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金属-有机笼状化合物在限域催化领域的研究进展
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作者 于立冬 程喜全 +1 位作者 杨璐 周振 《精细化工》 EI CAS CSCD 北大核心 2022年第7期1352-1359,1410,共9页
金属-有机笼状化合物(MOCs)是一种由金属离子与有机配体通过配位自组装而成的具有特定空腔的化合物。MOCs的可变价金属离子、功能性配体和形状各异的空腔结构为催化不同反应提供了条件,MOCs的限域催化作用实现了对不同类型反应效率的提... 金属-有机笼状化合物(MOCs)是一种由金属离子与有机配体通过配位自组装而成的具有特定空腔的化合物。MOCs的可变价金属离子、功能性配体和形状各异的空腔结构为催化不同反应提供了条件,MOCs的限域催化作用实现了对不同类型反应效率的提升。从金属离子、功能性配体以及其限域空腔三方面来详细阐述金属-有机笼状化合物在催化领域的研究进展,其中,金属-有机笼状化合物的金属离子催化性能主要表现在光致产H、光致产O_(2)和CO_(2)还原,其功能性配体能够调节不对称催化反应的对映选择能力,其限域空腔对光二聚体的形成起到了很好的催化效果,也能够对一般的有机反应起到明显的促进效果。最后提出了MOCs存在的问题并对其未来发展方向进行了展望。 展开更多
关键词 金属-有机笼状化合物 催化 功能化 限域空腔 超分子化学
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Heat and mass transfer of a circular porous moist object located in a triangular shaped vented cavity
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作者 SELIMEFENDIGIL Fatih OZCAN COBAN Seda OZTOP Hakan F 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第6期1956-1972,共17页
Heat and mass transfer of a circular-shaped porous moist object inside a two-dimensional triangle cavity is investigated by using finite element method.The porous object is considered to be a moist food sample,located... Heat and mass transfer of a circular-shaped porous moist object inside a two-dimensional triangle cavity is investigated by using finite element method.The porous object is considered to be a moist food sample,located in the middle of the cavity with inlet and outlet ports with different configurations of inlet/outlet ports.Convective drying performance is numerically assessed for different values of Reynolds numbers(between 50 and 250),dry air inlet temperature(between 40 and 80℃)and different locations of the port.It is observed that changing the port locations has significant impacts on the flow recirculaitons inside the triangular chamber while convective drying performance is highly affected.The moisture content reduces with longer time and for higher Reynolds number(Re)values.Case P4 where inlet and outlet ports are in the middle of the walls provides the most effective configuration in terms of convective drying performance while the worst case is seen for P1 case where inlet and outlet are closer to the corners of the chamber.There is a 192% difference between the moisture reduction of these two cases at Re=250,T=80℃ and t=120 min. 展开更多
关键词 convective drying porous domain cavity flow inlet/exit port finite element method
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