Poly(butylene adipate-co-terephthalate)(PBAT)is a promising biodegradable flexible polymer but suffers from slow crystallization rate,making it less attractive for some applications like the injection-molded products ...Poly(butylene adipate-co-terephthalate)(PBAT)is a promising biodegradable flexible polymer but suffers from slow crystallization rate,making it less attractive for some applications like the injection-molded products in comparison with low-density polyethylene(LDPE).This work aimed to accelerate the crystallization of PBAT by adding a self-assembly nucleating agent octamethylenedicarboxylic dibenzoylhydrazide(OMBH).PBAT/OMBH composites with various OMBH contents(0 wt%,0.5 wt%,0.7 wt%,1 wt%,2 wt%,3 wt%and 5 wt%)were prepared through melt-mixing.The effect of OMBH on the crystallization behavior,morphologies and mechanical properties of PBAT was investigated.The highest nucleation efficiency value of 59.6%was achieved for PBAT with 0.7 wt%OMBH,much higher than that of 22.7%for PBAT with 0.7 wt%talc.Atomic force microscopy results showed that OMBH formed fine fibers and induced the formation of transcrystalline layers of PBAT.Fourier transform infrared spectroscopy(FTIR)combined with two-dimensional correlation spectra suggested that the intermolecular dipole-dipole N—H…O=C interactions but not hydrogen bond between OMBH and PBAT promoted the crystallization of PBAT in the initial period of crystallization.The presence of OMBH did not change the crystal form of PBAT but had positive contribution in enhancing its crystallinity and mechanical properties.This work is essential for preparing PBAT with high crystallization rate,enhancing its potential applications in injection-molded products.展开更多
Poly(butylene adipate-co-terephthalate)(PBAT),a widely studied biodegradable material,has not effectively addressed the problem of plastic waste.Taking into consideration the cost-effectiveness,upcycling PBAT should t...Poly(butylene adipate-co-terephthalate)(PBAT),a widely studied biodegradable material,has not effectively addressed the problem of plastic waste.Taking into consideration the cost-effectiveness,upcycling PBAT should take precedence over direct composting degradation.The present work adopts a chain breaking-crosslinking strategy,upcycling PBAT into dual covalent adaptable networks(CANs).During the chainbreaking stage,the ammonolysis between PBAT and polyethyleneimine(PEI)established the primary crosslinked network.Subsequently,styrene maleic anhydride copolymer(SMA)reacted with the hydroxyl group,culminating in the formation of dual covalent adaptable networks.In contrast to PBAT,the PBAT-dual-CANs exhibited a notable Young's modulus of 239 MPa,alongside an inherent resistance to creep and solvents.Owing to catalysis from neighboring carboxyl group and excess hydroxyl groups,the PBAT-dual-CANs exhibited fast stress relaxation.Additionally,they could be recycled through extrusion and hot-press reprocessing,while retaining their biodegradability.This straightforward strategy offers a solution for dealing with plastic waste.展开更多
Development of home compostable materials based on bioavailable polymers is of high strategic interest as they ensure a significant reduction of the environmental footprint in many production sectors.In this work,the ...Development of home compostable materials based on bioavailable polymers is of high strategic interest as they ensure a significant reduction of the environmental footprint in many production sectors.In this work,the addition of thermoplastic starch to binary PLA/PBAT blends was studied.The compounds were obtained by a reactive extrusion process by means of a co-rotating twin screw extruder.Thermomechanical,physical and chemical characterization tests were carried out to highlight the effectiveness of the material design strategy.The compounds were subsequently reprocessed by cast extrusion and thermoforming in order to obtain products suitable for the storage of hot food.The extruded films and the thermoformed containers were further characterized to highlight their thermo-mechanical,physical and chemical properties.Thermo-rheological,mechanical and physical properties of the material and of the cast film were analyzed thoroughly using combined technique as capillary rheometer,MFI,DSC,VICAT/HDT,XRD,FTIR,UV-Vis,SEM,permeability and,lastly,running preliminary chemical inertness and biodegradation tests.Particular attention was also devoted to the evaluation of the thermo-mechanical resistance of the thermoformed containers,where the PLA/PBAT/TPS blends proved to be very effective,also presenting a high disintegration rate in ambient conditions.展开更多
