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Separation of Ions from Volatile Organic Compounds Using High-Field Asymmetric Waveform Ion Mobility Spectrometry-Mass Spectrometer 被引量:2
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作者 李华 王晓浩 +2 位作者 唐飞 杨吉 丁力 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第2期125-132,I0001,共9页
A combination of high-field asymmetric waveform ion mobility spectrometry (FAIMS) with mass spectrometer (MS) was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filte... A combination of high-field asymmetric waveform ion mobility spectrometry (FAIMS) with mass spectrometer (MS) was analyzed. FAIMS separates ions from the volatile organic compounds in the gas-phase as an ion-filter for MS. The sample ions were created at ambient pressure by ion source, which was equipped with a 10.6 eV UV discharge lamp (A=116.5 nm). The drift tube of FAIMS is composed of two parallel planar electrodes and the dimension is 10 mm×8 mm×0.5 mm. FAIMS was investigated when driven by the high-filed rectangular asymmetric waveform with the peak-to-peak voltage of 1.36 kV at the frequency of 1 MHz and the duty cycle of 30%. The acetone, the butanone, and their mixture were adopted to characterize the FAIMS-MS. The mass spectra obtained from MS illustrate that there are ion-molecular reactions between the ions and the sample neutral molecular. And the proton transfer behavior in the mixture of the acetone and the butanone is also observed. With the compensation voltage tuned from -30 V to 10 V with a step size of 0.1 V, the ion pre-separation before MS is realized. 展开更多
关键词 high-field asymmetric waveform ion mobility spectrometry Mass spectrometer Ion-filter Ion-molecular reaction Proton transfer
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Electric-magnetic-force characteristics of rare earth barium copper oxide superconductor high-field coils based on screening effect and strain sensitivity 被引量:3
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作者 Wenhai ZHOU Youhe ZHOU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2022年第8期1249-1268,共20页
Rare earth barium copper oxide(REBCO)is the most researched and commercialized second-generation high-temperature superconducting material.Due to the anisotropic structure,strong deformation sensitivity,and central fi... Rare earth barium copper oxide(REBCO)is the most researched and commercialized second-generation high-temperature superconducting material.Due to the anisotropic structure,strong deformation sensitivity,and central field errors caused by screening current effects,it is still a challenge for commercialization applications.In this study,the transversely isotropic constitutive relationship is selected as the mechanical model based on the structural characteristics of REBCO tapes,and suitable microelements are selected to equate the elastic constants using their average stress-strain relationships.Then,a two-dimensional axisymmetric model for coils wound by single-layer tapes is constructed to analyze the dependence of the electric-magnetic-force distribution in the tape on the strain.Finally,the anisotropic approximation of the homogenized bulk method is used to equate large-turn high-field coils,and the electric-magnetic-force distribution characteristics of the coils with/without screening effects and mechanical strain conditions are investigated,respectively.The results reveal that the mechanical strain has a weakening effect on the electromagnetic field distribution of superconducting tapes,but causes a significant enhancement in the force field distribution.In the presence of 0.5% mechanical strain,the maximum weakening of the peak value of the current density and the critical current density inside the high-field coil can reach about 8% and 13%,respectively,with a nearly 5 times increase in the peak stress.The screening current makes the current field distribution inside the coil improve by about 10 times.The screening current induced magnetic field can reach up to 0.8 T,making the relative error of the high-field coil center up to 7.8%. 展开更多
关键词 screening current strain sensitivity mechanical behavior rare earth barium copper oxide(REBCO)high-field coil electromagnetic field distribution
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High-Field MRI Contribution in Tolosa-Hunt Syndrome (THS). Report of Two Cases and Review of Literature 被引量:2
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作者 Chérif Mohamadou Aidara Philomène Kouna +6 位作者 Jennifer Nyangui Mapaga Nfally Badji Hamidou Deme Abdoulaye Dione Diop Abdoulaye Ndoye Diop Sokhna Ba El Hadj Niang 《Open Journal of Radiology》 2018年第3期141-149,共9页
