The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic ...The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic frameworks(MOFs)are ideal self-sacrificing templates for the construction of carbon-based EMW absorbers.In this work,bimetallic FeMn-MOF-derived MnFe_(2)O_(4)/C/graphene composites were fabricated via a two-step route of solvothermal reaction and the following pyrolysis treatment.The results re-veal the evolution of the microscopic morphology of carbon skeletons from loofah-like to octahedral and then to polyhedron and pomegran-ate after the adjustment of the Fe^(3+)to Mn^(2+)molar ratio.Furthermore,at the Fe^(3+)to Mn^(2+)molar ratio of 2:1,the obtained MnFe_(2)O_(4)/C/graphene composite exhibited the highest EMW absorption capacity.Specifically,a minimum reflection loss of-72.7 dB and a max-imum effective absorption bandwidth of 5.1 GHz were achieved at a low filling ratio of 10wt%.In addition,the possible EMW absorp-tion mechanism of MnFe_(2)O_(4)/C/graphene composites was proposed.Therefore,the results of this work will contribute to the construction of broadband and efficient carbon-based EMW absorbers derived from MOFs.展开更多
To improve the catalytic performance of La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3)(LSCF)towards carbon soot,we utilized the impregnation method to incorporate Ag into the prepared LSCF catalyst.We conducted a series of cha...To improve the catalytic performance of La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3)(LSCF)towards carbon soot,we utilized the impregnation method to incorporate Ag into the prepared LSCF catalyst.We conducted a series of characterization tests and evaluated the soot catalytic activity of the composite catalyst by comparing it with the LaCoO_(3) group,LaFeO_(3) group,and catalyst-free group.The results indicate that the Ag-LSCF composite catalyst exhibits the highest soot catalytic activity,with the characteristic temperature values of 376.3,431.1,and 473.9℃at 10%,50%,and 90%carbon soot conversion,respectively.These values are 24.8,20.2,and 23.1℃lower than those of the LSCF group.This also shows that LSCF can improve the catalytic activity of soot after compounding with Ag,and reflects the necessity of using catalysts in soot combustion reaction.XPS characterization and BET test show that Ag-LSCF has more abundant surface-adsorbed oxygen species,larger specific surface area and pore volume than LSCF,which also proves that Ag-LSCF has higher soot catalytic activity.展开更多
With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite h...With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.展开更多
To address the limitations of contemporary lithium-ion batteries,particularly their low energy density and safety concerns,all-solid-state lithium batteries equipped with solid-state electrolytes have been identified ...To address the limitations of contemporary lithium-ion batteries,particularly their low energy density and safety concerns,all-solid-state lithium batteries equipped with solid-state electrolytes have been identified as an up-and-coming alternative.Among the various SEs,organic–inorganic composite solid electrolytes(OICSEs)that combine the advantages of both polymer and inorganic materials demonstrate promising potential for large-scale applications.However,OICSEs still face many challenges in practical applications,such as low ionic conductivity and poor interfacial stability,which severely limit their applications.This review provides a comprehensive overview of recent research advancements in OICSEs.Specifically,the influence of inorganic fillers on the main functional parameters of OICSEs,including ionic conductivity,Li+transfer number,mechanical strength,electrochemical stability,electronic conductivity,and thermal stability are systematically discussed.The lithium-ion conduction mechanism of OICSE is thoroughly analyzed and concluded from the microscopic perspective.Besides,the classic inorganic filler types,including both inert and active fillers,are categorized with special emphasis on the relationship between inorganic filler structure design and the electrochemical performance of OICSEs.Finally,the advanced characterization techniques relevant to OICSEs are summarized,and the challenges and perspectives on the future development of OICSEs are also highlighted for constructing superior ASSLBs.展开更多
In this manuscript,we propose an analytical equivalent linear viscoelastic constitutive model for fiber-reinforced composites,bypassing general computational homogenization.The method is based on the reduced-order hom...In this manuscript,we propose an analytical equivalent linear viscoelastic constitutive model for fiber-reinforced composites,bypassing general computational homogenization.The method is based on the reduced-order homogenization(ROH)approach.The ROH method typically involves solving multiple finite element problems under periodic conditions to evaluate elastic strain and eigenstrain influence functions in an‘off-line’stage,which offers substantial cost savings compared to direct computational homogenization methods.Due to the unique structure of the fibrous unit cell,“off-line”stage calculation can be eliminated by influence functions obtained analytically.Introducing the standard solid model to the ROH method enables the creation of a comprehensive analytical homogeneous viscoelastic constitutive model.This method treats fibrous composite materials as homogeneous,anisotropic viscoelastic materials,significantly reducing computational time due to its analytical nature.This approach also enables precise determination of a homogenized anisotropic relaxation modulus and accurate capture of various viscoelastic responses under different loading conditions.Three sets of numerical examples,including unit cell tests,three-point beam bending tests,and torsion tests,are given to demonstrate the predictive performance of the homogenized viscoelastic model.Furthermore,the model is validated against experimental measurements,confirming its accuracy and reliability.展开更多
For the first time,the linear and nonlinear vibrations of composite rectangular sandwich plates with various geometric patterns of lattice core have been analytically examined in this work.The plate comprises a lattic...For the first time,the linear and nonlinear vibrations of composite rectangular sandwich plates with various geometric patterns of lattice core have been analytically examined in this work.The plate comprises a lattice core located in the middle and several homogeneous orthotropic layers that are symmetrical relative to it.For this purpose,the partial differential equations of motion have been derived based on the first-order shear deformation theory,employing Hamilton’s principle and Von Kármán’s nonlinear displacement-strain relations.Then,the nonlinear partial differential equations of the plate are converted into a time-dependent nonlinear ordinary differential equation(Duffing equation)by applying the Galerkin method.From the solution of this equation,the natural frequencies are extracted.Then,to calculate the non-linear frequencies of the plate,the non-linear equation of the plate has been solved analytically using the method of multiple scales.Finally,the effect of some critical parameters of the system,such as the thickness,height,and different angles of the stiffeners on the linear and nonlinear frequencies,has been analyzed in detail.To confirmthe solution method,the results of this research have been compared with the reported results in the literature and finite elements in ABAQUS,and a perfect match is observed.The results reveal that the geometry and configuration of core ribs strongly affect the natural frequencies of the plate.展开更多