A biodegradable blend foaming material of poly(butylene adipate-co-terephthalate)(PBAT)/poly(propylene carbonate)(PPC)was successfully prepared by chemical foaming agent and screw extrusion method.First,PBAT was modif...A biodegradable blend foaming material of poly(butylene adipate-co-terephthalate)(PBAT)/poly(propylene carbonate)(PPC)was successfully prepared by chemical foaming agent and screw extrusion method.First,PBAT was modified by bis(tert-butyl dioxy isopropyl)benzene(BIBP)for chain extension,and then the extended PBAT(E-PBAT)was foamed with PPC using a twin(single)screw extruder.By analyzing the properties of the blends,we found that Young’s modulus increased from 58.8 MPa of E-PBAT to 244.7 MPa of E-PBAT/PPC 50/50.The viscosity of the polymer has a critical influence on the formation of cells.Compared with neat PBAT(N-PBAT),the viscosity of E-PBAT increased by 3396 Pa·s and E-PBAT/PPC 50/50 increased by 8836 Pa·s.Meanwhile,the dynamic mechanical analysis(DMA)results showed that the storage modulus(E’)at room temperature increased from 538 MPa to 1650 MPa.The various phase morphologies(“sea-island”,“quasi-co-continuous”and“cocontinuous”)and crystallinity of the blends affected the spread velocity of gas and further affected the foaming morphology in E-PBAT/PPC foam.Therefore,through the analysis of phase morphology and foaming mechanism,we concluded that the E-PBAT/PPC 70/30 component has both excellent strength and the best foaming performance.展开更多
In recent years, poly(butylene adipate-co-terephthalate)(PBAT) has been widely used. However, PBAT-degrading bacteria have rarely been reported. PBAT-degrading bacteria were isolated from farmland soil and identified....In recent years, poly(butylene adipate-co-terephthalate)(PBAT) has been widely used. However, PBAT-degrading bacteria have rarely been reported. PBAT-degrading bacteria were isolated from farmland soil and identified. The effects of growth factors on the degradation of PBAT and the lipase activity of PBAT-degrading bacteria were assessed. The degradation mechanism was analyzed using scanning electron microscopy, attenuated total reflection Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, Xray diffraction, and liquid chromatography-mass spectrometry. The results showed that Stenotrophomonas sp. YCJ1 had a significant degrading effect on PBAT. Under certain conditions, the strain could secrete 10.53 U/m L of lipase activity and degrade 10.14 wt.% of PBAT films. The strain secreted lipase to catalyze the degradation of the ester bonds in PBAT, resulting in the production of degradation products such as terephthalic acid, 1,4-butanediol, and adipic acid. Furthermore, the degradation products could participate in the metabolism of YCJ1 as carbon sources to facilitate complete degradation of PBAT, indicating that the strain has potential value for the bioremediation of PBAT in the environment.展开更多
Binary biodegradable polymers films, poly(butylene adipate-co-terephthalate)(PBAT) and poly(glycolic acid)(PGA), were prepared through batch melt mixing to obtain Film Ⅰ and Film Ⅱ under two different processing con...Binary biodegradable polymers films, poly(butylene adipate-co-terephthalate)(PBAT) and poly(glycolic acid)(PGA), were prepared through batch melt mixing to obtain Film Ⅰ and Film Ⅱ under two different processing conditions. PGA crystals played a major role in enhancing the mechanical and barrier properties of the films. For Film Ⅰ, there were initial PGA crystals before the film blowing process, the PGA molecular chain further crystallized, forming the oriented crystallization of PGA. Moreover, the Xcand crystalline size in Film Ⅰ were higher than those in Film Ⅱ. Compared with the different processing methods, Film Ⅰ has excellent mechanical and oxygen barrier properties due to the crystallization and orientation. The tensile strength reached 45.0 MPa, and tear strength exceeded 138.2 kN/m, while the elongation at break was as high as 750% for PBAT/PGA 85/15 in Film Ⅰ. The WVTR, WVP coefficients, and OP coefficients of PBAT/PGA films were decreased obviously with increasing the PGA content both in Film Ⅰ and Film Ⅱ. Moreover, the barrier properties of oxygen in Film Ⅰ were better than that in Film Ⅱ. This work reveals a feasible processing technique by introducing of initial crystallization of PGA to blow PBAT/PGA films with excellent mechanical and barrier properties.展开更多
Rare earth （Nd, Y, La, Dy） stearates have been synthesized and used as single component catalysts for the polycondensation of dimethyl terephthalate, adipic acid and 1,4-butanediol for the first time preparing biode...Rare earth （Nd, Y, La, Dy） stearates have been synthesized and used as single component catalysts for the polycondensation of dimethyl terephthalate, adipic acid and 1,4-butanediol for the first time preparing biodegradable poly（butylene adipate-co-terephthalate） （PBAT） with high molecular weight, The microstructures of PBAT were characterized by ^1H NMR spectra. The PBAT exhibits good mechanical properties such as high tensile strength （ca. 20 MPa） and long break elongation （〉700%）.展开更多
