Heteroaggregates composed of cationic porphyrin, meso-tetra(p-trimethylamino)porphyrin iodide, its sine complex and anionic phthalocyanine sodium hydroxygallium 4,4',4 '',4 ''-tetrasulfonated phtha...Heteroaggregates composed of cationic porphyrin, meso-tetra(p-trimethylamino)porphyrin iodide, its sine complex and anionic phthalocyanine sodium hydroxygallium 4,4',4 '',4 ''-tetrasulfonated phthalocyanine have been investigated by absorption and fluorescence spectroscopy. It has been found that both free base cationic porphyrin and its zinc complex can form very stable heterodimers with anionic phthalocyanine in water, methanol and dimethylformamide. The stability of the aggregate depends on the polarity as well as the ligation ability of the solvent. No evidence of higher aggregates was detected. Besides axial coordination, steric hindrance which influences the relative orientation of the macrocycles are considered.展开更多
The ocean serves as a repository for various types of artificial nanoparticles.Nanoplastics(NPs)and nano zinc oxide(nZnO),which are frequently employed in personal care products and food packaging materials,are likely...The ocean serves as a repository for various types of artificial nanoparticles.Nanoplastics(NPs)and nano zinc oxide(nZnO),which are frequently employed in personal care products and food packaging materials,are likely simultaneously released and eventually into the ocean with surface runoff.Therefore,their mutual influence and shared destiny in marine environment cannot be ignored.This study examined how nanomaterials interacted and transported through sea sand in various salinity conditions.Results showed that NPs remained dispersed in brine,while nZnO formed homoaggregates.In seawater of 35 practical salinity units(PSU),nZnO formed heteroaggregates with NPs,inhibiting NPs mobility and decreasing the recovered mass percentage(Meff)from 24.52%to 12.65%.In 3.5 PSU brackish water,nZnO did not significantly aggregate with NPs,and thus barely affected their mobility.However,NPs greatly enhanced nZnO transport with Meff increasing from 14.20%to 25.08%,attributed to the carrier effect of higher mobility NPs.Cotransport from brackishwater to seawater was simulated in salinity change experiments and revealed a critical salinity threshold of 10.4 PSU,below which the mobility of NPs was not affected by coexisting nZnO and above which nZnO strongly inhibited NP transport.This study highlights the importance of considering the mutual influence and shared destiny of artificial nanoparticles in the marine environment and how their interaction and cotransport are dependent on changes in seawater salinity.展开更多
基金Project supperted the National Science Foundation of China and the Laboratory of Excited State Processes,Changchun Institute of Physics,Chinese Academy of Science.
文摘Heteroaggregates composed of cationic porphyrin, meso-tetra(p-trimethylamino)porphyrin iodide, its sine complex and anionic phthalocyanine sodium hydroxygallium 4,4',4 '',4 ''-tetrasulfonated phthalocyanine have been investigated by absorption and fluorescence spectroscopy. It has been found that both free base cationic porphyrin and its zinc complex can form very stable heterodimers with anionic phthalocyanine in water, methanol and dimethylformamide. The stability of the aggregate depends on the polarity as well as the ligation ability of the solvent. No evidence of higher aggregates was detected. Besides axial coordination, steric hindrance which influences the relative orientation of the macrocycles are considered.
基金supported by the National Natural Science Foundation of China (No.22176148)the Shanghai Rising-Star Program (No.23QB1406400)+1 种基金the Fundamental Research Funds for the Central Universities of Tongji University (No.2023-3-ZD-02)supported by the program INTPART (Plastic Pollution,No.275172)funded by the Research Council of Norway.
文摘The ocean serves as a repository for various types of artificial nanoparticles.Nanoplastics(NPs)and nano zinc oxide(nZnO),which are frequently employed in personal care products and food packaging materials,are likely simultaneously released and eventually into the ocean with surface runoff.Therefore,their mutual influence and shared destiny in marine environment cannot be ignored.This study examined how nanomaterials interacted and transported through sea sand in various salinity conditions.Results showed that NPs remained dispersed in brine,while nZnO formed homoaggregates.In seawater of 35 practical salinity units(PSU),nZnO formed heteroaggregates with NPs,inhibiting NPs mobility and decreasing the recovered mass percentage(Meff)from 24.52%to 12.65%.In 3.5 PSU brackish water,nZnO did not significantly aggregate with NPs,and thus barely affected their mobility.However,NPs greatly enhanced nZnO transport with Meff increasing from 14.20%to 25.08%,attributed to the carrier effect of higher mobility NPs.Cotransport from brackishwater to seawater was simulated in salinity change experiments and revealed a critical salinity threshold of 10.4 PSU,below which the mobility of NPs was not affected by coexisting nZnO and above which nZnO strongly inhibited NP transport.This study highlights the importance of considering the mutual influence and shared destiny of artificial nanoparticles in the marine environment and how their interaction and cotransport are dependent on changes in seawater salinity.