Continuous carbon fiber reinforced silicon carbide(C/SiC)composites are often subjected to low-velocity impacts when utilized as structural materials for thermal protection.However,research on in-plane impact damage a...Continuous carbon fiber reinforced silicon carbide(C/SiC)composites are often subjected to low-velocity impacts when utilized as structural materials for thermal protection.However,research on in-plane impact damage and multiple impact damage of C/SiC composites is limited.To investigate the in-plane impact damage behavior of C/SiC composites,a drop-weight impact test method was developed for strip samples,and these results were subsequently compared with those of C/SiC composite plates.Results show that the in-plane impact behavior of C/SiC strip samples is similar to that of C/SiC composite plates.Variation of the impact load with displacement is characterized by three stages:a nearly linear stage,a severe load drop stage,and a rebound stage where displacement occurs after the impact energy exceeds its peak value.Impact damage behavior under single and multiple impacts on 2D plain and 3D needled C/SiC composites was investigated at different impact energies and durations.Crack propagation in C/SiC composites was studied by computerized tomography(CT)technique.In the 2D plain C/SiC composite,load propagation between layers is hindered during impact,leading to delamination and 90°fiber brittle fracture.The crack length perpendicular to the impact direction increases with impact energy increases,resulting in more serious 0°fiber fracture and a larger area of fiber loss.In the 3D needled C/SiC composite,load propagates between the layers during impact through the connection of needled fibers.The fibers continue to provide substantial structural support,with notable instances of fiber pull-off and debonding.Consequently,the impact resistance is superior to that of 2D plain C/SiC composite.When the 3D needled C/SiC composite undergoes two successive impacts of 1.5 J,the energy absorption efficiency of the second impact is significantly lower,accompanied by a smaller impact displacement.Moreover,the total energy absorption efficiency of these two impacts of 1.5 J is lower than that of a single 3.0 J impact.展开更多
This study aimed to investigate the moment redistribution in continuous glass fiber reinforced polymer(GFRP)-concrete composite slabs caused by concrete cracking and steel bar yielding in the negative bending moment z...This study aimed to investigate the moment redistribution in continuous glass fiber reinforced polymer(GFRP)-concrete composite slabs caused by concrete cracking and steel bar yielding in the negative bending moment zone.An experimental bending moment redistribution test was conducted on continuous GFRP-concrete composite slabs,and a calculation method based on the conjugate beam method was proposed.The composite slabs were formed by combining GFRP profiles with a concrete layer and supported on steel beams to create two-span continuous composite slab specimens.Two methods,epoxy resin bonding,and stud connection,were used to connect the composite slabs with the steel beams.The experimental findings showed that the specimen connected with epoxy resin exhibited two moments redistribution phenomena during the loading process:concrete cracking and steel bar yielding at the internal support.In contrast,the composite slab connected with steel beams by studs exhibited only one-moment redistribution phenomenon throughout the loading process.As the concrete at the internal support cracked,the bending moment decreased in the internal support section and increased in the midspan section.When the steel bars yielded,the bending moment further decreased in the internal support section and increased in the mid-span section.Since GFRP profiles do not experience cracking,there was no significant decrease in the bending moment of the mid-span section.All test specimens experienced compressive failure of concrete at the mid-span section.Calculation results showed good agreement between the calculated and experimental values of bending moments in the mid-span section and internal support section.The proposed model can effectively predict the moment redistribution behavior of continuous GFRP-concrete composite slabs.展开更多
The mechanical, physical and thermal characterization of a composite made from woven raffia fiber vinifiera molded in epoxy resin intended for shipbuilding shows that the density (0.5 g/cm3 with a relative error of 0....The mechanical, physical and thermal characterization of a composite made from woven raffia fiber vinifiera molded in epoxy resin intended for shipbuilding shows that the density (0.5 g/cm3 with a relative error of 0.05 g/cm3) of the composite produced is lower than that of wood used in this field. The material has low porosity (9.8%) and is less absorbent (12.61%) than wood. The result of the thermal conductivity test by the hot plane method shows that this composite can contribute to the internal thermal insulation (an example of thermal conductivity is 0.32W/m.K) of floating boats. The mechanical tests of compression (young modulus is 22.86 GPa), resilience (1.238 J/Cm2) and hardness (233.04 BH30-2.5/187.5-15s) show that this composite is much harder and more absorbent than many wood and bio-composite materials used in the construction of pleasure boats. The abrasion test (0.005349) shows that this composite could well resist friction with the beach.展开更多
Mullite-silica rich glass(MSRG)composites are a more efficient material than chamotte for industrial utilization of clay in refractory applications.The properties of the MSRG composites depend on the amount and compos...Mullite-silica rich glass(MSRG)composites are a more efficient material than chamotte for industrial utilization of clay in refractory applications.The properties of the MSRG composites depend on the amount and composition of the mulite and glass phases,which are related to the chemical composition of the MSRG composites based on clay.In the present work,the relationship between the phase and the chemical composition of the MSRG composites,and the effects of the chemical composition of the glass phase on the viscosity and coefficient of thermal expansion(CTE)of the glass phase were discussed on the basis of the measurements on 17 MSRG composite samples produced from clay.It is found that the Al_(2)O_(3)/SiO_(2) ratio(AS ratio)in clay strongly affects the amount of the mullite and glass phases in the MSRG composites,and the distributions of SiO_(2),TiO_(2)and Al_(2)O_(3) contents in the mullite and glass phases.With the increase of the A/S ratio of clay,the mullite content increases but the the glass phase content decreases in the MSRG composites.The viscosity and CTE of the glass phase depend on its A/S ratio and the amount of impurity oxides.When the A/S ratio in the glass phase is less than 0.15,the viscosity of the liquid formed by the melting of the glass phase at elevated temperatures rapidly increases with the decrease in the A/S ratio.The CTE of the glass phase depends on the contents of Si0_(2)and(K_(2)O+Na_(2)O).展开更多
