Nitric oxide（NO）,a bioactive signaling molecule,serves as an antioxidant and anti-stress agent under abiotic stress.A hydroponics experiment was conducted to investigate the effects of sodium nitroprusside（SNP）,a ...Nitric oxide（NO）,a bioactive signaling molecule,serves as an antioxidant and anti-stress agent under abiotic stress.A hydroponics experiment was conducted to investigate the effects of sodium nitroprusside（SNP）,a NO donor,on tomato seedlings exposed to 50 μmol L-1CuCl 2.The results show that copper is primarily stored in the soluble cell sap fraction in the roots,especially after treatment with Cu＋SNP treatment,which accounted for 66.2% of the total copper content.The copper concentration gradually decreased from the roots to the leaves.In the leaves,exogenous NO induces the storage of excess copper in the cell walls.Copper stress decreases the proportion of copper integrated with pectates and proteins,but exogenous NO remarkably reverses this trend.The alleviating effect of NO is blocked by hemoglobin.Thus,exogenous NO is likely involved in the regulation of the subcellular copper concentrations and its chemical forms under copper stress.Although exogenous NO inhibited the absorption and transport of excess copper to some extent,the copper accumulation in tomato seedlings significantly increased under copper stress.The use of exogenous NO to enhance copper tolerance in some plants is a promising method for copper remediation.展开更多
Shizishan ore-field is a nonferrous and noble metal ore-field which is most rich in copper and gold.There are many types of fluid inclusions in minerals of the deposits.The homogeneous temperatures and the salinities ...Shizishan ore-field is a nonferrous and noble metal ore-field which is most rich in copper and gold.There are many types of fluid inclusions in minerals of the deposits.The homogeneous temperatures and the salinities of the fluid inclusions in main mineralization stages have wide ranges,while the different types of the fluid inclusions existed together and their homogeneous temperatures are almost identical in the same mineralization stage,which indicates that the ore-forming process has great relation with the fluid boiling.The gas and liquid chemical compositions and the carbon,hydrogen and oxygen isotopic compositions of the fluid inclusions show that the ore-forming fluids of copper-gold deposits have the same characteristics and evolution tendency,which reflects that the ore-forming material mainly came from the magmatism.The stratigraphic component and the meteoric water may mix in ore- forming fluids in the later mineralization stages.Furthermore,with the fall of the ore-forming temperature the ratios of water and rock decreased.The characteristics of chemical composition and carbon isotopic composition of fluid inclusions indicate that CH4 may play an important role for separating copper and gold in the ore-forming process.展开更多
The continuous extrusion forming process for producing large section copper concave bus bar under different extrusion wheel angular velocities was studied by three-dimensional finite element technology based on softwa...The continuous extrusion forming process for producing large section copper concave bus bar under different extrusion wheel angular velocities was studied by three-dimensional finite element technology based on software DEFORM-3D. The rigid-viscoplastic constitutive equation was employed in the model. The numerical simulation results show that the deformation body flow velocity in the die orifice increases gradually with the increase of the extrusion wheel angular velocity. But slippage between the rod and extrusion wheel occurs when the extrusion wheel angular velocity is high. The effective stress near the die orifice enhances gradually with increasing extrusion wheel angular velocity. High stress is concentrated in adjacent regions of the flash gap. The effective strain gradient is greater near the abutment than that near the die orifice. The effective strain of the product increases gradually with increasing extrusion wheel angular velocity. In the deformation process, the deformation body temperature increases remarkably due to friction and deformation. So the cooling is necessary in the region of the die and tools.展开更多
Petrography, microthermometry, and scanning electron microscope/energy dispersive spectrometer （SEM/EDS） studies were performed on the fluid inclusions in the ore-beating quartz veins and quartz phenocrysts in the p...Petrography, microthermometry, and scanning electron microscope/energy dispersive spectrometer （SEM/EDS） studies were performed on the fluid inclusions in the ore-beating quartz veins and quartz phenocrysts in the porphyry of the Chongjiang porphyry copper deposit. The analyses of the fluid inclusions indicate that the ore-forming fluids were exsolved from magma. They are near-saturated, supercritical, rich in volatile constituents, and have the capture temperature of 362-389℃ and salinities of 17.7wt%- 18.9wt% NaC1 eq. With the decreasing of temperature and pressure, the supercritical fluids were separated into a low salinity vapor phase and a high salinity liquid phase. During quartz-sericitization, the high salinity fluid boiled and separated into a low salinity vapor phase and a high salinity liquid phase. The high salinity inclusions that formed in the boiling process had daughter mineral melting temperatures higher than the homogenization temperatures of the vapor and liquid phases. The late fluids that are responsible for argillization are of lower temperature and salinity.展开更多
