Effect of graphene nanoplatelets(GNPs)addition on mechanical properties of magnesium–10wt%Titanium(Mg–10Ti)alloy is investigated in current work.The Mg-(10Ti+0.18GNPs)composite was synthesized using the semi powder ...Effect of graphene nanoplatelets(GNPs)addition on mechanical properties of magnesium–10wt%Titanium(Mg–10Ti)alloy is investigated in current work.The Mg-(10Ti+0.18GNPs)composite was synthesized using the semi powder metallurgy method followed by hot extrusion.Microstructural characterization results revealed the uniform distribution of reinforcement(Ti+GNPs)particles in the matrix,therefore(Ti+GNPs)particles act as an effective reinforcing filler to prevent the deformation.Room temperature tensile results showed that the addition of Ti+GNPs to monolithic Mg lead to increase in 0.2%yield strength(0.2%YS),ultimate tensile strength(UTS),and failure strain.Scanning Electron Microscopy(SEM),Energy-Dispersive X-ray Spectroscopy(EDS)and X-Ray Diffraction(XRD)were used to investigate the surface morphology,elemental dispersion and phase analysis,respectively.展开更多
A 0.3wt%graphene nanoplatelets(GNPs)reinforced 7075 aluminum alloy matrix(7075 Al)composite was fabricated by spark plasma sintering and its strength and wear resistance were investigated.The microstructures of the in...A 0.3wt%graphene nanoplatelets(GNPs)reinforced 7075 aluminum alloy matrix(7075 Al)composite was fabricated by spark plasma sintering and its strength and wear resistance were investigated.The microstructures of the internal structure,the friction surface,and the wear debris were characterized by scanning electron microscopy,X-ray diffraction,and Raman spectroscopy.Compared with the original 7075 aluminum alloy,the hardness and elastic modulus of the 7075 Al/GNPs composite were found to have increased by 29%and 36%,respectively.The results of tribological experiments indicated that the composite also exhibited a lower wear rate than the original 7075 aluminum alloy.展开更多
Lithium–sulfur batteries have great potential for high energy applications due to their high capacities,low cost and eco-friendliness. However, the particularly rapid capacity decay owing to the dissolution and diffu...Lithium–sulfur batteries have great potential for high energy applications due to their high capacities,low cost and eco-friendliness. However, the particularly rapid capacity decay owing to the dissolution and diffusion of polysulfide intermediate into the electrolyte still hamper their practical applications.And the reported preparation procedures to sulfur based cathode materials are often complex, and hence are rather difficult to produce at large scale. Here, we report a simple mechano-chemical sulfurization methodology in vacuum environment applying ball-milling method combined both the chemical and physical interaction for the one-pot synthesis of edge-sulfurized grapheme nanoplatelets with 3D porous foam structure as cathode materials. The optimal sample of 70%S–Gn Ps-48 h(ball-milled 48 h) obtains 13.2 wt% sulfur that chemically bonded onto the edge of Gn Ps. And the assembled batteries exhibit high initial discharge capacities of 1089 mAh/g at 0.1 C and 950 mAh/g at 0.5 C, and retain a stable discharge capacity of 776 mAh/g after 250 cycles at 0.5 C with a high Coulombic efficiency of over 98%. The excellent performance is mainly attributed to the mechano-chemical interaction between sulfur and grapheme nanoplatelets. This definitely triggers the currently extensive research in lithium–sulfur battery area.展开更多
A powder thixoforging route combined with slurry based mixing process was proposed to fabricate graphene nanoplatelets(GNPs) reinforced magnesium matrix composites(MgMCs). The originally spherical and ball-milled ZK60...A powder thixoforging route combined with slurry based mixing process was proposed to fabricate graphene nanoplatelets(GNPs) reinforced magnesium matrix composites(MgMCs). The originally spherical and ball-milled ZK60 powders were used as matrices, respectively.The mixing of 0.05 wt.% GNPs with the spherical powder led to GNPs clusters and degraded the mechanical properties of the composite.In contrast, with the addition of an optimal content(0.1 wt.%) of GNPs, the composite fabricated from ball-milled powder achieved a joint enhancement in tensile yield strength(52%) and fracture toughness(19%), demonstrating a pronounced strengthening efficiency of 650% and a good balance between strength and toughness. The ball-milled powder endowed the composite with a homogenous distribution of GNPs and a denser microstructure with reduced Mg-Zn eutectics, and the thixoforging process offered a well-bonded Mg/GNP interface, making full use of the strengthening and toughening potential of GNPs. Theoretical predication based on a modified shear-lag model suggested that load transfer dominated the strengthening mechanisms. In-situ tensile tests verified that crack deflection, secondary cracks and GNPs bridging mainly accounted for the toughening mechanisms. A numerical model with consideration of GNPs orientations was also established to understand the toughening effect from GNPs bridging.展开更多
Epoxy/graphene nanoplatelets（GNPs） powder coatings were fabricated using ultrasonic predispersion of GNPs and melt-blend extrusion method. The isothermal curing kinetics of epoxy/GNPs powder coating were monitored b...Epoxy/graphene nanoplatelets（GNPs） powder coatings were fabricated using ultrasonic predispersion of GNPs and melt-blend extrusion method. The isothermal curing kinetics of epoxy/GNPs powder coating were monitored by means of real-time Fourier transform infrared spectroscopy（FT-IR） with a heating cell. The mechanical properties of the epoxy/GNPs cured coatings had been investigated, by evaluating their fracture surfaces with field-emission scanning electron microscopy（FE-SEM） after three-point-bending tests. The thermal stability of the epoxy/GNPs cured coatings was studied by thermo-gravimetric analysis（TGA）. The isothermal curing kinetics result showed that the GNPs would not affect the autocatalytic reaction mechanism, but the loading of GNPs below 1.0 wt % additive played a prompting role in the curing of the epoxy/GNPs powder coatings. The fracture strain, fracture toughness and impact resistance of the epoxy/GNPs cured coatings increased dramatically at low levels of GNPs loading（1 wt %）, indicating that the GNPs could improve the toughness of the epoxy/GNPs powder coatings. Furthermore, from FE-SEM studies of the fracture surfaces, the possible toughening mechanisms of the epoxy/GNPs cured coatings were proposed. TGA result showed that the incorporation of GNPs improved the thermal stability of the cured coatings. Hence, the GNPs modified epoxy can be an efficient approach to toughen epoxy powder coating along with improving their thermal stability.展开更多
In aiming to obtain fibers with enhanced thermal and mechanical properties,graphene based textile fibers with 144 filaments were developed using an approach in which the PP/GnP(polypropylene/graphene nanoplatelets)nan...In aiming to obtain fibers with enhanced thermal and mechanical properties,graphene based textile fibers with 144 filaments were developed using an approach in which the PP/GnP(polypropylene/graphene nanoplatelets)nanocomposite was employed as conductive material in a fiber with circular cross-section geometry.The kinetics of thermal degradation was evaluated by the Broido method using thermogravimetric analysis(TGA).Activation energy was enhanced from 260.6 kJ·mol^-1 to 337.4 kJ·mol^-1 compared to the neat PP.GnP increased the thermal stability of the PP,slowing its degradation by thermal depolymerization.Furthermore,the degree of crystallization declined as the GnP content increased,reducing the tenacity of the yarn,but improving its elastic modulus from 91.9 to 95.9 cN/tex,being a promising alternative to produce smart textiles.In conclusion,it has been confirmed that GnP loading up to 1%(w/w)can be incorporated into polypropylene by melt spinning and that the resulting nanocomposite fibers are suitable for several applications in the textile industry.展开更多
