In order to investigate the chloride ion penetration resistance of coal gangue concrete under multi-factor comprehensive action, the non-steady-state accelerated chloride ion migration test was used to test the chlori...In order to investigate the chloride ion penetration resistance of coal gangue concrete under multi-factor comprehensive action, the non-steady-state accelerated chloride ion migration test was used to test the chloride diffusion law of coal gangue concrete specimens by crack width, curing temperature and water-cement ratio. Three groups of crack width (0 mm, 0.05 - 0.12 mm, 0.12 - 0.2 mm), three curing temperatures (high temperature 45, medium temperature 25, low temperature 10), three water cement ratios (0.3, 0.4, 0.5) were set in the experiment. The results show that when the curing temperature and water cement ratio are constant, the crack width less than 0.12 mm has little effect on the chloride content and chloride diffusion coefficient. When the crack width is larger than 0.12 mm, the chloride penetration depth increases with the crack width. The resistance to chloride ion penetration of gangue concrete is greatly influenced by the water cement ratio. The influ-ence degree of three factors on chloride ion migration coefficient of gangue concrete is as follows: water cement ratio > crack width > curing temperature.展开更多
Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial stre...Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial strengths, the specimens were placed in 40, 60, or 80 t water tanks foraccelerated curing. The Coulomb values of the specimens weemeasured with ASTM C1202 experiment at 28, 100, 200, ad300 d. Partial specimens were also selected for rapid chlorideion migration coefficient and mercury intrusion porosimetryexperiments. The experimental results show that theaccelerated curing for ordinary concrete linealy deterioratesthe chloride penetration resistance, whereas the incorporationof mineral admixtures improves the concrete microscopic pore-structures and negative effects. An upper temperature limit of60 t of the accelerated curing is suitable for obtainingsuperior chloride penetration resistance for the mineraladmixture concrete. Pre-curing at a normal temperature of 20t is beneficial for improving the negative effect, which isalso aieviated with increasing testing age as a result of thesuccessive hydration of binder materials in concrete.展开更多
The modification methods of pozzolan slurry combined with sodium silicate and silicon-based additive were respectively adopted to treat recycled coarse brick-mixed aggregate(RCBA)in this study.The compressive strength...The modification methods of pozzolan slurry combined with sodium silicate and silicon-based additive were respectively adopted to treat recycled coarse brick-mixed aggregate(RCBA)in this study.The compressive strength and chloride permeability resistance of recycled aggregate concrete(RAC)before and after modification treatment were tested,and the microstructure of RAC was analyzed by mercury intrusion porosimetry(MIP)and scanning electron microscopy(SEM).The results show that the physical properties of RCBA strengthened by modification treatment are improved,and the compressive strength and chloride permeability resistance of treated RAC are also significantly improved.The modification treatment optimizes the pore size distribution of RAC,which increases the number of gel pores and transition pores,and decreases the number of capillary pores and macro pores.The surface fractal dimension shows a significant correlation with chloride diffusion coefficient,indicating that the variation of chloride permeability of treated RAC is consistent with the microstructure evolution.展开更多
The lining concrete of subsea tunnel services under combined hydraulic pressure, mechanical and environmental loads. The chloride ion and water penetrations into concrete under hydraulic pressure were investigated. Th...The lining concrete of subsea tunnel services under combined hydraulic pressure, mechanical and environmental loads. The chloride ion and water penetrations into concrete under hydraulic pressure were investigated. The experimental results indicate that the water penetration depth, chloride ion transportation depth, and the concentration of chloride ion ingression into concrete increase with raised hydraulic pressure and hold press period. But the chloride ion transportation velocity is only 53% of that of water when concrete specimens are under hydraulic pressure. The chloride transportation coefficient of concrete decreases with hold press period as power function. And that would increase 500% 600% in chloride transportation coefficient when the hydraulic pressure increases from 0 to 1.2 MPa. The hydraulic pressure also decreases the bound chloride ion of concrete to about zero. Besides, the low water-cementitions materials and suitable content of mineral admixture(including fly ash and slag) improve the resistance capacity of chloride penetration, and binding capacity of concrete under hydraulic pressure.展开更多