Using forming-knitting technology and organic materials, copper foam with high porosity (>80%) and open-pore structure was successfully prepared. According to the method of immersion, the technical characteristics ...Using forming-knitting technology and organic materials, copper foam with high porosity (>80%) and open-pore structure was successfully prepared. According to the method of immersion, the technical characteristics of metal paste performance and influence factors of sinter process were discussed. The pore morphology and compressibility of copper foam were detected simultaneously, and the structural property of copper foam prepared by the process of once-infiltrating was compared with the one of copper foam prepared by the process of twice-infiltrating. The results show that pH value of metal paste has a large influence on rheological properties of slurry. By twice-infiltrating process, the microstructure of copper foam was altered. In case of the porosity dropping indistinctly, the compression stress of copper foam platform was raised from 0.5 MPa to 1 Mpa which was of great significance to improve the energy absorption capacity of the material.展开更多
Extending in a NNW-SSE direction. the Yulong porphyry copper belt is the largest and richest porphyry copper belt in China, originating in the Paleogene. Tectonically located on the eastern margin of the northern Tibe...Extending in a NNW-SSE direction. the Yulong porphyry copper belt is the largest and richest porphyry copper belt in China, originating in the Paleogene. Tectonically located on the eastern margin of the northern Tibet geodepression. and nearly 500 km of the Himalayan Yarlung Zangbo plate subduction zone of nearly E-W trend. it is a relatively typical intracontinental rejuvenated platform-type porphyry copper belt. Ore-bearing porphyry masses in the belt mainly represented by monzogranite-porphyry occurring as stocks in variegated sandshale of the lower Upper Triassic Jiapila Fromation and its overlying and underlying copper-bearing strata. They are characterized by enrichment in K. CI and LREE. abundant fluid inclusions and a distinct porphyroblastic texture. The oxygen. hydrogen. strotium. lead and sulfur isotopic values of the rock show the feature of crust-mantle mixing.The Orebodies are plpe-shaped stratoid; the mineralization is dominated by Cu and Mo, accompanied by Fe. Co. Au. Ag. Bi. W. Pb. Zn. and Pt-group elements. Alteration is strong. marked mainly by potassic alteration, silicification. skarnization and propylitization. The formation of this type of deposit largely progressed through two stages. The first stage was the stage of formation of Cu-bearing source beds. It occurred in the Triassic. when a transgressive copper-bearing formation was deposited on the western margin of the Qamdo Bay. which was represented by intermediate-acid volcanic rocks and variegated sandshale in the lower part. dolomitic carbonate rocks in the middle and black carbonaceous sandshale in the upper part. In the second stage. composite porphyry copper deposits were formed. This stage took place in the Paleogene. when this district was in a stage of platform rejuvenation. forming a series of NNW-trending deep faults. so that Na, K. Cl. H2O and CO2-rich hydrothermal fluids from the depths were injected into the upper crust and replaced and melted copper-bearing sialic rocks of the upper crust. e. g. the Triassic copper-bearing rock series in the Yulong area. to form porphyroblastic cooper-bearing intermediate-acid porphyry.展开更多
A two-dimensional axisymmetric model,with 8700 and 7500 quadrilateral elements for the fluid and substrate zone separately,was developed to simulate the impacting and flattening process. The volume of fluid technique ...A two-dimensional axisymmetric model,with 8700 and 7500 quadrilateral elements for the fluid and substrate zone separately,was developed to simulate the impacting and flattening process. The volume of fluid technique was employed to track the interface between the air and droplet. The relationships between the droplet pre-impact parameters and the flattening time as well as the flattening ratio were investigated by altering one of the parameters while remaining the others unchanged. The results show that the droplet height reaches its minimum value at approximately half of the spreading time,which also indicates the finish of vertical fluid flow at that time. The flattening ratio increases with the increase of the three pre-impact parameters-droplet diameter,temperature and velocity,even though the flattening time decreases when the droplet velocity increase.展开更多