Graphene nanoplatelets(GNPs)have attracted tremendous interest due to their unique properties and bonding capabilities.This study focuses on the effect of GNP dispersion on the mechanical,thermal,and morphological beh...Graphene nanoplatelets(GNPs)have attracted tremendous interest due to their unique properties and bonding capabilities.This study focuses on the effect of GNP dispersion on the mechanical,thermal,and morphological behavior of GNP/epoxy nanocomposites.This study aims to understand how the dispersion of GNPs affects the properties of epoxy nanocomposite and to identify the best dispersion approach for improving mechanical performance.A solvent mixing technique that includes mechanical stirring and ultrasonication was used for producing the nanocomposites.Fourier transform infrared spectroscopy was used to investigate the interaction between GNPs and the epoxy matrix.The measurements of density and moisture content were used to confirm that GNPs were successfully incorporated into the nanocomposite.The findings showed that GNPs are successfully dispersed in the epoxy matrix by combining mechanical stirring and ultrasonication in a single step,producing well-dispersed nanocomposites with improved mechanical properties.Particularly,the nanocomposites at a low GNP loading of 0.1 wt%,demonstrate superior mechanical strength,as shown by increased tensile properties,including improved Young's modulus(1.86 GPa),strength(57.31 MPa),and elongation at break(4.98).The nanocomposite with 0.25 wt%GNP loading performs better,according to the viscoelastic analysis and flexural properties(113.18 MPa).Except for the nanocomposite with a 0.5 wt%GNP loading,which has a higher thermal breakdown temperature,the thermal characteristics do not significantly alter.The effective dispersion of GNPs in the epoxy matrix and low agglomeration is confirmed by the morphological characterization.The findings help with filler selection and identifying the best dispersion approach,which improves mechanical performance.The effective integration of GNPs and their interaction with the epoxy matrix provides the doorway for additional investigation and the development of sophisticated nanocomposites.In fields like aerospace,automotive,and electronics where higher mechanical performance and functionality are required,GNPs'improved mechanical properties and successful dispersion present exciting potential.展开更多
Thermal energy storage(TES) systems use solar energy despite its irregular availability and day-night temperature difference.Current work reports the thermal characterizations of solar salt-based phase change composit...Thermal energy storage(TES) systems use solar energy despite its irregular availability and day-night temperature difference.Current work reports the thermal characterizations of solar salt-based phase change composites in the presence of graphene nanoplatelets(GNP).Solar salt(60:40 of NaNO_(3):KNO_(3)) possessing phase transition temperature and melting enthalpy of 221.01℃ and 134.58 kJ/kg is proposed as a phase change material(PCM) for high-temperature solar-based energy storage applications.Thermal conductivity must be improved to make them suitable for widespread applications and to close the gap between the system needs where they are employed.GNP is added at weight concentrations of 0.1%,0.3%,and 0.5% with solar salt using the ball milling method to boost its thermal conductivity.Morphological studies indicated the formation of a uniform surface of GNP on solar salt.FTIR spectrum peaks identified the physical interaction between salt and GNP.Thermal characterization of the composites,such as thermal conductivity,DSC and TGA was carried out for the samples earlier and later 300 thermal cycles.0.5% of GNP has improved the thermal conductivity of salt by 129.67% and after thermal cycling,the enhancement reduced to 125.21% indicating that thermal cycling has a minor impact on thermal conductivity.Phase change temperature decreased by around 2.32% in the presence of0.5% GNP and the latent heat reduced by 4.34% after thermal cycling.TGA thermograms depicted the composites initiated the weight loss at around 550℃ after which it was rapid.After thermal cycling,the weight loss initiated at ~40℃ lower compared to pure salt,which was found to be a minor change.Thermal characterization of solar salt and GNP-based solar salt composites revealed that the composites can be used for enhanced heat transfer in high-temperature solar-based heat transfer and energy storage applications.展开更多
Magnesium matrix composites(MgMCs)have always suffered low strengthening efficiency and poor ductility due to the difficulties in pursuing the well-bonded interface.Herein,graphene nanoplatelets(GNPs)were decorated wi...Magnesium matrix composites(MgMCs)have always suffered low strengthening efficiency and poor ductility due to the difficulties in pursuing the well-bonded interface.Herein,graphene nanoplatelets(GNPs)were decorated with magnesium oxide nanoparticles(MgO NPs)through chemical co-precipitation and then incorporated into AZ91 alloy to fabricate MgMCs via powder thixoforging.The effect of MgO on the interface of the Mg/graphene system was investigated based on the first-principles calculations,and the result indicated that modifying GNPs with MgO NPs was helpful in improving the Mg-GNP interface bonding.The interface structural analysis revealed that the MgO NPs were firmly bonded with both GNPs andα-Mg through the distortion area bonding and semi-coherent interfacial bonding,severing as a bridge to fasten the interface bonding of composites.In addition,the MgO NPs on GNPs acted as a barrier to prevent GNPs from seriously reacting with the AZ91 alloy.As a result,the AZ91/MgO@GNPs composite was endowed with enhancements of 31%and 10%in the yield strength,and increments of 71%and 61%in elongation compared with the AZ91 alloy and AZ91/GNPs composite,respectively,exhibiting a more significant potential in optimizing the strength-toughness tradeoffcompared with the AZ91/GNPs.Moreover,the possible strengthening and toughening mechanisms were also discussed in detail.This work offers a relatively novel surface modification strategy to modulate the Mg-GNP interface for a simultane-ous improvement of strength and ductility.展开更多
Insufficient hole cleaning,cutting suspension,clay swelling,and filtrate invasion of the formation might result from inadequate drilling mud properties.For effective drilling and wellbore stability,water-based mud(WBM...Insufficient hole cleaning,cutting suspension,clay swelling,and filtrate invasion of the formation might result from inadequate drilling mud properties.For effective drilling and wellbore stability,water-based mud(WBM)rheology,lubricity,filtration,and shale inhibition must be optimized and controlled.WBMs react with clays and cause time-dependent borehole issues,which is their principal drawback.Moreover,prolonged exposure destroys certain WBM components,resulting in minimal mud properties.These indicate the need for multifunctional additives to improve WBMs.Thus,this study developed WBM systems employing graphene nanoplatelets(GNPs)and locally acquired discarded coconut shells to overcome severe drilling challenges.By adding triton-X100 to coconut shell-based graphene(GN-CS),a greater dispersion of modified graphene(GN-TX)particles was produced.Characterization,rheology,lubricity,inhibition,and filtration tests were performed on these GN-CS and GN-TX at concentrations of 0.125,0.25,0.375,and 0.50 wt%.Furthermore,biotoxicity,biodegradability,and heavy metal content experiments were performed to study the environmental impact of GN-CS and GN-TX.The results showed that GN-TX had good thermal resistance up to 300℃ with only a 10%loss in weight.Both EDX and FTIR tests showed that the epoxy,carboxyl,and hydroxyl groups are in the GNP-based materials'basal plane.The GN-CS and GN-TX had better fluid properties,including better lubricity,rheology,filtration,and inhibition over the base mud,and the optimal rheological model of the drilling muds was the Herschel Buckley model.The GN-TX(modified)decreased the fluid loss to 20.6e14.3 mL from 24.6 mL at 353 K,whereas the GN-CS(unmodified)reduced it to 21.3e16.7 mL.GN-TX and GN-CS decreased the coefficient of friction of WBM from 0.47 to 0.55 to 0.25e0.41 and 0.33e0.44,respec-tively,from 298 to 353 K.In addition,0.50 wt%of GN-CS and GN-TX reduced the shale pellet swelling height to 5.4%and 5.6%,respectively,from 8.8%.Moreover,the EC 50 values for GN-CS and GN-TX were about 54,000 mg/L and the BOD/COD ratio was about 47%.These results show that the GNP-based products are safe and biodegradable.The GNP-based materials have promising prospects for drilling in environmentally sensitive formations.展开更多