The mechanism of chloride ion penetration in high performance concrete was analy zed. The experimental results indicate that there are two important reasons that influence the anti-chloride penetration of high perfor...The mechanism of chloride ion penetration in high performance concrete was analy zed. The experimental results indicate that there are two important reasons that influence the anti-chloride penetration of high performance concrete. One is the function effect of mineral functional material, so that it increases conc rete's capability to resist chloride ion penetration. The other is combined acti on of mineral functional material's original capability of binding the chloride ion (physical adsorption) and physicochemical adsorption after hydration.展开更多
The effect of carbonation on the chloride resistance of low-carbon steel and two Cr-bearing alloy steels in simulated concrete pore solutions was investigated.The chloride threshold values of steels were determined on...The effect of carbonation on the chloride resistance of low-carbon steel and two Cr-bearing alloy steels in simulated concrete pore solutions was investigated.The chloride threshold values of steels were determined on the basis of corrosion potential(Ecorr)and polarization resistance(Rp).Moreover,the chloride-induced corrosion behavior of steels was evaluated using electrochemical impedance spectroscopy,cyclic voltammetry,cathodic potentiodynamic polarization,and scanning electron microscopy/energy dispersive X-ray spectroscopy measurements.Alloy steels have higher chloride resistance than low-carbon steel in carbonated and non-carbonated concrete pore solutions.The chloride resistance of alloy steels improves with increasing Cr content.In addition,the chloride resistance of all steels is negatively affected by the carbonation of concrete pore solution,especially for alloy steel with high Cr content in the presence of high chloride content.展开更多
The influence of chloride type on the diffusivity of chloride ions in concrete was studied by experiment. The result shows that the glectric resistance of concrete and the chloride diffusion coefficient are influenced...The influence of chloride type on the diffusivity of chloride ions in concrete was studied by experiment. The result shows that the glectric resistance of concrete and the chloride diffusion coefficient are influenced by chloride type. For the same water/cement ratio (W/C), the diffusion coefficient D in KCl solution is larger than that in NaCl solution; however, the concrete resistance in KCl solution is smaller than that in NaCl solution. The experimental result is analyzed with theory of diffusion.展开更多
The feature of reinforcing bars is introduced into dynamic cavity-expansion theory. Based on the elastic-plastic response penetration model of plain (i.e., unreinforced) concrete (Forrestal and Tzou, 1997), a dynamic ...The feature of reinforcing bars is introduced into dynamic cavity-expansion theory. Based on the elastic-plastic response penetration model of plain (i.e., unreinforced) concrete (Forrestal and Tzou, 1997), a dynamic spherical cavity-expansion penetration model for reinforced-concrete targets is developed with consideration of the circumferential restriction effect derived from reinforcing bars in the crushed region. The theoretical solution and simplified calculation formula for the cavity radial stress in incompressible and compressible reinforced concrete are obtained by introducing a reinforcement ratio as the volume fraction of rebars in the concrete target. A damping function is presented to describe the restriction effect of a single layer of reinforcing bars on the surrounding concrete, thus establishing a model to calculate the penetration resistance of multilayer reinforced-concrete targets. Compared with test data for the penetration depth, this model considering the circumferential restriction effect produces better results compared with the existing theory.展开更多
