An attempt was made to improve the spatio-temporal resolution of the tangen- tial X-ray crystal spectrometer （XCS） on the Experimental Advanced Superconducting Tokamak （EAST） by evaluating experimentally the appli...An attempt was made to improve the spatio-temporal resolution of the tangen- tial X-ray crystal spectrometer （XCS） on the Experimental Advanced Superconducting Tokamak （EAST） by evaluating experimentally the applicability of a novel X-ray photon detection tech- nology for measuring the satellite spectra of Ar XVII with a high counting rate. High-resolution experimental data on the profiles of ion temperature and plasma rotation velocity facilitate the studies of the mechanisms underlining important physical phenomena, such as plasma heating, L-H transition and momentum transport. Based on silicon diode array and single-photon counting technology, a relatively small area （83.8 x 33.5 mm~） two-dimensional detector was successfully in- stalled and tested in the recent EAST campaign. X-ray photon counting rate higher than 20 MHz was observed for the first time, and high quality satellite spectra were recorded for ion temperature and plasma rotation measurement, indicating that the new technology is suitable for the next-step high-resolution XCS on EAST, and the deployment of a detector array with a much larger X-ray sensing area is planned for better plasma coverage.展开更多
Spectral measurement of tungsten(W)impurity is essential to study impurity transport.Therefore,an X-ray crystal spectrometer(XCS)on EAST was used to measure the line spectra from highly ionized W ions.On EAST,both pol...Spectral measurement of tungsten(W)impurity is essential to study impurity transport.Therefore,an X-ray crystal spectrometer(XCS)on EAST was used to measure the line spectra from highly ionized W ions.On EAST,both poloidal XCS and tangential XCS have been developed to measure the plasma temperature as well as the rotation velocity.Recently,He-like and H-like argon spectra have also been obtained using a two-crystal setup.W lines are identified in this study.Through a careful analysis,the W lines of 3.9336,3.9321,and 3.664(A)are found to be diffracted by He-like or H-like crystals.The lines are confirmed with the NIST database.We also calculated the ion temperature with Doppler broadening of these lines.The ion temperature from the W lines is entirely consistent with that from Ar line spectra.The measurement of these W line spectra could be used to study W impurity transport in future work.展开更多
Highly oriented pyrolitic graphite （HOPG） has high X-ray diffraction efficiency due to its unique mosaic crystal structure, and thus is very suitable for its application to X-ray Thomson scattering measurement of so...Highly oriented pyrolitic graphite （HOPG） has high X-ray diffraction efficiency due to its unique mosaic crystal structure, and thus is very suitable for its application to X-ray Thomson scattering measurement of solid-density plasmas. In this article, by using the K-shell X-ray source from laser-produced Ti plasma, the properties of the HOPG spectrometer are characterized and compared with those of the flat Pentaerythritol （PET） spectrometer. The results show that the diffraction efficiency of the HOPG spectrometer under focusing condition is an order higher than that of the PET spectrometer, while the spectral resolution of the HOPG is about 320, high enough to be used in the measurement of X-ray Thomson scattering spectra.展开更多
Inversion techniques are conducted based on the tangential x-ray crystal spectroscopy(TXCS)geometry on EAST to obtain the local profiles of ion temperature(Ti)and toroidal rotation velocity(vt).Firstly,local emissivit...Inversion techniques are conducted based on the tangential x-ray crystal spectroscopy(TXCS)geometry on EAST to obtain the local profiles of ion temperature(Ti)and toroidal rotation velocity(vt).Firstly,local emissivity profiles of the impurity argon are obtained using the asymmetrical Abel inversion.Then,the local vt and Ti profiles are calculated by considering the local emissivity profiles and the TXCS detailed geometry.In addition,how the changes in the vt profiles affect the accuracy in the Ti profiles is discussed in detail.It is also found that the lineintegrated Ti profiles are becoming less accurate with the increase in the radial gradient in the local vt profiles.Nonetheless,accurate Ti radial profiles are reconstructed after considering the effects of the emissivity and velocity,which are verified by comparing the inverted vt and Ti profiles with those local profile measurements from the Charge eXchange Recombination Spectroscopy(CXRS)on EAST.展开更多
A Johann-type X-ray spectrometer was successfully developed at the hard X-ray branch(in-vacuum undulator with a 24-mm periodic length)of the energy material beamline(E-line)at the Shanghai Synchrotron Radiation Facili...A Johann-type X-ray spectrometer was successfully developed at the hard X-ray branch(in-vacuum undulator with a 24-mm periodic length)of the energy material beamline(E-line)at the Shanghai Synchrotron Radiation Facility(SSRF).This spectrometer was utilized to implement X-ray emission spectroscopy(XES),high-energy resolution fluorescence-detected X-ray absorption spectroscopy(HERFD-XAS),and resonant inelastic X-ray scattering.Seven spherically bent crystals were positioned on the respective vertical 500-mm-diameter Rowland circles,adopting an area detector to increase the solid angle to 1.75%of 4πsr,facilitating the study of low-concentrate systems under complex reaction conditions.Operated under the atmosphere pressure,the spectrometer covers the energy region from 3.5 to 18 keV,with the Bragg angle ranging from 73°to 86°during vertical scanning.It offers a promised energy resolution of sub-eV(XES)and super-eV(HERFD-XAS).Generally,these comprehensive core-level spectroscopy methods based on hard X-rays at the E-line with an extremely high photon flux can meet the crucial requirements of a green energy strategy.Moreover,they provide substantial support for scientific advances in fundamental research.展开更多
