年第8期945-948,共4页
Ultrahigh molecular weight polyethylene (UHMWPE)/WS2 nanoparticle fibers were prepared by adding WS2 nanoparticles treated by coupling agent in the precursor solution of UHMWPE. The influence of WS2 nanoparticles on t... Ultrahigh molecular weight polyethylene (UHMWPE)/WS2 nanoparticle fibers were prepared by adding WS2 nanoparticles treated by coupling agent in the precursor solution of UHMWPE. The influence of WS2 nanoparticles on the microstructure and properties of UHMWPE fibers was characterized by SEM, TGA, mechanical property measurement and bullet-shock test. The results showed that WS2 nanoparticles can be uniformly dispersed in the UHMWPE fiber. After incorporating of WS2 nanoparticles, UHMWPE fibers became stiffer and tougher than the pristine ones. Particularly, the modulus of the fiber increased from 1203 to 1326cN/dtex. Furthermore, UHMWPE/WSfibers showed an improved thermal stability. 展开更多
关键词 超高分子量聚乙烯纤维 WS2纳米纤维 力学性能测试 防弹材料 UHMWPE 合成 钛酸酯偶联剂 纳米粒子
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Structural, Pasting, and Thermal Properties of Ultra-high Pressure-treated Lotus Seed Starch 被引量:3
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作者 郭泽镔 陈秉彦 +2 位作者 卢旭 曾绍校 郑宝东 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2014年第4期647-653,共7页
Lotus seed starch (15%, w/w) was subjected to ultra-high pressure (UHP) at 500 MPa for 10~60 min. The effects of UHP on the structural, pasting, and thermal properties of starch were investigated using solid-stat... Lotus seed starch (15%, w/w) was subjected to ultra-high pressure (UHP) at 500 MPa for 10~60 min. The effects of UHP on the structural, pasting, and thermal properties of starch were investigated using solid-state 13C CP/MAS NMR, differential scanning calorimetry (DSC), HPSEC-MALLS-RI, and a rapid visco analyzer. The 13C CP/MAS NMR results revealed a reduction in the relative crystallinity and peak intensity of the crystalline state with increasing the UHP time. The molecular weight of native starch was 1.433 × 107 Da, which was higher than that of the UHP-treated starch. Viscograms of UHP-treated starch revealed an increase in paste viscosity, peak time, and pasting temperature and a reduction in breakdown and setback viscosity compared to the native starch. Furthermore, the DSC results showed a reduction in gelatinization temperature and gelatinization enthalpy with increasing the UHP time. 展开更多
关键词 lotus seed Starch ultra-high pressure molecular weights pasting properties thermal properties
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Optimum Combination of Femoral Head Size, Femoral Head Material, and Acetabular Cup Liner’s Highly-Cross-Linked Polyethylene Brand for Hip Implant