The Hongshi copper deposit is located in the middle of the Kalatage ore district in the northern segment of the Dananhu-Tousuquan island-arc belt in East Tianshan, Xinjiang, NW China. This study analyses the fluid inc...The Hongshi copper deposit is located in the middle of the Kalatage ore district in the northern segment of the Dananhu-Tousuquan island-arc belt in East Tianshan, Xinjiang, NW China. This study analyses the fluid inclusions and H, O, and S stable isotopic compositions of the deposit. The fluid-inclusion data indicate that aqueous fluid inclusions were trapped in chalcopyrite-bearing quartz veins in the gangue minerals. The homogenization temperatures range from 108°C to 299°C, and the salinities range from 0.5% to 11.8%, indicating medium to low temperatures and salinities. The trapping pressures range from 34.5 MPa to 56.8 MPa. The δ^（18）O_（H_2O） values and δD values of the fluid range from -6.94‰ to -5.33‰ and from -95.31‰ to -48.20‰, respectively. The H and O isotopic data indicate that the ore-forming fluid derived from a mix of magmatic water and meteoric water and that meteoric water played a significant role. The S isotopic composition of pyrite ranges from 1.9‰ to 5.2‰, with an average value of 3.1‰, and the S isotopic composition of chalcopyrite ranges from -0.9‰ to 4‰, with an average value of 1.36‰, implying that the S in the ore-forming materials was derived from the mantle. The introduction of meteoric water decreased the temperature, volatile content, and pressure, resulting in immiscibility. These factors may have been the major causes of the mineralization of the Hongshi copper deposit. Based on all the geologic and fluid characteristics, we conclude that the Hongshi copper deposit is an epithermal deposit.展开更多
On the basis of results of the studies of primary fluid inclusions, and the hydrogen and oxygen isotope data, the authors concluded that the early-stage ore-forming fluid from the Jinchangqing gold (copper) ore deposi...On the basis of results of the studies of primary fluid inclusions, and the hydrogen and oxygen isotope data, the authors concluded that the early-stage ore-forming fluid from the Jinchangqing gold (copper) ore deposit is a kind of sulfate type hot brine characterized by medium temperature and salinity, genetically related to the late-stage ore-forming fluid derived from an acidic and more reductive environment. However, the late-stage ore-forming fluid is a sort of low temperature and low salinity chloride-type hot brine which originated from a lower pressure, acidic and more oxidative environment. In general, the ore fluids were derived from the late-stage, or largely from the early-stage groundwater-derived meteoric water, which has a 12‰-17‰ heavier oxygen isotopic composition than the original rain water (δ{}+{18}O={-15.3‰}), and were formed during gold mineralization as a product of oxygen isotope exchange during the reaction between ore-forming fluid and wall rocks under a lower water/rock ratio condition.展开更多
On the basis of the geological and geochemical studies, including chemical analysis of bulk rocks, rare-earth and trace element studies, fluid inclusion, and S and O isotopic analyses, the authors described the geolog...On the basis of the geological and geochemical studies, including chemical analysis of bulk rocks, rare-earth and trace element studies, fluid inclusion, and S and O isotopic analyses, the authors described the geological background of the deposit in detail and presented significant proofs for the conditions of formation of the Shaxi porphyry copper-gold deposit. Compared with other large and supper-large porphyry copper deposits in China and the adjacent Cu-Au mineralized areas, the ore-forming processes and conditions were analyzed; and the possibility of forming large porphyry copper deposits in the Shaxi area was discussed. The present study indicated that the ore-forming fluid and material were mainly of magmatic origin, while meteoric water played a certain role in the ore-forming processes. Interactions between subducting and overriding plates provided a major driving force for the formation of igneous rocks and the deposition of metal elements in East China since Jurassic. Based on the geo- chemical data of the Shaxi intrusive, it is found that the copper (gold) mineralization is closely related to the genesis of adakite-like intrusive in the Shaxi area. This adakite-like intrusive was formed in the subduction environment as a result of the subduction of the West Pacific plate toward the East China continent, where there is a great potentiality to form a large porphyry copper deposit.展开更多
The quantificational and normative design is the precondition of improving the design of copper staves for blast furnaces. Based on a 3-dimensional temperature field calculation model, from the view point of heat tran...The quantificational and normative design is the precondition of improving the design of copper staves for blast furnaces. Based on a 3-dimensional temperature field calculation model, from the view point of heat transfer and long campaigns note with the core of forming accretion, the forming-accretion-ability （FAA） and the rib hot surface maximum temperature difference （ATmax） as quantificational indexes to direct and evaluate the design of copper staves for blast furnaces were presented. The application of the two indexes in design essentially embodies the new long campaigns in the stage of design. With the application of the two indexes, good results can be obtained. Firstly, it was suggested that the rib height of a copper stave can be reduced to 15 mm, which is a new method and theory for the reduction of copper staves. Secondly, the influence of insert on FAA and ATmax, is decided by the volume of insert. According to this, the principle of design for the hot surface geometry of copper staves was put forward that the ratio of the rib hot surface to the copper stave hot surface （abbreviated as the ratio of rib to stave） must be maintained in the range of 45% to 55%; for the present copper stave with a 35-40 mm thick rib, the ratio of rib to stave in the range of 50% to 55% can optimize the design of copper staves; for the copper stave with a smaller rib thickness, for example 15 ram, the ratio of rib to stave in the range of 45% to 50% can optimize the design of copper staves. It can be summarized that the thicker the rib thickness, the larger is the ratio of rib to stave. 2008 University of Science and Technology Beijing. All rights reserved.展开更多