Graphene nanoplatelets/aluminum （GNPs/Al） nanocomposites were fabricated using a novel two-step method. High resolution transmission electron microscope （HRTEM）, Raman, field emission scanning electron microscopy ...Graphene nanoplatelets/aluminum （GNPs/Al） nanocomposites were fabricated using a novel two-step method. High resolution transmission electron microscope （HRTEM）, Raman, field emission scanning electron microscopy （FESEM）, X-ray diffraction （XRD）, energy dispersive X-ray spectroscopy （EDS）, EDS mapping, and mechanical testing system （MTS） were applied to characterize the microstructure and mechanical properties of the GNPs/Al nanocomposites. The GNPs were homogeneously dispersed in GNPs/Al nanocomposites, and presented a fine interface behavior and microstructure characteristics. A harmful phase, aluminum carbide （Al4C3）, was not observed in significant quantities in the nanocomposite. Compared with pure aluminum, the mechanical properties of the GNPs/Al nanocomposites containing a low volume fraction of GNPs were sharply improved. When 0.5 vol.%, 1.0 vol.%, and 2.0 vol.% GNPs were added to the aluminum matrix, the average compressive strength of GNPs/A1 nanocomposites was 297, 345, and 527 MPa, respectively, which remarkably increased the strength over the original aluminum by 330% to 586%.展开更多
Graphene nanoplatelets(GNPs)are considered to be one of the most promising new reinforcements due to their unique two-dimensional structure and remarkable mechanical properties.In addition,their impressive electrical ...Graphene nanoplatelets(GNPs)are considered to be one of the most promising new reinforcements due to their unique two-dimensional structure and remarkable mechanical properties.In addition,their impressive electrical and thermal properties make them attractive fillers for producing multifunctional ceramics with a wide range of applications.This paper reviews the current status of the research and development of graphene-reinforced ceramic matrix composite(CMC)materials.Firstly,we focused on the processing methods for effective dispersion of GNPs throughout ceramic matrices and the reduction of the porosity of CMC products.Then,the microstructure and mechanical properties are provided,together with an emphasis on the possible toughening mechanisms that may operate.Additionally,the unique functional properties endowed by GNPs,such as enhanced electrical/thermal conductivity,are discussed,with a comprehensive comparison in different ceramic matrices as oxide and nonoxide composites.Finally,the prospects and problems needed to be solved in GNPs-reinforced CMCs are discussed.展开更多
Epoxy resin is one of the most widely used thermoset polymers in high-performance composite materials for lightweight applications.However,epoxy has a high coefficient of friction,which limits its tribological applica...Epoxy resin is one of the most widely used thermoset polymers in high-performance composite materials for lightweight applications.However,epoxy has a high coefficient of friction,which limits its tribological applications.In this study,the effect was investigated of different weight fractions of solid lubricant graphene nanoplatelets(GNPs),ranging from 0 to 4.5 wt%,on mechanical and adhesive wear performance of epoxy.Adhesive wear tests covered mild and severe wear regimes.The correlation of tribological and mechanical properties was studied as well.Scanning electron microscopy(SEM)was used to observe the failure mechanisms for both tribological and mechanical samples after each test.The results revealed that the addition of GNPs to the epoxy improved its stiffness and hardness but reduced its fracture strength and toughness.Adhesive wear performance exhibited high efficiency with GNP additions and showed reductions in the specific wear rate,the coefficient of friction,and the induced interface temperature by 76%,37%,and 22%,respectively.A fatigue wear mechanism was predominant as the applied load increased.Most importantly,severe wear signs occurred when the interface temperature reached the heat distortion temperature of the epoxy.The tribological,and mechanical properties showed only a weak correlation to each other.The addition of GNPs to epoxy by less than 4.5 wt%was highly efficient to improve the wear performance while maintaining the fracture strength and toughness.Fourier transform infrared spectroscopy(FTIR)analysis shows no chemical interaction between the epoxy matrix with GNPs,which implies its physical interaction.展开更多
Herein,electrically conductive natural and synthetic yarns through electrophoretic deposition(EPD)technique were fabricated.A parametric study on the conductivity enhancement of the yarns is carried out by Taguchi met...Herein,electrically conductive natural and synthetic yarns through electrophoretic deposition(EPD)technique were fabricated.A parametric study on the conductivity enhancement of the yarns is carried out by Taguchi method.Using this method,the desirable conditions are determined by studying the effects of important parameters on the electrical conductivity of the yarns in the EPD coating process.Based on the L18 design of experiments table,the preferred combination of factors to obtain the highest electrical conductivity of the yarns is found by Taguchi analysis.In addition,the Pareto ANOVA analysis is conducted to identify the major contributing factors on the electrical conductivity of the yarns.Characterisation techniques,such as scanning electron microscopy(SEM),Fourier transformed infrared spectroscopy(FTIR)in attenuated total reflectance(ATR)mode,and thermogravimetric analysis(TGA)are utilised for better understanding the microstructure and physical properties.When powered by only 3 V,the maximum temperature of a Joule heated conductive sample based on natural fibre yarns reached 102°C in less than 25 s.展开更多
Variant graphene,graphene oxides(GO),and graphene nanoplatelets(GNP)dispersed in blood-based copper(Cu)nanoliquids over a leaning permeable cylinder are the focus of this study.These forms of graphene are highly benef...Variant graphene,graphene oxides(GO),and graphene nanoplatelets(GNP)dispersed in blood-based copper(Cu)nanoliquids over a leaning permeable cylinder are the focus of this study.These forms of graphene are highly beneficial in the biological and medical fields for cancer therapy,anti-infection measures,and drug delivery.The non-Newtonian Sutterby(blood-based)hybrid nanoliquid flows are generalized within the context of the Tiwari-Das model to simulate the effects of radiation and heating sources.The governing partial differential equations are reformulated into a nonlinear set of ordinary differential equations using similar transformational expressions.These equations are then transformed into boundary value problems through a shooting technique,followed by the implementation of the bvp4c tool in MATLAB.The influences of various parameters on the model’s nondimensional velocity and temperature profiles,reduced skin friction,and reduced Nusselt number are presented for detailed discussions.The results indicated that Cu-GNP/blood and Cu-GO/blood hybrid nanofluids exhibit the lowest and highest velocity distributions,respectively,for increased nanoparticles volume fraction,curvature parameter,Sutterby fluid parameter,Hartmann number,and wall permeability parameter.Conversely,opposite trends are observed for the temperature distribution for all considered parameters,except the mixed convection parameter.Increases in the reduced skin friction magnitude and the reduced Nusselt number with higher values of graphene/GO/GNP nanoparticle volume fraction are also reported.Finally,GNP is identified as the superior heat conductor,with an average increase of approximately 5%and a peak of 7.8%in the reduced Nusselt number compared to graphene and GO nanoparticles in the Cu/blood nanofluids.展开更多
3D printing is a valuable resource that allows flexibility in the production of objects based on a virtual file. When it is combined with nanotechnology, new features can be added to existing materials. Thus, form and...3D printing is a valuable resource that allows flexibility in the production of objects based on a virtual file. When it is combined with nanotechnology, new features can be added to existing materials. Thus, form and function can be associated to achieve a specific goal, such as the development of support structures for cell growth applicable to systems aiding tissue regeneration. Based on this rationale, the present work proposes a system composed of ABS and graphene nanoparticles solubilized in acetone to be 3D impressed using solvent casting technique. Our main goal was to develop a biocompatible and non-degradable material that fully makes use of the design versatility of 3D printing, to enable new practical employments in the future, for example in the medical field. In this study, different characterization techniques were used—such as microscopy, TGA, DSC, and others—to understand the features and properties of the material obtained, as well as the viability of its use and diffusion. Moreover, the artifacts impressed proved to be non-cytotoxic and promoted cellular adhesion to the cellular lineage of fibroblasts L929. In sum, we believe that the technology described in this article has the potential to serve as a basis for the development of future biocompatible materials that take advantage of their three-dimensional design to perform their functions.展开更多