Currently,there are a limited number of dynamic models available for braided composite plates with large overall motions,despite the incorporation of three-dimensional(3D)braided composites into rotating blade compone...Currently,there are a limited number of dynamic models available for braided composite plates with large overall motions,despite the incorporation of three-dimensional(3D)braided composites into rotating blade components.In this paper,a dynamic model of 3D 4-directional braided composite thin plates considering braiding directions is established.Based on Kirchhoff's plate assumptions,the displacement variables of the plate are expressed.By incorporating the braiding directions into the constitutive equation of the braided composites,the dynamic model of the plate considering braiding directions is obtained.The effects of the speeds,braiding directions,and braided angles on the responses of the plate with fixed-axis rotation and translational motion,respectively,are investigated.This paper presents a dynamic theory for calculating the deformation of 3D braided composite structures undergoing both translational and rotational motions.It also provides a simulation method for investigating the dynamic behavior of non-isotropic material plates in various applications.展开更多
Fe(Al,Ta)/Fe_(2)Ta(Al)eutectic composites with solidification rates of 6,20,30,and 80μm/s were prepared by a modified Bridgman directional solidification technology.The coarse Fe_(2)Ta(Al)Laves phase was precipitated...Fe(Al,Ta)/Fe_(2)Ta(Al)eutectic composites with solidification rates of 6,20,30,and 80μm/s were prepared by a modified Bridgman directional solidification technology.The coarse Fe_(2)Ta(Al)Laves phase was precipitated at the eutectic colony boundary during the solidification process,which can affect the stability of microstructure and properties of the composites.The coarse Laves phase was refined using different heat treatment processes in the present paper.The influences of different heat treatment parameters on the Laves phase content,lamella/rod spacing,and mechanical properties were investigated in detail.In addition,the corrosion behaviors of Fe(Al,Ta)/Fe_(2)Ta(Al)eutectic composites before and after being annealed heat treatment in a 3 g/L Na_(2)S_(2)O_(3)solution were also studied.It is shown that both the content of Laves phase and lamella/rod spacing are gradually decreased after heat treatment.Micro-hardness is decreased,while the yield strength,compressive strength,and corrosion resistance are improved.The optimum heat treatment process is selected as well.展开更多
The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several...The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several composite structure models,including a concrete lining structure(CLS)without foam geopolymer and six foam geopolymer composite structures(FGCS)with different backfill parameters,to study the dynamic response and wave dissipation mechanisms of FGCS under explosive loading.Pressure,strain,and vibration responses at different locations were synchronously tested.The damage modes and dynamic responses of different models were compared,and how wave elimination and energy absorption efficiencies were affected by foam geopolymer backfill parameters was analyzed.The results showed that the foam geopolymer absorbed and dissipated the impact energy through continuous compressive deformation under high strain rates and dynamic loading,reducing the strain in the liner structure by 52%and increasing the pressure attenuation rate by 28%.Additionally,the foam geopolymer backfill reduced structural vibration and liner deformation,with the FGCS structure showing 35%less displacement and 70%less acceleration compared to the CLS.The FGCS model with thicker,less dense foam geopolymer backfill,having more pores and higher porosity,demonstrated better compression and energy absorption under dynamic impact,increasing stress wave attenuation efficiency.By analyzing the stress wave propagation and the compression characteristics of the porous medium,it was concluded that the stress transfer ratio of FGCS-ρ-579 was 77%lower than that of CLS,and the transmitted wave energy was 90%lower.The results of this study provide a scientific basis for optimizing underground composite structure interlayer parameters.展开更多
The development of high-performance functional composites has become a research hotspot in response to the hazards of over-heating and electromagnetic radiation in modern electronic devices.Herein,we grew magnetic Fe_...The development of high-performance functional composites has become a research hotspot in response to the hazards of over-heating and electromagnetic radiation in modern electronic devices.Herein,we grew magnetic Fe_(3)O_(4)particles in situ on the MXene layer to obtain an MXene@Fe_(3)O_(4)composite with rich heterogeneous interfaces.Owing to the unique heterostructure and the synergistic effects of multiple electromagnetic wave absorption mechanisms,the composite achieved a minimum reflection loss of-27.14 dB and an effect-ive absorption bandwidth of 2.05 GHz at an absorption thickness of 2 mm.Moreover,the MXene@Fe_(3)O_(4)composite could be encapsu-lated in thermoplastic polyurethane(TPU)via thermal curing.The obtained composite elastomer exhibited a strong tensile strength,and its thermal diffusivity was 113%higher than that of pure TPU.Such additional mechanical properties and thermal conduction features render this composite elastomer an advanced electromagnetic absorber to adapt to the ever-changing environment for expanding practical applications.展开更多
The use of ultra-high molecular weight polyethylene(UHMWPE)composite in the design of lightweight protective equipment,has gained a lot of interest.However,there is an urgent need to understand the ballistic response ...The use of ultra-high molecular weight polyethylene(UHMWPE)composite in the design of lightweight protective equipment,has gained a lot of interest.However,there is an urgent need to understand the ballistic response mechanism and theoretical prediction model of performance.This paper explores the ballistic response mechanism of UHMWPE composite through experimental and simulation analyses.Then,a resistance-driven modeling method was proposed to establish a theoretical model for predicting the bulletproof performance.The ballistic response mechanism of UHMWPE composite encompassed three fundamental modes:local response,structural response,and coupled response.The occurrence ratio of these fundamental response modes during impact was dependent on the projectile velocity and laminate thickness.The bulletproof performance of laminate under different response modes was assessed based on the penetration depth of the projectile,the bulging height on the rear face of the laminate,the thickness of remaining sub-laminate,and residual velocity of the projectile.The absolute deviations of bulletproof performance indicator between theoretical value and experimental value were well within 11.13%,demonstrating that the established evaluation model possessed high degree of prediction accuracy.展开更多
In this paper,a type of reinforcing structure for composite shell with single and through hole is presented.The experimental tests for the composite shells without hole,with single hole and reinforced structure,with t...In this paper,a type of reinforcing structure for composite shell with single and through hole is presented.The experimental tests for the composite shells without hole,with single hole and reinforced structure,with through hole and reinforced structure subjected to hydrostatic pressure were carried out by the designed experimental test system.The mechanical responses of the composite shells under hydrostatic pressure are obtained by the high-speed camera and strain measurement.The results show that the entire deformation process of the shell can be divided into three:uniform compression,"buckling mode formation"and buckling.The"buckling mode formation"process is captured and reported for the first time.For the composite shell with single hole,the proposed reinforcing structure has a significant reinforcement effect on the shell and the buckling capacity of the shell is not weaker than the complete composite shell.For the composite shell with through hole,sealing effect can be achieved by the proposed reinforcing structure,but the buckling capacity of the shell after reinforcement can only reach 77%of the original buckling capacity.展开更多