Background: Tolosa Hunt Syndrome is an inflammatory condition of unknown etiology of the cavernous sinus and superior orbital fissure. Because of the difficulty in establishing histological evidence, his diagnosis is ... Background: Tolosa Hunt Syndrome is an inflammatory condition of unknown etiology of the cavernous sinus and superior orbital fissure. Because of the difficulty in establishing histological evidence, his diagnosis is based on a set of arguments established by the International Headache Society. MRI allows indirect visualization of the granuloma and plays a key role in diagnosis and follow-up. Aim: To illustrate High-field MRI contribution in Tolosa-Hunt Syndrome (THS). Cases Presentation: Two patients, a 25-year-old female and a 40-year-old male were recruited in this retrospective case report study at the Radiology service of Fann University Hospital (Dakar Senegal). The first patient has been suffering from a right retro-orbital pain and diplopia for 2 months and the second from a painful oculomotor nerve palsy for 3 months. Blood tests, lumbar puncture, thyroid hormone levels and an infectious screen were done. Screening for converting enzymes, and serum antibodies were also done. They underwent a high field MRI (Siemens 1.5T) with T1, T2, FLAIR, T2*, diffusion B1000, TOF polygon, CISS 3D and T1 gadolinium sequences in the 3 planes space. No significant abnormality was detected in blood tests or CSF analysis. Screening for converting enzymes and serum antibodies screen were also negative. For each patient, MRI examinations showed a non tumoral thickening of the right cavernous sinus, suggesting a granulomatous involvement. Tolosa Hunt Syndrome was evoked firstly. They were put on corticotherapy at high doses with a spectacular regression of symptoms. The Criteria of the International Headache Society of THS were met in both patients. Conclusion: High-field MRI is a significant diagnostic tool in the assessment of painful ophthalmoplegia. It allows a direct visualization of the granuloma of the cavernous sinus and assesses its course throughout the disease. 展开更多
关键词 PAINFUL OPHTHALMOPLEGIA Tolosa-Hunt Syndrome Criterias of International HEADACHE SOCIETY high-field MRI
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High Density Plasma Heating by EC-Waves Injected from the High-Field Side for Mode Conversion to Electron Bernstein Waves in LHD
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作者 Y.YOSHIMURA S.KUBO +8 位作者 T.SHIMOZUMA H.IGAMI H.TAKAHASHI M.NISHIURA S.OGASAWARA R.MAKINO T.MUTOH H.YAMADA A.KOMORI 《Plasma Science and Technology》 SCIE EI CAS CSCD 2013年第2期93-96,共4页
To realize an excitation of electron Bernstein waves (EBW) via mode conversion from X-mode waves injected from the high magnetic field side (HFS), new inner-vessel mirrors were installed close to a helicM coil in ... To realize an excitation of electron Bernstein waves (EBW) via mode conversion from X-mode waves injected from the high magnetic field side (HFS), new inner-vessel mirrors were installed close to a helicM coil in the large helicM device (LHD). 77 GHz electron cyclotron (EC) wave beams injected from an existing EC-wave injection system toward the new mirror are reflected on the mirror so that the beams are injected to plasmas from HFS. Evident increases in the electron temperature at the plasma core region and the plasma stored energy were observed by the HFS beam injection to the plasmas with the line-average electron density of 7.5~ 1019 m-3, which is slightly higher than the plasma cut-off density of 77 GHz EC-waves, 7.35~ 1019 m-3. The heating efficiency evaluated from the changes in the time derivative of the plasma stored energy reached ,,~70%. Although so far it is not clear which is the main cause of the heating effect, the mode-converted EBW or the X-mode wave itself injected from the HFS, an effective heating of high-density plasma over the plasma cut-off of EC-wave was successfully demonstrated. 展开更多
关键词 electron Bernstein wave EBW slow X-B overdense high density plasmaheating high-field side injection ECH LHD
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Laser-assisted Stark deceleration of CaF in its rovibronic ground (high-field-seeking) state
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作者 Yuefeng Gu Kai Chen +1 位作者 Yunxia Huang Xiaohua Yang 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第4期170-176,共7页
A near-resonant, red-detuning laser-assisted Stark deceleration scheme is proposed to slow CaF in its high-fieldseeking rovibronic ground state. The assisting Gaussian laser beam can confine CaF molecules transversely... A near-resonant, red-detuning laser-assisted Stark deceleration scheme is proposed to slow CaF in its high-fieldseeking rovibronic ground state. The assisting Gaussian laser beam can confine CaF molecules transversely owing to the optical Stark effect. Simulations suggest that the present scheme is superior to previous Stark decelerators. Under typical experimental conditions, when the assisting laser frequency is red-detuned to the molecular transition(λ~606.3 nm) by5.0 GHz and the laser power is about 5.6 W, the proposed decelerator can achieve a total number at the order of 10~4 CaF molecules with a number density at the order of 10~8 cm^(-3). The equivalent temperature of the obtained cold CaF molecules is 2.3 mK. Additionally, the desired assisting laser power can be as low as about 1.2 W if keeping the red-detuning value to be 1.0 GHz, which further suggests its experimental feasibility. 展开更多