The corrosion resistance and wear resistance of metallic biomaterials are critically important for orthopedic hard-tissue replacement applications because the lack of such properties not only adversely affects their m...The corrosion resistance and wear resistance of metallic biomaterials are critically important for orthopedic hard-tissue replacement applications because the lack of such properties not only adversely affects their mechanical integrity but also allows the release of wear debris into the human body.In this study,the potential of zirconium(Zr)as an alloying element and graphene nanoplatelets(GNPs)as a nano-reinforcement material were investigated in relation to improving the tribological performance of pure magnesium(Mg).The GNPs-reinforced Mg matrix nanocomposites(MNCs)were fabricated using powder metallurgy.Results indicate that additions of 0.5 wt.%Zr and0.1 wt.%GNPs to Mg matrices significantly improved the wear resistance by 89%and 92%at 200μN load,60%and 80%at 100μN load,and 94%and 93%at 50μN load,respectively,as compared to the wear resistance of pure Mg.The wear depth and coefficient of friction of the MNC containing 0.5 wt.%Zr and 0.1 wt.%GNPs(Mg0.5 Zr0.1 GNPs MNC)were considerably reduced as compared to pure Mg and Mg0.5 Zr.Our results demonstrate that the Mg0.5 Zr0.1 GNPs MNC is promising for orthopedic applications in relation to its excellent tribological performance.展开更多
Magnesium(Mg)-based biomaterials have gained acceptability in fracture fixation due to their ability to naturally degrade in the body after fulfilling the desired functions.However,pure Mg not only degrades rapidly in...Magnesium(Mg)-based biomaterials have gained acceptability in fracture fixation due to their ability to naturally degrade in the body after fulfilling the desired functions.However,pure Mg not only degrades rapidly in the physiological environment,but also evolves hydrogen gas during degradation.In this study,Mg0.5Zr and Mg0.5ZrxZn(x=1–5 wt.%)matrix nanocomposites(MNCs)reinforced with different contents(0.1–0.5 wt.%)of graphene nanoplatelets(GNP)were manufactured via a powder metallurgy technique and their mechanical and corrosion properties were evaluated.The increase in GNP concentration from 0.2 wt.%to 0.5 wt.%added to Mg0.5Zr matrices resulted in decreases in the compressive yield strength and corrosion resistance in Hanks’Balanced Salt Solution(HBSS).On the other hand,a higher concentration(4–5 wt.%)of Zn added to Mg0.5Zr0.1GNP resulted in an increase in ductility but a decrease in compressive yield strength.Overall,an addition of 0.1 wt.%GNPs to Mg0.5Zr3Zn matrices gave excellent ultimate compressive strength(387 MPa)and compressive yield strength(219 MPa).Mg0.5Zr1Zn0.1GNP and Mg0.5Zr3Zn0.1GNP nanocomposites exhibited 29%and 34%higher experimental yield strength,respectively,as compared to the theoretical yield strength of Mg0.5Zr0.1GNP calculated by synergistic strengthening mechanisms including the difference in thermal expansion,elastic modulus,and geometry of the particles,grain refinement,load transfer,and precipitation of GNPs in the Mg matrices.The corrosion rates of Mg0.5Zr1Zn0.1GNP,Mg0.5Zr3Zn0.1GNP,Mg0.5Zr4Zn0.1GNP,and Mg0.5Zr5Zn0.1GNP measured using potentiodynamic polarization were 7.5 mm/y,4.1 mm/y,6.1 mm/y,and 8.0 mm/y,respectively.Similarly,hydrogen gas evolution tests also demonstrated that Mg0.5Zr3Zn0.1GNP exhibited a lower corrosion rate(1.5 mm/y)than those of Mg0.5Zr1Zn0.1GNP(3.8 mm/y),Mg0.5Zr4Zn0.1GNP(1.9 mm/y),and Mg0.5Zr5Zn0.1GNP(2.2 mm/y).This study demonstrates the potential of GNPs as effective nano-reinforcement particulates for improving the mechanical and corrosion properties of Mg–Zr–Zn matrices.展开更多
In an effort to expand the insulating behavior of adhesives, incorporated nano-sized fillers, such as multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs), are usually selected. Including both MWCN...In an effort to expand the insulating behavior of adhesives, incorporated nano-sized fillers, such as multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs), are usually selected. Including both MWCNTs and GNPs into polymers is assumed to have complementary influence (synergy), providing a new research area. Nevertheless, limited studies have been carried out towards this hybrid direction, as it is challenging to achieve a uniform distribution of both fillers into the polymer matrix. In this work, the addition of MWCNTs and GNPs into the epoxy adhesives has been studied to increase their thermal and electrical conductivity without diminishing their mechanical properties. Three types of nano-reinforced adhesives were developed by using: 1) 2%wt. MWCNTs, 2) 8%wt. GNPs and 3) 1%wt. MWCNTs and 8%wt. GNPs. The production of nano-reinforced adhesives was achieved by using a three-roll milling technique, while during the experimental characterization single lap shear tests, thermal and electrical conductivity measurements were performed. According to the results, the introduction of nano-particles caused significant increases in electrical and thermal conductivity. MWCNTs in content of 2%wt. showed the highest improvement in the electrical conductivity (9 orders of magnitude), while GNPs in content of 8%wt. recorded the highest increase (207%) in the thermal conductivity of nano-reinforced adhesives. Finally, it was observed that the hybrid system successfully contributed to the development of a multi-functional epoxy adhesive with improved thermal and electrical properties without significantly compromising its mechanical properties.展开更多
The aim of this study is to investigate the dynamic response of axially moving two-layer laminated plates on the Winkler and Pasternak foundations. The upper and lower layers are formed from a bidirectional functional...The aim of this study is to investigate the dynamic response of axially moving two-layer laminated plates on the Winkler and Pasternak foundations. The upper and lower layers are formed from a bidirectional functionally graded(FG) layer and a graphene platelet(GPL) reinforced porous layer, respectively. Henceforth, the combined layers will be referred to as a two-dimensional(2D) FG/GPL plate. Two types of porosity and three graphene dispersion patterns, each of which is distributed through the plate thickness,are investigated. The mechanical properties of the closed-cell layers are used to define the variation of Poisson’s ratio and the relationship between the porosity coefficients and the mass density. For the GPL reinforced layer, the effective Young’s modulus is derived with the Halpin-Tsai micro-system model, and the rule of mixtures is used to calculate the effective mass density and Poisson’s ratio. The material of the upper 2D-FG layer is graded in two directions, and its effective mechanical properties are also derived with the rule of mixtures. The dynamic governing equations are derived with a first-order shear deformation theory(FSDT) and the von Kármán nonlinear theory. A combination of the dynamic relaxation(DR) and Newmark’s direct integration methods is used to solve the governing equations in both time and space. A parametric study is carried out to explore the effects of the porosity coefficients, porosity and GPL distributions, material gradients, damping ratios, boundary conditions, and elastic foundation stiffnesses on the plate response. It is shown that both the distributions of the porosity and graphene nanofillers significantly affect the dynamic behaviors of the plates. It is also shown that the reduction in the dynamic deflection of the bilayer composite plates is maximized when the porosity and GPL distributions are symmetric.展开更多
基金The present work was supported by the National Natural Science Funds of China(No.50725413)the Ministry of Science and Technology of China(MOST)(No.2010DFR50010 and 2011FU125Z07)Chongqing Science and Technology Commission(CSTC2013jcyjC60001).