The Tongyu copper deposit, located in the western part of the North Qinling Orogen, China, is one of several volcanic-hosted massive sulphide（VHMS） deposits with industrial value and is also a typical example of min...The Tongyu copper deposit, located in the western part of the North Qinling Orogen, China, is one of several volcanic-hosted massive sulphide（VHMS） deposits with industrial value and is also a typical example of mineralization related to the subduction and metallogenesis during the Caledonian orogeny. We conducted systematic lead-sulphur isotope geochemical analyses of the Tongyu deposit to understand the possible ore-forming material sources and tectonic settings. Twenty-six sulphide samples yielded clustered δ^34SCDT values of 1.13‰-3.36‰, average 2.22‰, and show a tower-type distribution,implying that the sulphur of the Tongyu copper deposit mainly originated from a mantle source. The Pb isotope compositions of sulphides（^206Pb/^204Pb = 17.59225-18.56354, average 18.32020; ^207Pb/^204Pb =15.51770-15.69381, average 15.66217; ^208Pb/^204Pb= 37.99969-39.06953, average 38.52722） are close to the values of the volcanic host rocks（^206Pb/^204PbPb= 18.10678-18.26293, average 18.21158; ^207Pb/^204PbPb =15.63196-15.68188, average 15.65345; ^208Pb/^204PbPb= 38.43676-38.56360, average 38.49171）, thus consistent with the Pb in ores and volcanic host rocks having been derived from a common source that was island-arc Pb related to oceanic crust subduction. The northward subduction of the Palaeo-Qinling oceanic crust triggered dehydration of the slab, which generated a large amount of high-oxygen-fugacity aqueous hydrothermal fluid. The fluid rose into the mantle wedge, activated and extracted metallogenic material and promoted partial melting of the mantle wedge. The magma and ore-forming fluid welled up and precipitated, finally forming the Tongyu VHMS copper deposit.展开更多
The compaction of pure Cu powder was carried out through a series of experiments using dynamic magnetic pulse compaction, and the effects of process parameters, such as discharge energy and compacting direction, on th...The compaction of pure Cu powder was carried out through a series of experiments using dynamic magnetic pulse compaction, and the effects of process parameters, such as discharge energy and compacting direction, on the homogeneity and the compaction density of compacted specimens were presented and discussed. The results indicated that the compaction density of specimens increased with the augment of discharge voltage and time. During unidirectional compaction, there was a density gradient along the loading direction in the compacted specimen, and the minimum compaction density was localized to the center of the bottom of the specimen. The larger the aspect ratio of a powder body, the higher the compaction density of the compacted specimen. And high conductivity drivers were beneficial to the increase of the compaction density. The iterative and the double direction compaction were efficient means to manufacture the homogeneous and high-density powder parts.展开更多
The bulk Fe<sup>60 CoxZr<sup>10 Mo5W2B<sup>23-x （x=1, 3, 5, 7, 9） amorphous rods with diameters of 1.5 mm were successfully prepared by copper mold casting method with the low purity raw materials....The bulk Fe<sup>60 CoxZr<sup>10 Mo5W2B<sup>23-x （x=1, 3, 5, 7, 9） amorphous rods with diameters of 1.5 mm were successfully prepared by copper mold casting method with the low purity raw materials. The amorphous and crystalline states, and thermal parameters, such as the glass transition temperature （Tg）, the initial crystallization temperature （Tx）, the supercooled liquid region （ΔTx=Tx-Tg）, the reduced glass transition temperature T<sup>rg （Tg/Tm, Tm: the onset temperature of melting of the alloy, and Tg/Tl, Tl: the finished temperature of melting of the alloy） were investigated by X-ray diffractometry （XRD） and differential scanning calorimetry （DSC） analysis. Glass forming ability of Fe<sup>60 CoxZr<sup>10 Mo5W2B<sup>23-x （x=1,3,5,7,9） bulk metallic glasses has been studied. According to the results, the alloy （x=7） with the highest T<sup>rg （Tg/Tl=0.607, Tg/Tl=0.590） value, has the strongest glass forming ability among these alloys because its composition is near eutectic composition. The wide supercooled liquid region over 72 K indicates the high thermal stability for this alloy system. This bulk metallic glass exhibits quite high strength （Hv 1020）. The success of production of the Fe-based bulk metallic glass with industrial materials is of great significance for the future progress of basic research and practical application.展开更多
The Chahe copper deposit occurs in the Early Proterozoic metamorphicseries in the area of Chahe and its chalcopyrite yielded a Pb-Pb isochron age of 951±36 Ma, providing evidence for copper mineralization at the ...The Chahe copper deposit occurs in the Early Proterozoic metamorphicseries in the area of Chahe and its chalcopyrite yielded a Pb-Pb isochron age of 951±36 Ma, providing evidence for copper mineralization at the early stage of the Jinningmovement. The ore-forming material came from terrestrial clastic sediments and marinevolcanic eruption and the ores were deposited in a relatively open beach environment.The Jinning movement led to folding and metamorphism of country strata, as well asto the rebomilization and transport of copper, resulting in ore deposition in structurallyweak locations. This deposit is a volcano-sedimentary metamorphic deposit.展开更多