The lattice parameter,measured with sufficient accuracy,can be utilized to evaluate the quality of single crystals and to determine the equation of state for materials.We propose an iterative method for obtaining more...The lattice parameter,measured with sufficient accuracy,can be utilized to evaluate the quality of single crystals and to determine the equation of state for materials.We propose an iterative method for obtaining more precise lattice parameters using the interaction points for the pseudo-Kossel pattern obtained from laser-induced X-ray diffraction(XRD).This method has been validated by the analysis of an XRD experiment conducted on iron single crystals.Furthermore,the method was used to calculate the compression ratio and rotated angle of an LiF sample under high pressure loading.This technique provides a robust tool for in-situ characterization of structural changes in single crystals under extreme conditions.It has significant implications for studying the equation of state and phase transitions.展开更多
Currently,with the advent of high-repetition-rate laser-plasma experiments,the demand for online diagnosis for the X-ray spectrum is increasing because the laser-plasma-generated X-ray spectrum is very important for c...Currently,with the advent of high-repetition-rate laser-plasma experiments,the demand for online diagnosis for the X-ray spectrum is increasing because the laser-plasma-generated X-ray spectrum is very important for characterizing electron dynamics and applications.In this study,scintillators and silicon PIN(P-type–intrinsic-N-type semiconductor)diodes were used to construct a wideband online filter stack spectrometer.The X-ray sensor and filter arrangement was optimized using a genetic algorithm to minimize the condition number of the response matrix.Consequently,the unfolding error was significantly reduced based on numerical experiments.The detector responses were quantitatively calibrated by irradiating the scintillator and PIN diode with various nuclides and comparing the measuredγ-ray peaks.A prototype 15-channel spectrometer was developed by integrating an X-ray detector with front-and back-end electronics.The prototype spectrometer could record X-ray pulse signals at a repetition rate of 1 kHz.Furthermore,an optimized spectrometer was employed to record the real-time spectra of laser-driven bremsstrahlung sources.This optimized spectrometer offers a compact solution for spectrum diagnostics of ultrashort X-ray pulses,exhibiting improved accuracy in terms of spectrum measurements and repetition rates,and could be widely used in next-generation high-repetition-rate high-power laser facilities.展开更多
To simultaneously measure the He-like and H-like argon spectra, a two-crystal assembly has been deployed to replace the previous single crystal on the tangential x-ray crystal spectrometer.By selecting appropriate cry...To simultaneously measure the He-like and H-like argon spectra, a two-crystal assembly has been deployed to replace the previous single crystal on the tangential x-ray crystal spectrometer.By selecting appropriate crystals with similar Bragg angles, plasma temperature in the range of 0.5 keV≤Te≤10 keV and rotation can be diagnosed based on the He-like and H-like argon spectra. However, due to the added complexity in the two-crystal assembly in which the spectra might be diffracted by two crystals, some additional impurity lines were identified. For example,tungsten（W） lines in different ionization states were diffracted by the He-like and H-like crystal.Additional molybdenum（Mo） lines in the wavelength range of He-like and H-like argon spectra lines were also summarized. The existence of these additional lines caused the fitted temperature to be different from the true values. This paper presents the identified lines through a comparison with available database, which should be included in the fitting procedure.展开更多
A new simple method is presented for the wavelength calibration and measurement of poloidal rotation velocities with X-ray imaging crystal spectrometer（XICS）in magnetic fusion devices.In this method,the toroidal rot...A new simple method is presented for the wavelength calibration and measurement of poloidal rotation velocities with X-ray imaging crystal spectrometer（XICS）in magnetic fusion devices.In this method,the toroidal rotation of plasma is applied for high precise alignment and wavelength calibration of the poloidal XICS.The measurement threshold of poloidal rotation velocity can be lowered to 1-3 km/s with this method.展开更多
Laser-driven proton-induced x-ray emission(laser-PIXE) is a nuclear analysis method based on the compact laser ion accelerator. Due to the transient process of ion acceleration, the laser-PIXE signals are usually spur...Laser-driven proton-induced x-ray emission(laser-PIXE) is a nuclear analysis method based on the compact laser ion accelerator. Due to the transient process of ion acceleration, the laser-PIXE signals are usually spurted within nanoseconds and accompanied by strong electromagnetic pulses(EMP), so traditional multi-channel detectors are no longer applicable.In this work, we designed a reflective elliptical crystal spectrometer for the diagnosis of laser-PIXE. The device can detect the energy range of 1 keV–11 ke V with a high resolution. A calibration experiment was completed on the electrostatic accelerator of Peking University using samples of Al, Ti, Cu, and ceramic artifacts. The detection efficiency of the elliptical crystal spectrometer was obtained in the order of 10-9.展开更多