Carbon nanotubes(CNTs)have garnered great attention in recent years due to their outstanding electrical,thermal,and mechanical properties.The incorporation of small amounts of CNTs in polymers can substantially improv...Carbon nanotubes(CNTs)have garnered great attention in recent years due to their outstanding electrical,thermal,and mechanical properties.The incorporation of small amounts of CNTs in polymers can substantially improve the sensitivity of the polymer's electrical conductivity.This paper presents a modified Maxwell model to evaluate the electrical conductivity of CNTs-filled polymer composites by introducing a transition zone to account for the tunneling effect.In this modified Maxwell model,the CNTs-filled polymer composite is modeled as a three-phase composite,consisting of a matrix(polymer),inclusions(CNTs),and a transition zone(tunneling zone).The effective electrical conductivity(EEC)of the composite is calculated based on the volume fractions and electrical conductivities of the matrix,inclusions,and transition zone.The model's validity is confirmed through the use of available test data,which demonstrates its capability to accurately capture the nonlinear conductivity behavior observed in CNTs-polymer composites.This study offers valuable insights into the design of high-performance conductive polymer nanocomposites,and enhances the understanding of electrical conduction mechanisms in CNT-dispersed polymer composites.展开更多
The aluminum(Al)/steel transition joints used in ships are processed from composite plates,and their mechanical properties have a significant impact on the safety of ships.In this paper,the Al/steel composite plate wa...The aluminum(Al)/steel transition joints used in ships are processed from composite plates,and their mechanical properties have a significant impact on the safety of ships.In this paper,the Al/steel composite plate was prepared using rolling,with 5083 aluminum plate as the cladding plate,Q235 steel plate as the substrate,and TA1 titanium(Ti)plate and DT4 pure iron(Fe)plate as the intermediate layers.The heterothermic billet was prepared through induction heating by the magnetic effects of the steel plate and the pure Fe plate,and then the Al/steel composite plate was obtained by rolling.The impacts of post-rolling cooling process on the microstructure and properties of the Al/Ti/pure Fe/steel composite plate were studied.The results manifested that the pure Fe/steel interface had a good composite effect.With the increase in the cooling rate,the bonding strength of the Al/Ti interface was raised,and that of the Ti/Fe interface was increased first and then decreased.When the oil cooling process was adopted,the Al/Ti/pure Fe/steel composite plate exhibited the highest comprehensive performance.The shear strength of the Al/Ti interface and the Ti/Fe interface was 102 MPa and 186 MPa,respectively.The plastic fracture was determined as the mode of interface fracture.展开更多
BACKGROUND Due to saliva and salivary glands are reservoir to severe acute respiratory syndrome-coronavirus 2(SARS-CoV-2),aerosols and saliva droplets are primary sources of cross-infection and are responsible for the...BACKGROUND Due to saliva and salivary glands are reservoir to severe acute respiratory syndrome-coronavirus 2(SARS-CoV-2),aerosols and saliva droplets are primary sources of cross-infection and are responsible for the high human–human transmission of SARS-CoV-2.However,there is no evidence about how SARSCoV-2 interacts with oral structures,particularly resin composites.AIM To evaluate the interaction of SARS-CoV-2 proteins with monomers present in resin composites using in silico analysis.METHODS Four SARS-CoV-2 proteins[i.e.main protease,3C-like protease,papain-like protease(PLpro),and glycoprotein spike]were selected along with salivary amylase as the positive control,and their binding affinity with bisphenol-A glycol dimethacrylate,bisphenol-A ethoxylated dimethacrylate,triethylene glycol dimethacrylate,and urethane dimethacrylate was evaluated.Molecular docking was performed using AutoDock Vina and visualised in Chimera UCSF 1.14.The best ligand–protein model was identified based on the binding energy(ΔG–kcal/moL).RESULTS Values for the binding energies ranged from-3.6 kcal/moL to-7.3 kcal/moL.The 3-monomer chain had the lowest binding energy(i.e.highest affinity)to PLpro and the glycoprotein spike.Non-polymerised monomers and polymerised chains interacted with SARS-CoV-2 proteins via hydrogen bonds and hydrophobic interactions.Those findings suggest an interaction between SARS-CoV-2 proteins and resin composites.CONCLUSION SARS-CoV-2 proteins show affinity to non-polymerised and polymerised resin composite chains.展开更多
B2-CuZr phase reinforced amorphous alloy matrix composites has become one of the research hotspots in the field of materials science due to the“transformation-induced plasticity”phenomenon,which makes the composites...B2-CuZr phase reinforced amorphous alloy matrix composites has become one of the research hotspots in the field of materials science due to the“transformation-induced plasticity”phenomenon,which makes the composites show better macroscopic plastic deformability and obvious work-hardening behavior compared to the conventional amorphous alloy matrix composites reinforced with ductile phases.However,the in-situ metastable B2-CuZr phase tends to undergo eutectoid decomposition during solidification,and the volume fraction,size,and distribution of B2-CuZr phase are difficult to control,which limits the development and application of these materials.To date,much efforts have been made to solve the above problems through composition optimization,casting parameter tailoring,and post-processing technique.In this study,a review was given based on relevant studies,focusing on the predictive approach,reinforcing mechanism,and microstructure tailoring methods of B2-CuZr phase reinforced amorphous alloy matrix composites.The research focus and future prospects were also given for the future development of the present composite system.展开更多
基金supported by the Natural Science Research Project of the Anhui Educational Committee,China(No.2022AH050827)the Open Research Fund Program of Anhui Province Key Laboratory of Specialty Polymers,Anhui University of Science and Technology,China(No.AHKLSP23-12)the Joint National-Local Engineering Research Center for Safe and Precise Coal Mining Fund,China(No.EC2022020)。
文摘The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic frameworks(MOFs)are ideal self-sacrificing templates for the construction of carbon-based EMW absorbers.In this work,bimetallic FeMn-MOF-derived MnFe_(2)O_(4)/C/graphene composites were fabricated via a two-step route of solvothermal reaction and the following pyrolysis treatment.The results re-veal the evolution of the microscopic morphology of carbon skeletons from loofah-like to octahedral and then to polyhedron and pomegran-ate after the adjustment of the Fe^(3+)to Mn^(2+)molar ratio.Furthermore,at the Fe^(3+)to Mn^(2+)molar ratio of 2:1,the obtained MnFe_(2)O_(4)/C/graphene composite exhibited the highest EMW absorption capacity.Specifically,a minimum reflection loss of-72.7 dB and a max-imum effective absorption bandwidth of 5.1 GHz were achieved at a low filling ratio of 10wt%.In addition,the possible EMW absorp-tion mechanism of MnFe_(2)O_(4)/C/graphene composites was proposed.Therefore,the results of this work will contribute to the construction of broadband and efficient carbon-based EMW absorbers derived from MOFs.