基金supported partially by the National Natural Science Foundation of China (31201619)Profession Expert Group of Facility Cultivation and Engineering (CARS25-D-03)the Sci-Tech Development Project of Tai’an City, China (32606)
文摘Nitric oxide（NO）,a bioactive signaling molecule,serves as an antioxidant and anti-stress agent under abiotic stress.A hydroponics experiment was conducted to investigate the effects of sodium nitroprusside（SNP）,a NO donor,on tomato seedlings exposed to 50 μmol L-1CuCl 2.The results show that copper is primarily stored in the soluble cell sap fraction in the roots,especially after treatment with Cu＋SNP treatment,which accounted for 66.2% of the total copper content.The copper concentration gradually decreased from the roots to the leaves.In the leaves,exogenous NO induces the storage of excess copper in the cell walls.Copper stress decreases the proportion of copper integrated with pectates and proteins,but exogenous NO remarkably reverses this trend.The alleviating effect of NO is blocked by hemoglobin.Thus,exogenous NO is likely involved in the regulation of the subcellular copper concentrations and its chemical forms under copper stress.Although exogenous NO inhibited the absorption and transport of excess copper to some extent,the copper accumulation in tomato seedlings significantly increased under copper stress.The use of exogenous NO to enhance copper tolerance in some plants is a promising method for copper remediation.
基金the National Natural Science Foundation of China （ No. 40472052） is sincerely acknowledged.
文摘Shizishan ore-field is a nonferrous and noble metal ore-field which is most rich in copper and gold.There are many types of fluid inclusions in minerals of the deposits.The homogeneous temperatures and the salinities of the fluid inclusions in main mineralization stages have wide ranges,while the different types of the fluid inclusions existed together and their homogeneous temperatures are almost identical in the same mineralization stage,which indicates that the ore-forming process has great relation with the fluid boiling.The gas and liquid chemical compositions and the carbon,hydrogen and oxygen isotopic compositions of the fluid inclusions show that the ore-forming fluids of copper-gold deposits have the same characteristics and evolution tendency,which reflects that the ore-forming material mainly came from the magmatism.The stratigraphic component and the meteoric water may mix in ore- forming fluids in the later mineralization stages.Furthermore,with the fall of the ore-forming temperature the ratios of water and rock decreased.The characteristics of chemical composition and carbon isotopic composition of fluid inclusions indicate that CH4 may play an important role for separating copper and gold in the ore-forming process.
文摘The continuous extrusion forming process for producing large section copper concave bus bar under different extrusion wheel angular velocities was studied by three-dimensional finite element technology based on software DEFORM-3D. The rigid-viscoplastic constitutive equation was employed in the model. The numerical simulation results show that the deformation body flow velocity in the die orifice increases gradually with the increase of the extrusion wheel angular velocity. But slippage between the rod and extrusion wheel occurs when the extrusion wheel angular velocity is high. The effective stress near the die orifice enhances gradually with increasing extrusion wheel angular velocity. High stress is concentrated in adjacent regions of the flash gap. The effective strain gradient is greater near the abutment than that near the die orifice. The effective strain of the product increases gradually with increasing extrusion wheel angular velocity. In the deformation process, the deformation body temperature increases remarkably due to friction and deformation. So the cooling is necessary in the region of the die and tools.
基金This study was financially supported by both the National Natural Science Foundation of China (No.40573035)the State BasicResearch Program of China (No.2002-CB-412600)
文摘Petrography, microthermometry, and scanning electron microscope/energy dispersive spectrometer （SEM/EDS） studies were performed on the fluid inclusions in the ore-beating quartz veins and quartz phenocrysts in the porphyry of the Chongjiang porphyry copper deposit. The analyses of the fluid inclusions indicate that the ore-forming fluids were exsolved from magma. They are near-saturated, supercritical, rich in volatile constituents, and have the capture temperature of 362-389℃ and salinities of 17.7wt%- 18.9wt% NaC1 eq. With the decreasing of temperature and pressure, the supercritical fluids were separated into a low salinity vapor phase and a high salinity liquid phase. During quartz-sericitization, the high salinity fluid boiled and separated into a low salinity vapor phase and a high salinity liquid phase. The high salinity inclusions that formed in the boiling process had daughter mineral melting temperatures higher than the homogenization temperatures of the vapor and liquid phases. The late fluids that are responsible for argillization are of lower temperature and salinity.