We report on using synthetic silicon for a high-precision X-ray polarimeter comprising a polarizer and an analyzer,each based on a monolithic channel-cut crystal used at multiple Brewster reflections with a Bragg angl...We report on using synthetic silicon for a high-precision X-ray polarimeter comprising a polarizer and an analyzer,each based on a monolithic channel-cut crystal used at multiple Brewster reflections with a Bragg angle very close to 45°.Experiments were performed at the BL09B bending magnet beamline of the Shanghai Synchrotron Radiation Facility using a Si(800)crystal at an X-ray energy of 12.914 keV.A polarization purity of 8.4×10^(-9)was measured.This result is encouraging,as the measured polarization purity is the best-reported value for the bending magnet source.Notably,this is the firstly systematic study on the hard X-ray polarimeter in China,which is crucial for exploring new physics,such as verifying vacuum birefringence.展开更多
A spaceborne hard X-ray spectrometer, composed of an array of 99 scintillation detectors and associated readout electronics, has been developed for the hard X-ray imager(HXI). The HXI is one of the three payloads onbo...A spaceborne hard X-ray spectrometer, composed of an array of 99 scintillation detectors and associated readout electronics, has been developed for the hard X-ray imager(HXI). The HXI is one of the three payloads onboard the advanced space-based solar observatory(ASO-S), which is scheduled to be launched in early 2022 as the first Chinese solar satellite. LaBr3 scintillators and photomultiplier tubes with a super bialkali cathode are used to achieve an energy resolution better than 20% at 30 keV.Further, a new multi-channel charge-sensitive readout application-specific integrated circuit guarantees high-frequency data acquisition with low power consumption. This paper presents a detailed design of the spectrometer for the engineering model of the HXI and discusses its noise and linearity performance.展开更多
A new time-resolved shifted dual transmission grating spectrometer （SDTGS） is designed and fabricated in this work. This SDTGS uses a new shifted dual transmission grating （SDTG） as its dispersive component, which...A new time-resolved shifted dual transmission grating spectrometer （SDTGS） is designed and fabricated in this work. This SDTGS uses a new shifted dual transmission grating （SDTG） as its dispersive component, which has two sub transmission gratings with different line densities, of 2000 lines/mm and 5000 lines/mm. The axes of the two sub transmission gratings in SDTG are horizontally and vertically shifted a certain distance to measure a broad range of 0.1-5 keV time-resolved X-ray spectra. The SDTG has been calibrated with a soft X-ray beam of the synchrotron radiation facility and its diffraction efficiency is also measured. The designed SDTGS can take full use of the space on a record panel and improve the precision for measuring spatial and temporal spectrum simultaneously. It will be a promising application for accurate diagnosis of the soft X-ray spectrum in inertial confinement fusion.展开更多
In order to mitigate the effect of the strong electromagnetic pulse, which produces laser-plasma interactions, we designed a new streaked X-ray spectrometer （SXS） enclosed within a well-sealed, electromag- netic int...In order to mitigate the effect of the strong electromagnetic pulse, which produces laser-plasma interactions, we designed a new streaked X-ray spectrometer （SXS） enclosed within a well-sealed, electromag- netic interference-free cavity. The SXS can cover a wide selection of spectral windows using interchangeable Bragg crystals and by appropriate adjustment of the Bragg angle. The SXS has been used to observe time-re- solved X-ray spectrum in the 2.5 keV to 3.5 keV photon-energy range, resulting in a demonstrated spectral res- olution of about 13 at 2960 eV with a time resolution of 10 ps. The observed time and spectral resolutions dem- onstrate the applicability of the SXS for studies of laser-produced plasmas.展开更多
A ray tracing method is introduced for helping adjustment and spectra analysis of the grazing incidence flat-field imaging soft X-ray spectrometer. For a single point source, the spectra images obtained by separate co...A ray tracing method is introduced for helping adjustment and spectra analysis of the grazing incidence flat-field imaging soft X-ray spectrometer. For a single point source, the spectra images obtained by separate components, the toroidal mirror, and the grazing incidence flat-field concave grating with varied line spaces are given respectively. The calculated spectral images of the single point source by the spectrometer are also given for comparison with measurements with different experimental alignments.展开更多
The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectro...The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectrometry, sometimes it exceeds the quality control limit.Influences, such as current, voltage, equipment(internal circulating water, 10%CH4+90%Ar, and vacuum) checking, instrument monitoring, sample cleaning, and oper-ators, were investigated by means of 6-sigma and lean operations to improve accuracy.展开更多
