The properties orAl based nanocomposite metal foams and their corrosion behaviors were investigated in this study. For this, the composite metal foams with different relative densities （porosity） reinforced with alu...The properties orAl based nanocomposite metal foams and their corrosion behaviors were investigated in this study. For this, the composite metal foams with different relative densities （porosity） reinforced with alumina nanoparticles were prepared using a powder me- tallurgy-based sintering-dissolution process （SDP） and NaC1 particles were used as space holders. Then, the effect of nanoparticle rein- forcement and different amounts of NaC1 space holders （corresponding porosity） on the microstructure, morphology, density, hardness, and electrochemical specifications of the samples were investigated. It was found that as the relative density increased from 60% to 70%, the wall thickness increased from about 200 to 300 pro, which led to a decrease in pore size. Also, the addition of nanoparticle reinforcement and the increased relative density result in increasing metal foam hardness. Moreover, electrochemical test results indicated that increasing the A1203 content reduced the corrosion rate, but increasing the porosity enhanced it.展开更多
We consider a modified Lnshnikov process as a model of a chemical polymer ization anf study the asymptotic behavior (in the thermodynamic limit;as N →∞)of a particular probability distribution on the set of N-dimens...We consider a modified Lnshnikov process as a model of a chemical polymer ization anf study the asymptotic behavior (in the thermodynamic limit;as N →∞)of a particular probability distribution on the set of N-dimensional vectors,tile kth component of which is the number of k-mers.The study study establisles the existence of three stages (subcritical,near-critical and supercritical stages)of polymerization,dependenting upon the ratio of association and dissociation rates of f polymers.The present paper concentrates on the analysis of tile subcritical stage.In the sibcritical.stages we show that tile size of the largest length of polymers of stize N is of the order.log N as N →+∞.展开更多
A new preparation method （reduction-decomposition process） for high purity SrCO3 was investigated, which mainly includes four processes: reduction, leaching, purification and precipitation. The affecting factors abo...A new preparation method （reduction-decomposition process） for high purity SrCO3 was investigated, which mainly includes four processes: reduction, leaching, purification and precipitation. The affecting factors about S2- behaviors in leaching process and the effects of variables on purity and particle sizes distribution of SrCO3 were analyzed theoretically and practically. It is concluded that with the increase of temperature or decrease of pH value in leaching process, the strontium recovery increases, but SrS decomposes and hydrogen sulphide （H2S） gas discharges. The purity of SrCO3 is dependent on dissolution-recrystallization times, for example, the purity of （SrCO3） is as high as 99.97% when it is recrystallized three times. Besides, the solution concentration of Sr（OH）2 and flow rate of CO2 have important effects on particle size distribution of SrCO3 particles, especially, the particle sizes of （SrCO3） meanly distribute in 0.11.0 μm when the flow rate of CO2 is about 2 000 mL/min and other parameters are invariable.展开更多
The chemorheological behaviors of a low viscosity epoxy resin system （Huntsman 1564/3486） for vacuum infusion moulding process （VIMP） were studied with viscosity experiments.The dual-Arrhenius rheological model an...The chemorheological behaviors of a low viscosity epoxy resin system （Huntsman 1564/3486） for vacuum infusion moulding process （VIMP） were studied with viscosity experiments.The dual-Arrhenius rheological model and the engineering viscosity model were established and compared with the experimental data.The result showed that the viscosity in the earlier stage calculated by dual-Arrhenius model were smaller than the experimental data,while the data calculated by the engineering model were larger.Combining the two models together can predict the rheological behaviors of the resin system in a more credible manner.The processing windows of the resin system for VIMP were determined based on the two models.The optimum processing temperature is 30-45 ℃.展开更多
In this paper, the near-critical and super-critical asymptotic behavior of a reversible Markov process as a chemical model for polymerization was studied. The results of the present paper, together with an analysis of...In this paper, the near-critical and super-critical asymptotic behavior of a reversible Markov process as a chemical model for polymerization was studied. The results of the present paper, together with an analysis of the sub-critical stage, establish the existence of three distinct stages (sub-critical, near-critical and super-critical stages) of polymerization (in the thermodynamic limit as N --> +infinity,),depending on the value of strength of the fragmentation reaction. These three stages correspond to the size of the largest length of polymers of size N to be itself of order log N, Nm/m+1 (m greater than or equal to 2, m not equal 4n, n greater than or equal to 1) and N, respectively.展开更多
