In order to improve the absorbing properties of M- type barium ferrite absorbing materials, M-type barium ferrite/graphene oxide composites with different graphene oxide contents were synthesized by the sol-gel autoco...In order to improve the absorbing properties of M- type barium ferrite absorbing materials, M-type barium ferrite/graphene oxide composites with different graphene oxide contents were synthesized by the sol-gel autocombustion method. X-ray diffraction （XRD）, a scanning electronic microscopy （ SEM ）, a physical properties measurement system （PPMS-9）, and a vector network analyzer were used to analyze their structure, surface morphology, magnetic and absorbing properties, respectively. The results show that the absorbing band of the composite absorbing material is widened and the absorbing strength is increased compared with the pure M-type barium ferrite. The sample with the content of doped graphene oxide of 3% has the minimum reflectivity at 10 to 18 GHz frequencies. Hence, the doped graphene oxide effectively improves the absorbing properties of M-type barium ferrite.展开更多
The electromagnetic and microwave absorbing properties of FeCoB powder composites prepared by sin- gle-roller melt-spinning and mechanical milling processes were investigated in this paper. The result indicates that t...The electromagnetic and microwave absorbing properties of FeCoB powder composites prepared by sin- gle-roller melt-spinning and mechanical milling processes were investigated in this paper. The result indicates that the flake-like powders are obtained. As milling time increases, the flake-like powder particles tend to agglomerate, causing the flake-like powders decrease gradually. The milling time plays an important role in the electromagnetic parameters which relates to the shape and size of the powder particles. The calculation shows that the sample milled for 6 h could achieve an optimal reflection loss of -11.5 dB at 5.8 GHz, with mass fraction of 83 % and a matching thickness of 1.8 mm. The result also indicates that the microwave absorbing properties of the FeCoB powder composites are adjustable by changing their thickness, and can be applied as a thinner microwave absorbing material in the range of 2-8 GHz.展开更多
The effects of types and amounts of silane coupling agent on mechanical properties of vuleanized rubber microwave absorbing patch （VRMAP） were studied. The mechanisms of silane coupling agent＇s effects on mechanica...The effects of types and amounts of silane coupling agent on mechanical properties of vuleanized rubber microwave absorbing patch （VRMAP） were studied. The mechanisms of silane coupling agent＇s effects on mechanical properties of rubber microwave absorbing patch （ RMAP ） and microvave absorbing patch＇s （MAP＇s） mierostrueture were also discussed by using SEM and FT-IR. The experimental results show that the tensile strength of RMAP could be increased through adding the filler of carbonyl iron powder （CIP） modified by silane coupling agent. RMAP fiUed with CIP, which was treated by silane coupling agent KH550, possessed a high tensile strength of 11.5 MPa, which was 448% more than that of MAP whose filler wus not modified by any coupling agent. It was found that the optimal amount of KH550 was 1.0 phr to 100.0 phr carbonyl iron powder. The effects of different modifying techniques on RMAP＇s mechanical properties were also inrestigated. It is indieated that MAP whose filler is modified by the wet process has the highest tensile strength, but it is not the optimal modiifying technique due to complieated wet process. On the contrary, the dry process was very simple, and VRMAP possessed fairly high mechanical properties, therefore, it was the perfect modifying process.展开更多
Two kinds of nickel particles with flower-like struc~＇es assembled with a number of nano-flakes were synthesized and the relationship of their morphology and microwave absorbing properties was studied. The electromag...Two kinds of nickel particles with flower-like struc~＇es assembled with a number of nano-flakes were synthesized and the relationship of their morphology and microwave absorbing properties was studied. The electromagnetic parameters of these flower-like Ni were measured with vector network analyzer at 2-18 GHz frequency and the reflection losses （RL） with different sample thicknesses were calculated. The results indicate that the flower-like nickel-wax composites with the sample thickness less than 2 mm show excellent absorbing ability. This result is expected to play a guiding role in the preparation of the highly efficient absorber.展开更多
REI3Fes4Cr3（RE=Ce, Pr, Tb, Er） and Pr13_XFes4Cr3Ti（x=0, 2, 4, 6） alloy powders were prepared by are smelting method and high energy ball milling technique. The phase structure and the morphology of the alloy powde...REI3Fes4Cr3（RE=Ce, Pr, Tb, Er） and Pr13_XFes4Cr3Ti（x=0, 2, 4, 6） alloy powders were prepared by are smelting method and high energy ball milling technique. The phase structure and the morphology of the alloy powders were investigated by X-ray diffraction （XRD） and scanning electron microscopy （SEM）, and their microwave absorbing properties were determined by a vector network analyzer. The results show that the alloys with light rare earths （Ce, Pr） have good low frequency absorbing property and those with heavy rare earths （Tb, Er） exhibit an improved high frequency absorbing property. The minimum refleetivity at the absorbing peak frequency of RE,FeuCr3（RE=Ce, Pr, Tb, Er） are -9.49 dB at 5.76 GHz, -22.38 dB at 7.92 GHz, -18.52 dB at 11.68 GHz and -17.59 dB at 10.24 GHz, respectively. The absorbing bandwidth under -10 dB of the Pr13FesaCr3 powder was widened from 1.91 GI-Iz to 3.89 GHz by adding 2% Ti, but the reflectivity of the alloy was increased from -22.38 dB to -14.91 riB.展开更多
To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into diffe...To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into different particle sizes by planetary ball mill,and the physicochemical properties of iron tailings were tested by laser particle size analyzer and scanning electron microscope(SEM).The electromagnetic parameters of iron tailings cementitious materials were characterized by a vector network analyzer and simulated MA properties,and the MA properties of iron tailings-cement composite system with steel fiber as absorber was studied.Based on the design of the single-layer structure,optimum mix ratio and thickness configuration method of double-layer structure were further studied,meanwhile,the mechanical properties and engineering application were analyzed and discussed.The results show that the particle size of iron tailings can afiect its electromagnetic behavior in cementitious materials,and the smaller particles lead the increase of demagnetisation efiect induced by domain wall motion and achieve better microwave absorbing properties in cementitious materials.When the thickness of matching layer and absorbing layer is 5 mm,the optimized microwave absorbing properties of C1/C3 double-layer cementitious material can obtain optimal RL value of-27.61 dB and efiective absorbing bandwidth of 0.97 GHz,which attributes to the synergistic efiect of impedance matching and attenuation characteristics.The double-layer microwave absorbing materials obtain excellent absorbing properties and show great design flexibility and diversity,which can be used as a suitable candidate for the preparation of favorable microwave absorbing cementitious materials.展开更多