INTRODUCTIONThe studies on the quantitative distribution of the conventional elements and their phases in the sediments of the Changjiang Estuary are of great importance to the understanding of the chemical processes ...INTRODUCTIONThe studies on the quantitative distribution of the conventional elements and their phases in the sediments of the Changjiang Estuary are of great importance to the understanding of the chemical processes of ion exchange, absorption, desorption and flocculation in the estuary.展开更多
An experiment facility has been set up for the study of metal cluster compounds in our laboratory, which consists of a nano-electrospray ionization source, an ion transmission and focus system, and a reflectron time-o...An experiment facility has been set up for the study of metal cluster compounds in our laboratory, which consists of a nano-electrospray ionization source, an ion transmission and focus system, and a reflectron time-of-fight mass spectrometer. Taking advantage of the nano-electrospray ionization source, polyvalent ions are usually produced in the ＂ionization＂ process and the obtained mass resolution of the equipment is over 8000. The molecular ion peaks of metal cluster compounds [Au20（PPhpy2）10Cl2]（SbF6）4, where PPhpy2=bis（2- pyridyl）phenylphosphine, and [AuaAg2（C）L6]（BF4）4, where L=2-（diphenylphosphino）-5- methylpyridine, are distinguished in the respective mass spectrum, accompanied by some fragment ion peaks. In addition, the mass-to-charge ratios of the parent ions are determi- nated. Preliminary results suggest that the device is a powerful tool for the study of metal cluster compounds. It turns out that the information obtained by the instrumentation serves as an essential supplement to single crystal X-ray diffraction for structure characterization of metal cluster compounds.展开更多
The synthesis and X-ray crystal structure of a new molecular clip 2 was reported. It （C24H24N4O2, Mr = 400.47） crystallizes in the space group C2/c with a = 15.587（2）, b = 8.5805（12）, c = 15.259（2） A, β = 102...The synthesis and X-ray crystal structure of a new molecular clip 2 was reported. It （C24H24N4O2, Mr = 400.47） crystallizes in the space group C2/c with a = 15.587（2）, b = 8.5805（12）, c = 15.259（2） A, β = 102.448（3）°, V= 1992.9 （5）A63, Z = 4, Dc = 1.335 g/cm63,μ = 0.087 mm^-1 and F（000） = 848. It remains monomeric in the crystal and a tape-like structure is formed in the crystal structure of molecular clip. The most unusual structural feature of 2 is the boat conformation of its cyclohexyl ring imposed by the ring fusion at C（9）-C（9a）.展开更多
Monochromatic x-ray imaging is an essential method for plasma diagnostics related to density information.Large-field high-resolution monochromatic imaging of a He-like iron(Fe XXV)Kαcharacteristic line(6.701 keV)for ...Monochromatic x-ray imaging is an essential method for plasma diagnostics related to density information.Large-field high-resolution monochromatic imaging of a He-like iron(Fe XXV)Kαcharacteristic line(6.701 keV)for laser plasma diagnostics was achieved using a developed toroidal crystal x-ray imager.A high-index crystal orientation Ge(531)wafer with a Bragg angle of 75.37°and the toroidal substrate were selected to obtain sufficient diffraction efficiency and compensate for astigmatism under oblique incidence.A precise offline assembly method of the toroidal crystal imager based on energy substitution was proposed,and a spatial resolution of 3-7μm was obtained by toroidal crystal imaging of a 600 line-pairs/inch Au grid within an object field of view larger than 1.0 mm.The toroidal crystal x-ray imager has been successfully tested via side-on backlight imaging experiments of the sinusoidal modulation target and a 1000 line-pairs/inch Au grid with a linewidth of 5μm using an online alignment method based on dual positioning balls to indicate the target and backlighter.This paper describes the optical design,adjustment method,and experimental results of a toroidal crystal system in a laboratory and laser facility.展开更多
基金supported by National Magnetic Confinement Fusion Science Program of China (Nos. 2011GB101000, 2011GB107000, 2012GB101000 and 2013GB112004)National Natural Science Foundation of China (Nos. 10975155, 10990212 and 11175208)JSPS-NRF-NSFC A3 Foresight Program in the Field of Plasma Physics (No. 11261140328)
文摘An attempt was made to improve the spatio-temporal resolution of the tangen- tial X-ray crystal spectrometer （XCS） on the Experimental Advanced Superconducting Tokamak （EAST） by evaluating experimentally the applicability of a novel X-ray photon detection tech- nology for measuring the satellite spectra of Ar XVII with a high counting rate. High-resolution experimental data on the profiles of ion temperature and plasma rotation velocity facilitate the studies of the mechanisms underlining important physical phenomena, such as plasma heating, L-H transition and momentum transport. Based on silicon diode array and single-photon counting technology, a relatively small area （83.8 x 33.5 mm~） two-dimensional detector was successfully in- stalled and tested in the recent EAST campaign. X-ray photon counting rate higher than 20 MHz was observed for the first time, and high quality satellite spectra were recorded for ion temperature and plasma rotation measurement, indicating that the new technology is suitable for the next-step high-resolution XCS on EAST, and the deployment of a detector array with a much larger X-ray sensing area is planned for better plasma coverage.