Projectile size effect is of great importance since the scaling researches are extensively applied to concrete penetration investigations. This paper numerically deals with the projectile size effect on penetration re...Projectile size effect is of great importance since the scaling researches are extensively applied to concrete penetration investigations. This paper numerically deals with the projectile size effect on penetration resistance via the recently developed Lattice Discrete Particles Model(LDPM) which is featured with mesoscale constitutive laws governing the interaction between adjacent particles to account for cohesive fracture, strain hardening in compression and compaction due to pore collapse. Simulations of two different penetration tests are carried to shed some light on the size effect issue. The penetration numerical model is validated by matching the projectile deceleration curve of and predicting the depth of penetration(DOP). By constant velocity penetration simulations, the target resistance is found to be dependent on the projectile size. By best fitting numerical results of constant velocity penetration, a size effect law for target resistance is proposed and validated against literature data. Moreover, the size effect is numerically obtained in the projectile with longer extended nose part meanwhile the shorter extended nose is found to improve the DOP since the projectile nose is sharpened.展开更多
Monitoring the service condition of concrete structures requires the quantitative assessment of properties and corrosion rate of structural steels surrounded by concrete.A multi-cell sensor system that included a refe...Monitoring the service condition of concrete structures requires the quantitative assessment of properties and corrosion rate of structural steels surrounded by concrete.A multi-cell sensor system that included a reference electrode,a chloride content sensor,a macrocell current unit and an electrical resistance measurement unit was developed.This system provided the following important electrochemical data in the cover-zone concrete on site:open circuit potential,macrocell current from anodes to cathode,chloride profile,concrete resistance and corrosion rate of built-in anodes.The experimental results show that the macrocell current increases when the chloride content in concrete is higher.Thus,monitoring the chloride content is a good method for monitoring the corrosion state.The chloride ion content and cover depth are the key factors that affect the electrical resistance of concrete.Without considering the temperature and time,a simplified model of the instantaneous corrosion rate of steel rebar in a concrete structure based on the measured chloride contents and concrete resistance was proposed.The test results further prove the reliability of this simplified predicting model.展开更多
This project was aimed to evaluate the chloride permeability and corrosion behavior of cement-based composites which comprised fibers and silica fume in the mixes~ Resistivity, polarization resistance, ponding and rap...This project was aimed to evaluate the chloride permeability and corrosion behavior of cement-based composites which comprised fibers and silica fume in the mixes~ Resistivity, polarization resistance, ponding and rapid chloride penetration results of specimens were obtained through tests. Test results indicate that resistivity, open circuit potentials and direct current polarization of specimens with w/b ratio of 0.35 are higher than those of specimens with w/b ratio of 0.55. For length-diameter ratio of 65, resistivity and direct current polarization of specimens with fiber length of 35 mm were similar to those of 60 mm. In addition the open circuit potentials of specimens with fiber length of 60 mm were slightly higher that those of 35 mm. The resistivity decreased with increasing steel fiber content, and the open circuit potential and direct current polarization increased with increasing steel fiber content. The specimens containing silica fume were found to provide higher resistivity, open circuit potentials and direct current polarization than the control specimens. The incorporation of steel fiber and silica fume in composites achieved more significantly decreases in resistivity and increases in direct current polarization than steel fiber composites or silica fume composites. The penetration depth and six-hour total charge passed of specimens for w/b ratio of 0.35 were lower than those for w/b ratio of 0.55. For length-diameter ratio of 65, the penetration depth of specimens for fiber length of 35 mm was similar to that of 60 mm. The penetration depth decreased with increased steel fiber content in the composites. By regression analysis, a good correlation between open circuit potential and direct current polarization, and chloride penetration depth and direct current polarization.展开更多
