Second harmonic generation （SHG） of a new organic optical crystal-urea L-malic acid （ULMA） was studied. A comparison of SHG efficiency of ULMA and KDP at a fundamental wavelength of 1064 nm using the Kurtz powder ...Second harmonic generation （SHG） of a new organic optical crystal-urea L-malic acid （ULMA） was studied. A comparison of SHG efficiency of ULMA and KDP at a fundamental wavelength of 1064 nm using the Kurtz powder method demonstrated that the second order nonlinear coefficient of ULMA is 1 57 times of that of KDP,and the damage threshold of ULMA is relatively higher Finally,both Type Ⅰ and Type Ⅱ phase match angles of the biaxial crystal ULMA were calculated.展开更多
[PO_(4)]3-possesses small microscopic secondorder susceptibility and polarizability anisotropy,which inherently result in weak second-harmonic generation (SHG)and small birefringence.Herein,a new noncentrosymmetric ph...[PO_(4)]3-possesses small microscopic secondorder susceptibility and polarizability anisotropy,which inherently result in weak second-harmonic generation (SHG)and small birefringence.Herein,a new noncentrosymmetric phosphate,[C(NH_(2))3]3PO_(4)·2H_(2)O,was successfully designed and synthesized by a solution evaporation method.[C(NH_(2))3]3PO_(4)·2H_(2)O without metal ions is composed of planar conjugated guanidine cations and PO_(4)tetrahedrons,which are connected by hydrogen bonds,forming a three-dimensional network.Physical property measurements indicate that the title compound displays an SHG response of 1.5×KH_(2)PO_(4)(KDP) and a larger birefringence (0.055@546.1 nm)compared with most reported ultraviolet nonlinear optical phosphates.Furthermore,first-principles calculations reveal that theπ-conjugated planar[C(NH_(2))3]+cations and[PO_(4)]3-groups are responsible for its excellent linear and NLOproperties.展开更多
文摘Second harmonic generation （SHG） of a new organic optical crystal-urea L-malic acid （ULMA） was studied. A comparison of SHG efficiency of ULMA and KDP at a fundamental wavelength of 1064 nm using the Kurtz powder method demonstrated that the second order nonlinear coefficient of ULMA is 1 57 times of that of KDP,and the damage threshold of ULMA is relatively higher Finally,both Type Ⅰ and Type Ⅱ phase match angles of the biaxial crystal ULMA were calculated.
基金supported by the National Natural Science Foundation of China (21975255,51890862,21921001 and U1605245)the National Key Research and Development Plan of Ministry of Science and Technology (2016YFB0402104)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB20000000)the Natural Science Foundation of Fujian Province (2019J01020758)Youth Innovation Promotion Association CAS (2019303)。
文摘[PO_(4)]3-possesses small microscopic secondorder susceptibility and polarizability anisotropy,which inherently result in weak second-harmonic generation (SHG)and small birefringence.Herein,a new noncentrosymmetric phosphate,[C(NH_(2))3]3PO_(4)·2H_(2)O,was successfully designed and synthesized by a solution evaporation method.[C(NH_(2))3]3PO_(4)·2H_(2)O without metal ions is composed of planar conjugated guanidine cations and PO_(4)tetrahedrons,which are connected by hydrogen bonds,forming a three-dimensional network.Physical property measurements indicate that the title compound displays an SHG response of 1.5×KH_(2)PO_(4)(KDP) and a larger birefringence (0.055@546.1 nm)compared with most reported ultraviolet nonlinear optical phosphates.Furthermore,first-principles calculations reveal that theπ-conjugated planar[C(NH_(2))3]+cations and[PO_(4)]3-groups are responsible for its excellent linear and NLOproperties.