基金the National Magnetic Confinement Fusion Science Program of China(Nos.2017YFE0301300 and 2018YFE0301100)the Key Program of Research and Development of the Hefei Science Center(No.2017HSC-KPRD002)+7 种基金National Natural Science Foundation of China(Nos.11805231 and 11705151)the ASIPP Science and Research Grant(No.DSJJ-17-03)the Anhui Provincial Natural Science Foundation(Nos.1808085QA14 and 1908085J01)the Instrument Developing Project of the Chi-nese Academy of Sciences(No.YJKYYQ20180013)the Collaborative Innovation Program of Hefei Science Center,CAS(No.2019HSC-CIP005)the Nature Science Foundation of Hunan Province(2017JJ3268)the Hunan Nuclear Fusion International Science and Technology Innovation Coopera-tion Base(No.2018WK4009)the Key Laboratory of Magnetic Confinement Nuclear Fusion Research in Hengyang(No.2018KJ108).
文摘Spectral measurement of tungsten(W)impurity is essential to study impurity transport.Therefore,an X-ray crystal spectrometer(XCS)on EAST was used to measure the line spectra from highly ionized W ions.On EAST,both poloidal XCS and tangential XCS have been developed to measure the plasma temperature as well as the rotation velocity.Recently,He-like and H-like argon spectra have also been obtained using a two-crystal setup.W lines are identified in this study.Through a careful analysis,the W lines of 3.9336,3.9321,and 3.664(A)are found to be diffracted by He-like or H-like crystals.The lines are confirmed with the NIST database.We also calculated the ion temperature with Doppler broadening of these lines.The ion temperature from the W lines is entirely consistent with that from Ar line spectra.The measurement of these W line spectra could be used to study W impurity transport in future work.
基金supported by National Natural Science Foundation of China(Nos.11175197)CAS Innovative Project of China(KJCX2-YW-N36)Ministry of Education of China(IRT1190)
文摘Highly oriented pyrolitic graphite （HOPG） has high X-ray diffraction efficiency due to its unique mosaic crystal structure, and thus is very suitable for its application to X-ray Thomson scattering measurement of solid-density plasmas. In this article, by using the K-shell X-ray source from laser-produced Ti plasma, the properties of the HOPG spectrometer are characterized and compared with those of the flat Pentaerythritol （PET） spectrometer. The results show that the diffraction efficiency of the HOPG spectrometer under focusing condition is an order higher than that of the PET spectrometer, while the spectral resolution of the HOPG is about 320, high enough to be used in the measurement of X-ray Thomson scattering spectra.
基金supported by National Natural Science Foundation of China(Nos.12175278 and 12205072)the Comprehensive Research Facility for Fusion Technology Program of China(No.2018-000052-73-01-001228)+3 种基金Major Science and Technology Infrastructure Maintenance and Reconstruction Projects of the Chinese Academy of Sciences(2021),the University Synergy Innovation Program of Anhui Province(No.GXXT-2021-029)Anhui Provincial Key Research and Development Project(No.202104a06020021)Open Fund of the Magnetic Confinement Fusion Laboratory of Anhui Province(No.2021AMF01002)the National Magnetic Confinement Fusion Science Program of China(Nos.2019YFE03040000 and 2018YFE0303103).
文摘Inversion techniques are conducted based on the tangential x-ray crystal spectroscopy(TXCS)geometry on EAST to obtain the local profiles of ion temperature(Ti)and toroidal rotation velocity(vt).Firstly,local emissivity profiles of the impurity argon are obtained using the asymmetrical Abel inversion.Then,the local vt and Ti profiles are calculated by considering the local emissivity profiles and the TXCS detailed geometry.In addition,how the changes in the vt profiles affect the accuracy in the Ti profiles is discussed in detail.It is also found that the lineintegrated Ti profiles are becoming less accurate with the increase in the radial gradient in the local vt profiles.Nonetheless,accurate Ti radial profiles are reconstructed after considering the effects of the emissivity and velocity,which are verified by comparing the inverted vt and Ti profiles with those local profile measurements from the Charge eXchange Recombination Spectroscopy(CXRS)on EAST.