In this study, the effect of melting temperature on the microstructural evolutions, behavior, and corrosion morphology of Hadfield steel in the casting process is investigated. The mold was prepared by the sodium sili...In this study, the effect of melting temperature on the microstructural evolutions, behavior, and corrosion morphology of Hadfield steel in the casting process is investigated. The mold was prepared by the sodium silicate/CO_2 method, using a blind riser, and then the desired molten steel was obtained using a coreless induction furnace. The casting was performed at melting temperatures of 1350, 1400, 1450, and 1500°C, and the cast blocks were immediately quenched in water. Optical microscopy was used to analyze the microstructure, and scanning electron microscopy(SEM) and X-ray diffractrometry(XRD) were used to analyze the corrosion morphology and phase formation in the microstructure, respectively. The corrosion behavior of the samples was analyzed using a potentiodynamic polarization test and electrochemical impedance spectroscopy(EIS) in 3.5 wt% NaCl. The optical microscopy observations and XRD patterns show that the increase in melting temperature led to a decrease of carbides and an increase in the austenite grain size in the Hadfield steel microstructure. The corrosion tests results show that with increasing melting temperature in the casting process, Hadfield steel shows a higher corrosion resistance. The SEM images of the corrosion morphologies show that the reduction of melting temperature in the Hadfield steel casting process induced micro-galvanic corrosion conditions.展开更多
The hot deformation behavior of Al-Cu-Mg-Ag was studied by isothermal hot compression tests in the temperature range of 573-773 K and strain rate range of 0.001-1 s^-1 on a Gleeble 1500 D thermal mechanical simulator....The hot deformation behavior of Al-Cu-Mg-Ag was studied by isothermal hot compression tests in the temperature range of 573-773 K and strain rate range of 0.001-1 s^-1 on a Gleeble 1500 D thermal mechanical simulator. The results show the flow stress of Al-Cu-Mg-Ag alloy increases with strain rate and decreases after a peak value, indicating dynamic recovery and recrystallization. A hyperbolic sine relationship is found to correlate well the flow stress with the strain rate and temperature, the flow stress equation is estimated to illustrate the relation of strain rate and stress and temperature during high temperature deformation process. The processing maps exhibit two domains as optimum fields for hot deformation at different strains, including the high strain rate domain in 623-773 K and the low strain rate domain in 573-673 K.展开更多
Laser shock processing is a very new technique and an emerging modern process that generates compressive stresses much deeper into the surfaces of metals or alloys. A brief parametric study of the effect of laser para...Laser shock processing is a very new technique and an emerging modern process that generates compressive stresses much deeper into the surfaces of metals or alloys. A brief parametric study of the effect of laser parameters on fatigue behavior and residual stress state generated in 6061-T651 alloy specimens was summarized. Residual stress of 6061-T651 alloy was analyzed both before and after laser processing with multishocks. The material remains in compressive residual stress of approximate 1mm in depth which is approximately 10 times deeper than that can be achieved with the conventional technique, and the maximal compressive residual stress at the surface of the sample is about -350MPa. Near the surface, yield strength and hardness are found to be increased by the laser shock. The ratio of fatigue crack initiation life for the laser-shocked to unshocked specimens is found to be 4.9 for specimens. The results clearly show that LSP is an effective surface treatment technique for improving the fatigue performance of aluminum alloys.展开更多