关键词 STARK DECELERATION polar molecule optical STARK effect high-field-seeking STATE
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Fast Growth of Highly Ordered TiO2 Nanotube Arrays on Si Substrate under High-Field Anodization 被引量:1
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作者 Jingnan Song Maojun Zheng +7 位作者 Bin Zhang Qiang Li Faze Wang Liguo Ma Yanbo Li Changqing Zhu Li Ma Wenzhong Shen 《Nano-Micro Letters》 SCIE EI CAS 2017年第2期3-13,共11页
Highly ordered TiO_2 nanotube arrays(NTAs) on Si substrate possess broad applications due to its high surfaceto-volume ratio and novel functionalities, however, there are still some challenges on facile synthesis. Her... Highly ordered TiO_2 nanotube arrays(NTAs) on Si substrate possess broad applications due to its high surfaceto-volume ratio and novel functionalities, however, there are still some challenges on facile synthesis. Here, we report a simple and cost-effective high-field(90–180V) anodization method to grow highly ordered TiO_2 NTAs on Si substrate,and investigate the effect of anodization time, voltage, and fluoride content on the formation of TiO_2 NTAs. The current density–time curves, recorded during anodization processes, can be used to determine the optimum anodization time. It is found that the growth rate of TiO_2 NTAs is improved significantly under high field, which is nearly 8 times faster than that under low fields(40–60 V). The length and growth rate of the nanotubes are further increased with the increase of fluoride content in the electrolyte. 展开更多
关键词 TiO2 nanotube arrays Si substrate Anodization High field Controllable preparation
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High-field-induced electron detrapping in an AlGaN/GaN high electron mobility transistor 被引量:4
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作者 付立华 陆海 +4 位作者 陈敦军 张荣 郑有炓 魏珂 刘新宇 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第10期512-515,共4页
A step stress test is carried out to study the reliability characteristics of an AlGaN/GaN high electron mobility transistor(HEMT).An anomalous critical drain-to-gate voltage with a negative temperature coefficient ... A step stress test is carried out to study the reliability characteristics of an AlGaN/GaN high electron mobility transistor(HEMT).An anomalous critical drain-to-gate voltage with a negative temperature coefficient is observed in the stress sequence,beyond which the HEMT device starts to recover from degradation induced by early lower voltage stress.While the performance degradation featuring the drain current slump stems from electron trapping in the surface or bulk states during low-to-medium bias stress,the recovery is attributed to high field induced electron detrapping.The carrier detrapping mechanism could be helpful for lessening the trapping-related performance degradation of a GaN-based HEMT. 展开更多
关键词 AlGaN/GaN HEMT step stress test high electric field electron detrapping
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High-Field-Strength Elements in Mafic Volcanics from North China Craton: Implications for Archean-Proterozoic Boundary and Source Composition 被引量:1
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作者 Liu Yongsheng Gao Shan Luo Tingchuan Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 《Journal of Earth Science》 SCIE CAS CSCD 1998年第2期17-23,共7页
Archean to Cenozoic mafic volcanic rocks from the North China craton are studied. They show Archean Proterozoic (Ar Pt) boundary and geochemical anomalies in Cenozoic basalts. Proterozoic mafic volcanics are enriche... Archean to Cenozoic mafic volcanic rocks from the North China craton are studied. They show Archean Proterozoic (Ar Pt) boundary and geochemical anomalies in Cenozoic basalts. Proterozoic mafic volcanics are enriched in most of the high field strength elements (HFSE) compared with Archean ones. Nb, Ta and Th show a distinct sequence of incompatibility in Archean and Proterozoic. The Cenozoic basalts are enriched in HFSE and Ni and their REEs are strongly differentiated with positive Eu anomalies ( δ (Eu)=1.14). The Ar Pt boundary could be related to change in oxygen fugacity and requires an increasing importance of enriched mantle source. The geochemistry of Cenozoic basalts implies a mantle source similar to OIB. Residuum from subducting partial melting of old basaltic oceanic crust and continental crust is likely to contribute to the formation of the enriched mantle. 展开更多
关键词 mafic volcanic rocks high field strength element Archean Proterozoic boundary enriched mantle.