基金supported by the National Key Research and Development Program of China(Nos.2022YFA1503801,2021YFA1600800)the Photon Science Center for Carbon Neutrality of Chinese Academy of Sciences+2 种基金Shanghai Science and Technology Development Funds(Nos.22YF1454500,23ZR1471400)the CAS Project for Young Scientists in Basic Research(No.YSBR-022)the National Natural Science Foundation of China(No.12305375)。
文摘A Johann-type X-ray spectrometer was successfully developed at the hard X-ray branch(in-vacuum undulator with a 24-mm periodic length)of the energy material beamline(E-line)at the Shanghai Synchrotron Radiation Facility(SSRF).This spectrometer was utilized to implement X-ray emission spectroscopy(XES),high-energy resolution fluorescence-detected X-ray absorption spectroscopy(HERFD-XAS),and resonant inelastic X-ray scattering.Seven spherically bent crystals were positioned on the respective vertical 500-mm-diameter Rowland circles,adopting an area detector to increase the solid angle to 1.75%of 4πsr,facilitating the study of low-concentrate systems under complex reaction conditions.Operated under the atmosphere pressure,the spectrometer covers the energy region from 3.5 to 18 keV,with the Bragg angle ranging from 73°to 86°during vertical scanning.It offers a promised energy resolution of sub-eV(XES)and super-eV(HERFD-XAS).Generally,these comprehensive core-level spectroscopy methods based on hard X-rays at the E-line with an extremely high photon flux can meet the crucial requirements of a green energy strategy.Moreover,they provide substantial support for scientific advances in fundamental research.
基金National Natural Science Foundation of China(12102410)Fund of National Key Laboratory of Shock Wave and Detonation Physics(JCKYS2022212005)。
文摘The lattice parameter,measured with sufficient accuracy,can be utilized to evaluate the quality of single crystals and to determine the equation of state for materials.We propose an iterative method for obtaining more precise lattice parameters using the interaction points for the pseudo-Kossel pattern obtained from laser-induced X-ray diffraction(XRD).This method has been validated by the analysis of an XRD experiment conducted on iron single crystals.Furthermore,the method was used to calculate the compression ratio and rotated angle of an LiF sample under high pressure loading.This technique provides a robust tool for in-situ characterization of structural changes in single crystals under extreme conditions.It has significant implications for studying the equation of state and phase transitions.
基金partially supported by the Natural Science Foundation of China(Nos.12004353,11975214,11991071,11905202,12175212,and 12120101005)the Key Laboratory Foundation of the Science and Technology on Plasma Physics Laboratory(Nos.6142A04200103 and 6142A0421010).
文摘Currently,with the advent of high-repetition-rate laser-plasma experiments,the demand for online diagnosis for the X-ray spectrum is increasing because the laser-plasma-generated X-ray spectrum is very important for characterizing electron dynamics and applications.In this study,scintillators and silicon PIN(P-type–intrinsic-N-type semiconductor)diodes were used to construct a wideband online filter stack spectrometer.The X-ray sensor and filter arrangement was optimized using a genetic algorithm to minimize the condition number of the response matrix.Consequently,the unfolding error was significantly reduced based on numerical experiments.The detector responses were quantitatively calibrated by irradiating the scintillator and PIN diode with various nuclides and comparing the measuredγ-ray peaks.A prototype 15-channel spectrometer was developed by integrating an X-ray detector with front-and back-end electronics.The prototype spectrometer could record X-ray pulse signals at a repetition rate of 1 kHz.Furthermore,an optimized spectrometer was employed to record the real-time spectra of laser-driven bremsstrahlung sources.This optimized spectrometer offers a compact solution for spectrum diagnostics of ultrashort X-ray pulses,exhibiting improved accuracy in terms of spectrum measurements and repetition rates,and could be widely used in next-generation high-repetition-rate high-power laser facilities.
基金partially supported by the National Magnetic Confinement Fusion Science Program of China(No.2015GB103002)Key Program of Research and Development of Hefei Science Center(No.2017HSC-KPRD002)+1 种基金the Major Program of Development Foundation of Hefei Center for Physical Science and Technology(No.2016FXZY008)the CASHIPS Director’s Funds Grant(No.YZJJ201612)
文摘To simultaneously measure the He-like and H-like argon spectra, a two-crystal assembly has been deployed to replace the previous single crystal on the tangential x-ray crystal spectrometer.By selecting appropriate crystals with similar Bragg angles, plasma temperature in the range of 0.5 keV≤Te≤10 keV and rotation can be diagnosed based on the He-like and H-like argon spectra. However, due to the added complexity in the two-crystal assembly in which the spectra might be diffracted by two crystals, some additional impurity lines were identified. For example,tungsten（W） lines in different ionization states were diffracted by the He-like and H-like crystal.Additional molybdenum（Mo） lines in the wavelength range of He-like and H-like argon spectra lines were also summarized. The existence of these additional lines caused the fitted temperature to be different from the true values. This paper presents the identified lines through a comparison with available database, which should be included in the fitting procedure.