文摘To improve the catalytic performance of La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3)(LSCF)towards carbon soot,we utilized the impregnation method to incorporate Ag into the prepared LSCF catalyst.We conducted a series of characterization tests and evaluated the soot catalytic activity of the composite catalyst by comparing it with the LaCoO_(3) group,LaFeO_(3) group,and catalyst-free group.The results indicate that the Ag-LSCF composite catalyst exhibits the highest soot catalytic activity,with the characteristic temperature values of 376.3,431.1,and 473.9℃at 10%,50%,and 90%carbon soot conversion,respectively.These values are 24.8,20.2,and 23.1℃lower than those of the LSCF group.This also shows that LSCF can improve the catalytic activity of soot after compounding with Ag,and reflects the necessity of using catalysts in soot combustion reaction.XPS characterization and BET test show that Ag-LSCF has more abundant surface-adsorbed oxygen species,larger specific surface area and pore volume than LSCF,which also proves that Ag-LSCF has higher soot catalytic activity.
基金sponsored by National Natural Science Foundation of China(No.52302121,No.52203386)Shanghai Sailing Program(No.23YF1454700)+1 种基金Shanghai Natural Science Foundation(No.23ZR1472700)Shanghai Post-doctoral Excellent Program(No.2022664).
文摘With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.
基金supported by the National Natural Science Foundation of China(Grant No.22075064,52302234,52272241)Zhejiang Provincial Natural Science Foundation of China under Grant No.LR24E020001+2 种基金Natural Science of Heilongjiang Province(No.LH2023B009)China Postdoctoral Science Foundation(2022M710950)Heilongjiang Postdoctoral Fund(LBH-Z21131),National Key Laboratory Projects(No.SYSKT20230056).
文摘To address the limitations of contemporary lithium-ion batteries,particularly their low energy density and safety concerns,all-solid-state lithium batteries equipped with solid-state electrolytes have been identified as an up-and-coming alternative.Among the various SEs,organic–inorganic composite solid electrolytes(OICSEs)that combine the advantages of both polymer and inorganic materials demonstrate promising potential for large-scale applications.However,OICSEs still face many challenges in practical applications,such as low ionic conductivity and poor interfacial stability,which severely limit their applications.This review provides a comprehensive overview of recent research advancements in OICSEs.Specifically,the influence of inorganic fillers on the main functional parameters of OICSEs,including ionic conductivity,Li+transfer number,mechanical strength,electrochemical stability,electronic conductivity,and thermal stability are systematically discussed.The lithium-ion conduction mechanism of OICSE is thoroughly analyzed and concluded from the microscopic perspective.Besides,the classic inorganic filler types,including both inert and active fillers,are categorized with special emphasis on the relationship between inorganic filler structure design and the electrochemical performance of OICSEs.Finally,the advanced characterization techniques relevant to OICSEs are summarized,and the challenges and perspectives on the future development of OICSEs are also highlighted for constructing superior ASSLBs.
基金support by the National Key R&D Program of China(Grant No.2023YFA1008901)the National Natural Science Foundation of China(Grant Nos.11988102,12172009)is gratefully acknowledged.
文摘In this manuscript,we propose an analytical equivalent linear viscoelastic constitutive model for fiber-reinforced composites,bypassing general computational homogenization.The method is based on the reduced-order homogenization(ROH)approach.The ROH method typically involves solving multiple finite element problems under periodic conditions to evaluate elastic strain and eigenstrain influence functions in an‘off-line’stage,which offers substantial cost savings compared to direct computational homogenization methods.Due to the unique structure of the fibrous unit cell,“off-line”stage calculation can be eliminated by influence functions obtained analytically.Introducing the standard solid model to the ROH method enables the creation of a comprehensive analytical homogeneous viscoelastic constitutive model.This method treats fibrous composite materials as homogeneous,anisotropic viscoelastic materials,significantly reducing computational time due to its analytical nature.This approach also enables precise determination of a homogenized anisotropic relaxation modulus and accurate capture of various viscoelastic responses under different loading conditions.Three sets of numerical examples,including unit cell tests,three-point beam bending tests,and torsion tests,are given to demonstrate the predictive performance of the homogenized viscoelastic model.Furthermore,the model is validated against experimental measurements,confirming its accuracy and reliability.
文摘For the first time,the linear and nonlinear vibrations of composite rectangular sandwich plates with various geometric patterns of lattice core have been analytically examined in this work.The plate comprises a lattice core located in the middle and several homogeneous orthotropic layers that are symmetrical relative to it.For this purpose,the partial differential equations of motion have been derived based on the first-order shear deformation theory,employing Hamilton’s principle and Von Kármán’s nonlinear displacement-strain relations.Then,the nonlinear partial differential equations of the plate are converted into a time-dependent nonlinear ordinary differential equation(Duffing equation)by applying the Galerkin method.From the solution of this equation,the natural frequencies are extracted.Then,to calculate the non-linear frequencies of the plate,the non-linear equation of the plate has been solved analytically using the method of multiple scales.Finally,the effect of some critical parameters of the system,such as the thickness,height,and different angles of the stiffeners on the linear and nonlinear frequencies,has been analyzed in detail.To confirmthe solution method,the results of this research have been compared with the reported results in the literature and finite elements in ABAQUS,and a perfect match is observed.The results reveal that the geometry and configuration of core ribs strongly affect the natural frequencies of the plate.