Microwave absorbing properties of high titanium slag were investigated by using microwave cavity perturbation technique. High titanium slag containing more than 90% TiO2 was prepared by carbothermal reduction of ilmen...Microwave absorbing properties of high titanium slag were investigated by using microwave cavity perturbation technique. High titanium slag containing more than 90% TiO2 was prepared by carbothermal reduction of ilmenite. The temperature rise curve of high titanium slag in microwave heating process was obtained. Crystalline compounds of high titanium slag before and after microwave irradiation were obtained and characterized by X-ray diffractometry （XRD）. Effects of particle size of high titanium slag anal mixtures of high titanium slag with different mass fractions of V2o5 on microwave absorbing properties were investigated systematically. The results show that high titanium slag has good microwave absorption property; untreated high titanium slag mainly consists of crystalline compounds of anatase and iron titanium oxide, while the microwave-irradiation treated one is mainly composed of crystalline compounds of rutile and irgn titanium oxide. Synthetic anatase is transformed completely into rutile at about 1 050 ℃ for 20 min under microwave irradiation. High frequency shift and low amplitude of voltage make high titanium slag an ideal microwave absorbent. 180 μm of particle size and 10% mass fraction of V2O5 are found to be the optimum conditions for microwave absorption.展开更多
In this paper,Fe-Al solid solution was prepared by mechanical alloying technology,and Fe-Al powder was dispersed into unsaturated polyester (UP) with different contents as absorber to form mixture Fe-Al-UP.The result...In this paper,Fe-Al solid solution was prepared by mechanical alloying technology,and Fe-Al powder was dispersed into unsaturated polyester (UP) with different contents as absorber to form mixture Fe-Al-UP.The results indicate that the alloying process is almost accomplished and most of the particles are nanometer.Meanwhile,the microwave absorbability of Fe-Al-UP samples in frequency from 0.3 MHz to 1.5 GHz was studied.The results indicate that the more the absorber,the better the absorbing property.The absorbing property of Fe-50Al-UP was slightly higher than Fe-28Al-UP.展开更多
The microwave absorbing behaviour of Mn-Zn ferrite sintered at 1100,1200,1300,1400 and 1500℃ has been investigated.The phase constitution of the ferrite was analyzed by X-ray diffraction.The results show that the fer...The microwave absorbing behaviour of Mn-Zn ferrite sintered at 1100,1200,1300,1400 and 1500℃ has been investigated.The phase constitution of the ferrite was analyzed by X-ray diffraction.The results show that the ferrite sintered at 1 500℃ has better microwave absorbing prop- erty than those prepared at other temperatures,due to the increase of turbulent loss generated by the formation of excessive Fe^(2+) in deoxidizing of Fe_2O_3 at high temperatures.展开更多
Magnesium-substituted Mn0.8Zn0.2Fe2O4 ferrite is synthesized by the sol–gel combustion method using citrate acid as the complex agent. The electromagnetic absorbing behaviors of ferrite/polymer coatings fabricated by...Magnesium-substituted Mn0.8Zn0.2Fe2O4 ferrite is synthesized by the sol–gel combustion method using citrate acid as the complex agent. The electromagnetic absorbing behaviors of ferrite/polymer coatings fabricated by dispersing Mn–Zn ferrite into epoxy resin （EP） are studied. The microstructure and morphology are characterized by X-ray diffraction and scanning electron microscope. Complex permittivity, complex permeability, and reflection loss of ferrite/EP composite coating are investigated in a low frequency range. It is found that the prepared ferrite particles are traditional cubic spinel ferrite particles with an average size of 200 nm. The results reveal that the electromagnetic microwave absorbing properties are significantly influenced by the weight ratio of ferrite to polymer. The composites with a weight ratio of ferrite/polymer being 3：20 have a maximum reflection loss of –16 dB and wide absorbing band. Thus, the Mn–Zn ferrite is the potential candidate in electromagnetic absorbing application in the low frequency range （10 MHz–1 GHz）.展开更多
The SiCf/SiC composites containing PyC interphase were prepared by chemical vapor infiltration process. The influences of thermal oxidation on the complex permittivity and microwave absorption properties of Si Cf/Si C...The SiCf/SiC composites containing PyC interphase were prepared by chemical vapor infiltration process. The influences of thermal oxidation on the complex permittivity and microwave absorption properties of Si Cf/Si C composites were investigated in the frequency range of 8.2-12.4 GHz. Both the real and imaginary parts of the complex permittivity decreased after thermal oxidation. The composites after 100 h thermal oxidation showed that reflection loss exceeded-10 d B in the frequency of 9.7-11.9 GHz and the minimum value was-11.4 d B at 11.0 GHz. The flexural strength of composites decreased but fracture behavior was improved obviously after thermal oxidation. These results indicate that the SiCf/SiC composites containing PyC interphase after thermal oxidation possess good microwave absorbing property and fracture behavior.展开更多
La-doped Sr-hexaferrite（Sr（1-x）LaxFe（12）O（19））（x=0.05,0.10,0.15,0.20） nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation te...La-doped Sr-hexaferrite（Sr（1-x）LaxFe（12）O（19））（x=0.05,0.10,0.15,0.20） nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation temperature increases, while the particle size decreases as the Ladoping content goes up. The partial substitution of Sr^（2＋） by La^（3＋） results in the suppression effects on the growth-up of the crystallites and the enhancement of the electron hopping between Fe^（3＋） with different valences, which leads to the improvement in the dielectric loss and magnetic loss.Therefore, both the microwave absorbing abilities and absorbing frequency ranges are tuned by La-doping. The synthesized Sr-hexaferrite nanopowders with doping element content of 0.10 demonstrate the fine broad microwave absorbing properties.展开更多