基金supported by National Natural Science Foundation of China(Nos.11175208,11305212 and 11405212)the National Magnetic Confinement Fusion Science Program of China(No.2013GB112004)JSPS-NRF-NSFC A3 Foresight Program in the Field of Plasma Physics(No.11261140328)
文摘A new simple method is presented for the wavelength calibration and measurement of poloidal rotation velocities with X-ray imaging crystal spectrometer（XICS）in magnetic fusion devices.In this method,the toroidal rotation of plasma is applied for high precise alignment and wavelength calibration of the poloidal XICS.The measurement threshold of poloidal rotation velocity can be lowered to 1-3 km/s with this method.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11975037 and 11921006)the National Grand Instrument Project of China (Grant Nos. 2019YFF01014400 and 2019YFF01014404)。
文摘Laser-driven proton-induced x-ray emission(laser-PIXE) is a nuclear analysis method based on the compact laser ion accelerator. Due to the transient process of ion acceleration, the laser-PIXE signals are usually spurted within nanoseconds and accompanied by strong electromagnetic pulses(EMP), so traditional multi-channel detectors are no longer applicable.In this work, we designed a reflective elliptical crystal spectrometer for the diagnosis of laser-PIXE. The device can detect the energy range of 1 keV–11 ke V with a high resolution. A calibration experiment was completed on the electrostatic accelerator of Peking University using samples of Al, Ti, Cu, and ceramic artifacts. The detection efficiency of the elliptical crystal spectrometer was obtained in the order of 10-9.
基金supported by the Shanghai Municipal Science and Technology Major Project(No.2017SHZDZX02)the National Natural Science Foundation of China(No.12205360)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2018297)。
文摘We report on using synthetic silicon for a high-precision X-ray polarimeter comprising a polarizer and an analyzer,each based on a monolithic channel-cut crystal used at multiple Brewster reflections with a Bragg angle very close to 45°.Experiments were performed at the BL09B bending magnet beamline of the Shanghai Synchrotron Radiation Facility using a Si(800)crystal at an X-ray energy of 12.914 keV.A polarization purity of 8.4×10^(-9)was measured.This result is encouraging,as the measured polarization purity is the best-reported value for the bending magnet source.Notably,this is the firstly systematic study on the hard X-ray polarimeter in China,which is crucial for exploring new physics,such as verifying vacuum birefringence.
基金supported by the Strategic Priority Program Stage Ⅱ on Space Science of Chinese Academy of Sciences(No.XDA15320104)the National Natural Science Foundation of China(Nos.11703097,11427803,11820101002,11622327,11773087,U1631116,and 11803093)
文摘A spaceborne hard X-ray spectrometer, composed of an array of 99 scintillation detectors and associated readout electronics, has been developed for the hard X-ray imager(HXI). The HXI is one of the three payloads onboard the advanced space-based solar observatory(ASO-S), which is scheduled to be launched in early 2022 as the first Chinese solar satellite. LaBr3 scintillators and photomultiplier tubes with a super bialkali cathode are used to achieve an energy resolution better than 20% at 30 keV.Further, a new multi-channel charge-sensitive readout application-specific integrated circuit guarantees high-frequency data acquisition with low power consumption. This paper presents a detailed design of the spectrometer for the engineering model of the HXI and discusses its noise and linearity performance.
基金supported by National Natural Science Foundation of China(Nos.11405158 and 11435011)Development Foundation of China Academy of Engineering Physics(Nos.2014B0102011 and 2014B0102012)
文摘A new time-resolved shifted dual transmission grating spectrometer （SDTGS） is designed and fabricated in this work. This SDTGS uses a new shifted dual transmission grating （SDTG） as its dispersive component, which has two sub transmission gratings with different line densities, of 2000 lines/mm and 5000 lines/mm. The axes of the two sub transmission gratings in SDTG are horizontally and vertically shifted a certain distance to measure a broad range of 0.1-5 keV time-resolved X-ray spectra. The SDTG has been calibrated with a soft X-ray beam of the synchrotron radiation facility and its diffraction efficiency is also measured. The designed SDTGS can take full use of the space on a record panel and improve the precision for measuring spatial and temporal spectrum simultaneously. It will be a promising application for accurate diagnosis of the soft X-ray spectrum in inertial confinement fusion.