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作者 Gladius Lewis Daniel M. Werdofa 《Journal of Biomedical Science and Engineering》 2015年第1期31-39,共9页
Clinical two-dimensional linear wear rate data for acetabular cup liners fabricated using approved brands of highly cross-linked ultra-high-molecular-weight polyethylene, as reported in 39 articles in the literature, ... Clinical two-dimensional linear wear rate data for acetabular cup liners fabricated using approved brands of highly cross-linked ultra-high-molecular-weight polyethylene, as reported in 39 articles in the literature, were analyzed using a statistical technique called response surface methodology. The output was a series comprising16 acceptable combinations of femoral head diameter (HD), femoral head material (HM), and HXLPE brand (PB), each of which would yield the optimum wear rate (herein taken to be a wear rate of practically zero). An example of such a combination is 28- mm-diameter Oxinium? femoral head articulated against an acetabular cup liner fabricated from ReflectionTM HXLPE. The findings in this work may guide an orthopaedic surgeon’s selection of the combination of HD, HM, and PB to use in a primary total hip joint replacement. 展开更多
关键词 highly-Cross-Linked ultra-high molecular-weight polyethylene ACETABULAR Cup Liner Linear Wear
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Investigation of the Low Molecular Weight Thiol Composition in a Metastatic Prostate Cancer Cell Line (LNCaP) by LC-UV-MS and NMR after Labelling with the Ellman Reagent
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作者 Stephen Childs Nicolas Haroune +1 位作者 Lee Williams Michael Gronow 《American Journal of Analytical Chemistry》 2017年第1期1-18,共18页
The low molecular weight thiols present in the deproteinized extract of a prostate cancer cell line (LNCaP-FGC) were analysed after derivatization with the Ellman reagent (ESSE). The mixed disulphides formed (RSSE) we... The low molecular weight thiols present in the deproteinized extract of a prostate cancer cell line (LNCaP-FGC) were analysed after derivatization with the Ellman reagent (ESSE). The mixed disulphides formed (RSSE) were fractionated, characterized and quantified by liquid chromatography on a C-18 column using UV detection. This revealed the presence, in femtomoles per cell, of glutathione (8.30 ± 0.73), cysteine (2.71 ± 0.04) and cysteinylglycine (0.83 ± 0.10), accounting for the bulk of the thiol present. Further analysis of the cell extracts using a novel and sensitive mass spectrometry technique allowed the detection of low level of an additional derivative which was identified as cysteinylglycerate using NMRspectroscopy. 展开更多
关键词 Prostate Cancer Low molecular weight THIOLS THIOL Analysis ultra-high Performance Liquid Chromatography Novel THIOL LC-MS NMR Ellman’s REAGENT