Composite fabrics with excellent microwave absorbing performance are highly desired.Herein,reduced graphene oxide/carbon nanofiber(rGO/CNF)based composite fabrics with spider web-like structure were successfully synth...Composite fabrics with excellent microwave absorbing performance are highly desired.Herein,reduced graphene oxide/carbon nanofiber(rGO/CNF)based composite fabrics with spider web-like structure were successfully synthesized by electrostatic spinning technique.The spider web-like structure in the composite fabrics provides a connected network for efficient conductive loss of microwave energies.Magnetic loss benefits from the deposited nickel nanoparticles(Ni NPs)anchored in the carbon nanofibers.Meanwhile,the deposited thin polypyrrole(PPy)layers on the conductive network acts as a protective layer for Ni NPs as well as provides abundant interfaces for dissipating electromagnetic energies,which endow the composite fabrics stable microwave absorbing performance.Due to the synergistic effect of microwave absorb-ing mechanism,the maximum reflection loss(RL_(max))of the composite fabric at 6.72 GHz is-46.15 dB,and the effective absorption bandwidth(EAB)is as wide as 8.63 GHz(from 9.37 to 18 GHz).What's more,favorable mechanical and heat insulation properties of the composite fabrics reveal its multifunctional advantages.This rGO/CNF based composite fabric demonstrates a new direction for multifunctional and flexible microwave absorbing materials(MAMs).展开更多
The microwave absorption property and infrared emissivity have been investigated for the single-layer coating made of the epoxy-polyurethane resin and carbonyl iron powders with variation of annealing treatment. Micro...The microwave absorption property and infrared emissivity have been investigated for the single-layer coating made of the epoxy-polyurethane resin and carbonyl iron powders with variation of annealing treatment. Microwave-absorbing property was investigated by measuring the complex permittivity and complex permeability of the absorber in the frequency range from 2 to 18 GHz. Infrared emissivity value was measured using IR-2 Infrared Emissometer in the wavelength range of 8-14 μm. After annealing, the Fe （110） peak became sharp, and the crystallization improved significantly. Annealing treatment could reduce the sttrface energy of powders, improve compatibility between fillers and adhesives, and result in increase of the density of the coating. The lowest value of infrared emissivity （0.419） was obtained from the coating made of the carbonyl iron powder annealed at 700℃ for 1 h. With the variation of the annealing temperature, the magnetic and dielectric properties of the carbonyl iron particle were changed. The maximum reflection loss decreased and the matching frequency shifted to lower frequency with increasing the annealing temperature of carbonyl iron particles, which coincided with the variation of the complex permeability and permittivity according to the annealing temperature. Magnetic loss factor and dielectric loss factor of carbonyl iron particles were improved with increasing the annealing temperature in the 2-18 GHz range.展开更多
Synthesis and characterization of lanthanum-doped yttrium iro n garnet(YIG)in the compositional se ries of Y_(3-x)La_(x)Fe_(5)O_(12)(x=0.0,0.1,0.3,and 0.5)were carried out.All compositions were made by using solid sta...Synthesis and characterization of lanthanum-doped yttrium iro n garnet(YIG)in the compositional se ries of Y_(3-x)La_(x)Fe_(5)O_(12)(x=0.0,0.1,0.3,and 0.5)were carried out.All compositions were made by using solid state reaction method with ball-milling technique.The phase formation,surface morphology,magnetic properties,and microwave absorbing ability of all compositions were characterized by using an X-ray diffractometer,a scanning electron microscope,a vibrating sample magnetometer,and a Vector network analyzer.The results reveal that all compositions are crystallized into Y_(3)Fe_(5)O_(12)phase(space group la-3d(230).It was observed that the lattice constant is increased from 1.2373 to 1.2421 nm with the increase of lanthanum substitution level from x=0.0-0.5.The crystallite size of Y_(3-x)La_(x)Fe_(5)O_(12)series calculated by Scherrer method is found to decrease from 78 nm in x=0.0-63 nm in x=0.5.The particle size distribution from the surface morphology image analysis is shifted to lower-range number with the increase of lanthanum substitution level from x=0.0 to 0.5.The substitution process also affects the lattice distortion in La-doped samples and changes the bond angles and bond lengths of the YIG structure.As the results,a linear correlation between the Fe'-O-Fe bond angle with magnetic properties parameters of saturation magnetization(M_(s))and remanence magnetization(M_(r))was studied.Due to the lanthanum substitution process,all La^(3+)-doped samples possess higher M_(s)and M_(r)values compared to the original composition.The results of Vector network analyzer show that the improvement of the M_(s)and M_(r)plays an important role in enhancing the microwave absorbing ability of the materials.The minimum RL changes from-8.22 dB(~85.22%microwave absorption)in x=0.0 to-14.21 dB(~96.25%microwave absorption)in x=0.5.The enhancement is mainly ascribed to the natural magnetic resonance loss and dipoIe-polarization loss due to the substitution process.The decreasing particle size also enhances the microwave absorbing ability of the La-doped samples via multiple-reflections mechanism.展开更多
The spinel cobalt chromium zinc ferrites（Co0.7Cr0.1Zn0.2Fe2O4） and the polyaniline（PANI）-Co0.7Cr0.1Zn0.2Fe2O4 composites were prepared by polyacrylamide gel and an in situ polymerization method,respectively.The st...The spinel cobalt chromium zinc ferrites（Co0.7Cr0.1Zn0.2Fe2O4） and the polyaniline（PANI）-Co0.7Cr0.1Zn0.2Fe2O4 composites were prepared by polyacrylamide gel and an in situ polymerization method,respectively.The structure of the synthesized material was characterized by X-ray diffraction（XRD） and Fourier transform infrared spectrometer（FTIR）,which shows that the spinel Co0.7Cr0.1Zn0.2Fe2O4 ferrites and the PANI Co0.7Cr0.1Zn0.2Fe2O4 composites are obtained.As a small amount of Co^2＋ in the octahedron ferrite is replaced by Cr^3＋,the lattice constant of Co0.8Cr0.2Zn0.2Fe2O4 ferrites reduces from0.8409 to 0.8377 nm.The magnetic properties of the two materials were investigated by vibrating sample magnetometer（VSM）.The VSM results confirm that the saturation magnetization（Ms）,remanent magnetization（Mr） and coercive force（Hc） of the PANI-Co0.7Cr0.1Zn0.2Fe2O4composites are 8.80 mA·m^2·g^-1,3.14 mA·m^2·g^-1 and37.22 kA·m^-1,respectively,which are smaller than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites.The microwave absorbing capability of the two materials was studied by waveguide method.In the frequency range of 5-20 GHz,two reflection loss maximum values of the PANI-Co0.7Cr0.1Zn0.2Fe2O4 composites appear at 14.1 and 17.9 GHz with-13.17 and-15.36 dB,respectively,which are obviously higher than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites.展开更多