Vaporization behavior （1163-1463 K） of lead in the slag system of FeO-CaO-SiO2-Al2O3 with CaC% was examined. A thermodynamic estimation with the principle of Gibbs free energy minimization showed that the major vapo...Vaporization behavior （1163-1463 K） of lead in the slag system of FeO-CaO-SiO2-Al2O3 with CaC% was examined. A thermodynamic estimation with the principle of Gibbs free energy minimization showed that the major vapor species from the sample of the FeO-CaO-SiO2-Al2O3 system＋PbO＋CaCl2 were metallic Pb, PbCl, PbCl2, and FeCl2, at the experimental temperature range. The experimental results show that the mole ratio of vaporized Cl in lead chlorides to vaporized Pb, simply expressed as Cl/Pb decreases with increasing temperature. The larger Cl/Pb means a larger ratio of gaseous PbCl2, since metallic Pb and PbCl vapors are formed in a similar reduction atmosphere. The evaporation is initially rapid and becomes steady after holding for 10 min. Gaseous PbCl2 is mainly formed during the heating period, and at the holding stage, it reacts with FeO to produce gaseous FeCl2 With regard to slag composition, FeO content and basicity significantly affect the evaporation of lead. High FeO content and high basicity promotes the formation of metallic Pb and PbCI, whereas, it prohibits PbCl2 evaporation.展开更多
A visualized investigation was carried out on the effect of the diverging angle on the bubble motion and interfacial behavior in a Venturi-type bubble generator.It was found two or three large vortexes formed in the d...A visualized investigation was carried out on the effect of the diverging angle on the bubble motion and interfacial behavior in a Venturi-type bubble generator.It was found two or three large vortexes formed in the diverging section,resulting in strong reentrant jet flow in the front of the bubbles or slugs rushing out of the throat.The jet flow in return bumps into the ongoing bubbles or slugs,leading to strong interaction between the gas and liquid phases.The diverging angle has significant influence on the reentrant flow process and the performance of the bubble generator as well.Increasing the diverging angle results in the reentrant flow moving further forward to the upstream and intensifies the interaction between the two phases.As a consequence,the breakup or collapse of bubbles becomes more violent,whereby finer bubbles are generated.As such,the reentrant flow strongly links to the performance of the Venturi channel taken as a bubble generator,and that a moderate increase in the diverging angle can improve its performance without additional increase in flow resistance like that by increasing liquid flow rate.展开更多
This paper intuitively examines the dynamic behavior of two highly relevant interest rates in China. The first one is the government rate, which is decided and published by the central bank and can be simulated by pur...This paper intuitively examines the dynamic behavior of two highly relevant interest rates in China. The first one is the government rate, which is decided and published by the central bank and can be simulated by pure jump process. Estimation of the jump intension is given out. And by different robustness test, it keeps stable. The jump size has met the condition to make interest rate within reasonable bounds and shown some meaning of economic cycle behavior. The second one is the market rate, which is estimated by spline approximation based on the transaction data of government bonds. Several models, including Vasicek model, Vasicek-GARCH （1,1） model, CIR model, and CIR-GARCH（1,1）, are empirically tested and the best performance is done by the Vasicek-GARCH（1,1） model. Furthermore, the estimate bias problem due to the near unit root process is tested and evidenced by both traditional methods and GPH test. Impact of government rate on market rate is finally checked and analyzed.展开更多
文摘The properties orAl based nanocomposite metal foams and their corrosion behaviors were investigated in this study. For this, the composite metal foams with different relative densities （porosity） reinforced with alumina nanoparticles were prepared using a powder me- tallurgy-based sintering-dissolution process （SDP） and NaC1 particles were used as space holders. Then, the effect of nanoparticle rein- forcement and different amounts of NaC1 space holders （corresponding porosity） on the microstructure, morphology, density, hardness, and electrochemical specifications of the samples were investigated. It was found that as the relative density increased from 60% to 70%, the wall thickness increased from about 200 to 300 pro, which led to a decrease in pore size. Also, the addition of nanoparticle reinforcement and the increased relative density result in increasing metal foam hardness. Moreover, electrochemical test results indicated that increasing the A1203 content reduced the corrosion rate, but increasing the porosity enhanced it.
文摘We consider a modified Lnshnikov process as a model of a chemical polymer ization anf study the asymptotic behavior (in the thermodynamic limit;as N →∞)of a particular probability distribution on the set of N-dimensional vectors,tile kth component of which is the number of k-mers.The study study establisles the existence of three stages (subcritical,near-critical and supercritical stages)of polymerization,dependenting upon the ratio of association and dissociation rates of f polymers.The present paper concentrates on the analysis of tile subcritical stage.In the sibcritical.stages we show that tile size of the largest length of polymers of stize N is of the order.log N as N →+∞.