Structure characteristics of three kinds of ceramsite with different water absorption and the influence on microstructure of interfacial zone as well as performance of chloride permeabil-ity and frost resistance of co...Structure characteristics of three kinds of ceramsite with different water absorption and the influence on microstructure of interfacial zone as well as performance of chloride permeabil-ity and frost resistance of combined aggregate concrete were investigated. The results show that, dense shell and closed internal pore have sharp effects on lowering water absorption of ceramsite. However, the ceramsite with high water absorption has obvious effect on the densification of interfa-cial paste which would develop a structure with lower porosity, finer aperture and higher microhard-ness. Furthermore, the impermeability and frost-resistance of concrete can be improved due to the ef-fect of water absorption and releasing by ceramsite with higher water absorption.展开更多
Nano particles have been found to be effective in enhancing many properties of regular concretes. However, there is little information on the effect of nano particles on shotcrete. In fact, if similar positive effect ...Nano particles have been found to be effective in enhancing many properties of regular concretes. However, there is little information on the effect of nano particles on shotcrete. In fact, if similar positive effect of nano particles can also appear in shotcrete, they will greatly benefit the wide application of shotcrete in more and more repair and strengthening of structures in civil engineering, especially in corrosive environments. In this study, through experiments on 70 specimens, the effects of nano SiO2, CaCO3 and Al2O3 particles on the early-age porosity, pore size distribution, compressive strength and chloride permeability of shotcrete were investigated.Test results indicated that nano SiO2 particles significantly increased the compressive strength and chloride penetration resistance; nano Al2O3 and CaCO3 particles had slight enhancing effect on the compressive strength; nano CaCO3 particles were most effective in promoting the chloride penetration resistance of shotcrete. As a conclusion, nano SiO2 particles were recommended when both early age compressive strength and chloride penetration resistance were crucial, and nano CaCO3 particles were recommended when only chloride penetration resistance was concerned for their high cost-effectiveness.展开更多
To accurately evaluate the degradation process of prestressed concrete continuous bridges exposed to aggressive environments in life-cycle,a finite element-based approach with respect to the lifetime performance asses...To accurately evaluate the degradation process of prestressed concrete continuous bridges exposed to aggressive environments in life-cycle,a finite element-based approach with respect to the lifetime performance assessment of concrete bridges was proposed.The existing assessment methods were firstly introduced and compared.Some essential mechanics problems involved in the degradation process,such as the deterioration of materials properties,the reduction of sectional areas and the variation of overall structural performance caused by the first two problems,were investigated and solved.A computer program named CBDAS(Concrete Bridge Durability Analysis System) was written to perform the above-metioned approach.Finally,the degradation process of a prestressed concrete continuous bridge under chloride penetration was discussed.The results show that the concrete normal stress for serviceability limit state exceeds the threshold value after 60 a,but the various performance indicators at ultimate limit state are consistently in the allowable level during service life.Therefore,in the case of prestressed concrete bridges,the serviceability limit state is more possible to have durability problems in life-cycle;however,the performance indicators at ultimate limit state can satisfy the requirements.展开更多
Microbiologically⁃induced calcite⁃precipitation(MICP)has been increasingly studied in structural repair including self⁃healing and external applications.Among various MICP pathways,enzymatic urea hydrolysis is suggest...Microbiologically⁃induced calcite⁃precipitation(MICP)has been increasingly studied in structural repair including self⁃healing and external applications.Among various MICP pathways,enzymatic urea hydrolysis is suggested to be applied as external repair instead of self⁃healing.This study comprehensively characterised the enzymatic urea hydrolysis pathway in physical,impermeable,and mechanical rejuvenation of concrete cracks.The visual quality of repaired structures was presented,and the importance of humidity in the remediation of cracks was demonstrated.Moreover,this study investigated the differences in the effectiveness of repair between premixing bacteria with urea and without any premixing.With premixing,there was a concern that the accelerated reactions would precipitate calcite in the shallow spaces of the cracks and impede deeper healing.However,the observed results indicated that neither physical nor impermeable rejuvenation of concrete cracks repair would be detrimentally affected.The results obtained from this study will allow further development in commercialisation since the effectiveness of repair has been confirmed with an improvement in its efficiency.展开更多