The composites of Ce-Co-based alloys doped with La content were fabricated via a vacuum arc melting method.The influences of La addition on microstructure,electromagnetic parameters,magnetic property and microwave abs...The composites of Ce-Co-based alloys doped with La content were fabricated via a vacuum arc melting method.The influences of La addition on microstructure,electromagnetic parameters,magnetic property and microwave absorbing property were measured by the corresponding equipment.The morphology characteristics manifest that all samples display sheet structure,and the average particle size of alloy powders increases with increasing La content The saturation magnetization(MS) decreases with increasing La addition as a whole.The minimum reflection loss(RL) of La0.4Ce1.6Co17 alloy powder about-42.29 dB can be obtained about-42.29 dB at 7.84 GHz with the matching thickness of 1.8 mm,and the corresponding effective bandwidth can achieve about 2.24 GHz.In addition,the minimum RL frequency moves towards a lower frequency region as the La content increases.The minimum RL of La0.3Ce1.7Co17alloy powder is less than-20 dB ranging from 1.2 to 2.4 mm in the whole 4-16 GHz.The maximum bandwidth can reach about 4.88 GHz at the given thickness of 1.2 mm.In general,these all indicate that the La addition is beneficial to improving the microwave absorbing performance in both effective bandwidth and absorption intensity.展开更多
Magnesium-substituted MnZn ferrites with composition of Mn0.4Zn0.6MgxFe（2-x）O4（x=0.00,0.05） were prepared by citrate-EDTA（ethylenediamine tetraacetic acid） complexing method.The crystal structure,surface morphol...Magnesium-substituted MnZn ferrites with composition of Mn0.4Zn0.6MgxFe（2-x）O4（x=0.00,0.05） were prepared by citrate-EDTA（ethylenediamine tetraacetic acid） complexing method.The crystal structure,surface morphology and electromagnetic properties of the calcined samples were characterized by X-ray diffraction（XRD） analysis,scanning electron microscopy（SEM） and network analyzer（Agilent 8722ET）.All the XRD patterns showed the single phase of the spinel-type MnZn ferrite without other intermediate phase.The lattice parameter and average particle size increased with the substitution of magnesium.The microwave electromagnetic properties of the samples have been studied at the frequency range from 2 to 18 GHz.It was shown that the values of ε′ and ε″ decreased slightly with the substitution of magnesium.The values of μ′ and μ″ were improved significantly,and the peak of μ″ shifted to low frequency with Mg2＋ ions substituting.Furthermore,the reasons have also been discussed by using electromagnetic theory.The reflection loss（RL） ascended after magnesium was substituted.Magnesium-substituted ferrite had excellent microwave absorption properties.The frequency（with respect to-10 dB） started from 11.3 GHz,and the bandwidth reached about 3.5 GHz.The peak value of RL was about-19 dB at a matching thickness of 3.1 mm.展开更多
A novel bunched cerium oxide(CeO_(2))was prepared and its binary composite material with multi-walled carbon nanotubes presented an excellent microwave absorbing properties.The morphology,structure,and absorbing prope...A novel bunched cerium oxide(CeO_(2))was prepared and its binary composite material with multi-walled carbon nanotubes presented an excellent microwave absorbing properties.The morphology,structure,and absorbing properties of the composite material were investigated.It was found that the minimum reflection loss(RL)of the composite material at 15.79 GHz was−45.7 dB when the thickness was 5.5 mm.It was worth noting that when the composite material was in the thickness range of 5.0-7.5 mm and the frequency was 11.36-17.77 GHz,the electromagnetic wave RL was<−30 dB,which illustrated that the composite material had a good absorbing effect over a wide thickness range.The results of the study contributed to the design and preparation of efficient microwave absorbing materials(MAM)with rare earth oxide composites and their applications,which demonstrated the importance of new composites with special structures in the field of MAM.展开更多
Microwave absorbing materials(MAMs)are playing an increasingly essential role in the development of wireless communications,high-power electronic devices,and advanced target detection technology.MAMs with a broad-band...Microwave absorbing materials(MAMs)are playing an increasingly essential role in the development of wireless communications,high-power electronic devices,and advanced target detection technology.MAMs with a broad-bandwidth response are particularly important in the area of communication security,radiation prevention,electronic reliability,and military stealth.Although considerable progress has been made in the design and preparation of MAMs with a broad-bandwidth response,a number of challenges still remain,and the structure–function relationship of MAMs is still far from being completely understood.Herein,the advances in the design and research of MAMs with a broad-bandwidth response are outlined.The main strategies for expanding the effective absorption bandwidth of MAMs are comprehensively summarized considering three perspectives:the chemical combination strategy,morphological control strategy,and macrostructure control strategy.Several important results as well as design principles and absorption mechanisms are highlighted.A coherent explanation detailing the influence of the chemical composition and structure of various materials on the microwave absorption properties of MAMs is provided.The main challenges,new opportunities,and future perspectives in this promising field are also presented.展开更多
基金The National Natural Science Foundation of China(No.51205282)
文摘In order to improve the absorbing properties of M- type barium ferrite absorbing materials, M-type barium ferrite/graphene oxide composites with different graphene oxide contents were synthesized by the sol-gel autocombustion method. X-ray diffraction （XRD）, a scanning electronic microscopy （ SEM ）, a physical properties measurement system （PPMS-9）, and a vector network analyzer were used to analyze their structure, surface morphology, magnetic and absorbing properties, respectively. The results show that the absorbing band of the composite absorbing material is widened and the absorbing strength is increased compared with the pure M-type barium ferrite. The sample with the content of doped graphene oxide of 3% has the minimum reflectivity at 10 to 18 GHz frequencies. Hence, the doped graphene oxide effectively improves the absorbing properties of M-type barium ferrite.