文摘In order to mitigate the effect of the strong electromagnetic pulse, which produces laser-plasma interactions, we designed a new streaked X-ray spectrometer （SXS） enclosed within a well-sealed, electromag- netic interference-free cavity. The SXS can cover a wide selection of spectral windows using interchangeable Bragg crystals and by appropriate adjustment of the Bragg angle. The SXS has been used to observe time-re- solved X-ray spectrum in the 2.5 keV to 3.5 keV photon-energy range, resulting in a demonstrated spectral res- olution of about 13 at 2960 eV with a time resolution of 10 ps. The observed time and spectral resolutions dem- onstrate the applicability of the SXS for studies of laser-produced plasmas.
基金supported by the National Natural Science Foundation of China(Grant Nos.11221002,11274152,and 11074297)
文摘A ray tracing method is introduced for helping adjustment and spectra analysis of the grazing incidence flat-field imaging soft X-ray spectrometer. For a single point source, the spectra images obtained by separate components, the toroidal mirror, and the grazing incidence flat-field concave grating with varied line spaces are given respectively. The calculated spectral images of the single point source by the spectrometer are also given for comparison with measurements with different experimental alignments.
文摘The accuracy(repeatability and reproducibility) of the iron content analysis of galvanized coating using an X-ray fluorescence spectrometer with an L-spectrum is not better than that of flame atomic absorption spectrometry, sometimes it exceeds the quality control limit.Influences, such as current, voltage, equipment(internal circulating water, 10%CH4+90%Ar, and vacuum) checking, instrument monitoring, sample cleaning, and oper-ators, were investigated by means of 6-sigma and lean operations to improve accuracy.
基金The project was supported by the National Natural Science Foundation of China.
文摘INTRODUCTIONThe studies on the quantitative distribution of the conventional elements and their phases in the sediments of the Changjiang Estuary are of great importance to the understanding of the chemical processes of ion exchange, absorption, desorption and flocculation in the estuary.
文摘An experiment facility has been set up for the study of metal cluster compounds in our laboratory, which consists of a nano-electrospray ionization source, an ion transmission and focus system, and a reflectron time-of-fight mass spectrometer. Taking advantage of the nano-electrospray ionization source, polyvalent ions are usually produced in the ＂ionization＂ process and the obtained mass resolution of the equipment is over 8000. The molecular ion peaks of metal cluster compounds [Au20（PPhpy2）10Cl2]（SbF6）4, where PPhpy2=bis（2- pyridyl）phenylphosphine, and [AuaAg2（C）L6]（BF4）4, where L=2-（diphenylphosphino）-5- methylpyridine, are distinguished in the respective mass spectrum, accompanied by some fragment ion peaks. In addition, the mass-to-charge ratios of the parent ions are determi- nated. Preliminary results suggest that the device is a powerful tool for the study of metal cluster compounds. It turns out that the information obtained by the instrumentation serves as an essential supplement to single crystal X-ray diffraction for structure characterization of metal cluster compounds.
基金the National Natural Science Foundation of China (20672042)
文摘The synthesis and X-ray crystal structure of a new molecular clip 2 was reported. It （C24H24N4O2, Mr = 400.47） crystallizes in the space group C2/c with a = 15.587（2）, b = 8.5805（12）, c = 15.259（2） A, β = 102.448（3）°, V= 1992.9 （5）A63, Z = 4, Dc = 1.335 g/cm63,μ = 0.087 mm^-1 and F（000） = 848. It remains monomeric in the crystal and a tape-like structure is formed in the crystal structure of molecular clip. The most unusual structural feature of 2 is the boat conformation of its cyclohexyl ring imposed by the ring fusion at C（9）-C（9a）.
基金National Natural Science Foundation of China(No.11805212)National Key Research and Development Program of China(No.2019YFE03080200)。
文摘Monochromatic x-ray imaging is an essential method for plasma diagnostics related to density information.Large-field high-resolution monochromatic imaging of a He-like iron(Fe XXV)Kαcharacteristic line(6.701 keV)for laser plasma diagnostics was achieved using a developed toroidal crystal x-ray imager.A high-index crystal orientation Ge(531)wafer with a Bragg angle of 75.37°and the toroidal substrate were selected to obtain sufficient diffraction efficiency and compensate for astigmatism under oblique incidence.A precise offline assembly method of the toroidal crystal imager based on energy substitution was proposed,and a spatial resolution of 3-7μm was obtained by toroidal crystal imaging of a 600 line-pairs/inch Au grid within an object field of view larger than 1.0 mm.The toroidal crystal x-ray imager has been successfully tested via side-on backlight imaging experiments of the sinusoidal modulation target and a 1000 line-pairs/inch Au grid with a linewidth of 5μm using an online alignment method based on dual positioning balls to indicate the target and backlighter.This paper describes the optical design,adjustment method,and experimental results of a toroidal crystal system in a laboratory and laser facility.