文摘Effect of graphene nanoplatelets(GNPs)addition on mechanical properties of magnesium–10wt%Titanium(Mg–10Ti)alloy is investigated in current work.The Mg-(10Ti+0.18GNPs)composite was synthesized using the semi powder metallurgy method followed by hot extrusion.Microstructural characterization results revealed the uniform distribution of reinforcement(Ti+GNPs)particles in the matrix,therefore(Ti+GNPs)particles act as an effective reinforcing filler to prevent the deformation.Room temperature tensile results showed that the addition of Ti+GNPs to monolithic Mg lead to increase in 0.2%yield strength(0.2%YS),ultimate tensile strength(UTS),and failure strain.Scanning Electron Microscopy(SEM),Energy-Dispersive X-ray Spectroscopy(EDS)and X-Ray Diffraction(XRD)were used to investigate the surface morphology,elemental dispersion and phase analysis,respectively.
基金This work was financially supported by the Program for New Century Excellent Talents in University(No.NCET-11-0951).
文摘A 0.3wt%graphene nanoplatelets(GNPs)reinforced 7075 aluminum alloy matrix(7075 Al)composite was fabricated by spark plasma sintering and its strength and wear resistance were investigated.The microstructures of the internal structure,the friction surface,and the wear debris were characterized by scanning electron microscopy,X-ray diffraction,and Raman spectroscopy.Compared with the original 7075 aluminum alloy,the hardness and elastic modulus of the 7075 Al/GNPs composite were found to have increased by 29%and 36%,respectively.The results of tribological experiments indicated that the composite also exhibited a lower wear rate than the original 7075 aluminum alloy.
基金the Link Project of the National Natural Science Foundation of China and Guangdong Province(Grant no.U1301244)the National Natural Science Foundation of China(Grant nos.51573215,21506260)+2 种基金Guangdong Province Science&Technology Foundation(2011B050300008)Guangdong Natural Science Foundation(Grant nos.2014A030313159,2016A030313354)Guangzhou Scientific and Technological Planning Project(2014J4500002,201607010042)for financial support of this work
文摘Lithium–sulfur batteries have great potential for high energy applications due to their high capacities,low cost and eco-friendliness. However, the particularly rapid capacity decay owing to the dissolution and diffusion of polysulfide intermediate into the electrolyte still hamper their practical applications.And the reported preparation procedures to sulfur based cathode materials are often complex, and hence are rather difficult to produce at large scale. Here, we report a simple mechano-chemical sulfurization methodology in vacuum environment applying ball-milling method combined both the chemical and physical interaction for the one-pot synthesis of edge-sulfurized grapheme nanoplatelets with 3D porous foam structure as cathode materials. The optimal sample of 70%S–Gn Ps-48 h(ball-milled 48 h) obtains 13.2 wt% sulfur that chemically bonded onto the edge of Gn Ps. And the assembled batteries exhibit high initial discharge capacities of 1089 mAh/g at 0.1 C and 950 mAh/g at 0.5 C, and retain a stable discharge capacity of 776 mAh/g after 250 cycles at 0.5 C with a high Coulombic efficiency of over 98%. The excellent performance is mainly attributed to the mechano-chemical interaction between sulfur and grapheme nanoplatelets. This definitely triggers the currently extensive research in lithium–sulfur battery area.
基金financially supported by the National natural Science Foundation of China (Grant No.51761028)。
文摘A powder thixoforging route combined with slurry based mixing process was proposed to fabricate graphene nanoplatelets(GNPs) reinforced magnesium matrix composites(MgMCs). The originally spherical and ball-milled ZK60 powders were used as matrices, respectively.The mixing of 0.05 wt.% GNPs with the spherical powder led to GNPs clusters and degraded the mechanical properties of the composite.In contrast, with the addition of an optimal content(0.1 wt.%) of GNPs, the composite fabricated from ball-milled powder achieved a joint enhancement in tensile yield strength(52%) and fracture toughness(19%), demonstrating a pronounced strengthening efficiency of 650% and a good balance between strength and toughness. The ball-milled powder endowed the composite with a homogenous distribution of GNPs and a denser microstructure with reduced Mg-Zn eutectics, and the thixoforging process offered a well-bonded Mg/GNP interface, making full use of the strengthening and toughening potential of GNPs. Theoretical predication based on a modified shear-lag model suggested that load transfer dominated the strengthening mechanisms. In-situ tensile tests verified that crack deflection, secondary cracks and GNPs bridging mainly accounted for the toughening mechanisms. A numerical model with consideration of GNPs orientations was also established to understand the toughening effect from GNPs bridging.
基金Funded by the National Natural Science Foundation of China(No.51473104)
文摘Epoxy/graphene nanoplatelets（GNPs） powder coatings were fabricated using ultrasonic predispersion of GNPs and melt-blend extrusion method. The isothermal curing kinetics of epoxy/GNPs powder coating were monitored by means of real-time Fourier transform infrared spectroscopy（FT-IR） with a heating cell. The mechanical properties of the epoxy/GNPs cured coatings had been investigated, by evaluating their fracture surfaces with field-emission scanning electron microscopy（FE-SEM） after three-point-bending tests. The thermal stability of the epoxy/GNPs cured coatings was studied by thermo-gravimetric analysis（TGA）. The isothermal curing kinetics result showed that the GNPs would not affect the autocatalytic reaction mechanism, but the loading of GNPs below 1.0 wt % additive played a prompting role in the curing of the epoxy/GNPs powder coatings. The fracture strain, fracture toughness and impact resistance of the epoxy/GNPs cured coatings increased dramatically at low levels of GNPs loading（1 wt %）, indicating that the GNPs could improve the toughness of the epoxy/GNPs powder coatings. Furthermore, from FE-SEM studies of the fracture surfaces, the possible toughening mechanisms of the epoxy/GNPs cured coatings were proposed. TGA result showed that the incorporation of GNPs improved the thermal stability of the cured coatings. Hence, the GNPs modified epoxy can be an efficient approach to toughen epoxy powder coating along with improving their thermal stability.
基金financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior-Brasil(CAPES)-Finance Code 001.