基金Aeronautical Science Foundation of China(2021Z057053001)。
文摘Continuous carbon fiber reinforced silicon carbide(C/SiC)composites are often subjected to low-velocity impacts when utilized as structural materials for thermal protection.However,research on in-plane impact damage and multiple impact damage of C/SiC composites is limited.To investigate the in-plane impact damage behavior of C/SiC composites,a drop-weight impact test method was developed for strip samples,and these results were subsequently compared with those of C/SiC composite plates.Results show that the in-plane impact behavior of C/SiC strip samples is similar to that of C/SiC composite plates.Variation of the impact load with displacement is characterized by three stages:a nearly linear stage,a severe load drop stage,and a rebound stage where displacement occurs after the impact energy exceeds its peak value.Impact damage behavior under single and multiple impacts on 2D plain and 3D needled C/SiC composites was investigated at different impact energies and durations.Crack propagation in C/SiC composites was studied by computerized tomography(CT)technique.In the 2D plain C/SiC composite,load propagation between layers is hindered during impact,leading to delamination and 90°fiber brittle fracture.The crack length perpendicular to the impact direction increases with impact energy increases,resulting in more serious 0°fiber fracture and a larger area of fiber loss.In the 3D needled C/SiC composite,load propagates between the layers during impact through the connection of needled fibers.The fibers continue to provide substantial structural support,with notable instances of fiber pull-off and debonding.Consequently,the impact resistance is superior to that of 2D plain C/SiC composite.When the 3D needled C/SiC composite undergoes two successive impacts of 1.5 J,the energy absorption efficiency of the second impact is significantly lower,accompanied by a smaller impact displacement.Moreover,the total energy absorption efficiency of these two impacts of 1.5 J is lower than that of a single 3.0 J impact.
基金supported by National Natural Science Foundation of China(Project No.51878156,received by Wen-Wei Wang) and EPC Innovation Consulting Project for Longkou Nanshan LNG Phase I Receiving Terminal(Z2000LGENT0399,received by Wen-Wei Wang and ZhaoJun Zhang).
文摘This study aimed to investigate the moment redistribution in continuous glass fiber reinforced polymer(GFRP)-concrete composite slabs caused by concrete cracking and steel bar yielding in the negative bending moment zone.An experimental bending moment redistribution test was conducted on continuous GFRP-concrete composite slabs,and a calculation method based on the conjugate beam method was proposed.The composite slabs were formed by combining GFRP profiles with a concrete layer and supported on steel beams to create two-span continuous composite slab specimens.Two methods,epoxy resin bonding,and stud connection,were used to connect the composite slabs with the steel beams.The experimental findings showed that the specimen connected with epoxy resin exhibited two moments redistribution phenomena during the loading process:concrete cracking and steel bar yielding at the internal support.In contrast,the composite slab connected with steel beams by studs exhibited only one-moment redistribution phenomenon throughout the loading process.As the concrete at the internal support cracked,the bending moment decreased in the internal support section and increased in the midspan section.When the steel bars yielded,the bending moment further decreased in the internal support section and increased in the mid-span section.Since GFRP profiles do not experience cracking,there was no significant decrease in the bending moment of the mid-span section.All test specimens experienced compressive failure of concrete at the mid-span section.Calculation results showed good agreement between the calculated and experimental values of bending moments in the mid-span section and internal support section.The proposed model can effectively predict the moment redistribution behavior of continuous GFRP-concrete composite slabs.
文摘The mechanical, physical and thermal characterization of a composite made from woven raffia fiber vinifiera molded in epoxy resin intended for shipbuilding shows that the density (0.5 g/cm3 with a relative error of 0.05 g/cm3) of the composite produced is lower than that of wood used in this field. The material has low porosity (9.8%) and is less absorbent (12.61%) than wood. The result of the thermal conductivity test by the hot plane method shows that this composite can contribute to the internal thermal insulation (an example of thermal conductivity is 0.32W/m.K) of floating boats. The mechanical tests of compression (young modulus is 22.86 GPa), resilience (1.238 J/Cm2) and hardness (233.04 BH30-2.5/187.5-15s) show that this composite is much harder and more absorbent than many wood and bio-composite materials used in the construction of pleasure boats. The abrasion test (0.005349) shows that this composite could well resist friction with the beach.
基金Research Project of Hubei Provincial Department of Science and Technology(Grant no.2024CSA075)Key Project of the National Natural Science Foundation of China(Grant No.U21A2058)for fnancially supporting this work.
文摘Mullite-silica rich glass(MSRG)composites are a more efficient material than chamotte for industrial utilization of clay in refractory applications.The properties of the MSRG composites depend on the amount and composition of the mulite and glass phases,which are related to the chemical composition of the MSRG composites based on clay.In the present work,the relationship between the phase and the chemical composition of the MSRG composites,and the effects of the chemical composition of the glass phase on the viscosity and coefficient of thermal expansion(CTE)of the glass phase were discussed on the basis of the measurements on 17 MSRG composite samples produced from clay.It is found that the Al_(2)O_(3)/SiO_(2) ratio(AS ratio)in clay strongly affects the amount of the mullite and glass phases in the MSRG composites,and the distributions of SiO_(2),TiO_(2)and Al_(2)O_(3) contents in the mullite and glass phases.With the increase of the A/S ratio of clay,the mullite content increases but the the glass phase content decreases in the MSRG composites.The viscosity and CTE of the glass phase depend on its A/S ratio and the amount of impurity oxides.When the A/S ratio in the glass phase is less than 0.15,the viscosity of the liquid formed by the melting of the glass phase at elevated temperatures rapidly increases with the decrease in the A/S ratio.The CTE of the glass phase depends on the contents of Si0_(2)and(K_(2)O+Na_(2)O).