With the rapid development of electronic equipment and communication technology,the demand for polymer composites with high thermal conductivity and mechanical properties has increased significantly.However,its nondeg...With the rapid development of electronic equipment and communication technology,the demand for polymer composites with high thermal conductivity and mechanical properties has increased significantly.However,its nondegradable polymer matrix will inevitably bring more and more serious environmental pollution.Therefore,it is urgent to develop biodegradable thermally conductive polymer composites.In this work,biodegradable poly(butylene adipate-coterephthalate)(PBAT)is used as the matrix material,and vacuum-assisted filtration technology is employed to prepare carbon nanotube(CNT)and cellulose nanocrystal(CNC)networks with high thermal conductivity.Then CNT-CNC/PBAT composites with high thermal conductivity and excellent mechanical properties are prepared by the ultrasonic-assisted forced infiltration method.Both experiment and simulation methods are used to systematically investigate the thermally conductive and dissipation performances of the CNT-CNC/PBAT composites.Above all,a simple alcoholysis reaction is applied to realize the separation of the PBAT matrix and functional fillers without destroying the conductive network skeleton,which makes it possible for the recycling of thermally conductive polymer composites.展开更多
Polylactide(PLA)/poly(butylene adipate-co-terephthalate)(PBAT)blend nanocomposites including 3 wt%of cel-lulose nanocrystals(CNCs)were prepared by melt compounding method in a twin-screw extruder and an inter-nal mixe...Polylactide(PLA)/poly(butylene adipate-co-terephthalate)(PBAT)blend nanocomposites including 3 wt%of cel-lulose nanocrystals(CNCs)were prepared by melt compounding method in a twin-screw extruder and an inter-nal mixer.Blend nanocomposites were formulated by diluting three different masterbatches prepared by solution casting method that contained 7 wt%of CNC.These masterbatches were:(m1)PLA/PBAT/CNC masterbatch;(m2)PLA/CNC masterbatch;and(m3)PBAT/CNC masterbatch.These were to explore how different prepara-tion methods affect the dispersion and localization of CNC and hence the properties of PLA/PBAT/CNC blend nanocomposites.Scanning electron microscopy(SEM)was used to study the structural changes of the blends.Rheological properties of PLA/PBAT blends and PLA/PBAT/CNC blend nanocomposites were also investigated.In the samples prepared by internal mixer,the rheological behavior of blend nanocomposite prepared through premixing of CNC particles with PLA showed a transition from liquid-like to a gel-like behavior.According to the rheological results and differential scanning calorimetry(DSC)analysis,it was found that the CNC overall enhanced the viscoelastic properties of blends and improved the PLA crystallization,respectively.Dynamic mechanical analysis(DMA)illustrated that the incorporation of CNC also enhanced the elastic modulus of PLA/PBAT blends specifically above the glass transition temperature of PLA.The expected improvements in mechanical properties did not occur due to the possible existence of residual solvent in the blends.展开更多
In recent years,degradable materials to replace petroleum-based materials in preparing high-performance foams have received much research attention.Degradable polymer foaming mostly uses supercritical fluids,especiall...In recent years,degradable materials to replace petroleum-based materials in preparing high-performance foams have received much research attention.Degradable polymer foaming mostly uses supercritical fluids,especially carbon dioxide(Sc-CO_(2)).The main reason is that the foams obtained by Sc-CO_(2) foaming have excellent performance,and the foaming agent is green and pollution-free.In current research,Poly(butylene adipate-co-terephthalate)(PBAT),poly(lactic acid)(PLA),and other degradable polymers are generally used as the main foaming materials,but the foaming performance of these degradable polyesters is poor and requires modification.In this work,10%PLA was added to PBAT to enhance the melt strength and improve the foaming performance.To improve the foaming properties of the PBAT/PLA composites,two kinds of nano-filler(nano-Fe_(3)O_(4) and carbon nanotubes(CNTs))were innovatively introduced for foaming modification.There was a synergistic effect between the two nano-fillers to enhance the foaming properties significantly.When 6 wt%CNTs and 4 wt%nano-Fe_(3)O_(4) were added,the 4Fe_(3)O_(4)/6CNT foam had the best comprehensive performance.Its foaming rate reached 14.8 times,which was 2.8 and 2.1 times that after adding 10 wt%CNTs or 10 wt%nano-Fe_(3)O_(4) alone.The combined action could adjust the melt elasticity of different PBAT/PLA composites to the optimum.The nanofillers also served as skeleton structures to support the foam cells,significantly improving the foaming performance.The density and foaming ratio did not change significantly at 14 days after foaming.The compressive strength of the composite foam reached up to 0.27 MPa and the water contact angle reached 120.1°.The synergistic foaming effect of nano-Fe_(3)O_(4) and CNTs could significantly improve the Sc-CO_(2) foaming performances of the composites,providing a new method for degradable materials to replace petroleum-based materials.展开更多