基金National Natural Science Foundation of China(No.50572084)Natural Science Basic Research Plan in Shaanxi Province of China(No.2012JQ6011)+1 种基金Shaanxi Provincial Key Laboratory Scientific Research Project,China(No.12JS044)Shaanxi Leading Academic Discipline Project,China(No.[2008]169)
文摘Using forming-knitting technology and organic materials, copper foam with high porosity (>80%) and open-pore structure was successfully prepared. According to the method of immersion, the technical characteristics of metal paste performance and influence factors of sinter process were discussed. The pore morphology and compressibility of copper foam were detected simultaneously, and the structural property of copper foam prepared by the process of once-infiltrating was compared with the one of copper foam prepared by the process of twice-infiltrating. The results show that pH value of metal paste has a large influence on rheological properties of slurry. By twice-infiltrating process, the microstructure of copper foam was altered. In case of the porosity dropping indistinctly, the compression stress of copper foam platform was raised from 0.5 MPa to 1 Mpa which was of great significance to improve the energy absorption capacity of the material.
文摘Extending in a NNW-SSE direction. the Yulong porphyry copper belt is the largest and richest porphyry copper belt in China, originating in the Paleogene. Tectonically located on the eastern margin of the northern Tibet geodepression. and nearly 500 km of the Himalayan Yarlung Zangbo plate subduction zone of nearly E-W trend. it is a relatively typical intracontinental rejuvenated platform-type porphyry copper belt. Ore-bearing porphyry masses in the belt mainly represented by monzogranite-porphyry occurring as stocks in variegated sandshale of the lower Upper Triassic Jiapila Fromation and its overlying and underlying copper-bearing strata. They are characterized by enrichment in K. CI and LREE. abundant fluid inclusions and a distinct porphyroblastic texture. The oxygen. hydrogen. strotium. lead and sulfur isotopic values of the rock show the feature of crust-mantle mixing.The Orebodies are plpe-shaped stratoid; the mineralization is dominated by Cu and Mo, accompanied by Fe. Co. Au. Ag. Bi. W. Pb. Zn. and Pt-group elements. Alteration is strong. marked mainly by potassic alteration, silicification. skarnization and propylitization. The formation of this type of deposit largely progressed through two stages. The first stage was the stage of formation of Cu-bearing source beds. It occurred in the Triassic. when a transgressive copper-bearing formation was deposited on the western margin of the Qamdo Bay. which was represented by intermediate-acid volcanic rocks and variegated sandshale in the lower part. dolomitic carbonate rocks in the middle and black carbonaceous sandshale in the upper part. In the second stage. composite porphyry copper deposits were formed. This stage took place in the Paleogene. when this district was in a stage of platform rejuvenation. forming a series of NNW-trending deep faults. so that Na, K. Cl. H2O and CO2-rich hydrothermal fluids from the depths were injected into the upper crust and replaced and melted copper-bearing sialic rocks of the upper crust. e. g. the Triassic copper-bearing rock series in the Yulong area. to form porphyroblastic cooper-bearing intermediate-acid porphyry.
基金Project (50675072) supported by the National Natural Science Foundation of ChinaProject (E0610018) supported by the Natural Science Foundation of Fujian Province, ChinaProject (20062178) supported by the Natural Science Foundation of Liaoning Province, China
文摘A two-dimensional axisymmetric model,with 8700 and 7500 quadrilateral elements for the fluid and substrate zone separately,was developed to simulate the impacting and flattening process. The volume of fluid technique was employed to track the interface between the air and droplet. The relationships between the droplet pre-impact parameters and the flattening time as well as the flattening ratio were investigated by altering one of the parameters while remaining the others unchanged. The results show that the droplet height reaches its minimum value at approximately half of the spreading time,which also indicates the finish of vertical fluid flow at that time. The flattening ratio increases with the increase of the three pre-impact parameters-droplet diameter,temperature and velocity,even though the flattening time decreases when the droplet velocity increase.
基金financially supported by the National Key R&D Program of China(2017YFC0601201-2)funds from the Chinese Ministry of Land and Resources for public welfare industry research(201411026-1)the Chinese Geological Survey Project(DD20160071)
文摘The Hongshi copper deposit is located in the middle of the Kalatage ore district in the northern segment of the Dananhu-Tousuquan island-arc belt in East Tianshan, Xinjiang, NW China. This study analyses the fluid inclusions and H, O, and S stable isotopic compositions of the deposit. The fluid-inclusion data indicate that aqueous fluid inclusions were trapped in chalcopyrite-bearing quartz veins in the gangue minerals. The homogenization temperatures range from 108°C to 299°C, and the salinities range from 0.5% to 11.8%, indicating medium to low temperatures and salinities. The trapping pressures range from 34.5 MPa to 56.8 MPa. The δ^（18）O_（H_2O） values and δD values of the fluid range from -6.94‰ to -5.33‰ and from -95.31‰ to -48.20‰, respectively. The H and O isotopic data indicate that the ore-forming fluid derived from a mix of magmatic water and meteoric water and that meteoric water played a significant role. The S isotopic composition of pyrite ranges from 1.9‰ to 5.2‰, with an average value of 3.1‰, and the S isotopic composition of chalcopyrite ranges from -0.9‰ to 4‰, with an average value of 1.36‰, implying that the S in the ore-forming materials was derived from the mantle. The introduction of meteoric water decreased the temperature, volatile content, and pressure, resulting in immiscibility. These factors may have been the major causes of the mineralization of the Hongshi copper deposit. Based on all the geologic and fluid characteristics, we conclude that the Hongshi copper deposit is an epithermal deposit.