To examine the protection against reinforcement corrosion due to the combined action of CO2 and chlorides, experimental results of the evaluation of a study with three types of cement are presented. The study was perf...To examine the protection against reinforcement corrosion due to the combined action of CO2 and chlorides, experimental results of the evaluation of a study with three types of cement are presented. The study was performed observing the behavior of reinforcements which were put in samples submitted to accelerated carbonatation tests and accelerated tests under the effect of chlorides. For the evaluation, intensity corrosion measurements were used using the Pr (polarization resistance) technique, employing these measures as a deterioration indicator. Three types of cement available in the national market were used. The obtained results enabled the classification of the used cements, comparing their profile behaviors in the conditions of the proposed tests.展开更多
文摘In order to investigate the chloride ion penetration resistance of coal gangue concrete under multi-factor comprehensive action, the non-steady-state accelerated chloride ion migration test was used to test the chloride diffusion law of coal gangue concrete specimens by crack width, curing temperature and water-cement ratio. Three groups of crack width (0 mm, 0.05 - 0.12 mm, 0.12 - 0.2 mm), three curing temperatures (high temperature 45, medium temperature 25, low temperature 10), three water cement ratios (0.3, 0.4, 0.5) were set in the experiment. The results show that when the curing temperature and water cement ratio are constant, the crack width less than 0.12 mm has little effect on the chloride content and chloride diffusion coefficient. When the crack width is larger than 0.12 mm, the chloride penetration depth increases with the crack width. The resistance to chloride ion penetration of gangue concrete is greatly influenced by the water cement ratio. The influ-ence degree of three factors on chloride ion migration coefficient of gangue concrete is as follows: water cement ratio > crack width > curing temperature.
基金The National Natural Science Foundation of China(No.51178455)the Transformation Program of Science and Technology Achievements of Jiangsu Province(No.BA2015133)
文摘Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial strengths, the specimens were placed in 40, 60, or 80 t water tanks foraccelerated curing. The Coulomb values of the specimens weemeasured with ASTM C1202 experiment at 28, 100, 200, ad300 d. Partial specimens were also selected for rapid chlorideion migration coefficient and mercury intrusion porosimetryexperiments. The experimental results show that theaccelerated curing for ordinary concrete linealy deterioratesthe chloride penetration resistance, whereas the incorporationof mineral admixtures improves the concrete microscopic pore-structures and negative effects. An upper temperature limit of60 t of the accelerated curing is suitable for obtainingsuperior chloride penetration resistance for the mineraladmixture concrete. Pre-curing at a normal temperature of 20t is beneficial for improving the negative effect, which isalso aieviated with increasing testing age as a result of thesuccessive hydration of binder materials in concrete.
基金Funded by the National Natural Science Foundation of China(No.52078050)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2020JZ-22)。
文摘The modification methods of pozzolan slurry combined with sodium silicate and silicon-based additive were respectively adopted to treat recycled coarse brick-mixed aggregate(RCBA)in this study.The compressive strength and chloride permeability resistance of recycled aggregate concrete(RAC)before and after modification treatment were tested,and the microstructure of RAC was analyzed by mercury intrusion porosimetry(MIP)and scanning electron microscopy(SEM).The results show that the physical properties of RCBA strengthened by modification treatment are improved,and the compressive strength and chloride permeability resistance of treated RAC are also significantly improved.The modification treatment optimizes the pore size distribution of RAC,which increases the number of gel pores and transition pores,and decreases the number of capillary pores and macro pores.The surface fractal dimension shows a significant correlation with chloride diffusion coefficient,indicating that the variation of chloride permeability of treated RAC is consistent with the microstructure evolution.