Poly(butylene adipate-co-terephthalate) (PBAT) is currently the largest commercial biodegradable plastics with good toughness and film forming properties, whereas, the inferior barrier and mechanical properties hinder...Poly(butylene adipate-co-terephthalate) (PBAT) is currently the largest commercial biodegradable plastics with good toughness and film forming properties, whereas, the inferior barrier and mechanical properties hinder its applications. Biodegradable poly(propylene carbonate) (PPC) with excellent barrier properties and high strength is a natural choice to address above issue. However, it is challenging to improve the compatibility of these two polymers. Herein, we prepared a reactive compatibilizer with double bond side group through terpolymerization of CO_(2)/propylene oxide/glycidyl methacrylate to enhance the properties of PBAT/PPC blends. Upon addition of 1 wt% compatibilizer, the PBAT/PPC blends (75/25, W/W) showed an increased water vapor barrier property changed from 424 g·m^(−2)·d^(−1) to 204 g·m^(−2)·d^(−1) compared to the control sample. Moreover, the tensile strength and elongation at break increased from 24.7 MPa to 30.3 MPa and from 858% to 1142%, respectively. The PBAT/PPC composite also displayed excellent biodegradability under composting conditions, as confirmed by the significantly decreased molecular weight. The present work provides an efficient way to barrier biodegradable film from PBAT of practical utilization.展开更多
Graphene nanoplatelets （GNPs） were used as multifunctional nanofiller to enhance thermal and mechanical properties as well as electrical conductivity of two different biodegradable thermoplastics： poly lactide （PL...Graphene nanoplatelets （GNPs） were used as multifunctional nanofiller to enhance thermal and mechanical properties as well as electrical conductivity of two different biodegradable thermoplastics： poly lactide （PLA） and poly （butylene adipate-co-terephthalate） （PBAT）. Morphological investigations showed different levels of GNP dispersion in the two matrices, and consequently physical properties of the two systems exhibited dissimilar behaviours with GNP incorporation. Crystallinity of PLA, determined from differential scanning calorimetry, was observed to increase markedly with addition of GNPs in contrast to the decrease in crystallinity of PBAT. Isothermal and non-isothermal thermogravimetric analyses also revealed a more significant delay in thermal decomposition of PLA upon addition of GNPs compared to that of PBAT. Furthermore, results showed that increasing GNP content of PLA and PBAT nanocomposites influenced their Young＇s modulus and electrical conductivity in different ways. Modulus of PBAT increased continuously with increasing GNP loading while that of PLA reached a maximum at 9wt% GNPs and then decreased. Moreover, despite the higher conductivity of pure PBAT compared to pure PLA, conductivity of PLA/GNP nanocomposites overtook that of PBATIGNP nanocomposites above a certain GNP concentration. This demonstrated the determining effect of nanoplatelets dispersion state on the matrices properties.展开更多
基金This work was financially supported by the National Natural Science Foundation of China(Nos.52073261 and U1704162).
文摘Poly(butylene adipate-co-terephthalate)(PBAT)is a promising biodegradable flexible polymer but suffers from slow crystallization rate,making it less attractive for some applications like the injection-molded products in comparison with low-density polyethylene(LDPE).This work aimed to accelerate the crystallization of PBAT by adding a self-assembly nucleating agent octamethylenedicarboxylic dibenzoylhydrazide(OMBH).PBAT/OMBH composites with various OMBH contents(0 wt%,0.5 wt%,0.7 wt%,1 wt%,2 wt%,3 wt%and 5 wt%)were prepared through melt-mixing.The effect of OMBH on the crystallization behavior,morphologies and mechanical properties of PBAT was investigated.The highest nucleation efficiency value of 59.6%was achieved for PBAT with 0.7 wt%OMBH,much higher than that of 22.7%for PBAT with 0.7 wt%talc.Atomic force microscopy results showed that OMBH formed fine fibers and induced the formation of transcrystalline layers of PBAT.Fourier transform infrared spectroscopy(FTIR)combined with two-dimensional correlation spectra suggested that the intermolecular dipole-dipole N—H…O=C interactions but not hydrogen bond between OMBH and PBAT promoted the crystallization of PBAT in the initial period of crystallization.The presence of OMBH did not change the crystal form of PBAT but had positive contribution in enhancing its crystallinity and mechanical properties.This work is essential for preparing PBAT with high crystallization rate,enhancing its potential applications in injection-molded products.