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Ultra-high-field magnetic resonance:Why and when? 被引量:1
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作者 Ewald Moser 《World Journal of Radiology》 CAS 2010年第1期37-40,共4页
This paper briefly summarizes the development of magnetic resonance imaging and spectroscopy in medicine.Aspects of magnetic resonancephysics and-technology relevant at ultra-high magnetic fields as well as current li... This paper briefly summarizes the development of magnetic resonance imaging and spectroscopy in medicine.Aspects of magnetic resonancephysics and-technology relevant at ultra-high magnetic fields as well as current limitations are highlighted.Based on the first promising studies,potential clinical applications at 7 Tesla are suggested.Other aims are to stimulate awareness of the potential of ultra-high field magnetic resonance and to stimulate active participation in much needed basic or clinical research at 7 Tesla or higher. 展开更多
关键词 Alzheimer’s disease Brain tumors CARTILAGE Functional MAGNETIC RESONANCE imaging MAGNETIC RESONANCE MAGNETIC RESONANCE spectroscopy Multiple SCLEROSIS Ultra-high field MAGNETIC RESONANCE methods
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磁场、超声场、高压静电场抑垢阻垢研究进展
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作者 陈小砖 李栋 +1 位作者 赵嫚 黎永福 《工业水处理》 北大核心 2025年第3期22-33,共12页
提高工业生产过程中换热设备的换热效率对节能减排有着重要意义,抑垢阻垢是提高换热效率的有效途径,也是当前能源动力工程领域达到“双碳”目标的重要手段。磁场、超声场、高压静电场等物理场抑垢阻垢技术具有操作简单,杀菌灭藻,不停机... 提高工业生产过程中换热设备的换热效率对节能减排有着重要意义,抑垢阻垢是提高换热效率的有效途径,也是当前能源动力工程领域达到“双碳”目标的重要手段。磁场、超声场、高压静电场等物理场抑垢阻垢技术具有操作简单,杀菌灭藻,不停机处理,不产生化学废液等优点。首先,介绍了恒定磁场和高频电磁水处理技术抑垢阻垢的研究现状,并详细讨论了不同工况下磁场的最佳阻垢频率/频段;其次,介绍了国内外超声场和高压静电场在抑垢阻垢方面的最新研究成果,超声场的空化作用及预处理作用,能够提前过滤去除污垢,高压静电场处理后,垢层变得疏松,形貌和特性均发生改变;最后提出了磁场、超声场、高压静电场等物理场抑垢阻垢存在的不足,并对未来关于物理场抑垢阻垢研究在协同作用和分子动力学模拟方面进行了展望。 展开更多
关键词 磁场 超声场 高压静电场 抑垢阻垢
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Elastic properties of Cu–6wt% Ag alloy wires for pulsed magnets investigated by ultrasonic techniques
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作者 Ziyu Li Tianyi Gu +12 位作者 Wenqi Wei Yang Yuan Zhuo Wang Kangjian Luo Yupeng Pan Jianfeng Xie Shaozhe Zhang Tao Peng Lin Liu Qi Chen Xiaotao Han Yongkang Luo Liang Li 《Chinese Physics B》 2025年第2期90-95,共6页