基金Project supported by the National Natural Science Foundation of China(Nos.12372071 and 12372070)the Aeronautical Science Fund of China(No.2022Z055052001)the Foundation of China Scholarship Council(No.202306830079)。
文摘Currently,there are a limited number of dynamic models available for braided composite plates with large overall motions,despite the incorporation of three-dimensional(3D)braided composites into rotating blade components.In this paper,a dynamic model of 3D 4-directional braided composite thin plates considering braiding directions is established.Based on Kirchhoff's plate assumptions,the displacement variables of the plate are expressed.By incorporating the braiding directions into the constitutive equation of the braided composites,the dynamic model of the plate considering braiding directions is obtained.The effects of the speeds,braiding directions,and braided angles on the responses of the plate with fixed-axis rotation and translational motion,respectively,are investigated.This paper presents a dynamic theory for calculating the deformation of 3D braided composite structures undergoing both translational and rotational motions.It also provides a simulation method for investigating the dynamic behavior of non-isotropic material plates in various applications.
基金Funded by the Key Industry Innovation Chain(Group)Project of Shaanxi Province,China(No.2019ZDLGY 04-04)the Project of Yulin Science and Technology Bureau(No.2023-CXY-197)。
文摘Fe(Al,Ta)/Fe_(2)Ta(Al)eutectic composites with solidification rates of 6,20,30,and 80μm/s were prepared by a modified Bridgman directional solidification technology.The coarse Fe_(2)Ta(Al)Laves phase was precipitated at the eutectic colony boundary during the solidification process,which can affect the stability of microstructure and properties of the composites.The coarse Laves phase was refined using different heat treatment processes in the present paper.The influences of different heat treatment parameters on the Laves phase content,lamella/rod spacing,and mechanical properties were investigated in detail.In addition,the corrosion behaviors of Fe(Al,Ta)/Fe_(2)Ta(Al)eutectic composites before and after being annealed heat treatment in a 3 g/L Na_(2)S_(2)O_(3)solution were also studied.It is shown that both the content of Laves phase and lamella/rod spacing are gradually decreased after heat treatment.Micro-hardness is decreased,while the yield strength,compressive strength,and corrosion resistance are improved.The optimum heat treatment process is selected as well.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52378401,12202494)the Fundamental Research Funds for the Central Universities(Grant No.30922010918)。
文摘The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several composite structure models,including a concrete lining structure(CLS)without foam geopolymer and six foam geopolymer composite structures(FGCS)with different backfill parameters,to study the dynamic response and wave dissipation mechanisms of FGCS under explosive loading.Pressure,strain,and vibration responses at different locations were synchronously tested.The damage modes and dynamic responses of different models were compared,and how wave elimination and energy absorption efficiencies were affected by foam geopolymer backfill parameters was analyzed.The results showed that the foam geopolymer absorbed and dissipated the impact energy through continuous compressive deformation under high strain rates and dynamic loading,reducing the strain in the liner structure by 52%and increasing the pressure attenuation rate by 28%.Additionally,the foam geopolymer backfill reduced structural vibration and liner deformation,with the FGCS structure showing 35%less displacement and 70%less acceleration compared to the CLS.The FGCS model with thicker,less dense foam geopolymer backfill,having more pores and higher porosity,demonstrated better compression and energy absorption under dynamic impact,increasing stress wave attenuation efficiency.By analyzing the stress wave propagation and the compression characteristics of the porous medium,it was concluded that the stress transfer ratio of FGCS-ρ-579 was 77%lower than that of CLS,and the transmitted wave energy was 90%lower.The results of this study provide a scientific basis for optimizing underground composite structure interlayer parameters.
基金supported by the Zhejiang Provincial Natural Science Foundation of China(No.LQ22E030016)the National Natural Science Foundation of China(No.52275137)+1 种基金the China Postdoctoral Science Foundation(No.2022M722831)the Postdoctoral Research Selected Funding Project of Zhejiang Province,China(No.ZJ2022063).
文摘The development of high-performance functional composites has become a research hotspot in response to the hazards of over-heating and electromagnetic radiation in modern electronic devices.Herein,we grew magnetic Fe_(3)O_(4)particles in situ on the MXene layer to obtain an MXene@Fe_(3)O_(4)composite with rich heterogeneous interfaces.Owing to the unique heterostructure and the synergistic effects of multiple electromagnetic wave absorption mechanisms,the composite achieved a minimum reflection loss of-27.14 dB and an effect-ive absorption bandwidth of 2.05 GHz at an absorption thickness of 2 mm.Moreover,the MXene@Fe_(3)O_(4)composite could be encapsu-lated in thermoplastic polyurethane(TPU)via thermal curing.The obtained composite elastomer exhibited a strong tensile strength,and its thermal diffusivity was 113%higher than that of pure TPU.Such additional mechanical properties and thermal conduction features render this composite elastomer an advanced electromagnetic absorber to adapt to the ever-changing environment for expanding practical applications.
基金supported by the National Key Research and Development of China(Grant No.2022YFB4601901)the National Natural Science Foundation of China(Grant No.12122202)。
文摘The use of ultra-high molecular weight polyethylene(UHMWPE)composite in the design of lightweight protective equipment,has gained a lot of interest.However,there is an urgent need to understand the ballistic response mechanism and theoretical prediction model of performance.This paper explores the ballistic response mechanism of UHMWPE composite through experimental and simulation analyses.Then,a resistance-driven modeling method was proposed to establish a theoretical model for predicting the bulletproof performance.The ballistic response mechanism of UHMWPE composite encompassed three fundamental modes:local response,structural response,and coupled response.The occurrence ratio of these fundamental response modes during impact was dependent on the projectile velocity and laminate thickness.The bulletproof performance of laminate under different response modes was assessed based on the penetration depth of the projectile,the bulging height on the rear face of the laminate,the thickness of remaining sub-laminate,and residual velocity of the projectile.The absolute deviations of bulletproof performance indicator between theoretical value and experimental value were well within 11.13%,demonstrating that the established evaluation model possessed high degree of prediction accuracy.
基金supported by the Ningbo Major Research and Development Plan Project(Grant No.2024Z135)the Natural Science Basic Research Program of Shaanxi Province(Grant No.2024JC-YBMS-322)+1 种基金China Postdoctoral Science Foundation(Grant No.2020M673492)National Natural Science Foundation of China(Grant No.51909219)。
文摘In this paper,a type of reinforcing structure for composite shell with single and through hole is presented.The experimental tests for the composite shells without hole,with single hole and reinforced structure,with through hole and reinforced structure subjected to hydrostatic pressure were carried out by the designed experimental test system.The mechanical responses of the composite shells under hydrostatic pressure are obtained by the high-speed camera and strain measurement.The results show that the entire deformation process of the shell can be divided into three:uniform compression,"buckling mode formation"and buckling.The"buckling mode formation"process is captured and reported for the first time.For the composite shell with single hole,the proposed reinforcing structure has a significant reinforcement effect on the shell and the buckling capacity of the shell is not weaker than the complete composite shell.For the composite shell with through hole,sealing effect can be achieved by the proposed reinforcing structure,but the buckling capacity of the shell after reinforcement can only reach 77%of the original buckling capacity.