基金financially supported by the National Natural Science Foundation of China(Nos.52373007 and 52073296)Innovative Leading Talent of Taihu Lake Talent Plan in Wuxi City+1 种基金Zhejiang Ten Thousand Talent ProgramResearch startup fund from Jiangnan University。
文摘Poly(butylene adipate-co-terephthalate)(PBAT),a widely studied biodegradable material,has not effectively addressed the problem of plastic waste.Taking into consideration the cost-effectiveness,upcycling PBAT should take precedence over direct composting degradation.The present work adopts a chain breaking-crosslinking strategy,upcycling PBAT into dual covalent adaptable networks(CANs).During the chainbreaking stage,the ammonolysis between PBAT and polyethyleneimine(PEI)established the primary crosslinked network.Subsequently,styrene maleic anhydride copolymer(SMA)reacted with the hydroxyl group,culminating in the formation of dual covalent adaptable networks.In contrast to PBAT,the PBAT-dual-CANs exhibited a notable Young's modulus of 239 MPa,alongside an inherent resistance to creep and solvents.Owing to catalysis from neighboring carboxyl group and excess hydroxyl groups,the PBAT-dual-CANs exhibited fast stress relaxation.Additionally,they could be recycled through extrusion and hot-press reprocessing,while retaining their biodegradability.This straightforward strategy offers a solution for dealing with plastic waste.
文摘Development of home compostable materials based on bioavailable polymers is of high strategic interest as they ensure a significant reduction of the environmental footprint in many production sectors.In this work,the addition of thermoplastic starch to binary PLA/PBAT blends was studied.The compounds were obtained by a reactive extrusion process by means of a co-rotating twin screw extruder.Thermomechanical,physical and chemical characterization tests were carried out to highlight the effectiveness of the material design strategy.The compounds were subsequently reprocessed by cast extrusion and thermoforming in order to obtain products suitable for the storage of hot food.The extruded films and the thermoformed containers were further characterized to highlight their thermo-mechanical,physical and chemical properties.Thermo-rheological,mechanical and physical properties of the material and of the cast film were analyzed thoroughly using combined technique as capillary rheometer,MFI,DSC,VICAT/HDT,XRD,FTIR,UV-Vis,SEM,permeability and,lastly,running preliminary chemical inertness and biodegradation tests.Particular attention was also devoted to the evaluation of the thermo-mechanical resistance of the thermoformed containers,where the PLA/PBAT/TPS blends proved to be very effective,also presenting a high disintegration rate in ambient conditions.
基金financially supported by the National Key Research and Development Program of China(No.2016YFC0501402)Science and Technology Services Network Program of Chinese Science Academy(STS Project)(No.KFJSTS-ZDTP-082)Chinese Academy of Sciences(Changchun Branch)(Nos.2020SYHZ0002 and No.2020SYHZ0047)。
文摘A biodegradable blend foaming material of poly(butylene adipate-co-terephthalate)(PBAT)/poly(propylene carbonate)(PPC)was successfully prepared by chemical foaming agent and screw extrusion method.First,PBAT was modified by bis(tert-butyl dioxy isopropyl)benzene(BIBP)for chain extension,and then the extended PBAT(E-PBAT)was foamed with PPC using a twin(single)screw extruder.By analyzing the properties of the blends,we found that Young’s modulus increased from 58.8 MPa of E-PBAT to 244.7 MPa of E-PBAT/PPC 50/50.The viscosity of the polymer has a critical influence on the formation of cells.Compared with neat PBAT(N-PBAT),the viscosity of E-PBAT increased by 3396 Pa·s and E-PBAT/PPC 50/50 increased by 8836 Pa·s.Meanwhile,the dynamic mechanical analysis(DMA)results showed that the storage modulus(E’)at room temperature increased from 538 MPa to 1650 MPa.The various phase morphologies(“sea-island”,“quasi-co-continuous”and“cocontinuous”)and crystallinity of the blends affected the spread velocity of gas and further affected the foaming morphology in E-PBAT/PPC foam.Therefore,through the analysis of phase morphology and foaming mechanism,we concluded that the E-PBAT/PPC 70/30 component has both excellent strength and the best foaming performance.