文摘In aiming to obtain fibers with enhanced thermal and mechanical properties,graphene based textile fibers with 144 filaments were developed using an approach in which the PP/GnP(polypropylene/graphene nanoplatelets)nanocomposite was employed as conductive material in a fiber with circular cross-section geometry.The kinetics of thermal degradation was evaluated by the Broido method using thermogravimetric analysis(TGA).Activation energy was enhanced from 260.6 kJ·mol^-1 to 337.4 kJ·mol^-1 compared to the neat PP.GnP increased the thermal stability of the PP,slowing its degradation by thermal depolymerization.Furthermore,the degree of crystallization declined as the GnP content increased,reducing the tenacity of the yarn,but improving its elastic modulus from 91.9 to 95.9 cN/tex,being a promising alternative to produce smart textiles.In conclusion,it has been confirmed that GnP loading up to 1%(w/w)can be incorporated into polypropylene by melt spinning and that the resulting nanocomposite fibers are suitable for several applications in the textile industry.
基金the Puncak RM for the project under the grant 6733204-13069 to carry out the experiments。
文摘Graphene nanoplatelets(GNPs)have attracted tremendous interest due to their unique properties and bonding capabilities.This study focuses on the effect of GNP dispersion on the mechanical,thermal,and morphological behavior of GNP/epoxy nanocomposites.This study aims to understand how the dispersion of GNPs affects the properties of epoxy nanocomposite and to identify the best dispersion approach for improving mechanical performance.A solvent mixing technique that includes mechanical stirring and ultrasonication was used for producing the nanocomposites.Fourier transform infrared spectroscopy was used to investigate the interaction between GNPs and the epoxy matrix.The measurements of density and moisture content were used to confirm that GNPs were successfully incorporated into the nanocomposite.The findings showed that GNPs are successfully dispersed in the epoxy matrix by combining mechanical stirring and ultrasonication in a single step,producing well-dispersed nanocomposites with improved mechanical properties.Particularly,the nanocomposites at a low GNP loading of 0.1 wt%,demonstrate superior mechanical strength,as shown by increased tensile properties,including improved Young's modulus(1.86 GPa),strength(57.31 MPa),and elongation at break(4.98).The nanocomposite with 0.25 wt%GNP loading performs better,according to the viscoelastic analysis and flexural properties(113.18 MPa).Except for the nanocomposite with a 0.5 wt%GNP loading,which has a higher thermal breakdown temperature,the thermal characteristics do not significantly alter.The effective dispersion of GNPs in the epoxy matrix and low agglomeration is confirmed by the morphological characterization.The findings help with filler selection and identifying the best dispersion approach,which improves mechanical performance.The effective integration of GNPs and their interaction with the epoxy matrix provides the doorway for additional investigation and the development of sophisticated nanocomposites.In fields like aerospace,automotive,and electronics where higher mechanical performance and functionality are required,GNPs'improved mechanical properties and successful dispersion present exciting potential.
文摘Thermal energy storage(TES) systems use solar energy despite its irregular availability and day-night temperature difference.Current work reports the thermal characterizations of solar salt-based phase change composites in the presence of graphene nanoplatelets(GNP).Solar salt(60:40 of NaNO_(3):KNO_(3)) possessing phase transition temperature and melting enthalpy of 221.01℃ and 134.58 kJ/kg is proposed as a phase change material(PCM) for high-temperature solar-based energy storage applications.Thermal conductivity must be improved to make them suitable for widespread applications and to close the gap between the system needs where they are employed.GNP is added at weight concentrations of 0.1%,0.3%,and 0.5% with solar salt using the ball milling method to boost its thermal conductivity.Morphological studies indicated the formation of a uniform surface of GNP on solar salt.FTIR spectrum peaks identified the physical interaction between salt and GNP.Thermal characterization of the composites,such as thermal conductivity,DSC and TGA was carried out for the samples earlier and later 300 thermal cycles.0.5% of GNP has improved the thermal conductivity of salt by 129.67% and after thermal cycling,the enhancement reduced to 125.21% indicating that thermal cycling has a minor impact on thermal conductivity.Phase change temperature decreased by around 2.32% in the presence of0.5% GNP and the latent heat reduced by 4.34% after thermal cycling.TGA thermograms depicted the composites initiated the weight loss at around 550℃ after which it was rapid.After thermal cycling,the weight loss initiated at ~40℃ lower compared to pure salt,which was found to be a minor change.Thermal characterization of solar salt and GNP-based solar salt composites revealed that the composites can be used for enhanced heat transfer in high-temperature solar-based heat transfer and energy storage applications.
基金supported by the National Natural Science Foundation of China(No.51761028)the Natural Science Foundation of Gansu Province,China(No.21JR7RA232).
文摘Magnesium matrix composites(MgMCs)have always suffered low strengthening efficiency and poor ductility due to the difficulties in pursuing the well-bonded interface.Herein,graphene nanoplatelets(GNPs)were decorated with magnesium oxide nanoparticles(MgO NPs)through chemical co-precipitation and then incorporated into AZ91 alloy to fabricate MgMCs via powder thixoforging.The effect of MgO on the interface of the Mg/graphene system was investigated based on the first-principles calculations,and the result indicated that modifying GNPs with MgO NPs was helpful in improving the Mg-GNP interface bonding.The interface structural analysis revealed that the MgO NPs were firmly bonded with both GNPs andα-Mg through the distortion area bonding and semi-coherent interfacial bonding,severing as a bridge to fasten the interface bonding of composites.In addition,the MgO NPs on GNPs acted as a barrier to prevent GNPs from seriously reacting with the AZ91 alloy.As a result,the AZ91/MgO@GNPs composite was endowed with enhancements of 31%and 10%in the yield strength,and increments of 71%and 61%in elongation compared with the AZ91 alloy and AZ91/GNPs composite,respectively,exhibiting a more significant potential in optimizing the strength-toughness tradeoffcompared with the AZ91/GNPs.Moreover,the possible strengthening and toughening mechanisms were also discussed in detail.This work offers a relatively novel surface modification strategy to modulate the Mg-GNP interface for a simultane-ous improvement of strength and ductility.
文摘Insufficient hole cleaning,cutting suspension,clay swelling,and filtrate invasion of the formation might result from inadequate drilling mud properties.For effective drilling and wellbore stability,water-based mud(WBM)rheology,lubricity,filtration,and shale inhibition must be optimized and controlled.WBMs react with clays and cause time-dependent borehole issues,which is their principal drawback.Moreover,prolonged exposure destroys certain WBM components,resulting in minimal mud properties.These indicate the need for multifunctional additives to improve WBMs.Thus,this study developed WBM systems employing graphene nanoplatelets(GNPs)and locally acquired discarded coconut shells to overcome severe drilling challenges.By adding triton-X100 to coconut shell-based graphene(GN-CS),a greater dispersion of modified graphene(GN-TX)particles was produced.Characterization,rheology,lubricity,inhibition,and filtration tests were performed on these GN-CS and GN-TX at concentrations of 0.125,0.25,0.375,and 0.50 wt%.Furthermore,biotoxicity,biodegradability,and heavy metal content experiments were performed to study the environmental impact of GN-CS and GN-TX.The results showed that GN-TX had good thermal resistance up to 300℃ with only a 10%loss in weight.Both EDX and FTIR tests showed that the epoxy,carboxyl,and hydroxyl groups are in the GNP-based materials'basal plane.The GN-CS and GN-TX had better fluid properties,including better lubricity,rheology,filtration,and inhibition over the base mud,and the optimal rheological model of the drilling muds was the Herschel Buckley model.The GN-TX(modified)decreased the fluid loss to 20.6e14.3 mL from 24.6 mL at 353 K,whereas the GN-CS(unmodified)reduced it to 21.3e16.7 mL.GN-TX and GN-CS decreased the coefficient of friction of WBM from 0.47 to 0.55 to 0.25e0.41 and 0.33e0.44,respec-tively,from 298 to 353 K.In addition,0.50 wt%of GN-CS and GN-TX reduced the shale pellet swelling height to 5.4%and 5.6%,respectively,from 8.8%.Moreover,the EC 50 values for GN-CS and GN-TX were about 54,000 mg/L and the BOD/COD ratio was about 47%.These results show that the GNP-based products are safe and biodegradable.The GNP-based materials have promising prospects for drilling in environmentally sensitive formations.
