In the Northern Jiangsu basin there are high pure CO2 gas pools, low condensed oil-containing CO2 gas pools, high condensed oil-containing CO2 gas pools and He-containing natural gas pools, with the δ13Cco2 (PDB) val...In the Northern Jiangsu basin there are high pure CO2 gas pools, low condensed oil-containing CO2 gas pools, high condensed oil-containing CO2 gas pools and He-containing natural gas pools, with the δ13Cco2 (PDB) values ranging from ?2.87%o to ?6.50%o, 3He/4He 3.71 × 10?6 to 6.42 × 10?6, R/Ra 2.64 to 4.5, 40Ar/36Ar 705 to 734, belonging to typical mantle source inorganic gas pools which are related to young magmatic activity. The gas layers occur in two major reservoir-caprock systems, the terrestrial Meso-Cenozoic clastic rock system and the marine Meso-Palaeozoic carbonate rock-clastic rock system. Controlled by the difference in the scale of traps in the two reservoir-caprock systems, large and medium-scale inorganic gas pools are formed in the marine Meso-Palaeozoic Group and only small ones are formed in the terrestrial Meso-Cenozoic strata. Inorganic gas pools in this basin are distributed along the two deep lithospheric faults on the west and south boundaries of the basin. Gas pools are developed at the intersected part of the ENE-trending faults that control the half graben and the E-W tenso-shear faults, mainly distributed near the Es1, Ny1 and Ny2-Q basalt eruption centres.展开更多
Carbon dioxide gas pools occur widely in the basins of eastern China.CO_2 gas-bearing beds are from the Teritary to Ordovician,and reservoirs are sandstone,carbonates and volcanics.The gases from these gas pools conta...Carbon dioxide gas pools occur widely in the basins of eastern China.CO_2 gas-bearing beds are from the Teritary to Ordovician,and reservoirs are sandstone,carbonates and volcanics.The gases from these gas pools contain CO_2 of 62.86 ‰ —99.55 ‰.In the Mesozoic-Cenozoic extensional basins,such as Songliao,Bohai Bay,Subei,Sanshui and Zhujingkou,the δ^(13)C_(CO_2)values of CO_2 gas pools range from-2.65‰ to-8.83‰,mainly from-3.5‰ to-6.0‰,~3He/~4He ratios are 2.65R_a to 4.96R_a.The regression equa- tion of CO_2 content and helium isotope ratio is CO_2(%)=61.3852+7.9745R/R_a,correlation coefficient r is 0.9430,CO_2 is mainly mantle-derived and magmatic origin.δ^(13)C_(CO_2)value of CO_2 gas from Well X in Yinggehai Basin is-3.80‰.~3He/~4He ratio is 0.07R_a,CO_2 is metamorphic origin.Mantle-derived and magmatic CO_2 gases are discharged from the cross areas of northeastern trending and northwestern trending faults in these Mesozoic-Cenozoic extensional basins,in the shallow level,the CO_2 gases migrate and accumulate along northeastern trending extensional faults.The activity of the Neogene to Quaternary northwestern trending tectonic-magmatism zones in eastern China is another important discharge event for mantle-derived and magmatic gases,which have great contribution to the CO_2 gas pools in this area.Metamorphic CO_2 in the Yinggehai Basin is released by the dynamic metamorphism of shear fractures.展开更多
Gas separation is a key issue in various industrial fields. Hydrogen has the potential for application in clean fuel technologies. Therefore, the separation and purification of hydrogen is an important research subjec...Gas separation is a key issue in various industrial fields. Hydrogen has the potential for application in clean fuel technologies. Therefore, the separation and purification of hydrogen is an important research subject. CO2 capture and storage have important roles in ＂green chemistry＂. As an effective clean technology, gas separation using inorganic membranes has attracted much attention in the last several decades. Membrane processes have many applications in the field of gas separation. Cement is one type of inorganic material, with the advantages of a lower cost and a longer lifespan. An experimental setup has been created and improved to measure twenty different cement membranes. The purpose of this work was to investigate the influence of gas molecule properties on the material transport and to explore the influence of operating conditions and membrane composition on separation efficiency. The influences of the above parameters are determined, the best conditions and membrane type are found, it is shown that cementitious material has the ability to separate gas mixtures, and the gas transport mechanism is studied.展开更多