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Compression Molded Ultra High Molecular Weight Polyethylene-Hydroxyapatite-Aluminum Oxide-Carbon Nanotube Hybrid Composites for Hard Tissue Replacement 被引量:8
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作者 Ankur Gupta Garima Tripathi +1 位作者 Debrupa Lahiri Kantesh Balani 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2013年第6期514-522,共9页
Ultra high molecular weight polyethylene (UHMWPE) is widely used for articulating surfaces in total hip and knee replacements. In the present work, UHMWPE based polymer composites were synthesized by synergistic rei... Ultra high molecular weight polyethylene (UHMWPE) is widely used for articulating surfaces in total hip and knee replacements. In the present work, UHMWPE based polymer composites were synthesized by synergistic reinforcing of bioactive hydroxyapatite (HA), bioinert aluminum oxide (Al2O3), and carbon nanotubes (CNTs) using compression molding. Phase and microstructural analysis suggests retention of UHMWPE and reinforcing phases in the compression molded composites. Microstructural analysis elicited variation in densification due to the size effect of the reinforcing particles. The hybrid composites exhibited hardness, elastic modulus and toughness comparable to that of UHMWPE. The interfacial effect of reinforcement phases has evinced the effectiveness of Al2O3 over HA and CNT reinforcements, depicting synergistic enhancement in hardness and elastic modulus. Weak interfacial bonding of polymer matrix with HA and CNT requires utilization of coupling agents to achieve enhanced mechanical properties without deteriorating cytocompatible properties. 展开更多
关键词 Compression molding ultra high molecular weight polyethylene (UHMWPE) HYDROXYAPATITE Aluminum oxide (AI2O3) Carbon nanotubes (CNTs) Nanoindcntation
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无孔双向拉伸超高分子量聚乙烯薄膜的成型工艺及性能
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作者 王荣勇 李景波 刘小超 《工程塑料应用》 北大核心 2025年第3期96-103,共8页
采用薄膜双向拉伸试验机制备了无孔双向拉伸超高分子量聚乙烯(PE-UHMW)薄膜,探究了双向拉伸PEUHMW薄膜的成型工艺,研究了双向拉伸工艺参数对双向拉伸PE-UHMW薄膜晶体结构、力学性能以及光学性能的影响。结果表明,当拉伸速率达到200%/s... 采用薄膜双向拉伸试验机制备了无孔双向拉伸超高分子量聚乙烯(PE-UHMW)薄膜,探究了双向拉伸PEUHMW薄膜的成型工艺,研究了双向拉伸工艺参数对双向拉伸PE-UHMW薄膜晶体结构、力学性能以及光学性能的影响。结果表明,当拉伸速率达到200%/s或者拉伸比大于3×3时,有助于PE-UHMW薄膜中串晶结构的形成。双向拉伸PE-UHMW薄膜中仅有正交晶存在,双向拉伸可以显著减小薄膜的晶粒尺寸。双向拉伸对PE-UHMW薄膜的力学性能影响显著,随着拉伸速率以及拉伸比的增大,薄膜的拉伸强度也随之增大,当薄膜中出现串晶结构后薄膜拉伸强度增大更加明显,拉伸比为6×6的薄膜在纵向与横向的拉伸强度分别达到了201.7 MPa与183.7 MPa,相比未拉伸前提高了4.56倍和3.69倍。薄膜的耐穿刺强度随着薄膜拉伸比的增大而增大,拉伸比为6×6的薄膜耐穿刺强度达到了623.3 N/mm,是未拉伸前的9.7倍。拉伸比达到3×3后,薄膜透光率稳定在93%左右,而薄膜的雾度受晶粒尺寸的影响随着拉伸速率以及拉伸比的增大呈现先减小后增大的趋势。无孔双向拉伸PE-UHMW薄膜具有较高的强度以及良好的透光率,在包装领域具备潜在的应用前景。 展开更多
关键词 超高分子量聚乙烯薄膜 双向拉伸 晶体结构 力学性能 光学性能