基金Thisresearchprojectwasgrantedjointlybythe95’StateKeyScienceandTechnologyProjects(96 914 03 04),ResearchProjectsin95’KeyRegionsandZonessponsoredbytheoriginalNon ferrousMetalIndustry GeneralCompany(96 D 42),theStateKeyBasicResearch,Develop mentandPlanningProgram(G1999043208)andtheFoundationProjects ofYunnanProvincialEducationDepartment(0142104).
文摘On the basis of results of the studies of primary fluid inclusions, and the hydrogen and oxygen isotope data, the authors concluded that the early-stage ore-forming fluid from the Jinchangqing gold (copper) ore deposit is a kind of sulfate type hot brine characterized by medium temperature and salinity, genetically related to the late-stage ore-forming fluid derived from an acidic and more reductive environment. However, the late-stage ore-forming fluid is a sort of low temperature and low salinity chloride-type hot brine which originated from a lower pressure, acidic and more oxidative environment. In general, the ore fluids were derived from the late-stage, or largely from the early-stage groundwater-derived meteoric water, which has a 12‰-17‰ heavier oxygen isotopic composition than the original rain water (δ{}+{18}O={-15.3‰}), and were formed during gold mineralization as a product of oxygen isotope exchange during the reaction between ore-forming fluid and wall rocks under a lower water/rock ratio condition.
基金supported by the Knowledge Innovation Project of the Chinese Academy of Sciences (Grant No. KZCX1-YW-15)the National Natural Science Foundation of China (Grant No. 90814008)parts of experimental work is supported from the Opening Funding of State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences (GPMR0506)
文摘On the basis of the geological and geochemical studies, including chemical analysis of bulk rocks, rare-earth and trace element studies, fluid inclusion, and S and O isotopic analyses, the authors described the geological background of the deposit in detail and presented significant proofs for the conditions of formation of the Shaxi porphyry copper-gold deposit. Compared with other large and supper-large porphyry copper deposits in China and the adjacent Cu-Au mineralized areas, the ore-forming processes and conditions were analyzed; and the possibility of forming large porphyry copper deposits in the Shaxi area was discussed. The present study indicated that the ore-forming fluid and material were mainly of magmatic origin, while meteoric water played a certain role in the ore-forming processes. Interactions between subducting and overriding plates provided a major driving force for the formation of igneous rocks and the deposition of metal elements in East China since Jurassic. Based on the geo- chemical data of the Shaxi intrusive, it is found that the copper (gold) mineralization is closely related to the genesis of adakite-like intrusive in the Shaxi area. This adakite-like intrusive was formed in the subduction environment as a result of the subduction of the West Pacific plate toward the East China continent, where there is a great potentiality to form a large porphyry copper deposit.
基金the National Natural Science Foundation of China(No.60672145).
文摘The quantificational and normative design is the precondition of improving the design of copper staves for blast furnaces. Based on a 3-dimensional temperature field calculation model, from the view point of heat transfer and long campaigns note with the core of forming accretion, the forming-accretion-ability （FAA） and the rib hot surface maximum temperature difference （ATmax） as quantificational indexes to direct and evaluate the design of copper staves for blast furnaces were presented. The application of the two indexes in design essentially embodies the new long campaigns in the stage of design. With the application of the two indexes, good results can be obtained. Firstly, it was suggested that the rib height of a copper stave can be reduced to 15 mm, which is a new method and theory for the reduction of copper staves. Secondly, the influence of insert on FAA and ATmax, is decided by the volume of insert. According to this, the principle of design for the hot surface geometry of copper staves was put forward that the ratio of the rib hot surface to the copper stave hot surface （abbreviated as the ratio of rib to stave） must be maintained in the range of 45% to 55%; for the present copper stave with a 35-40 mm thick rib, the ratio of rib to stave in the range of 50% to 55% can optimize the design of copper staves; for the copper stave with a smaller rib thickness, for example 15 ram, the ratio of rib to stave in the range of 45% to 50% can optimize the design of copper staves. It can be summarized that the thicker the rib thickness, the larger is the ratio of rib to stave. 2008 University of Science and Technology Beijing. All rights reserved.