Conductor materials with good mechanical performance as well as high electrical and thermal conductivities are particularly important to break through the current bottle-neck limit(~ 100 T) of pulsed magnets. Here, we... Conductor materials with good mechanical performance as well as high electrical and thermal conductivities are particularly important to break through the current bottle-neck limit(~ 100 T) of pulsed magnets. Here, we perform systematic studies on the elastic properties of the Cu–6wt% Ag alloy wire, which is a promising candidate material for the new-generation pulsed magnets, by employing two independent ultrasonic techniques, i.e., resonant ultrasound spectroscopy(RUS) and ultrasound pulse-echo experiments. Our RUS measurements manifest that the elastic properties of the Cu–6wt% Ag alloy wires can be improved by an electroplastic drawing procedure as compared with the conventional cold drawing. We also take this opportunity to test the availability of our newly-built ultrasound pulse-echo facility at the Wuhan National High Magnetic Field Center(WHMFC, China), and the results suggest that the elastic performance of the electroplastically-drawn Cu–6wt% Ag alloy wire remains excellent without anomalous softening under extreme conditions,e.g., in ultra-high magnetic field up to 50 T and nitrogen or helium cryogenic liquids. 展开更多
关键词 high-field magnet Cu–Ag alloy ultrasonic techniques elastic constants
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6G新高频无线接入技术的创新与试验
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作者 彭琳 罗钧 +4 位作者 方敏 田珅 张忠皓 李福昌 唐雪 《邮电设计技术》 2025年第1期21-26,共6页
阐述了太赫兹技术成为6G无线接入关键技术所面临的挑战,详细介绍了解决传统太赫兹技术低谱效、高阻塞、非视距(NLOS)等瓶颈问题的技术方案,包括高谱效大带宽实时通信系统、近场自愈合抗阻塞、超表面非视距覆盖等技术试验的初步结果,以... 阐述了太赫兹技术成为6G无线接入关键技术所面临的挑战,详细介绍了解决传统太赫兹技术低谱效、高阻塞、非视距(NLOS)等瓶颈问题的技术方案,包括高谱效大带宽实时通信系统、近场自愈合抗阻塞、超表面非视距覆盖等技术试验的初步结果,以推进太赫兹技术向6G新高频无线接入技术的发展进程。 展开更多
关键词 6G新高频 近场移动接入 自愈合 超表面
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不同产地虾酱代谢物组的比较 被引量:1
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作者 刘佳乐 郑兰萍 +4 位作者 刘颖 刘敏 陈亚泉 龙肇 付湘晋 《食品科学》 北大核心 2025年第4期147-153,共7页
目的:探究不同产地虾酱非挥发性小分子组成。方法:采用超高效液相色谱-静电场轨道阱高分辨质谱技术对山东、广东、河北地区虾酱中的代谢物进行检测;结合正交偏最小二乘判别分析识别不同产地虾酱特征性代谢物。结果:虾酱富含氨基酸、脂... 目的:探究不同产地虾酱非挥发性小分子组成。方法:采用超高效液相色谱-静电场轨道阱高分辨质谱技术对山东、广东、河北地区虾酱中的代谢物进行检测;结合正交偏最小二乘判别分析识别不同产地虾酱特征性代谢物。结果:虾酱富含氨基酸、脂肪酸类代谢物,形成了大量N-脂酰化合物,相对含量高的有肉桂酸、11’-羧基-α-铬醇和β-亮氨酸等,虾酱中还新发现多巴胺、去甲肾上腺素、6-羟基褪黑素、γ-谷氨酰胺-5-羟基色氨酸等积极神经递质类活性物质;山东虾酱主要有肉桂酸、β-亮氨酸等特征代谢物;广东虾酱主要有12-Hete-T和N-油酰牛磺酸等特征代谢物;河北虾酱主要有二十碳五烯酸和花青素-3-O-(6’-丙酰基阿拉伯糖苷)等特征代谢物。结论:虾酱富含β-亮氨酸、谷氨酸、脯氨酸-缬氨酸和亮氨酸-甘氨酸等小分子物质和牛磺酸、去甲肾上腺素和多巴胺等生物活性成分。不同产地虾酱中代谢产物组成具有一定的产地特异性。 展开更多
关键词 虾酱 代谢组学 超高效液相色谱-静电场轨道阱高分辨质谱 正交偏最小二乘判别分析 特征代谢物