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Improving the Stab-Resistance Performance of Ultra High Molecular Weight Polyethylene Fabric Intercalated with Nano-Silica-Fluid 被引量:2
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作者 顾隽 黄献聪 +3 位作者 李焱 王新灵 施楣梧 郑震 《Journal of Shanghai Jiaotong university(Science)》 EI 2014年第1期102-109,共8页
High performance fibers impregnated by shear thickening fluids(STFs) have been recognized as a kind of latent stab-resistant materials. In our work, the rheological properties of various nano-silica particles in diffi... High performance fibers impregnated by shear thickening fluids(STFs) have been recognized as a kind of latent stab-resistant materials. In our work, the rheological properties of various nano-silica particles in diffierent carriers were first investigated, some of which showed the typical characteristic of shear thickening phenomena.And then, the effiects of add-on and surface hydrophilicity of silica particles, the type and concentration of the carriers were discussed in detail. It was found that the systems of hydrophilic silica in ethylene glycol, butylenes glycol and polyethylene glycol(PEG) demonstrated shear thickening; moreover, the reversibility of rheological behaviors of hydrophilic silica-PEG300 suspensions indicated energy dissipation existed within a circulation of shear stress. Furthermore, the detail mechanism of STF based nano-silica particles was explored and a process diagram was presented. Finally, the stab-resistance and morphology of cutting edge of ultra high molecular weight polyethylene(UHMWPE) fabric impregnated STF composites were investigated and the results were analyzed.The higher silica add-on was benefit to the improvement of the stab resistance of the composites. 展开更多
关键词 nanoparticle ultra high molecular weight polyethylene(UHMWPE) composite shear thickening stab-resistance
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缠结度对超高相对分子质量聚乙烯凝聚态结构和冲击强度的影响
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作者 宋新月 胡本旻 +5 位作者 孟帅 石恒冲 施德安 王兆阳 杨华伟 栾世方 《应用化学》 北大核心 2025年第1期58-68,共11页
以实验室合成的低缠结超高相对分子质量聚乙烯(UHMWPE)及11种商用UHMWPE树脂为实验对象,系统探究了熔体缠结度(G_(N)^(t))对UHMWPE凝聚态结构的影响,并将之与冲击强度进行了关联。实验结果表明,缠结度增加,结晶度(X_(m))变化较小,结晶... 以实验室合成的低缠结超高相对分子质量聚乙烯(UHMWPE)及11种商用UHMWPE树脂为实验对象,系统探究了熔体缠结度(G_(N)^(t))对UHMWPE凝聚态结构的影响,并将之与冲击强度进行了关联。实验结果表明,缠结度增加,结晶度(X_(m))变化较小,结晶活化能(?E)先减小后增大;在凝聚态结构上,片晶长周期(l)随缠结度的变化表现出与结晶活化能类似的现象。在缠结度较高的区域,l与缠结度具有指数相关性,缠结度越高,片晶厚度越大;最后,将凝聚态结构与冲击强度进行关联,发现UHMWPE的缺口冲击强度与非晶区厚度表现出负线性相关性,线性拟合系数达0.94,即非晶区厚度越小,UHMWPE冲击强度越高。 展开更多
关键词 超高相对分子质量聚乙烯 分子链缠结 长周期 凝聚态结构 冲击强度
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超高分子量聚乙烯纤维表面改性及其与水性聚氨酯复合粘接性能的研究
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作者 张虹 王贵 +3 位作者 李晓明 李佳辉 邢凌新 裴克梅 《中国胶粘剂》 2025年第1期27-32,共6页