基金supported by the Research Fund at the Shaanxi Provincial Science and Technology Department of China (No. 2018SF-375)Beijing Key Laboratory of Plastics Health and Safety Quality Evaluation Technology, Beijing Technology and Business University (No. TQETJP2018 004)。
文摘In recent years, poly(butylene adipate-co-terephthalate)(PBAT) has been widely used. However, PBAT-degrading bacteria have rarely been reported. PBAT-degrading bacteria were isolated from farmland soil and identified. The effects of growth factors on the degradation of PBAT and the lipase activity of PBAT-degrading bacteria were assessed. The degradation mechanism was analyzed using scanning electron microscopy, attenuated total reflection Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, Xray diffraction, and liquid chromatography-mass spectrometry. The results showed that Stenotrophomonas sp. YCJ1 had a significant degrading effect on PBAT. Under certain conditions, the strain could secrete 10.53 U/m L of lipase activity and degrade 10.14 wt.% of PBAT films. The strain secreted lipase to catalyze the degradation of the ester bonds in PBAT, resulting in the production of degradation products such as terephthalic acid, 1,4-butanediol, and adipic acid. Furthermore, the degradation products could participate in the metabolism of YCJ1 as carbon sources to facilitate complete degradation of PBAT, indicating that the strain has potential value for the bioremediation of PBAT in the environment.
基金supported by the Science and Technology Development Plan of Jilin Province(Nos.20210203199SF and 20210509017RQ)the Science and Technology Development Program of Yantai of China(No.2022ZDCX015)+2 种基金the Chinese Academy of Sciences(Changchun Branch)(Nos.2021SYHZ0044 and 2021SYHZ0042)Science and Technology Bureau of Changchun City of China(Nos.21SH13 and 21KY01)Development and Reform commission of Jilin Province of China(No.2021C039-2).
文摘Binary biodegradable polymers films, poly(butylene adipate-co-terephthalate)(PBAT) and poly(glycolic acid)(PGA), were prepared through batch melt mixing to obtain Film Ⅰ and Film Ⅱ under two different processing conditions. PGA crystals played a major role in enhancing the mechanical and barrier properties of the films. For Film Ⅰ, there were initial PGA crystals before the film blowing process, the PGA molecular chain further crystallized, forming the oriented crystallization of PGA. Moreover, the Xcand crystalline size in Film Ⅰ were higher than those in Film Ⅱ. Compared with the different processing methods, Film Ⅰ has excellent mechanical and oxygen barrier properties due to the crystallization and orientation. The tensile strength reached 45.0 MPa, and tear strength exceeded 138.2 kN/m, while the elongation at break was as high as 750% for PBAT/PGA 85/15 in Film Ⅰ. The WVTR, WVP coefficients, and OP coefficients of PBAT/PGA films were decreased obviously with increasing the PGA content both in Film Ⅰ and Film Ⅱ. Moreover, the barrier properties of oxygen in Film Ⅰ were better than that in Film Ⅱ. This work reveals a feasible processing technique by introducing of initial crystallization of PGA to blow PBAT/PGA films with excellent mechanical and barrier properties.
基金Project supported by the National Natural Science Foundation of China （No. 20434020）, the Major State Basic Research Development Program （No. 2005CB623802）, and China Postdoctor Science Foundation （No. 20060390334）.
文摘Rare earth （Nd, Y, La, Dy） stearates have been synthesized and used as single component catalysts for the polycondensation of dimethyl terephthalate, adipic acid and 1,4-butanediol for the first time preparing biodegradable poly（butylene adipate-co-terephthalate） （PBAT） with high molecular weight, The microstructures of PBAT were characterized by ^1H NMR spectra. The PBAT exhibits good mechanical properties such as high tensile strength （ca. 20 MPa） and long break elongation （〉700%）.