文摘A new preparation method （reduction-decomposition process） for high purity SrCO3 was investigated, which mainly includes four processes: reduction, leaching, purification and precipitation. The affecting factors about S2- behaviors in leaching process and the effects of variables on purity and particle sizes distribution of SrCO3 were analyzed theoretically and practically. It is concluded that with the increase of temperature or decrease of pH value in leaching process, the strontium recovery increases, but SrS decomposes and hydrogen sulphide （H2S） gas discharges. The purity of SrCO3 is dependent on dissolution-recrystallization times, for example, the purity of （SrCO3） is as high as 99.97% when it is recrystallized three times. Besides, the solution concentration of Sr（OH）2 and flow rate of CO2 have important effects on particle size distribution of SrCO3 particles, especially, the particle sizes of （SrCO3） meanly distribute in 0.11.0 μm when the flow rate of CO2 is about 2 000 mL/min and other parameters are invariable.
基金Supported by the 863 National Project of China (No.2007AA03Z563)the Specialized Project of the HUNAN Province of China(No.2006GK1002)
文摘The chemorheological behaviors of a low viscosity epoxy resin system （Huntsman 1564/3486） for vacuum infusion moulding process （VIMP） were studied with viscosity experiments.The dual-Arrhenius rheological model and the engineering viscosity model were established and compared with the experimental data.The result showed that the viscosity in the earlier stage calculated by dual-Arrhenius model were smaller than the experimental data,while the data calculated by the engineering model were larger.Combining the two models together can predict the rheological behaviors of the resin system in a more credible manner.The processing windows of the resin system for VIMP were determined based on the two models.The optimum processing temperature is 30-45 ℃.
基金supported in part by National NaturalScience Foundation of China!196610O3
文摘In this paper, the near-critical and super-critical asymptotic behavior of a reversible Markov process as a chemical model for polymerization was studied. The results of the present paper, together with an analysis of the sub-critical stage, establish the existence of three distinct stages (sub-critical, near-critical and super-critical stages) of polymerization (in the thermodynamic limit as N --> +infinity,),depending on the value of strength of the fragmentation reaction. These three stages correspond to the size of the largest length of polymers of size N to be itself of order log N, Nm/m+1 (m greater than or equal to 2, m not equal 4n, n greater than or equal to 1) and N, respectively.
文摘In this study, the effect of melting temperature on the microstructural evolutions, behavior, and corrosion morphology of Hadfield steel in the casting process is investigated. The mold was prepared by the sodium silicate/CO_2 method, using a blind riser, and then the desired molten steel was obtained using a coreless induction furnace. The casting was performed at melting temperatures of 1350, 1400, 1450, and 1500°C, and the cast blocks were immediately quenched in water. Optical microscopy was used to analyze the microstructure, and scanning electron microscopy(SEM) and X-ray diffractrometry(XRD) were used to analyze the corrosion morphology and phase formation in the microstructure, respectively. The corrosion behavior of the samples was analyzed using a potentiodynamic polarization test and electrochemical impedance spectroscopy(EIS) in 3.5 wt% NaCl. The optical microscopy observations and XRD patterns show that the increase in melting temperature led to a decrease of carbides and an increase in the austenite grain size in the Hadfield steel microstructure. The corrosion tests results show that with increasing melting temperature in the casting process, Hadfield steel shows a higher corrosion resistance. The SEM images of the corrosion morphologies show that the reduction of melting temperature in the Hadfield steel casting process induced micro-galvanic corrosion conditions.
基金the National Basic Research Program of China(No.2005CB623705)
文摘The hot deformation behavior of Al-Cu-Mg-Ag was studied by isothermal hot compression tests in the temperature range of 573-773 K and strain rate range of 0.001-1 s^-1 on a Gleeble 1500 D thermal mechanical simulator. The results show the flow stress of Al-Cu-Mg-Ag alloy increases with strain rate and decreases after a peak value, indicating dynamic recovery and recrystallization. A hyperbolic sine relationship is found to correlate well the flow stress with the strain rate and temperature, the flow stress equation is estimated to illustrate the relation of strain rate and stress and temperature during high temperature deformation process. The processing maps exhibit two domains as optimum fields for hot deformation at different strains, including the high strain rate domain in 623-773 K and the low strain rate domain in 573-673 K.