基金Projects(50708046,51178230)supported by the National Natural Science Foundation of ChinaProject(2009CB623203)supported by the National Basic Research Program(973 Program)of ChinaProject(2010CEM006)supported by State Key Lab of High Performance Civil Engineering Materials,China
文摘The lining concrete of subsea tunnel services under combined hydraulic pressure, mechanical and environmental loads. The chloride ion and water penetrations into concrete under hydraulic pressure were investigated. The experimental results indicate that the water penetration depth, chloride ion transportation depth, and the concentration of chloride ion ingression into concrete increase with raised hydraulic pressure and hold press period. But the chloride ion transportation velocity is only 53% of that of water when concrete specimens are under hydraulic pressure. The chloride transportation coefficient of concrete decreases with hold press period as power function. And that would increase 500% 600% in chloride transportation coefficient when the hydraulic pressure increases from 0 to 1.2 MPa. The hydraulic pressure also decreases the bound chloride ion of concrete to about zero. Besides, the low water-cementitions materials and suitable content of mineral admixture(including fly ash and slag) improve the resistance capacity of chloride penetration, and binding capacity of concrete under hydraulic pressure.
基金Funded by the Country Project of Tacking Key Problem for Fif teen Plan(No.2001BA307B05 08)
文摘The mechanism of chloride ion penetration in high performance concrete was analy zed. The experimental results indicate that there are two important reasons that influence the anti-chloride penetration of high performance concrete. One is the function effect of mineral functional material, so that it increases conc rete's capability to resist chloride ion penetration. The other is combined acti on of mineral functional material's original capability of binding the chloride ion (physical adsorption) and physicochemical adsorption after hydration.
基金the National Natural Science Foundation of China(No.51678144)the National Basic Research Program of China(No.2015CB655100)+1 种基金the Natural Science Foundation of Jiangsu Province,China(No.BK20161420)Southeast University“Zhongying Young Scholars”.
文摘The effect of carbonation on the chloride resistance of low-carbon steel and two Cr-bearing alloy steels in simulated concrete pore solutions was investigated.The chloride threshold values of steels were determined on the basis of corrosion potential(Ecorr)and polarization resistance(Rp).Moreover,the chloride-induced corrosion behavior of steels was evaluated using electrochemical impedance spectroscopy,cyclic voltammetry,cathodic potentiodynamic polarization,and scanning electron microscopy/energy dispersive X-ray spectroscopy measurements.Alloy steels have higher chloride resistance than low-carbon steel in carbonated and non-carbonated concrete pore solutions.The chloride resistance of alloy steels improves with increasing Cr content.In addition,the chloride resistance of all steels is negatively affected by the carbonation of concrete pore solution,especially for alloy steel with high Cr content in the presence of high chloride content.
基金Funded by the National Natural Science Foundation of China(No. 50278039, 50578068 and 50538070)
文摘The influence of chloride type on the diffusivity of chloride ions in concrete was studied by experiment. The result shows that the glectric resistance of concrete and the chloride diffusion coefficient are influenced by chloride type. For the same water/cement ratio (W/C), the diffusion coefficient D in KCl solution is larger than that in NaCl solution; however, the concrete resistance in KCl solution is smaller than that in NaCl solution. The experimental result is analyzed with theory of diffusion.
基金the National Outstanding Young Scientist Foundation of China (Grant 11225213)the National Natural Science Foundation of China (Grants 11390361 and 11390362).
文摘The feature of reinforcing bars is introduced into dynamic cavity-expansion theory. Based on the elastic-plastic response penetration model of plain (i.e., unreinforced) concrete (Forrestal and Tzou, 1997), a dynamic spherical cavity-expansion penetration model for reinforced-concrete targets is developed with consideration of the circumferential restriction effect derived from reinforcing bars in the crushed region. The theoretical solution and simplified calculation formula for the cavity radial stress in incompressible and compressible reinforced concrete are obtained by introducing a reinforcement ratio as the volume fraction of rebars in the concrete target. A damping function is presented to describe the restriction effect of a single layer of reinforcing bars on the surrounding concrete, thus establishing a model to calculate the penetration resistance of multilayer reinforced-concrete targets. Compared with test data for the penetration depth, this model considering the circumferential restriction effect produces better results compared with the existing theory.