对纤维进行表面改性处理是解决超高分子量聚乙烯(UHMWPE)纤维表面活性较低以及粘接性能问题的重要方法。为解决单独一种改性方法的不足,本研究采用液相氧化法(高锰酸钾法、氢氧化钠法和过氧化氢法)、等离子体处理法以及两者相结合的方... 对纤维进行表面改性处理是解决超高分子量聚乙烯(UHMWPE)纤维表面活性较低以及粘接性能问题的重要方法。为解决单独一种改性方法的不足,本研究采用液相氧化法(高锰酸钾法、氢氧化钠法和过氧化氢法)、等离子体处理法以及两者相结合的方法来对UHMWPE纤维布进行表面改性处理,研究了改性前后纤维的表面分子结构特征、外观形貌以及与水性聚氨酯树脂之间的粘接性能。研究结果表明:(1)通过对比不同液相氧化处理、不同处理时间的峰值载荷和180°剥离强度,可以看出高锰酸钾溶液处理24 h的改性效果相对最好(180°剥离强度最高可达1.28 N/mm,峰值载荷最高可达32.831 N)。这从FT-IR谱图的有关吸收峰得到明显加强以及SEM图的表面粗糙度明显增加可以得到印证。(2)对未处理的UHMWPE纤维布试样条进行等离子体处理,经180 s等离子体处理改性后,180°剥离强度最高可达到1.01 N/mm,峰值载荷最高可达到26.439 N,说明等离子体处理可以明显提升UHMWPE纤维布的表面粘接性能。但过度处理,表面粘接性能会因为形成致密的交联层而下降。(3)经过高锰酸钾液相氧化处理和等离子体共同处理后,180°剥离强度最高可达到2.12 N/mm,峰值载荷最高可达到53.087 N。改性处理后的剥离强度较改性前提高了4倍多,峰值载荷提高了近4倍。高锰酸钾溶液和等离子体共同改性后纤维表面的极性基团和粗糙度明显增加,有效提高纤维与水性聚氨酯基体的粘接性能。 展开更多
关键词 超高分子量聚乙烯纤维 表面改性 水性聚氨酯 粘接
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超高相对分子质量聚乙烯熔融纺丝及其改性研究进展
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作者 成晓燕 马海燕 徐锦锦 《合成纤维工业》 2025年第1期79-83,共5页
介绍了超高相对分子质量聚乙烯(UHMWPE)加工特性和UHMWPE纤维的制备方法,并综述了UHMWPE的改性方法。UHMWPE纤维的制备方法包括冻胶纺丝法和熔融纺丝法。采用冻胶纺丝法制备高强度UHMWPE纤维,存在溶剂污染、工艺流程长、成本高等问题。... 介绍了超高相对分子质量聚乙烯(UHMWPE)加工特性和UHMWPE纤维的制备方法,并综述了UHMWPE的改性方法。UHMWPE纤维的制备方法包括冻胶纺丝法和熔融纺丝法。采用冻胶纺丝法制备高强度UHMWPE纤维,存在溶剂污染、工艺流程长、成本高等问题。采用熔融纺丝法制备中高强度UHMWPE纤维,由于UHMWPE分子链高度缠结,热运动困难,熔体黏度大,流动性差,在熔融纺丝过程中容易发生熔体破裂。UHMWPE的改性方法包括润滑剂改性、共混改性、填料改性等,这些改性方法可提高UHMWPE的流动性,减少熔体破裂现象,使UHMWPE可进行熔融纺丝,但会导致UHMWPE纤维的力学性能下降。指出未来UHMWPE熔融纺丝的研究方向为寻找合适的润滑剂、共混剂及纳米粒子填料,通过多种改性方式联用,在提高UHMWPE流动性能的同时减少助剂对纤维力学性能的影响。 展开更多
关键词 超高分子量聚乙烯 熔融纺丝 流动性 改性 力学性能
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基于FEM-SPH耦合算法的子弹侵彻复合装甲数值模拟
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作者 李福强 史彦飞 +2 位作者 黄敬如 刘润华 赵亮 《兵工自动化》 北大核心 2025年第2期74-78,共5页
为研究7.62 mm穿甲子弹对陶瓷/芳纶/超高分子量聚乙烯(ultra-high molecular weight polyethylene,PE-UHMW)复合装甲的毁伤效应,对子弹侵彻复合装甲问题进行模拟研究。通过分析毁伤效应中陶瓷锥的形成、裂纹扩展和破碎飞溅过程,分析弹... 为研究7.62 mm穿甲子弹对陶瓷/芳纶/超高分子量聚乙烯(ultra-high molecular weight polyethylene,PE-UHMW)复合装甲的毁伤效应,对子弹侵彻复合装甲问题进行模拟研究。通过分析毁伤效应中陶瓷锥的形成、裂纹扩展和破碎飞溅过程,分析弹体对芳纶和PE-UHMW的破坏模式,并研究不同的弹速对复合装甲毁伤效能的影响规律。结果表明:FEM-SPH耦合算法可很好地模拟弹体侵彻陶瓷/芳纶/PE-UHMW复合装甲的过程;在弹速小于弹道极限时,复合装甲吸能和背板最大变形值都随着弹速的增大而增大;当弹速大于弹道极限时,复合装甲吸能增加的速率开始下降。 展开更多
关键词 陶瓷/芳纶/超高分子量聚乙烯 复合装甲 FEM-SPH耦合算法 陶瓷锥 毁伤效能
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加工及测试温度对间隔织物增强复合板材力学性能的影响
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作者 李杉杉 田飞 《纺织科技进展》 2025年第1期22-26,43,共6页
为提高复合板材加工效率,研究不同固化温度、不同测试温度下复合板材的性能。以超高分子量聚乙烯长丝为原料织造机织间隔织物,通过泡沫填充、树脂复合制作间隔织物复合板材,在不同的温度下完成树脂固化,探讨固化温度对间隔织物增强复合... 为提高复合板材加工效率,研究不同固化温度、不同测试温度下复合板材的性能。以超高分子量聚乙烯长丝为原料织造机织间隔织物,通过泡沫填充、树脂复合制作间隔织物复合板材,在不同的温度下完成树脂固化,探讨固化温度对间隔织物增强复合板材力学性能的影响,在不同的温度下对复合板材进行力学性能测试,探究测试温度对复合板材的力学性能的影响。结果表明,随着固化温度的升高,完全固化的时间随之降低,但与常温固化力学性能数据差异不显著。在高温下,复合板材的平压性能和弯曲性能没有受到显著影响,但使经纬向侧压性能下降,下降幅度分别高达69.59%和60.08%,经纬向平均下降幅度为64.84%;在低温下,复合板材的平压性能、经纬向侧压性能没有受到显著影响,但使弯曲性能大幅提高,提高幅度达61.67%。 展开更多
关键词 超高分子量聚乙烯 间隔织物 复合板材 加工温度 力学性能
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