基金Project(50275068) supported by the National Natural Science Foundation of China
文摘Laser shock processing is a very new technique and an emerging modern process that generates compressive stresses much deeper into the surfaces of metals or alloys. A brief parametric study of the effect of laser parameters on fatigue behavior and residual stress state generated in 6061-T651 alloy specimens was summarized. Residual stress of 6061-T651 alloy was analyzed both before and after laser processing with multishocks. The material remains in compressive residual stress of approximate 1mm in depth which is approximately 10 times deeper than that can be achieved with the conventional technique, and the maximal compressive residual stress at the surface of the sample is about -350MPa. Near the surface, yield strength and hardness are found to be increased by the laser shock. The ratio of fatigue crack initiation life for the laser-shocked to unshocked specimens is found to be 4.9 for specimens. The results clearly show that LSP is an effective surface treatment technique for improving the fatigue performance of aluminum alloys.
基金supported by the National Natural Science Foundation of China (No.50704004)
文摘Vaporization behavior （1163-1463 K） of lead in the slag system of FeO-CaO-SiO2-Al2O3 with CaC% was examined. A thermodynamic estimation with the principle of Gibbs free energy minimization showed that the major vapor species from the sample of the FeO-CaO-SiO2-Al2O3 system＋PbO＋CaCl2 were metallic Pb, PbCl, PbCl2, and FeCl2, at the experimental temperature range. The experimental results show that the mole ratio of vaporized Cl in lead chlorides to vaporized Pb, simply expressed as Cl/Pb decreases with increasing temperature. The larger Cl/Pb means a larger ratio of gaseous PbCl2, since metallic Pb and PbCl vapors are formed in a similar reduction atmosphere. The evaporation is initially rapid and becomes steady after holding for 10 min. Gaseous PbCl2 is mainly formed during the heating period, and at the holding stage, it reacts with FeO to produce gaseous FeCl2 With regard to slag composition, FeO content and basicity significantly affect the evaporation of lead. High FeO content and high basicity promotes the formation of metallic Pb and PbCI, whereas, it prohibits PbCl2 evaporation.
基金supported by the National Natural Science Foundation of China (Grants 51709191, 51606130, and 51506099)
文摘A visualized investigation was carried out on the effect of the diverging angle on the bubble motion and interfacial behavior in a Venturi-type bubble generator.It was found two or three large vortexes formed in the diverging section,resulting in strong reentrant jet flow in the front of the bubbles or slugs rushing out of the throat.The jet flow in return bumps into the ongoing bubbles or slugs,leading to strong interaction between the gas and liquid phases.The diverging angle has significant influence on the reentrant flow process and the performance of the bubble generator as well.Increasing the diverging angle results in the reentrant flow moving further forward to the upstream and intensifies the interaction between the two phases.As a consequence,the breakup or collapse of bubbles becomes more violent,whereby finer bubbles are generated.As such,the reentrant flow strongly links to the performance of the Venturi channel taken as a bubble generator,and that a moderate increase in the diverging angle can improve its performance without additional increase in flow resistance like that by increasing liquid flow rate.
文摘This paper intuitively examines the dynamic behavior of two highly relevant interest rates in China. The first one is the government rate, which is decided and published by the central bank and can be simulated by pure jump process. Estimation of the jump intension is given out. And by different robustness test, it keeps stable. The jump size has met the condition to make interest rate within reasonable bounds and shown some meaning of economic cycle behavior. The second one is the market rate, which is estimated by spline approximation based on the transaction data of government bonds. Several models, including Vasicek model, Vasicek-GARCH （1,1） model, CIR model, and CIR-GARCH（1,1）, are empirically tested and the best performance is done by the Vasicek-GARCH（1,1） model. Furthermore, the estimate bias problem due to the near unit root process is tested and evidenced by both traditional methods and GPH test. Impact of government rate on market rate is finally checked and analyzed.
