A new 3d-4f（CuⅡ-CeⅢ） hetero-metallic compound containing two kinds of ligands, namely [CuⅡ（H2pdc）（phen）（H2O）]（HⅢ3O）2[CeⅢ（pdc）3][CuⅡ（phen）Ce（pdc）3]（1, H2 pdc = pyridine-2,6-dicarboxylic acid, phe...A new 3d-4f（CuⅡ-CeⅢ） hetero-metallic compound containing two kinds of ligands, namely [CuⅡ（H2pdc）（phen）（H2O）]（HⅢ3O）2[CeⅢ（pdc）3][CuⅡ（phen）Ce（pdc）3]（1, H2 pdc = pyridine-2,6-dicarboxylic acid, phen = 1,10-phenanthroline）, has been synthesized by an ionothermal method using the ionic liquid 3-butyl-1-methylimidazolium bromide（[Bmim]Br） as solvent, and characterized by elemental analysis, energy-dispersive X-ray spectroscopy（EDS）, IR, XPS and single-crystal X-ray diffraction. The structure reveals that 1 belongs to the triclinic system, space group P1 with a = 12.044（7）, b = 14.841（8）, c = 22.305（13） A, α = 85.802（12）, β = 85.471（12）, γ = 89.174（11）°, Z = 2, V = 3964（4） A3, Dc = 1.804 g·cm-3, F（000） = 2140, μ = 1.757 mm-1, the final R = 0.0734, wR = 0.1094 and S = 1.013. The compound can be viewed as a two-dimensional layered structure composed by 3d-4f hetero-nuclear anions [Cu（phen）Ce（pdc）3]-, coordination cations [Cu（H2pdc）（phen）（H2O）]2＋, coordination anions [Ce（pdc）3]3- and protonated water molecules via hydrogen bonding interactions and π-π stacking. Moreover, the antimicrobial activities of 1 have been also investigated. The results indicated that its inhibitory activity is slightly higher than that of penicillin against Candida albicans.展开更多
A series of hetero-metal(Ni,Mn,and Cu)doped Co-based catalysts were prepared by a unipolar pulse electro-deposition(UPED)method and applied for the catalytic combustion of toluene.It is found that hetero-metal doping ...A series of hetero-metal(Ni,Mn,and Cu)doped Co-based catalysts were prepared by a unipolar pulse electro-deposition(UPED)method and applied for the catalytic combustion of toluene.It is found that hetero-metal doping significantly influenced the morphology and surface elemental compositions of Co-based catalysts,and the increase in the contents of Ni and Mn elements made a negative influence on the catalyst structure.H_(2)-TPR and O_(2)-TPD analysis results suggested that the hetero-metal doping enhanced the low temperature reducibility and resulted in the formation of lattice defects,which were favorable to generate more easily reducible species and facilitate the oxygen mobility,thereby improved the performance for the catalytic combustion of toluene.Especially,the Co-Cu/NF catalyst performed the best catalytic activity with the lowest toluene conversion temperature of T90 at 248℃,which should be contributed by its low-temperature reducibility,increased surface and lattice oxygen species,and high content of active Co^(3+)species promoted by the interaction of the mixed metal oxides.Moreover,the Co-Cu/NF also performed excellent catalytic stability and high selectivity to CO_(2) in the presence and absence of water vapor for the catalytic combustion of toluene for a long term.展开更多
基金Project supported by the Youth Project of Nanyang Normal University(No.QN2015027)
文摘A new 3d-4f（CuⅡ-CeⅢ） hetero-metallic compound containing two kinds of ligands, namely [CuⅡ（H2pdc）（phen）（H2O）]（HⅢ3O）2[CeⅢ（pdc）3][CuⅡ（phen）Ce（pdc）3]（1, H2 pdc = pyridine-2,6-dicarboxylic acid, phen = 1,10-phenanthroline）, has been synthesized by an ionothermal method using the ionic liquid 3-butyl-1-methylimidazolium bromide（[Bmim]Br） as solvent, and characterized by elemental analysis, energy-dispersive X-ray spectroscopy（EDS）, IR, XPS and single-crystal X-ray diffraction. The structure reveals that 1 belongs to the triclinic system, space group P1 with a = 12.044（7）, b = 14.841（8）, c = 22.305（13） A, α = 85.802（12）, β = 85.471（12）, γ = 89.174（11）°, Z = 2, V = 3964（4） A3, Dc = 1.804 g·cm-3, F（000） = 2140, μ = 1.757 mm-1, the final R = 0.0734, wR = 0.1094 and S = 1.013. The compound can be viewed as a two-dimensional layered structure composed by 3d-4f hetero-nuclear anions [Cu（phen）Ce（pdc）3]-, coordination cations [Cu（H2pdc）（phen）（H2O）]2＋, coordination anions [Ce（pdc）3]3- and protonated water molecules via hydrogen bonding interactions and π-π stacking. Moreover, the antimicrobial activities of 1 have been also investigated. The results indicated that its inhibitory activity is slightly higher than that of penicillin against Candida albicans.
文摘A series of hetero-metal(Ni,Mn,and Cu)doped Co-based catalysts were prepared by a unipolar pulse electro-deposition(UPED)method and applied for the catalytic combustion of toluene.It is found that hetero-metal doping significantly influenced the morphology and surface elemental compositions of Co-based catalysts,and the increase in the contents of Ni and Mn elements made a negative influence on the catalyst structure.H_(2)-TPR and O_(2)-TPD analysis results suggested that the hetero-metal doping enhanced the low temperature reducibility and resulted in the formation of lattice defects,which were favorable to generate more easily reducible species and facilitate the oxygen mobility,thereby improved the performance for the catalytic combustion of toluene.Especially,the Co-Cu/NF catalyst performed the best catalytic activity with the lowest toluene conversion temperature of T90 at 248℃,which should be contributed by its low-temperature reducibility,increased surface and lattice oxygen species,and high content of active Co^(3+)species promoted by the interaction of the mixed metal oxides.Moreover,the Co-Cu/NF also performed excellent catalytic stability and high selectivity to CO_(2) in the presence and absence of water vapor for the catalytic combustion of toluene for a long term.