文摘In the Northern Jiangsu basin there are high pure CO2 gas pools, low condensed oil-containing CO2 gas pools, high condensed oil-containing CO2 gas pools and He-containing natural gas pools, with the δ13Cco2 (PDB) values ranging from ?2.87%o to ?6.50%o, 3He/4He 3.71 × 10?6 to 6.42 × 10?6, R/Ra 2.64 to 4.5, 40Ar/36Ar 705 to 734, belonging to typical mantle source inorganic gas pools which are related to young magmatic activity. The gas layers occur in two major reservoir-caprock systems, the terrestrial Meso-Cenozoic clastic rock system and the marine Meso-Palaeozoic carbonate rock-clastic rock system. Controlled by the difference in the scale of traps in the two reservoir-caprock systems, large and medium-scale inorganic gas pools are formed in the marine Meso-Palaeozoic Group and only small ones are formed in the terrestrial Meso-Cenozoic strata. Inorganic gas pools in this basin are distributed along the two deep lithospheric faults on the west and south boundaries of the basin. Gas pools are developed at the intersected part of the ENE-trending faults that control the half graben and the E-W tenso-shear faults, mainly distributed near the Es1, Ny1 and Ny2-Q basalt eruption centres.
基金the National Natural Scienoe Foundation of China
文摘Carbon dioxide gas pools occur widely in the basins of eastern China.CO_2 gas-bearing beds are from the Teritary to Ordovician,and reservoirs are sandstone,carbonates and volcanics.The gases from these gas pools contain CO_2 of 62.86 ‰ —99.55 ‰.In the Mesozoic-Cenozoic extensional basins,such as Songliao,Bohai Bay,Subei,Sanshui and Zhujingkou,the δ^(13)C_(CO_2)values of CO_2 gas pools range from-2.65‰ to-8.83‰,mainly from-3.5‰ to-6.0‰,~3He/~4He ratios are 2.65R_a to 4.96R_a.The regression equa- tion of CO_2 content and helium isotope ratio is CO_2(%)=61.3852+7.9745R/R_a,correlation coefficient r is 0.9430,CO_2 is mainly mantle-derived and magmatic origin.δ^(13)C_(CO_2)value of CO_2 gas from Well X in Yinggehai Basin is-3.80‰.~3He/~4He ratio is 0.07R_a,CO_2 is metamorphic origin.Mantle-derived and magmatic CO_2 gases are discharged from the cross areas of northeastern trending and northwestern trending faults in these Mesozoic-Cenozoic extensional basins,in the shallow level,the CO_2 gases migrate and accumulate along northeastern trending extensional faults.The activity of the Neogene to Quaternary northwestern trending tectonic-magmatism zones in eastern China is another important discharge event for mantle-derived and magmatic gases,which have great contribution to the CO_2 gas pools in this area.Metamorphic CO_2 in the Yinggehai Basin is released by the dynamic metamorphism of shear fractures.
基金supported by Federal Ministry of Food,Agriculture and Consumer Protection,Agency for Renewable Resources in Germany(No.22010502)
文摘Gas separation is a key issue in various industrial fields. Hydrogen has the potential for application in clean fuel technologies. Therefore, the separation and purification of hydrogen is an important research subject. CO2 capture and storage have important roles in ＂green chemistry＂. As an effective clean technology, gas separation using inorganic membranes has attracted much attention in the last several decades. Membrane processes have many applications in the field of gas separation. Cement is one type of inorganic material, with the advantages of a lower cost and a longer lifespan. An experimental setup has been created and improved to measure twenty different cement membranes. The purpose of this work was to investigate the influence of gas molecule properties on the material transport and to explore the influence of operating conditions and membrane composition on separation efficiency. The influences of the above parameters are determined, the best conditions and membrane type are found, it is shown that cementitious material has the ability to separate gas mixtures, and the gas transport mechanism is studied.
