The effect of the Al2O3 structure on the performance of Pt/Ga/Al2O3 catalysts is investigated for the direct dehydrogenation of propane. The study unveils that the structure of Al3+determines the bulk structure of cat...The effect of the Al2O3 structure on the performance of Pt/Ga/Al2O3 catalysts is investigated for the direct dehydrogenation of propane. The study unveils that the structure of Al3+determines the bulk structure of catalysts, particularly a high content of coordinatively unsaturated Al3+sites(penta-coordinated Al3+,denoted as Al3+penta) could lead to a remarkably improved dehydrogenation activity of the catalyst. The bulk characterization reveals that the sufficient amount of Al3+pentain Al2O3 benefit the dispersion of Pt and Ga2O3 on the Al2O3 support. At the same time, TPR results reveal that the presence of Pt facilitates the reduction of Ga2O3, likely due to the hydrogen spillover between the well dispersed Pt and Ga2O3,which consequently enhances the synergistic function between Pt and Ga2O3 in the dehydrogenation of propane. Recyclability tests demonstrate that the dehydrogenation activity stabilizes after three cycles over the Pt/Ga/Al2O3 catalyst.展开更多
An AI2O3-TiB2 nanocomposite was success- fully synthesized by the high energy ball milling of A1, B2O3 and TiO2. The structures of the powdered particles formed at different milling times were evaluated by X-ray diffr...An AI2O3-TiB2 nanocomposite was success- fully synthesized by the high energy ball milling of A1, B2O3 and TiO2. The structures of the powdered particles formed at different milling times were evaluated by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. Thermo- dynamic calculations showed that the composite formed in two steps via highly exothermic mechanically induced self-sustaining reactions （MSRs）. The composite started to form at milling times of 9-10 h but the reaction was not complete. The remaining starting materials were consumed by increasing the milling time to 15 h. The XRD patterns of the annealed powders showed that aluminum borate is one of the intermediate products and that it is consumed at higher temperatures. Heat treatment of the 6-h milled sample at l l00℃ led to a complete formation of the composite. Increasing the milling time to 15 h led to a refining of the crystallite sizes. A nanocomposite powder with a mean crystallite size of 35-40 nm was obtained after milling for 15 h.展开更多
以镍基负载γ-Al2O3为催化剂,对环戊二烯(CPD)选择加氢制备环戊烯(CPE)的工艺过程进行了研究.以双环戊二烯(DCPD)为初始原料,经过精馏塔高温解聚后得到加氢原料环戊二烯,在装填了Ni/γ-Al2O3催化剂的常压固定床反应器中与氢气发生选择...以镍基负载γ-Al2O3为催化剂,对环戊二烯(CPD)选择加氢制备环戊烯(CPE)的工艺过程进行了研究.以双环戊二烯(DCPD)为初始原料,经过精馏塔高温解聚后得到加氢原料环戊二烯,在装填了Ni/γ-Al2O3催化剂的常压固定床反应器中与氢气发生选择加氢反应.实验结果表明:适宜的催化剂制备条件为:Ni含量20%,浸渍时间12 h;适宜的工艺操作条件为:预还原温度500℃,氢烃比1.0,液空速6.0 h 1.在此条件下,CPD的转化率达到87.7%,CPE的选择性为92.8%.展开更多
基金the National Natural Science Foundation of China(No.21676195)the China Postdoctoral Science Foundation(2016M601347)。
文摘The effect of the Al2O3 structure on the performance of Pt/Ga/Al2O3 catalysts is investigated for the direct dehydrogenation of propane. The study unveils that the structure of Al3+determines the bulk structure of catalysts, particularly a high content of coordinatively unsaturated Al3+sites(penta-coordinated Al3+,denoted as Al3+penta) could lead to a remarkably improved dehydrogenation activity of the catalyst. The bulk characterization reveals that the sufficient amount of Al3+pentain Al2O3 benefit the dispersion of Pt and Ga2O3 on the Al2O3 support. At the same time, TPR results reveal that the presence of Pt facilitates the reduction of Ga2O3, likely due to the hydrogen spillover between the well dispersed Pt and Ga2O3,which consequently enhances the synergistic function between Pt and Ga2O3 in the dehydrogenation of propane. Recyclability tests demonstrate that the dehydrogenation activity stabilizes after three cycles over the Pt/Ga/Al2O3 catalyst.
文摘An AI2O3-TiB2 nanocomposite was success- fully synthesized by the high energy ball milling of A1, B2O3 and TiO2. The structures of the powdered particles formed at different milling times were evaluated by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. Thermo- dynamic calculations showed that the composite formed in two steps via highly exothermic mechanically induced self-sustaining reactions （MSRs）. The composite started to form at milling times of 9-10 h but the reaction was not complete. The remaining starting materials were consumed by increasing the milling time to 15 h. The XRD patterns of the annealed powders showed that aluminum borate is one of the intermediate products and that it is consumed at higher temperatures. Heat treatment of the 6-h milled sample at l l00℃ led to a complete formation of the composite. Increasing the milling time to 15 h led to a refining of the crystallite sizes. A nanocomposite powder with a mean crystallite size of 35-40 nm was obtained after milling for 15 h.
文摘以镍基负载γ-Al2O3为催化剂,对环戊二烯(CPD)选择加氢制备环戊烯(CPE)的工艺过程进行了研究.以双环戊二烯(DCPD)为初始原料,经过精馏塔高温解聚后得到加氢原料环戊二烯,在装填了Ni/γ-Al2O3催化剂的常压固定床反应器中与氢气发生选择加氢反应.实验结果表明:适宜的催化剂制备条件为:Ni含量20%,浸渍时间12 h;适宜的工艺操作条件为:预还原温度500℃,氢烃比1.0,液空速6.0 h 1.在此条件下,CPD的转化率达到87.7%,CPE的选择性为92.8%.
基金supported by the National Natural Science Foundation of China(50772107)National Key Basic Research Program of China(973)(2007CB210206)National High-Tech Research and Development Program of China(863)(2009AA05Z435)~~