基金Basic Science Center Program,Grant/Award Number:51988102National Natural Science Foundation of China,Grant/Award Numbers:52003019,52073011+1 种基金National Natural Science Foundation of China,Sinopec Key Projects,Grant/Award Number:420043-6Talents Introduction Project in Beijing University of Chemical Technology,Grant/Award Number:buctrc201909。
文摘With the rapid development of electronic equipment and communication technology,the demand for polymer composites with high thermal conductivity and mechanical properties has increased significantly.However,its nondegradable polymer matrix will inevitably bring more and more serious environmental pollution.Therefore,it is urgent to develop biodegradable thermally conductive polymer composites.In this work,biodegradable poly(butylene adipate-coterephthalate)(PBAT)is used as the matrix material,and vacuum-assisted filtration technology is employed to prepare carbon nanotube(CNT)and cellulose nanocrystal(CNC)networks with high thermal conductivity.Then CNT-CNC/PBAT composites with high thermal conductivity and excellent mechanical properties are prepared by the ultrasonic-assisted forced infiltration method.Both experiment and simulation methods are used to systematically investigate the thermally conductive and dissipation performances of the CNT-CNC/PBAT composites.Above all,a simple alcoholysis reaction is applied to realize the separation of the PBAT matrix and functional fillers without destroying the conductive network skeleton,which makes it possible for the recycling of thermally conductive polymer composites.
基金The authors would like to acknowledge the financial supports by the Scientific and Technological Research Council of Turkey(TUBITAK)in the Context of 1001 Project with the Project No.of 117M238.
文摘Polylactide(PLA)/poly(butylene adipate-co-terephthalate)(PBAT)blend nanocomposites including 3 wt%of cel-lulose nanocrystals(CNCs)were prepared by melt compounding method in a twin-screw extruder and an inter-nal mixer.Blend nanocomposites were formulated by diluting three different masterbatches prepared by solution casting method that contained 7 wt%of CNC.These masterbatches were:(m1)PLA/PBAT/CNC masterbatch;(m2)PLA/CNC masterbatch;and(m3)PBAT/CNC masterbatch.These were to explore how different prepara-tion methods affect the dispersion and localization of CNC and hence the properties of PLA/PBAT/CNC blend nanocomposites.Scanning electron microscopy(SEM)was used to study the structural changes of the blends.Rheological properties of PLA/PBAT blends and PLA/PBAT/CNC blend nanocomposites were also investigated.In the samples prepared by internal mixer,the rheological behavior of blend nanocomposite prepared through premixing of CNC particles with PLA showed a transition from liquid-like to a gel-like behavior.According to the rheological results and differential scanning calorimetry(DSC)analysis,it was found that the CNC overall enhanced the viscoelastic properties of blends and improved the PLA crystallization,respectively.Dynamic mechanical analysis(DMA)illustrated that the incorporation of CNC also enhanced the elastic modulus of PLA/PBAT blends specifically above the glass transition temperature of PLA.The expected improvements in mechanical properties did not occur due to the possible existence of residual solvent in the blends.
基金funded by National Undergraduate Training Programs for Innovations(Northeast Forestry University,grant number 202410225023)funded by Young Elite Scientist Sponsorship Program by Heilongjiang Province(2024QNTG006)+1 种基金the Fundamental Research Funds for the Central Universities(2572024DP05)funded by The Collaborative Innovation Project of First-Class Disciplines in Heilongjiang Province(LJGXCG2024-F11).
文摘In recent years,degradable materials to replace petroleum-based materials in preparing high-performance foams have received much research attention.Degradable polymer foaming mostly uses supercritical fluids,especially carbon dioxide(Sc-CO_(2)).The main reason is that the foams obtained by Sc-CO_(2) foaming have excellent performance,and the foaming agent is green and pollution-free.In current research,Poly(butylene adipate-co-terephthalate)(PBAT),poly(lactic acid)(PLA),and other degradable polymers are generally used as the main foaming materials,but the foaming performance of these degradable polyesters is poor and requires modification.In this work,10%PLA was added to PBAT to enhance the melt strength and improve the foaming performance.To improve the foaming properties of the PBAT/PLA composites,two kinds of nano-filler(nano-Fe_(3)O_(4) and carbon nanotubes(CNTs))were innovatively introduced for foaming modification.There was a synergistic effect between the two nano-fillers to enhance the foaming properties significantly.When 6 wt%CNTs and 4 wt%nano-Fe_(3)O_(4) were added,the 4Fe_(3)O_(4)/6CNT foam had the best comprehensive performance.Its foaming rate reached 14.8 times,which was 2.8 and 2.1 times that after adding 10 wt%CNTs or 10 wt%nano-Fe_(3)O_(4) alone.The combined action could adjust the melt elasticity of different PBAT/PLA composites to the optimum.The nanofillers also served as skeleton structures to support the foam cells,significantly improving the foaming performance.The density and foaming ratio did not change significantly at 14 days after foaming.The compressive strength of the composite foam reached up to 0.27 MPa and the water contact angle reached 120.1°.The synergistic foaming effect of nano-Fe_(3)O_(4) and CNTs could significantly improve the Sc-CO_(2) foaming performances of the composites,providing a new method for degradable materials to replace petroleum-based materials.