基金financially supported by the National Hi-tech R&D Project Supporting Programs Funded by Ministry of Science&Technology of China(No.2012AA063202)the National Natural Science Foundation of China(Nos.50972013,50802008,and 51004011)+1 种基金the National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science&Technology of China(Nos.2012BAC02B01,2012BAC12B05,2011BAE13B07,and 2011BAC10B02)the Guangdong Province&Ministry of Education Industry-Study-Research United Project(No.2009A090100017)
文摘The electromagnetic and microwave absorbing properties of FeCoB powder composites prepared by sin- gle-roller melt-spinning and mechanical milling processes were investigated in this paper. The result indicates that the flake-like powders are obtained. As milling time increases, the flake-like powder particles tend to agglomerate, causing the flake-like powders decrease gradually. The milling time plays an important role in the electromagnetic parameters which relates to the shape and size of the powder particles. The calculation shows that the sample milled for 6 h could achieve an optimal reflection loss of -11.5 dB at 5.8 GHz, with mass fraction of 83 % and a matching thickness of 1.8 mm. The result also indicates that the microwave absorbing properties of the FeCoB powder composites are adjustable by changing their thickness, and can be applied as a thinner microwave absorbing material in the range of 2-8 GHz.
文摘The effects of types and amounts of silane coupling agent on mechanical properties of vuleanized rubber microwave absorbing patch （VRMAP） were studied. The mechanisms of silane coupling agent＇s effects on mechanical properties of rubber microwave absorbing patch （ RMAP ） and microvave absorbing patch＇s （MAP＇s） mierostrueture were also discussed by using SEM and FT-IR. The experimental results show that the tensile strength of RMAP could be increased through adding the filler of carbonyl iron powder （CIP） modified by silane coupling agent. RMAP fiUed with CIP, which was treated by silane coupling agent KH550, possessed a high tensile strength of 11.5 MPa, which was 448% more than that of MAP whose filler wus not modified by any coupling agent. It was found that the optimal amount of KH550 was 1.0 phr to 100.0 phr carbonyl iron powder. The effects of different modifying techniques on RMAP＇s mechanical properties were also inrestigated. It is indieated that MAP whose filler is modified by the wet process has the highest tensile strength, but it is not the optimal modiifying technique due to complieated wet process. On the contrary, the dry process was very simple, and VRMAP possessed fairly high mechanical properties, therefore, it was the perfect modifying process.
基金Project(JC201006020838A)supported by the Basic Research Funds of Science and Technology Foundation of Shenzhen,China
文摘Two kinds of nickel particles with flower-like struc~＇es assembled with a number of nano-flakes were synthesized and the relationship of their morphology and microwave absorbing properties was studied. The electromagnetic parameters of these flower-like Ni were measured with vector network analyzer at 2-18 GHz frequency and the reflection losses （RL） with different sample thicknesses were calculated. The results indicate that the flower-like nickel-wax composites with the sample thickness less than 2 mm show excellent absorbing ability. This result is expected to play a guiding role in the preparation of the highly efficient absorber.
基金Funded by National Natural Science Foundation of China(Nos.50961005 and 51361007)National Natural Science Foundation of Guangxi(Nos.2012 GXNSFGA06002 and 2013GXNSFAA019295)
文摘REI3Fes4Cr3（RE=Ce, Pr, Tb, Er） and Pr13_XFes4Cr3Ti（x=0, 2, 4, 6） alloy powders were prepared by are smelting method and high energy ball milling technique. The phase structure and the morphology of the alloy powders were investigated by X-ray diffraction （XRD） and scanning electron microscopy （SEM）, and their microwave absorbing properties were determined by a vector network analyzer. The results show that the alloys with light rare earths （Ce, Pr） have good low frequency absorbing property and those with heavy rare earths （Tb, Er） exhibit an improved high frequency absorbing property. The minimum refleetivity at the absorbing peak frequency of RE,FeuCr3（RE=Ce, Pr, Tb, Er） are -9.49 dB at 5.76 GHz, -22.38 dB at 7.92 GHz, -18.52 dB at 11.68 GHz and -17.59 dB at 10.24 GHz, respectively. The absorbing bandwidth under -10 dB of the Pr13FesaCr3 powder was widened from 1.91 GI-Iz to 3.89 GHz by adding 2% Ti, but the reflectivity of the alloy was increased from -22.38 dB to -14.91 riB.