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爆炸火球内部温度测量方法研究
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作者 赵敏 张丕状 +2 位作者 豆鑫 赵毅 田其森 《化工自动化及仪表》 2025年第2期198-204,共7页
针对爆炸温度场测量环境复杂、参数变化动态范围大和测量难度大的问题,提出了一种基于比色测温技术的爆炸场内部温度测量方法,并搭建了相应的爆炸场温度测量系统。该系统成功测试了由30kg甲、乙配方温压弹形成的火球温度场。研究结果显... 针对爆炸温度场测量环境复杂、参数变化动态范围大和测量难度大的问题,提出了一种基于比色测温技术的爆炸场内部温度测量方法,并搭建了相应的爆炸场温度测量系统。该系统成功测试了由30kg甲、乙配方温压弹形成的火球温度场。研究结果显示,甲配方炸药爆炸最高温度达到2950℃,爆炸持续时间为420ms左右;而乙配方炸药爆炸最高温度可达3200℃,爆炸持续时间小于400ms,实现了对爆炸火球内部温度的测量。与传统的热电偶传感器相比,所提系统能够有效地获取爆炸火球内部温度,具有可行性。 展开更多
关键词 比色测温 爆炸温度场 瞬态高温 火球内部温度
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Negligible oxygen vacancies,low critical current density,electric-field modulation,in-plane anisotropic and high-field transport of a superconducting Nd_(0.8)Sr_(0.2)NiO_(2)/SrTiO_(3) heterostructure 被引量:2
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作者 Xiao-Rong Zhou Ze-Xin Feng +9 位作者 Pei-Xin Qin Han Yan Xiao-Ning Wang Pan Nie Hao-Jiang Wu Xin Zhang Hong-Yu Chen Zi-Ang Meng Zeng-Wei Zhu Zhi-Qi Liu 《Rare Metals》 SCIE EI CAS CSCD 2021年第10期2847-2854,共8页
The emerging Ni-based superconducting oxide thin films are rather intriguing to the entire condensed matter physics. Here, we report some brief experimental results on transport measurements for a 14-nm-thick supercon... The emerging Ni-based superconducting oxide thin films are rather intriguing to the entire condensed matter physics. Here, we report some brief experimental results on transport measurements for a 14-nm-thick superconducting Nd_(0.8)Sr_(0.2)NiO_(2)/SrTiO_(3) thin-film heterostructure with an onset transition temperature of~9.5 K. Photoluminescence measurements reveal that there is negligible oxygen vacancy creation in the SrTiO_(3) substrate during thin-film deposition and post chemical reduction for the Nd_(0.8)Sr_(0.2)NiO_(2)/SrTiO_(3) heterostructure. It was found that the critical current density of the Nd_(0.8)Sr_(0.2)NiO_(2)/SrTiO_(3) thin-film heterostructure is relatively small, ~4×10^(3) A·cm^(-2). Although the surface steps of SrTiO_(3) substrates lead to an anisotropy for in-plane resistivity, the superconducting transition temperatures are almost the same. The out-of-plane magnetotransport measurements yield an upper critical field of~11.4 T and an estimated in-plane Ginzburg–Landau coherence length of~5.4 nm. High-field magnetotransport measurements up to 50 T reveal anisotropic critical fields at 1.8 K for three different measurement geometries and a complicated Hall effect. An electric field applied via the SrTiO_(3) substrate slightly varies the superconducting transition temperature. These experimental results could be useful for this rapidly developing field. 展开更多