基金supported by National Key Research and Development Program of China (No. 2021YFD1700700).
文摘Poly(butylene adipate-co-terephthalate) (PBAT) is currently the largest commercial biodegradable plastics with good toughness and film forming properties, whereas, the inferior barrier and mechanical properties hinder its applications. Biodegradable poly(propylene carbonate) (PPC) with excellent barrier properties and high strength is a natural choice to address above issue. However, it is challenging to improve the compatibility of these two polymers. Herein, we prepared a reactive compatibilizer with double bond side group through terpolymerization of CO_(2)/propylene oxide/glycidyl methacrylate to enhance the properties of PBAT/PPC blends. Upon addition of 1 wt% compatibilizer, the PBAT/PPC blends (75/25, W/W) showed an increased water vapor barrier property changed from 424 g·m^(−2)·d^(−1) to 204 g·m^(−2)·d^(−1) compared to the control sample. Moreover, the tensile strength and elongation at break increased from 24.7 MPa to 30.3 MPa and from 858% to 1142%, respectively. The PBAT/PPC composite also displayed excellent biodegradability under composting conditions, as confirmed by the significantly decreased molecular weight. The present work provides an efficient way to barrier biodegradable film from PBAT of practical utilization.
文摘随着废弃塑料带来的环境污染越来越严重,生物可降解聚酯已成为大众关注的焦点。聚己二酸/对苯二甲酸丁二醇酯[poly(butylene adipate-co-terephthalate),PBAT]是脂肪族和芳香族共聚形成的生物可降解聚酯,兼具两者的优异性能。针对PBAT在自然条件下对降解环境要求严格且降解周期长的不足之处,本研究探究了角质酶在PBAT降解中的应用和对苯二甲酸-丁二醇酯(butylene terephthalate,BT)含量对PBAT生物降解性的影响,以实现对PBAT降解速率的提升。选取5种不同来源的聚酯降解酶对PBAT进行降解应用并比较出降解效果最优的酶,并测定了含有不同BT含量的PBAT聚酯的降解效率。结果表明,角质酶ICCG为降解效果最好的酶,且BT含量越高PBAT的降解率越低。此外,还确定了角质酶ICCG对高BT含量的PBAT(H)降解的最适温度、最适缓冲液类型、最适pH、最适E/S(enzyme to substrate)和最适底物浓度比分别为75℃、Tris-HCl、9.0、0.4%和1.0%。本研究结果可为角质酶在PBAT降解中的应用提供一定的理论依据和实验参考。
基金the support received from the Australian Government through a Research Training Program(RTP)Scholarshipthe support received from the School of Engineering,RMIT Universitythe support received from the Australian Research Council(ARC)Research Hub for Future Fibres(IH140100018)funded by the Australian Government
文摘Graphene nanoplatelets （GNPs） were used as multifunctional nanofiller to enhance thermal and mechanical properties as well as electrical conductivity of two different biodegradable thermoplastics： poly lactide （PLA） and poly （butylene adipate-co-terephthalate） （PBAT）. Morphological investigations showed different levels of GNP dispersion in the two matrices, and consequently physical properties of the two systems exhibited dissimilar behaviours with GNP incorporation. Crystallinity of PLA, determined from differential scanning calorimetry, was observed to increase markedly with addition of GNPs in contrast to the decrease in crystallinity of PBAT. Isothermal and non-isothermal thermogravimetric analyses also revealed a more significant delay in thermal decomposition of PLA upon addition of GNPs compared to that of PBAT. Furthermore, results showed that increasing GNP content of PLA and PBAT nanocomposites influenced their Young＇s modulus and electrical conductivity in different ways. Modulus of PBAT increased continuously with increasing GNP loading while that of PLA reached a maximum at 9wt% GNPs and then decreased. Moreover, despite the higher conductivity of pure PBAT compared to pure PLA, conductivity of PLA/GNP nanocomposites overtook that of PBATIGNP nanocomposites above a certain GNP concentration. This demonstrated the determining effect of nanoplatelets dispersion state on the matrices properties.