基金This project was supported by the National Natural Science Foundation of China （NSFC） （Nos. 51562027 and 11372100）, and Jiangsu Key Laboratory of Precision and Micro-Manufacturing Technology.
文摘Graphene nanoplatelets/aluminum （GNPs/Al） nanocomposites were fabricated using a novel two-step method. High resolution transmission electron microscope （HRTEM）, Raman, field emission scanning electron microscopy （FESEM）, X-ray diffraction （XRD）, energy dispersive X-ray spectroscopy （EDS）, EDS mapping, and mechanical testing system （MTS） were applied to characterize the microstructure and mechanical properties of the GNPs/Al nanocomposites. The GNPs were homogeneously dispersed in GNPs/Al nanocomposites, and presented a fine interface behavior and microstructure characteristics. A harmful phase, aluminum carbide （Al4C3）, was not observed in significant quantities in the nanocomposite. Compared with pure aluminum, the mechanical properties of the GNPs/Al nanocomposites containing a low volume fraction of GNPs were sharply improved. When 0.5 vol.%, 1.0 vol.%, and 2.0 vol.% GNPs were added to the aluminum matrix, the average compressive strength of GNPs/A1 nanocomposites was 297, 345, and 527 MPa, respectively, which remarkably increased the strength over the original aluminum by 330% to 586%.
基金financially supported by the National Natural Science Foundation of China(Nos.51432004 and 51672041)the Fundamental Research Funds for the Central Universities(No.2232018G-07)+2 种基金the Innovation Program of Shanghai Municipal Education Commission(No.2017-01-07-00-03-E00025)the Program for Innovative Research Team in University of Ministry of Education of China(No.IRT_16R13)Shanghai Sailing Program(No.17YF1400400)。
文摘Graphene nanoplatelets(GNPs)are considered to be one of the most promising new reinforcements due to their unique two-dimensional structure and remarkable mechanical properties.In addition,their impressive electrical and thermal properties make them attractive fillers for producing multifunctional ceramics with a wide range of applications.This paper reviews the current status of the research and development of graphene-reinforced ceramic matrix composite(CMC)materials.Firstly,we focused on the processing methods for effective dispersion of GNPs throughout ceramic matrices and the reduction of the porosity of CMC products.Then,the microstructure and mechanical properties are provided,together with an emphasis on the possible toughening mechanisms that may operate.Additionally,the unique functional properties endowed by GNPs,such as enhanced electrical/thermal conductivity,are discussed,with a comprehensive comparison in different ceramic matrices as oxide and nonoxide composites.Finally,the prospects and problems needed to be solved in GNPs-reinforced CMCs are discussed.
文摘Epoxy resin is one of the most widely used thermoset polymers in high-performance composite materials for lightweight applications.However,epoxy has a high coefficient of friction,which limits its tribological applications.In this study,the effect was investigated of different weight fractions of solid lubricant graphene nanoplatelets(GNPs),ranging from 0 to 4.5 wt%,on mechanical and adhesive wear performance of epoxy.Adhesive wear tests covered mild and severe wear regimes.The correlation of tribological and mechanical properties was studied as well.Scanning electron microscopy(SEM)was used to observe the failure mechanisms for both tribological and mechanical samples after each test.The results revealed that the addition of GNPs to the epoxy improved its stiffness and hardness but reduced its fracture strength and toughness.Adhesive wear performance exhibited high efficiency with GNP additions and showed reductions in the specific wear rate,the coefficient of friction,and the induced interface temperature by 76%,37%,and 22%,respectively.A fatigue wear mechanism was predominant as the applied load increased.Most importantly,severe wear signs occurred when the interface temperature reached the heat distortion temperature of the epoxy.The tribological,and mechanical properties showed only a weak correlation to each other.The addition of GNPs to epoxy by less than 4.5 wt%was highly efficient to improve the wear performance while maintaining the fracture strength and toughness.Fourier transform infrared spectroscopy(FTIR)analysis shows no chemical interaction between the epoxy matrix with GNPs,which implies its physical interaction.
基金This work was supported by the Ministry of Business,Innovation&Employment Grant,New Zealand[UOAX1415]。
文摘Herein,electrically conductive natural and synthetic yarns through electrophoretic deposition(EPD)technique were fabricated.A parametric study on the conductivity enhancement of the yarns is carried out by Taguchi method.Using this method,the desirable conditions are determined by studying the effects of important parameters on the electrical conductivity of the yarns in the EPD coating process.Based on the L18 design of experiments table,the preferred combination of factors to obtain the highest electrical conductivity of the yarns is found by Taguchi analysis.In addition,the Pareto ANOVA analysis is conducted to identify the major contributing factors on the electrical conductivity of the yarns.Characterisation techniques,such as scanning electron microscopy(SEM),Fourier transformed infrared spectroscopy(FTIR)in attenuated total reflectance(ATR)mode,and thermogravimetric analysis(TGA)are utilised for better understanding the microstructure and physical properties.When powered by only 3 V,the maximum temperature of a Joule heated conductive sample based on natural fibre yarns reached 102°C in less than 25 s.
基金funded by the Ministry of Higher Education,Malaysia,through the Research Fund of Fundamental Research Grant Scheme (FRGS/1/2020/STG06/UM/02/1:FP009-2020).
文摘Variant graphene,graphene oxides(GO),and graphene nanoplatelets(GNP)dispersed in blood-based copper(Cu)nanoliquids over a leaning permeable cylinder are the focus of this study.These forms of graphene are highly beneficial in the biological and medical fields for cancer therapy,anti-infection measures,and drug delivery.The non-Newtonian Sutterby(blood-based)hybrid nanoliquid flows are generalized within the context of the Tiwari-Das model to simulate the effects of radiation and heating sources.The governing partial differential equations are reformulated into a nonlinear set of ordinary differential equations using similar transformational expressions.These equations are then transformed into boundary value problems through a shooting technique,followed by the implementation of the bvp4c tool in MATLAB.The influences of various parameters on the model’s nondimensional velocity and temperature profiles,reduced skin friction,and reduced Nusselt number are presented for detailed discussions.The results indicated that Cu-GNP/blood and Cu-GO/blood hybrid nanofluids exhibit the lowest and highest velocity distributions,respectively,for increased nanoparticles volume fraction,curvature parameter,Sutterby fluid parameter,Hartmann number,and wall permeability parameter.Conversely,opposite trends are observed for the temperature distribution for all considered parameters,except the mixed convection parameter.Increases in the reduced skin friction magnitude and the reduced Nusselt number with higher values of graphene/GO/GNP nanoparticle volume fraction are also reported.Finally,GNP is identified as the superior heat conductor,with an average increase of approximately 5%and a peak of 7.8%in the reduced Nusselt number compared to graphene and GO nanoparticles in the Cu/blood nanofluids.
