We report an organic/inorganic hybridized nanocomposite consisting of a bi-functional poly（N-vinyl）-3-[p-nitrophenylazo]carbazolyl serves as a polymeric charge-transporting and second-order nonliner optical matrix, ...We report an organic/inorganic hybridized nanocomposite consisting of a bi-functional poly（N-vinyl）-3-[p-nitrophenylazo]carbazolyl serves as a polymeric charge-transporting and second-order nonliner optical matrix, and CdS nanoparticles as photosensitizers to manifest photorefractive （PR） effect. The unpoled PVNPAK film exhibits a second harmonic generation （SHG） coefficient of 4.7 pm/V due to the possibility of self-alignment of the azo chromophore. Significant enhancement of photoconductivity is noticed with the increase of CdS nanoparticles concentration. The photorefractive property of the polymer nanocomposites were determined by two-beam coupling （TBC） experiment. The TBC gain and diffraction efficiency of 11.89 cm-1 and 3.2% were obtained for PVNPAK/CdS at zero electrical field.展开更多
基金Funded by the National Natural Science Foundation of China (No.50802069)the Natural Science Foundation of Wuhan University of Tech-nology (471-38650378)
文摘We report an organic/inorganic hybridized nanocomposite consisting of a bi-functional poly（N-vinyl）-3-[p-nitrophenylazo]carbazolyl serves as a polymeric charge-transporting and second-order nonliner optical matrix, and CdS nanoparticles as photosensitizers to manifest photorefractive （PR） effect. The unpoled PVNPAK film exhibits a second harmonic generation （SHG） coefficient of 4.7 pm/V due to the possibility of self-alignment of the azo chromophore. Significant enhancement of photoconductivity is noticed with the increase of CdS nanoparticles concentration. The photorefractive property of the polymer nanocomposites were determined by two-beam coupling （TBC） experiment. The TBC gain and diffraction efficiency of 11.89 cm-1 and 3.2% were obtained for PVNPAK/CdS at zero electrical field.