基金Funded by the Natural Science Foundation of Nanping of China(No.N2021J002)Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110304)+3 种基金Guangzhou Science and Technology Plan(No.202102020224)Natural Science Foundation of Fujian Province(No.2020Y0092)Natural Science Foundation of Fujian Province(No.2023J011044)Resource Chemical Industry and Technology Foundation of Nanping(No.N2020Z003)。
文摘To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into different particle sizes by planetary ball mill,and the physicochemical properties of iron tailings were tested by laser particle size analyzer and scanning electron microscope(SEM).The electromagnetic parameters of iron tailings cementitious materials were characterized by a vector network analyzer and simulated MA properties,and the MA properties of iron tailings-cement composite system with steel fiber as absorber was studied.Based on the design of the single-layer structure,optimum mix ratio and thickness configuration method of double-layer structure were further studied,meanwhile,the mechanical properties and engineering application were analyzed and discussed.The results show that the particle size of iron tailings can afiect its electromagnetic behavior in cementitious materials,and the smaller particles lead the increase of demagnetisation efiect induced by domain wall motion and achieve better microwave absorbing properties in cementitious materials.When the thickness of matching layer and absorbing layer is 5 mm,the optimized microwave absorbing properties of C1/C3 double-layer cementitious material can obtain optimal RL value of-27.61 dB and efiective absorbing bandwidth of 0.97 GHz,which attributes to the synergistic efiect of impedance matching and attenuation characteristics.The double-layer microwave absorbing materials obtain excellent absorbing properties and show great design flexibility and diversity,which can be used as a suitable candidate for the preparation of favorable microwave absorbing cementitious materials.
基金Project(2007CB613606) supported by the Major State Basic Research and Development Program of ChinaProject(50734007) supported by the National Natural Science Foundation of China
文摘Microwave absorbing properties of high titanium slag were investigated by using microwave cavity perturbation technique. High titanium slag containing more than 90% TiO2 was prepared by carbothermal reduction of ilmenite. The temperature rise curve of high titanium slag in microwave heating process was obtained. Crystalline compounds of high titanium slag before and after microwave irradiation were obtained and characterized by X-ray diffractometry （XRD）. Effects of particle size of high titanium slag anal mixtures of high titanium slag with different mass fractions of V2o5 on microwave absorbing properties were investigated systematically. The results show that high titanium slag has good microwave absorption property; untreated high titanium slag mainly consists of crystalline compounds of anatase and iron titanium oxide, while the microwave-irradiation treated one is mainly composed of crystalline compounds of rutile and irgn titanium oxide. Synthetic anatase is transformed completely into rutile at about 1 050 ℃ for 20 min under microwave irradiation. High frequency shift and low amplitude of voltage make high titanium slag an ideal microwave absorbent. 180 μm of particle size and 10% mass fraction of V2O5 are found to be the optimum conditions for microwave absorption.
文摘In this paper,Fe-Al solid solution was prepared by mechanical alloying technology,and Fe-Al powder was dispersed into unsaturated polyester (UP) with different contents as absorber to form mixture Fe-Al-UP.The results indicate that the alloying process is almost accomplished and most of the particles are nanometer.Meanwhile,the microwave absorbability of Fe-Al-UP samples in frequency from 0.3 MHz to 1.5 GHz was studied.The results indicate that the more the absorber,the better the absorbing property.The absorbing property of Fe-50Al-UP was slightly higher than Fe-28Al-UP.
文摘The microwave absorbing behaviour of Mn-Zn ferrite sintered at 1100,1200,1300,1400 and 1500℃ has been investigated.The phase constitution of the ferrite was analyzed by X-ray diffraction.The results show that the ferrite sintered at 1 500℃ has better microwave absorbing prop- erty than those prepared at other temperatures,due to the increase of turbulent loss generated by the formation of excessive Fe^(2+) in deoxidizing of Fe_2O_3 at high temperatures.
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20121101110014)
文摘Magnesium-substituted Mn0.8Zn0.2Fe2O4 ferrite is synthesized by the sol–gel combustion method using citrate acid as the complex agent. The electromagnetic absorbing behaviors of ferrite/polymer coatings fabricated by dispersing Mn–Zn ferrite into epoxy resin （EP） are studied. The microstructure and morphology are characterized by X-ray diffraction and scanning electron microscope. Complex permittivity, complex permeability, and reflection loss of ferrite/EP composite coating are investigated in a low frequency range. It is found that the prepared ferrite particles are traditional cubic spinel ferrite particles with an average size of 200 nm. The results reveal that the electromagnetic microwave absorbing properties are significantly influenced by the weight ratio of ferrite to polymer. The composites with a weight ratio of ferrite/polymer being 3：20 have a maximum reflection loss of –16 dB and wide absorbing band. Thus, the Mn–Zn ferrite is the potential candidate in electromagnetic absorbing application in the low frequency range （10 MHz–1 GHz）.
基金Project(51072165)supported by the National Natural Science Foundation of ChinaProject(201305)supported by the Fund of State Key Laboratory of Solidification Processing,ChinaProjects(2013JK0921,2013JK0922)supported by Shaanxi Provincial Education Department of China
文摘The SiCf/SiC composites containing PyC interphase were prepared by chemical vapor infiltration process. The influences of thermal oxidation on the complex permittivity and microwave absorption properties of Si Cf/Si C composites were investigated in the frequency range of 8.2-12.4 GHz. Both the real and imaginary parts of the complex permittivity decreased after thermal oxidation. The composites after 100 h thermal oxidation showed that reflection loss exceeded-10 d B in the frequency of 9.7-11.9 GHz and the minimum value was-11.4 d B at 11.0 GHz. The flexural strength of composites decreased but fracture behavior was improved obviously after thermal oxidation. These results indicate that the SiCf/SiC composites containing PyC interphase after thermal oxidation possess good microwave absorbing property and fracture behavior.