基金supported by the Natural Science Foundation of Jiangsu Province (No. BK20170824)the Fundamental Research Funds for the Central Universities (No. 30917011343)
文摘Projectile size effect is of great importance since the scaling researches are extensively applied to concrete penetration investigations. This paper numerically deals with the projectile size effect on penetration resistance via the recently developed Lattice Discrete Particles Model(LDPM) which is featured with mesoscale constitutive laws governing the interaction between adjacent particles to account for cohesive fracture, strain hardening in compression and compaction due to pore collapse. Simulations of two different penetration tests are carried to shed some light on the size effect issue. The penetration numerical model is validated by matching the projectile deceleration curve of and predicting the depth of penetration(DOP). By constant velocity penetration simulations, the target resistance is found to be dependent on the projectile size. By best fitting numerical results of constant velocity penetration, a size effect law for target resistance is proposed and validated against literature data. Moreover, the size effect is numerically obtained in the projectile with longer extended nose part meanwhile the shorter extended nose is found to improve the DOP since the projectile nose is sharpened.
基金Project(200632800003-11) supported by Western Communications Construction Scientific and Technological Project in China
文摘Monitoring the service condition of concrete structures requires the quantitative assessment of properties and corrosion rate of structural steels surrounded by concrete.A multi-cell sensor system that included a reference electrode,a chloride content sensor,a macrocell current unit and an electrical resistance measurement unit was developed.This system provided the following important electrochemical data in the cover-zone concrete on site:open circuit potential,macrocell current from anodes to cathode,chloride profile,concrete resistance and corrosion rate of built-in anodes.The experimental results show that the macrocell current increases when the chloride content in concrete is higher.Thus,monitoring the chloride content is a good method for monitoring the corrosion state.The chloride ion content and cover depth are the key factors that affect the electrical resistance of concrete.Without considering the temperature and time,a simplified model of the instantaneous corrosion rate of steel rebar in a concrete structure based on the measured chloride contents and concrete resistance was proposed.The test results further prove the reliability of this simplified predicting model.
文摘This project was aimed to evaluate the chloride permeability and corrosion behavior of cement-based composites which comprised fibers and silica fume in the mixes~ Resistivity, polarization resistance, ponding and rapid chloride penetration results of specimens were obtained through tests. Test results indicate that resistivity, open circuit potentials and direct current polarization of specimens with w/b ratio of 0.35 are higher than those of specimens with w/b ratio of 0.55. For length-diameter ratio of 65, resistivity and direct current polarization of specimens with fiber length of 35 mm were similar to those of 60 mm. In addition the open circuit potentials of specimens with fiber length of 60 mm were slightly higher that those of 35 mm. The resistivity decreased with increasing steel fiber content, and the open circuit potential and direct current polarization increased with increasing steel fiber content. The specimens containing silica fume were found to provide higher resistivity, open circuit potentials and direct current polarization than the control specimens. The incorporation of steel fiber and silica fume in composites achieved more significantly decreases in resistivity and increases in direct current polarization than steel fiber composites or silica fume composites. The penetration depth and six-hour total charge passed of specimens for w/b ratio of 0.35 were lower than those for w/b ratio of 0.55. For length-diameter ratio of 65, the penetration depth of specimens for fiber length of 35 mm was similar to that of 60 mm. The penetration depth decreased with increased steel fiber content in the composites. By regression analysis, a good correlation between open circuit potential and direct current polarization, and chloride penetration depth and direct current polarization.
基金Funded by the Western Transportation Construction of Communication Ministry (No. 200331882008)
文摘Structure characteristics of three kinds of ceramsite with different water absorption and the influence on microstructure of interfacial zone as well as performance of chloride permeabil-ity and frost resistance of combined aggregate concrete were investigated. The results show that, dense shell and closed internal pore have sharp effects on lowering water absorption of ceramsite. However, the ceramsite with high water absorption has obvious effect on the densification of interfa-cial paste which would develop a structure with lower porosity, finer aperture and higher microhard-ness. Furthermore, the impermeability and frost-resistance of concrete can be improved due to the ef-fect of water absorption and releasing by ceramsite with higher water absorption.