基金Project supported by the National Natural Science Foundation of China(Nos.11972203 and 11572162)the Science and Technology Innovation 2025 Major Project of Ningbo City of China(No.2022Z209)Ningbo Key Technology Breakthrough Plan Project of“Science and Technology Innovation Yongjiang 2035”(No.2024Z256)。
文摘Carbon nanotubes(CNTs)have garnered great attention in recent years due to their outstanding electrical,thermal,and mechanical properties.The incorporation of small amounts of CNTs in polymers can substantially improve the sensitivity of the polymer's electrical conductivity.This paper presents a modified Maxwell model to evaluate the electrical conductivity of CNTs-filled polymer composites by introducing a transition zone to account for the tunneling effect.In this modified Maxwell model,the CNTs-filled polymer composite is modeled as a three-phase composite,consisting of a matrix(polymer),inclusions(CNTs),and a transition zone(tunneling zone).The effective electrical conductivity(EEC)of the composite is calculated based on the volume fractions and electrical conductivities of the matrix,inclusions,and transition zone.The model's validity is confirmed through the use of available test data,which demonstrates its capability to accurately capture the nonlinear conductivity behavior observed in CNTs-polymer composites.This study offers valuable insights into the design of high-performance conductive polymer nanocomposites,and enhances the understanding of electrical conduction mechanisms in CNT-dispersed polymer composites.
基金Supported by Science Research Project of Hebei Education Department(Grant No.BJK2024138)Hebei Provincial Natural Science Foundation(Grant No.E2023203129)National Natural Science Foundation of China(Grant Nos.52004242,52075472).
文摘The aluminum(Al)/steel transition joints used in ships are processed from composite plates,and their mechanical properties have a significant impact on the safety of ships.In this paper,the Al/steel composite plate was prepared using rolling,with 5083 aluminum plate as the cladding plate,Q235 steel plate as the substrate,and TA1 titanium(Ti)plate and DT4 pure iron(Fe)plate as the intermediate layers.The heterothermic billet was prepared through induction heating by the magnetic effects of the steel plate and the pure Fe plate,and then the Al/steel composite plate was obtained by rolling.The impacts of post-rolling cooling process on the microstructure and properties of the Al/Ti/pure Fe/steel composite plate were studied.The results manifested that the pure Fe/steel interface had a good composite effect.With the increase in the cooling rate,the bonding strength of the Al/Ti interface was raised,and that of the Ti/Fe interface was increased first and then decreased.When the oil cooling process was adopted,the Al/Ti/pure Fe/steel composite plate exhibited the highest comprehensive performance.The shear strength of the Al/Ti interface and the Ti/Fe interface was 102 MPa and 186 MPa,respectively.The plastic fracture was determined as the mode of interface fracture.
文摘BACKGROUND Due to saliva and salivary glands are reservoir to severe acute respiratory syndrome-coronavirus 2(SARS-CoV-2),aerosols and saliva droplets are primary sources of cross-infection and are responsible for the high human–human transmission of SARS-CoV-2.However,there is no evidence about how SARSCoV-2 interacts with oral structures,particularly resin composites.AIM To evaluate the interaction of SARS-CoV-2 proteins with monomers present in resin composites using in silico analysis.METHODS Four SARS-CoV-2 proteins[i.e.main protease,3C-like protease,papain-like protease(PLpro),and glycoprotein spike]were selected along with salivary amylase as the positive control,and their binding affinity with bisphenol-A glycol dimethacrylate,bisphenol-A ethoxylated dimethacrylate,triethylene glycol dimethacrylate,and urethane dimethacrylate was evaluated.Molecular docking was performed using AutoDock Vina and visualised in Chimera UCSF 1.14.The best ligand–protein model was identified based on the binding energy(ΔG–kcal/moL).RESULTS Values for the binding energies ranged from-3.6 kcal/moL to-7.3 kcal/moL.The 3-monomer chain had the lowest binding energy(i.e.highest affinity)to PLpro and the glycoprotein spike.Non-polymerised monomers and polymerised chains interacted with SARS-CoV-2 proteins via hydrogen bonds and hydrophobic interactions.Those findings suggest an interaction between SARS-CoV-2 proteins and resin composites.CONCLUSION SARS-CoV-2 proteins show affinity to non-polymerised and polymerised resin composite chains.
基金supported by the National Natural Science Foundation of China(No.52101138,No.52201075)the Natural Science Foundation of Hubei Province(No.2023AFB798,No.2022CFB614)+3 种基金the Shenzhen Science and Technology Program(No.JCYJ20220530160813032)the State Key Laboratory of Solidification Processing in NWPU(No.SKLSP202309,No.SKLSP202308)the Guangdong Basic and Applied Basic Research Foundation(No.2022A1515011227)the State Key Laboratory of Powder Metallurgy of Central South University(No.SklpmKF-05)。
文摘B2-CuZr phase reinforced amorphous alloy matrix composites has become one of the research hotspots in the field of materials science due to the“transformation-induced plasticity”phenomenon,which makes the composites show better macroscopic plastic deformability and obvious work-hardening behavior compared to the conventional amorphous alloy matrix composites reinforced with ductile phases.However,the in-situ metastable B2-CuZr phase tends to undergo eutectoid decomposition during solidification,and the volume fraction,size,and distribution of B2-CuZr phase are difficult to control,which limits the development and application of these materials.To date,much efforts have been made to solve the above problems through composition optimization,casting parameter tailoring,and post-processing technique.In this study,a review was given based on relevant studies,focusing on the predictive approach,reinforcing mechanism,and microstructure tailoring methods of B2-CuZr phase reinforced amorphous alloy matrix composites.The research focus and future prospects were also given for the future development of the present composite system.