基金financially supported by the National Natural Science Foundation of China(No.51103125)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(Chemistry)+2 种基金the Natural Science Foundation of Yangzhou(No.YZ2014043)the Science Innovative Foundation of Yangzhou University(No.2014CXJ017)the Graduate Student Innovation foundation of Yangzhou University(No.CXLX 1413)
文摘La-doped Sr-hexaferrite（Sr（1-x）LaxFe（12）O（19））（x=0.05,0.10,0.15,0.20） nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation temperature increases, while the particle size decreases as the Ladoping content goes up. The partial substitution of Sr^（2＋） by La^（3＋） results in the suppression effects on the growth-up of the crystallites and the enhancement of the electron hopping between Fe^（3＋） with different valences, which leads to the improvement in the dielectric loss and magnetic loss.Therefore, both the microwave absorbing abilities and absorbing frequency ranges are tuned by La-doping. The synthesized Sr-hexaferrite nanopowders with doping element content of 0.10 demonstrate the fine broad microwave absorbing properties.
基金supported by the Natural Science Foundation of China(51902083,62104060)the Foundation Strengthening Program(2019-JCJQ-142-00)+2 种基金Natural Science Foundation of Hebei Province(F2021202066)Higher Education Science and Technology Research Project of Hebei Province(ZD2019087,ZD2021027)Star of Science and Technology in Hebei University of Technology(JBKYXX2001).
文摘Composite fabrics with excellent microwave absorbing performance are highly desired.Herein,reduced graphene oxide/carbon nanofiber(rGO/CNF)based composite fabrics with spider web-like structure were successfully synthesized by electrostatic spinning technique.The spider web-like structure in the composite fabrics provides a connected network for efficient conductive loss of microwave energies.Magnetic loss benefits from the deposited nickel nanoparticles(Ni NPs)anchored in the carbon nanofibers.Meanwhile,the deposited thin polypyrrole(PPy)layers on the conductive network acts as a protective layer for Ni NPs as well as provides abundant interfaces for dissipating electromagnetic energies,which endow the composite fabrics stable microwave absorbing performance.Due to the synergistic effect of microwave absorb-ing mechanism,the maximum reflection loss(RL_(max))of the composite fabric at 6.72 GHz is-46.15 dB,and the effective absorption bandwidth(EAB)is as wide as 8.63 GHz(from 9.37 to 18 GHz).What's more,favorable mechanical and heat insulation properties of the composite fabrics reveal its multifunctional advantages.This rGO/CNF based composite fabric demonstrates a new direction for multifunctional and flexible microwave absorbing materials(MAMs).
基金supported by the National Natural Science Foundation of China (Grant No. 90505008)the Weaponry Equipment Preresearch Foundation of China (Grant No. 51410040305HK0214)
文摘The microwave absorption property and infrared emissivity have been investigated for the single-layer coating made of the epoxy-polyurethane resin and carbonyl iron powders with variation of annealing treatment. Microwave-absorbing property was investigated by measuring the complex permittivity and complex permeability of the absorber in the frequency range from 2 to 18 GHz. Infrared emissivity value was measured using IR-2 Infrared Emissometer in the wavelength range of 8-14 μm. After annealing, the Fe （110） peak became sharp, and the crystallization improved significantly. Annealing treatment could reduce the sttrface energy of powders, improve compatibility between fillers and adhesives, and result in increase of the density of the coating. The lowest value of infrared emissivity （0.419） was obtained from the coating made of the carbonyl iron powder annealed at 700℃ for 1 h. With the variation of the annealing temperature, the magnetic and dielectric properties of the carbonyl iron particle were changed. The maximum reflection loss decreased and the matching frequency shifted to lower frequency with increasing the annealing temperature of carbonyl iron particles, which coincided with the variation of the complex permeability and permittivity according to the annealing temperature. Magnetic loss factor and dielectric loss factor of carbonyl iron particles were improved with increasing the annealing temperature in the 2-18 GHz range.
基金Project supported by the Ministry of Finance Indonesia for the research grant through the competitive research program of RISPRO Kompetisi(PRJ-45/LPDP/2020)。
文摘Synthesis and characterization of lanthanum-doped yttrium iro n garnet(YIG)in the compositional se ries of Y_(3-x)La_(x)Fe_(5)O_(12)(x=0.0,0.1,0.3,and 0.5)were carried out.All compositions were made by using solid state reaction method with ball-milling technique.The phase formation,surface morphology,magnetic properties,and microwave absorbing ability of all compositions were characterized by using an X-ray diffractometer,a scanning electron microscope,a vibrating sample magnetometer,and a Vector network analyzer.The results reveal that all compositions are crystallized into Y_(3)Fe_(5)O_(12)phase(space group la-3d(230).It was observed that the lattice constant is increased from 1.2373 to 1.2421 nm with the increase of lanthanum substitution level from x=0.0-0.5.The crystallite size of Y_(3-x)La_(x)Fe_(5)O_(12)series calculated by Scherrer method is found to decrease from 78 nm in x=0.0-63 nm in x=0.5.The particle size distribution from the surface morphology image analysis is shifted to lower-range number with the increase of lanthanum substitution level from x=0.0 to 0.5.The substitution process also affects the lattice distortion in La-doped samples and changes the bond angles and bond lengths of the YIG structure.As the results,a linear correlation between the Fe'-O-Fe bond angle with magnetic properties parameters of saturation magnetization(M_(s))and remanence magnetization(M_(r))was studied.Due to the lanthanum substitution process,all La^(3+)-doped samples possess higher M_(s)and M_(r)values compared to the original composition.The results of Vector network analyzer show that the improvement of the M_(s)and M_(r)plays an important role in enhancing the microwave absorbing ability of the materials.The minimum RL changes from-8.22 dB(~85.22%microwave absorption)in x=0.0 to-14.21 dB(~96.25%microwave absorption)in x=0.5.The enhancement is mainly ascribed to the natural magnetic resonance loss and dipoIe-polarization loss due to the substitution process.The decreasing particle size also enhances the microwave absorbing ability of the La-doped samples via multiple-reflections mechanism.