基金Funded by National Natural Science Foundation of China(Nos.51522905,51379186)
文摘Nano particles have been found to be effective in enhancing many properties of regular concretes. However, there is little information on the effect of nano particles on shotcrete. In fact, if similar positive effect of nano particles can also appear in shotcrete, they will greatly benefit the wide application of shotcrete in more and more repair and strengthening of structures in civil engineering, especially in corrosive environments. In this study, through experiments on 70 specimens, the effects of nano SiO2, CaCO3 and Al2O3 particles on the early-age porosity, pore size distribution, compressive strength and chloride permeability of shotcrete were investigated.Test results indicated that nano SiO2 particles significantly increased the compressive strength and chloride penetration resistance; nano Al2O3 and CaCO3 particles had slight enhancing effect on the compressive strength; nano CaCO3 particles were most effective in promoting the chloride penetration resistance of shotcrete. As a conclusion, nano SiO2 particles were recommended when both early age compressive strength and chloride penetration resistance were crucial, and nano CaCO3 particles were recommended when only chloride penetration resistance was concerned for their high cost-effectiveness.
基金Project(2006.318.223.02-01) supported by the Ministry of Transportation and Communications through the Scientific and Technological Funds of ChinaProject(2007AA11Z104) supported by the High Technology Research and Development of ChinaProject(20090072110045) supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘To accurately evaluate the degradation process of prestressed concrete continuous bridges exposed to aggressive environments in life-cycle,a finite element-based approach with respect to the lifetime performance assessment of concrete bridges was proposed.The existing assessment methods were firstly introduced and compared.Some essential mechanics problems involved in the degradation process,such as the deterioration of materials properties,the reduction of sectional areas and the variation of overall structural performance caused by the first two problems,were investigated and solved.A computer program named CBDAS(Concrete Bridge Durability Analysis System) was written to perform the above-metioned approach.Finally,the degradation process of a prestressed concrete continuous bridge under chloride penetration was discussed.The results show that the concrete normal stress for serviceability limit state exceeds the threshold value after 60 a,but the various performance indicators at ultimate limit state are consistently in the allowable level during service life.Therefore,in the case of prestressed concrete bridges,the serviceability limit state is more possible to have durability problems in life-cycle;however,the performance indicators at ultimate limit state can satisfy the requirements.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51278157).
文摘Microbiologically⁃induced calcite⁃precipitation(MICP)has been increasingly studied in structural repair including self⁃healing and external applications.Among various MICP pathways,enzymatic urea hydrolysis is suggested to be applied as external repair instead of self⁃healing.This study comprehensively characterised the enzymatic urea hydrolysis pathway in physical,impermeable,and mechanical rejuvenation of concrete cracks.The visual quality of repaired structures was presented,and the importance of humidity in the remediation of cracks was demonstrated.Moreover,this study investigated the differences in the effectiveness of repair between premixing bacteria with urea and without any premixing.With premixing,there was a concern that the accelerated reactions would precipitate calcite in the shallow spaces of the cracks and impede deeper healing.However,the observed results indicated that neither physical nor impermeable rejuvenation of concrete cracks repair would be detrimentally affected.The results obtained from this study will allow further development in commercialisation since the effectiveness of repair has been confirmed with an improvement in its efficiency.
文摘To examine the protection against reinforcement corrosion due to the combined action of CO2 and chlorides, experimental results of the evaluation of a study with three types of cement are presented. The study was performed observing the behavior of reinforcements which were put in samples submitted to accelerated carbonatation tests and accelerated tests under the effect of chlorides. For the evaluation, intensity corrosion measurements were used using the Pr (polarization resistance) technique, employing these measures as a deterioration indicator. Three types of cement available in the national market were used. The obtained results enabled the classification of the used cements, comparing their profile behaviors in the conditions of the proposed tests.