基金jointly supported by National Natural Science Foundation of China(Grant Nos.41421002,41272092,and 41030423)MOST Special Fund from the State Key Laboratory of Continental Dynamics,Northwest University,China
文摘The Tongyu copper deposit, located in the western part of the North Qinling Orogen, China, is one of several volcanic-hosted massive sulphide（VHMS） deposits with industrial value and is also a typical example of mineralization related to the subduction and metallogenesis during the Caledonian orogeny. We conducted systematic lead-sulphur isotope geochemical analyses of the Tongyu deposit to understand the possible ore-forming material sources and tectonic settings. Twenty-six sulphide samples yielded clustered δ^34SCDT values of 1.13‰-3.36‰, average 2.22‰, and show a tower-type distribution,implying that the sulphur of the Tongyu copper deposit mainly originated from a mantle source. The Pb isotope compositions of sulphides（^206Pb/^204Pb = 17.59225-18.56354, average 18.32020; ^207Pb/^204Pb =15.51770-15.69381, average 15.66217; ^208Pb/^204Pb= 37.99969-39.06953, average 38.52722） are close to the values of the volcanic host rocks（^206Pb/^204PbPb= 18.10678-18.26293, average 18.21158; ^207Pb/^204PbPb =15.63196-15.68188, average 15.65345; ^208Pb/^204PbPb= 38.43676-38.56360, average 38.49171）, thus consistent with the Pb in ores and volcanic host rocks having been derived from a common source that was island-arc Pb related to oceanic crust subduction. The northward subduction of the Palaeo-Qinling oceanic crust triggered dehydration of the slab, which generated a large amount of high-oxygen-fugacity aqueous hydrothermal fluid. The fluid rose into the mantle wedge, activated and extracted metallogenic material and promoted partial melting of the mantle wedge. The magma and ore-forming fluid welled up and precipitated, finally forming the Tongyu VHMS copper deposit.
文摘The compaction of pure Cu powder was carried out through a series of experiments using dynamic magnetic pulse compaction, and the effects of process parameters, such as discharge energy and compacting direction, on the homogeneity and the compaction density of compacted specimens were presented and discussed. The results indicated that the compaction density of specimens increased with the augment of discharge voltage and time. During unidirectional compaction, there was a density gradient along the loading direction in the compacted specimen, and the minimum compaction density was localized to the center of the bottom of the specimen. The larger the aspect ratio of a powder body, the higher the compaction density of the compacted specimen. And high conductivity drivers were beneficial to the increase of the compaction density. The iterative and the double direction compaction were efficient means to manufacture the homogeneous and high-density powder parts.
文摘The bulk Fe<sup>60 CoxZr<sup>10 Mo5W2B<sup>23-x （x=1, 3, 5, 7, 9） amorphous rods with diameters of 1.5 mm were successfully prepared by copper mold casting method with the low purity raw materials. The amorphous and crystalline states, and thermal parameters, such as the glass transition temperature （Tg）, the initial crystallization temperature （Tx）, the supercooled liquid region （ΔTx=Tx-Tg）, the reduced glass transition temperature T<sup>rg （Tg/Tm, Tm: the onset temperature of melting of the alloy, and Tg/Tl, Tl: the finished temperature of melting of the alloy） were investigated by X-ray diffractometry （XRD） and differential scanning calorimetry （DSC） analysis. Glass forming ability of Fe<sup>60 CoxZr<sup>10 Mo5W2B<sup>23-x （x=1,3,5,7,9） bulk metallic glasses has been studied. According to the results, the alloy （x=7） with the highest T<sup>rg （Tg/Tl=0.607, Tg/Tl=0.590） value, has the strongest glass forming ability among these alloys because its composition is near eutectic composition. The wide supercooled liquid region over 72 K indicates the high thermal stability for this alloy system. This bulk metallic glass exhibits quite high strength （Hv 1020）. The success of production of the Fe-based bulk metallic glass with industrial materials is of great significance for the future progress of basic research and practical application.
文摘The Chahe copper deposit occurs in the Early Proterozoic metamorphicseries in the area of Chahe and its chalcopyrite yielded a Pb-Pb isochron age of 951±36 Ma, providing evidence for copper mineralization at the early stage of the Jinningmovement. The ore-forming material came from terrestrial clastic sediments and marinevolcanic eruption and the ores were deposited in a relatively open beach environment.The Jinning movement led to folding and metamorphism of country strata, as well asto the rebomilization and transport of copper, resulting in ore deposition in structurallyweak locations. This deposit is a volcano-sedimentary metamorphic deposit.