基金financially supported by the Natural Science Foundation of Liaoning Province(No.2014020094)the Key Laboratory Construction Fund of Shenyang(No.F14187-1-00)
文摘The spinel cobalt chromium zinc ferrites（Co0.7Cr0.1Zn0.2Fe2O4） and the polyaniline（PANI）-Co0.7Cr0.1Zn0.2Fe2O4 composites were prepared by polyacrylamide gel and an in situ polymerization method,respectively.The structure of the synthesized material was characterized by X-ray diffraction（XRD） and Fourier transform infrared spectrometer（FTIR）,which shows that the spinel Co0.7Cr0.1Zn0.2Fe2O4 ferrites and the PANI Co0.7Cr0.1Zn0.2Fe2O4 composites are obtained.As a small amount of Co^2＋ in the octahedron ferrite is replaced by Cr^3＋,the lattice constant of Co0.8Cr0.2Zn0.2Fe2O4 ferrites reduces from0.8409 to 0.8377 nm.The magnetic properties of the two materials were investigated by vibrating sample magnetometer（VSM）.The VSM results confirm that the saturation magnetization（Ms）,remanent magnetization（Mr） and coercive force（Hc） of the PANI-Co0.7Cr0.1Zn0.2Fe2O4composites are 8.80 mA·m^2·g^-1,3.14 mA·m^2·g^-1 and37.22 kA·m^-1,respectively,which are smaller than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites.The microwave absorbing capability of the two materials was studied by waveguide method.In the frequency range of 5-20 GHz,two reflection loss maximum values of the PANI-Co0.7Cr0.1Zn0.2Fe2O4 composites appear at 14.1 and 17.9 GHz with-13.17 and-15.36 dB,respectively,which are obviously higher than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites.
基金Project supported by the National Natural Science Foundation of China (51361007)2017 Director Fund of Guangxi Key Laboratory of Wireless Wideband Communication and Signal Processing (GXKL06170107)。
文摘The composites of Ce-Co-based alloys doped with La content were fabricated via a vacuum arc melting method.The influences of La addition on microstructure,electromagnetic parameters,magnetic property and microwave absorbing property were measured by the corresponding equipment.The morphology characteristics manifest that all samples display sheet structure,and the average particle size of alloy powders increases with increasing La content The saturation magnetization(MS) decreases with increasing La addition as a whole.The minimum reflection loss(RL) of La0.4Ce1.6Co17 alloy powder about-42.29 dB can be obtained about-42.29 dB at 7.84 GHz with the matching thickness of 1.8 mm,and the corresponding effective bandwidth can achieve about 2.24 GHz.In addition,the minimum RL frequency moves towards a lower frequency region as the La content increases.The minimum RL of La0.3Ce1.7Co17alloy powder is less than-20 dB ranging from 1.2 to 2.4 mm in the whole 4-16 GHz.The maximum bandwidth can reach about 4.88 GHz at the given thickness of 1.2 mm.In general,these all indicate that the La addition is beneficial to improving the microwave absorbing performance in both effective bandwidth and absorption intensity.
基金supported by the National Defence Fundamental Research of China under grant No.MKPT-232
文摘Magnesium-substituted MnZn ferrites with composition of Mn0.4Zn0.6MgxFe（2-x）O4（x=0.00,0.05） were prepared by citrate-EDTA（ethylenediamine tetraacetic acid） complexing method.The crystal structure,surface morphology and electromagnetic properties of the calcined samples were characterized by X-ray diffraction（XRD） analysis,scanning electron microscopy（SEM） and network analyzer（Agilent 8722ET）.All the XRD patterns showed the single phase of the spinel-type MnZn ferrite without other intermediate phase.The lattice parameter and average particle size increased with the substitution of magnesium.The microwave electromagnetic properties of the samples have been studied at the frequency range from 2 to 18 GHz.It was shown that the values of ε′ and ε″ decreased slightly with the substitution of magnesium.The values of μ′ and μ″ were improved significantly,and the peak of μ″ shifted to low frequency with Mg2＋ ions substituting.Furthermore,the reasons have also been discussed by using electromagnetic theory.The reflection loss（RL） ascended after magnesium was substituted.Magnesium-substituted ferrite had excellent microwave absorption properties.The frequency（with respect to-10 dB） started from 11.3 GHz,and the bandwidth reached about 3.5 GHz.The peak value of RL was about-19 dB at a matching thickness of 3.1 mm.
文摘A novel bunched cerium oxide(CeO_(2))was prepared and its binary composite material with multi-walled carbon nanotubes presented an excellent microwave absorbing properties.The morphology,structure,and absorbing properties of the composite material were investigated.It was found that the minimum reflection loss(RL)of the composite material at 15.79 GHz was−45.7 dB when the thickness was 5.5 mm.It was worth noting that when the composite material was in the thickness range of 5.0-7.5 mm and the frequency was 11.36-17.77 GHz,the electromagnetic wave RL was<−30 dB,which illustrated that the composite material had a good absorbing effect over a wide thickness range.The results of the study contributed to the design and preparation of efficient microwave absorbing materials(MAM)with rare earth oxide composites and their applications,which demonstrated the importance of new composites with special structures in the field of MAM.
基金supported by the National Natural Science Foundation of China(Nos.21771151 and 21931009).
文摘Microwave absorbing materials(MAMs)are playing an increasingly essential role in the development of wireless communications,high-power electronic devices,and advanced target detection technology.MAMs with a broad-bandwidth response are particularly important in the area of communication security,radiation prevention,electronic reliability,and military stealth.Although considerable progress has been made in the design and preparation of MAMs with a broad-bandwidth response,a number of challenges still remain,and the structure–function relationship of MAMs is still far from being completely understood.Herein,the advances in the design and research of MAMs with a broad-bandwidth response are outlined.The main strategies for expanding the effective absorption bandwidth of MAMs are comprehensively summarized considering three perspectives:the chemical combination strategy,morphological control strategy,and macrostructure control strategy.Several important results as well as design principles and absorption mechanisms are highlighted.A coherent explanation detailing the influence of the chemical composition and structure of various materials on the microwave absorption properties of MAMs is provided.The main challenges,new opportunities,and future perspectives in this promising field are also presented.