文摘3D printing is a valuable resource that allows flexibility in the production of objects based on a virtual file. When it is combined with nanotechnology, new features can be added to existing materials. Thus, form and function can be associated to achieve a specific goal, such as the development of support structures for cell growth applicable to systems aiding tissue regeneration. Based on this rationale, the present work proposes a system composed of ABS and graphene nanoparticles solubilized in acetone to be 3D impressed using solvent casting technique. Our main goal was to develop a biocompatible and non-degradable material that fully makes use of the design versatility of 3D printing, to enable new practical employments in the future, for example in the medical field. In this study, different characterization techniques were used—such as microscopy, TGA, DSC, and others—to understand the features and properties of the material obtained, as well as the viability of its use and diffusion. Moreover, the artifacts impressed proved to be non-cytotoxic and promoted cellular adhesion to the cellular lineage of fibroblasts L929. In sum, we believe that the technology described in this article has the potential to serve as a basis for the development of future biocompatible materials that take advantage of their three-dimensional design to perform their functions.
基金financial support for this research by the Australian Research Council(ARC)through the Future Fellowship(FT160100252)the Discovery Project(DP170102557)。
文摘The corrosion resistance and wear resistance of metallic biomaterials are critically important for orthopedic hard-tissue replacement applications because the lack of such properties not only adversely affects their mechanical integrity but also allows the release of wear debris into the human body.In this study,the potential of zirconium(Zr)as an alloying element and graphene nanoplatelets(GNPs)as a nano-reinforcement material were investigated in relation to improving the tribological performance of pure magnesium(Mg).The GNPs-reinforced Mg matrix nanocomposites(MNCs)were fabricated using powder metallurgy.Results indicate that additions of 0.5 wt.%Zr and0.1 wt.%GNPs to Mg matrices significantly improved the wear resistance by 89%and 92%at 200μN load,60%and 80%at 100μN load,and 94%and 93%at 50μN load,respectively,as compared to the wear resistance of pure Mg.The wear depth and coefficient of friction of the MNC containing 0.5 wt.%Zr and 0.1 wt.%GNPs(Mg0.5 Zr0.1 GNPs MNC)were considerably reduced as compared to pure Mg and Mg0.5 Zr.Our results demonstrate that the Mg0.5 Zr0.1 GNPs MNC is promising for orthopedic applications in relation to its excellent tribological performance.
基金the Australian Research Council(ARC)through the Future Fellowship(FT160100252)the Discovery Project(DP170102557).
文摘Magnesium(Mg)-based biomaterials have gained acceptability in fracture fixation due to their ability to naturally degrade in the body after fulfilling the desired functions.However,pure Mg not only degrades rapidly in the physiological environment,but also evolves hydrogen gas during degradation.In this study,Mg0.5Zr and Mg0.5ZrxZn(x=1–5 wt.%)matrix nanocomposites(MNCs)reinforced with different contents(0.1–0.5 wt.%)of graphene nanoplatelets(GNP)were manufactured via a powder metallurgy technique and their mechanical and corrosion properties were evaluated.The increase in GNP concentration from 0.2 wt.%to 0.5 wt.%added to Mg0.5Zr matrices resulted in decreases in the compressive yield strength and corrosion resistance in Hanks’Balanced Salt Solution(HBSS).On the other hand,a higher concentration(4–5 wt.%)of Zn added to Mg0.5Zr0.1GNP resulted in an increase in ductility but a decrease in compressive yield strength.Overall,an addition of 0.1 wt.%GNPs to Mg0.5Zr3Zn matrices gave excellent ultimate compressive strength(387 MPa)and compressive yield strength(219 MPa).Mg0.5Zr1Zn0.1GNP and Mg0.5Zr3Zn0.1GNP nanocomposites exhibited 29%and 34%higher experimental yield strength,respectively,as compared to the theoretical yield strength of Mg0.5Zr0.1GNP calculated by synergistic strengthening mechanisms including the difference in thermal expansion,elastic modulus,and geometry of the particles,grain refinement,load transfer,and precipitation of GNPs in the Mg matrices.The corrosion rates of Mg0.5Zr1Zn0.1GNP,Mg0.5Zr3Zn0.1GNP,Mg0.5Zr4Zn0.1GNP,and Mg0.5Zr5Zn0.1GNP measured using potentiodynamic polarization were 7.5 mm/y,4.1 mm/y,6.1 mm/y,and 8.0 mm/y,respectively.Similarly,hydrogen gas evolution tests also demonstrated that Mg0.5Zr3Zn0.1GNP exhibited a lower corrosion rate(1.5 mm/y)than those of Mg0.5Zr1Zn0.1GNP(3.8 mm/y),Mg0.5Zr4Zn0.1GNP(1.9 mm/y),and Mg0.5Zr5Zn0.1GNP(2.2 mm/y).This study demonstrates the potential of GNPs as effective nano-reinforcement particulates for improving the mechanical and corrosion properties of Mg–Zr–Zn matrices.
文摘In an effort to expand the insulating behavior of adhesives, incorporated nano-sized fillers, such as multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs), are usually selected. Including both MWCNTs and GNPs into polymers is assumed to have complementary influence (synergy), providing a new research area. Nevertheless, limited studies have been carried out towards this hybrid direction, as it is challenging to achieve a uniform distribution of both fillers into the polymer matrix. In this work, the addition of MWCNTs and GNPs into the epoxy adhesives has been studied to increase their thermal and electrical conductivity without diminishing their mechanical properties. Three types of nano-reinforced adhesives were developed by using: 1) 2%wt. MWCNTs, 2) 8%wt. GNPs and 3) 1%wt. MWCNTs and 8%wt. GNPs. The production of nano-reinforced adhesives was achieved by using a three-roll milling technique, while during the experimental characterization single lap shear tests, thermal and electrical conductivity measurements were performed. According to the results, the introduction of nano-particles caused significant increases in electrical and thermal conductivity. MWCNTs in content of 2%wt. showed the highest improvement in the electrical conductivity (9 orders of magnitude), while GNPs in content of 8%wt. recorded the highest increase (207%) in the thermal conductivity of nano-reinforced adhesives. Finally, it was observed that the hybrid system successfully contributed to the development of a multi-functional epoxy adhesive with improved thermal and electrical properties without significantly compromising its mechanical properties.
文摘The aim of this study is to investigate the dynamic response of axially moving two-layer laminated plates on the Winkler and Pasternak foundations. The upper and lower layers are formed from a bidirectional functionally graded(FG) layer and a graphene platelet(GPL) reinforced porous layer, respectively. Henceforth, the combined layers will be referred to as a two-dimensional(2D) FG/GPL plate. Two types of porosity and three graphene dispersion patterns, each of which is distributed through the plate thickness,are investigated. The mechanical properties of the closed-cell layers are used to define the variation of Poisson’s ratio and the relationship between the porosity coefficients and the mass density. For the GPL reinforced layer, the effective Young’s modulus is derived with the Halpin-Tsai micro-system model, and the rule of mixtures is used to calculate the effective mass density and Poisson’s ratio. The material of the upper 2D-FG layer is graded in two directions, and its effective mechanical properties are also derived with the rule of mixtures. The dynamic governing equations are derived with a first-order shear deformation theory(FSDT) and the von Kármán nonlinear theory. A combination of the dynamic relaxation(DR) and Newmark’s direct integration methods is used to solve the governing equations in both time and space. A parametric study is carried out to explore the effects of the porosity coefficients, porosity and GPL distributions, material gradients, damping ratios, boundary conditions, and elastic foundation stiffnesses on the plate response. It is shown that both the distributions of the porosity and graphene nanofillers significantly affect the dynamic behaviors of the plates. It is also shown that the reduction in the dynamic deflection of the bilayer composite plates is maximized when the porosity and GPL distributions are symmetric.