关键词 NICKELATES SUPERCONDUCTIVITY Ni-based superconductivity high-field transport Electric-field modulation
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深层高阶煤层CO_(2)-ECBM技术研究与应用启示——以沁水盆地晋中地区为例 被引量:1
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作者 郑永旺 崔轶男 +3 位作者 李鑫 肖翠 郭涛 张登峰 《石油实验地质》 北大核心 2025年第1期143-152,共10页
深层高阶煤层资源潜力大,但具有“强吸附、难解吸”的特点,常规开发方式难以实现效益动用。与化学驱、热力驱等其他提高采收率技术相比,CO_(2)-ECBM(CO_(2)地质封存及强化煤层开采)技术具有节能减排和提高煤层气采收率双重效益。为明确C... 深层高阶煤层资源潜力大,但具有“强吸附、难解吸”的特点,常规开发方式难以实现效益动用。与化学驱、热力驱等其他提高采收率技术相比,CO_(2)-ECBM(CO_(2)地质封存及强化煤层开采)技术具有节能减排和提高煤层气采收率双重效益。为明确CO_(2)吸附、解吸特性,论证CO_(2)-ECBM技术提高深层高阶煤层气采收率可行性,助力深层高阶煤层气产能释放,以沁水盆地晋中地区为研究对象,开展深层高阶煤层CO_(2)吸附、解吸特征研究实验。研究结果表明,随着平衡压力的增加,煤层对CH_(4)的吸附量逐渐增加,而受煤层孔裂隙发育特征及CO_(2)特征影响,煤层对CO_(2)的吸附量呈先持续上升再在临界压力附近骤降后大幅上升的特征。深层高阶煤层对CO_(2)的吸附能力约为CH_(4)的2~5倍,超临界CO_(2)在煤层中的吸附能力更强,CO_(2)的敏感解吸压力为CH_(4)的3/4,且吸附于煤层后,CO_(2)呈现出明显的吸附、解吸滞后特征,大比例CO_(2)以吸附封存和残余封存形式滞留在煤层中无法脱附,成为实现大规模封存CO_(2)和替换CH_(4)的有利条件。通过实验结果分析,明确了深层高阶煤层气开展CO_(2)-ECBM具备大幅提高采收率的可行性。矿场应用中,可通过超前注气、加大注入压力等方式提高气藏压力水平,提升竞争吸附效率,同时低敏感解吸压力也表明注入CO_(2)后返排率较高,需考虑CO_(2)循环利用。 展开更多
关键词 深层煤层气 高阶煤 CO_(2)-ECBM 竞争吸附 矿场应用启示
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磁场增强型高通量辉光放电溅射源的设计与研究
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作者 沈懿璇 万真真 +4 位作者 余兴 王海舟 王永清 朱一妃 刘少锋 《光谱学与光谱分析》 北大核心 2025年第2期410-419,共10页
高通量表征技术在金属材料分析领域具有重要应用价值,它能够实现对金属材料进行跨尺度的全域分析,评价材料表面宏观特性、微观不均匀性及局部缺陷。辉光放电溅射可沿样品表面的纵深方向,以大尺寸、平坦且快速的方式逐层剥蚀样品,再将暴... 高通量表征技术在金属材料分析领域具有重要应用价值,它能够实现对金属材料进行跨尺度的全域分析,评价材料表面宏观特性、微观不均匀性及局部缺陷。辉光放电溅射可沿样品表面的纵深方向,以大尺寸、平坦且快速的方式逐层剥蚀样品,再将暴露出真实显微组织的样品送至多种分析仪器中进行成分、性能、组织结构的分析,从而作为金属材料的高通量表征样品前处理环节的关键设备。在传统Grimm型辉光溅射源的基础上,本研究搭建了一种专为高通量实验设计的辉光放电溅射系统,该系统将辉光溅射尺度由mm级扩展至cm级,同时实验发现了大尺寸溅射会导致辉光放电强度及溅射速率降低这一现象。针对这一现象,结合通过COMSOL Multiphysics仿真计算的辉光放电电子运动轨迹、电子密度以及化学反应速率等结果,该研究提出了一种通过施加扫描磁场来增强辉光放电光谱(GD-OES)强度以及溅射速率的方法。实验选用T2紫铜样品来探究扫描磁场的增强效果,结果表明,应用扫描磁场增强装置可获得更强的光谱信号强度及更快的溅射速率。在保持放电电压和电流不变的前提下,Mo、Cu元素的光谱强度分别增至无磁场时的1.43~11.97倍和1.13~26.50倍。其中,Mo元素光谱强度最大值可达53421 Cts,Cu元素光谱强度最大值可达76948 Cts,分别是无磁场时的6.86倍、4.32倍。此外,该方法可以显著地提高溅射速率,当阳极筒孔径为?15 mm时,T2紫铜样品的溅射速率提高了4.35倍,最高可达2662.09 nm·min^(-1)。使用白光干涉仪和金相显微镜对溅射坑表面的平整度和显微组织图像进行了采集,结果显示磁场引入对溅射坑表面粗糙度未产生显著影响,同时能清晰地呈现样品的真实显微组织特征。综上,实验结果证实,应用扫描磁场增强装置可在确保溅射平整度不受影响的前提下,实现光谱信号强度和溅射速率的提升,为解决大尺寸溅射引起的低溅射速率问题提供了新方法。 展开更多
