Both of chromium and zinc could appear as either minor impurities or alloying elements in recycled and commercial aluminum alloys, and they could have detrimental effects on the final product properties if not control...Both of chromium and zinc could appear as either minor impurities or alloying elements in recycled and commercial aluminum alloys, and they could have detrimental effects on the final product properties if not controlled in an appropriate way. A Kampmann-Wagner numerical modeling approach, built on the basis of computational thermodynamics and diffusion kinetics, is employed to investigate the effect of these two minor impurities on dispersoids precipitation during homogenization heat treatment of AA3xxx alloys. The simulation results obtained from different simulation set-ups were compared. The aim is to demonstrate that the modeling approach has the potential to guide the design or optimization of the chemical compositions and heat treatment parameters of aluminum alloys.展开更多
以实际工艺流程50 t EBT-VOD-LF-VC冶炼15-5PH不锈钢为背景,通过FactSage 8.0和经典Wagner模型研究冶炼硅铝复合脱氧过程中钢液中的铝含量、炉渣组成以及冶炼温度等因素对钢液中氧含量的影响进行了热力学研究。结果表明:Al-Si复合脱氧为...以实际工艺流程50 t EBT-VOD-LF-VC冶炼15-5PH不锈钢为背景,通过FactSage 8.0和经典Wagner模型研究冶炼硅铝复合脱氧过程中钢液中的铝含量、炉渣组成以及冶炼温度等因素对钢液中氧含量的影响进行了热力学研究。结果表明:Al-Si复合脱氧为15-5PH不锈钢冶炼过程中的最佳脱氧工艺,为了保证脱氧的冶炼效果,应控制钢液中的酸溶铝的质量分数在0.015%左右;降低冶炼温度有利于降低钢液平衡氧含量;考虑炉渣的物理性能和钢渣界面平衡反应得出脱氧工艺的最优炉渣成分,碱度为2.5~3.0,w((Cr_(2)O_(3)))=0.5%,w((Al_(2)O_(3)))=20%,w((MgO))=5%,w((CaF_(2)))=5%;经过工艺优化后生产的15-5PH不锈钢中氧含量明显降低,均满足产品要求,炉渣碱度对平衡氧含量和实际生产全氧含量的影响规律基本相同。展开更多
文摘Both of chromium and zinc could appear as either minor impurities or alloying elements in recycled and commercial aluminum alloys, and they could have detrimental effects on the final product properties if not controlled in an appropriate way. A Kampmann-Wagner numerical modeling approach, built on the basis of computational thermodynamics and diffusion kinetics, is employed to investigate the effect of these two minor impurities on dispersoids precipitation during homogenization heat treatment of AA3xxx alloys. The simulation results obtained from different simulation set-ups were compared. The aim is to demonstrate that the modeling approach has the potential to guide the design or optimization of the chemical compositions and heat treatment parameters of aluminum alloys.
文摘以实际工艺流程50 t EBT-VOD-LF-VC冶炼15-5PH不锈钢为背景,通过FactSage 8.0和经典Wagner模型研究冶炼硅铝复合脱氧过程中钢液中的铝含量、炉渣组成以及冶炼温度等因素对钢液中氧含量的影响进行了热力学研究。结果表明:Al-Si复合脱氧为15-5PH不锈钢冶炼过程中的最佳脱氧工艺,为了保证脱氧的冶炼效果,应控制钢液中的酸溶铝的质量分数在0.015%左右;降低冶炼温度有利于降低钢液平衡氧含量;考虑炉渣的物理性能和钢渣界面平衡反应得出脱氧工艺的最优炉渣成分,碱度为2.5~3.0,w((Cr_(2)O_(3)))=0.5%,w((Al_(2)O_(3)))=20%,w((MgO))=5%,w((CaF_(2)))=5%;经过工艺优化后生产的15-5PH不锈钢中氧含量明显降低,均满足产品要求,炉渣碱度对平衡氧含量和实际生产全氧含量的影响规律基本相同。