关键词 高通量实验 磁场 光谱增强 辉光放电光谱 溅射
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安徽大学强光磁试验装置水冷系统研制及其水温高精度控制实现
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作者 陈帆 邓天白 +6 位作者 徐忠祥 陶骏 丁石川 潘天红 刘东洋 吴俊峰 陈思跃 《强激光与粒子束》 北大核心 2025年第2期46-53,共8页
介绍了安徽大学正在建设的强光磁试验装置的整体布局,详细分析了装置的稳定运行对水冷系统的设计要求及难点,根据需求完成了整个装置的水冷系统设计研制,装置的水冷系统一共包含了两路独立的水冷机组系统,设计温度分别为(42±0.1)℃... 介绍了安徽大学正在建设的强光磁试验装置的整体布局,详细分析了装置的稳定运行对水冷系统的设计要求及难点,根据需求完成了整个装置的水冷系统设计研制,装置的水冷系统一共包含了两路独立的水冷机组系统,设计温度分别为(42±0.1)℃与(25±0.5)℃,并且可在一定范围内调节。装置水冷控制系统基于EPICS框架开发,温度调节及控制功能通过PLC程序实现,PID参数配置通过PID调节器实现。控制系统的软件开发主要是在EPICS环境下实现对设备参数的设定和状态数据的回读,并将历史数据存入Archiver Appliances数据库中。试运行期间水冷控制系统的温度控制精度达到了(42±0.03)℃和(25±0.08)℃,符合设计要求,运行期间该系统稳定可靠,可以很好地保障装置安全稳定运行。 展开更多
关键词 强光磁试验装置 水冷系统 控制系统 EPICS PID
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高压静电场对鮰鱼中不动杆菌与希瓦氏菌互作的影响
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作者 王晓芸 高天麒 +3 位作者 孙卫青 吴文锦 汪兰 熊光权 《中国食品学报》 北大核心 2025年第2期353-364,共12页
为研究高压静电场(HVEF)处理斑点叉尾鮰中不动杆菌对希瓦氏菌群体感应调控的影响,对不动杆菌(AR)中酰基高丝氨酸内酯(AHLs)种类进行检测,以HVEF处理前、后的抗辐射不动杆菌(AR)分别与哈夫尼希瓦氏菌(SH)、腐败希瓦氏菌(SP)混合培养体系... 为研究高压静电场(HVEF)处理斑点叉尾鮰中不动杆菌对希瓦氏菌群体感应调控的影响,对不动杆菌(AR)中酰基高丝氨酸内酯(AHLs)种类进行检测,以HVEF处理前、后的抗辐射不动杆菌(AR)分别与哈夫尼希瓦氏菌(SH)、腐败希瓦氏菌(SP)混合培养体系为研究对象,分析HVEF处理对希瓦氏菌膜电位、蛋白酶活性、生物被膜、胞外聚合物、聚集性及运动性的影响。结果表明:在混菌共培养体系中菌株SP和菌株SH虽不能产生AHLs信号分子,但在菌株AR的影响下其致腐能力和生物膜形成能力明显提高。菌株AR分别与菌株SH和菌株SP共培养后,其蛋白酶活性分别提高了3.29倍和4.43倍,生物膜形成分别提高了5.00倍和4.60倍,聚集性提高了1.53倍和2.22倍,泳动迁移能力分别提高了5.47倍和5.76倍,群集迁移能力分别提高了4.89倍和2.21倍。菌株AR经HVEF处理后与菌株SH和菌株SP共培养体系相较于未经HVEF处理组,作用效果显著。本研究结果可为菌群间互作机制研究提供一定的理论参考。 展开更多
关键词 斑点叉尾鮰 群体感应 高压静电场 信号分子
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大庆油田萨中开发区特高含水后期生产气油比变化规律
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作者 金贤镐 何金钢 +2 位作者 万建荣 郭军辉 刘笑莹 《大庆石油地质与开发》 北大核心 2025年第2期58-67,共10页
为了研究大庆油田萨中开发区特高含水后期生产气油比在正地饱压差条件下仍急剧上升且远高于原始溶解气油比的现象,利用油/气/水高压物性室内实验研究了溶解气油比和溶解气水比的影响因素,开展了单油层开发生产气油比全生命周期评价矿场... 为了研究大庆油田萨中开发区特高含水后期生产气油比在正地饱压差条件下仍急剧上升且远高于原始溶解气油比的现象,利用油/气/水高压物性室内实验研究了溶解气油比和溶解气水比的影响因素,开展了单油层开发生产气油比全生命周期评价矿场试验,通过增加“溶解气水比”参数修正了生产气油比的理论计算公式,利用修正后的理论生产气油比曲线分析并解释了生产气油比在水驱特高含水后期大幅上升和化学驱阶段大幅波动的主要原因,并开展了萨中开发区生产气油比变化趋势评价等研究。结果表明:注入水或聚合物溶液能够从饱和气体的原油中获取部分溶解气,实验测得萨中开发区的溶解气水比达到1.952~2.138cm^(3)/g;在单油层开发矿场试验阶段,正地饱压差下生产气油比仍随综合含水率的升高而增大,且在化学驱过程中也表现出了相同的变化规律;在实际生产气油比计算时需要考虑油和水中溶解气的共同影响,通过溶解气油比和溶解气水比建立生产气油比与综合含水率之间的关系,即对生产气油比的理论公式进行修正。因此,在特高含水后期生产气油比的分析过程中,需要充分考虑水中的溶解气的影响,才能对开发形势作出更准确的判断。 展开更多
关键词 油田开发 特高含水后期 生产气油比 压力 含水率
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