Cyclic voltammetric behavior of electrooxidation of Mn(Ⅱ) under ultrasound and without ultrasound were compared. With the ultrasound irradiation the reduction peak potential of Pb(Ⅳ)/ Pb(Ⅱ) was found shifted negati...Cyclic voltammetric behavior of electrooxidation of Mn(Ⅱ) under ultrasound and without ultrasound were compared. With the ultrasound irradiation the reduction peak potential of Pb(Ⅳ)/ Pb(Ⅱ) was found shifted negatively about 0.14 V, initial electrolytic potential reduced 0.2 V and reduction peak current increased. At the same conditions,the conversion of Mn(Ⅱ) was increased. The optimum conditions for electrooxidation were 0.3 mol/L solution of Mn(Ⅱ), 6 mol/L H 2SO 4, electrolysis potential 2.3 V and 44 W ultrasound.展开更多
Sodium hypochlorite was used to treat the standard molybdenum concentrates; the oxidization conditions for sodium hypochlorite were investigated, and the electro-oxidation process was performed. The results indicate t...Sodium hypochlorite was used to treat the standard molybdenum concentrates; the oxidization conditions for sodium hypochlorite were investigated, and the electro-oxidation process was performed. The results indicate that in the suitable conditions, such as temperature around 25℃, NaCl concentration 4.0mol/L, mass ratio of ore slurry liquid to solid （mL/mS） 20, electric charge per gram Mo 0.522C, pH value of original slurry 8, anodic current density 700A·m-2 （cell potential 2.72.9V）, the Mo leaching rate and the current efficiency reach 98% and 36%, respectively. In order to overcome some shortages of the electro-oxidation process, such as low current efficiency, low Mo concentration in the leaching solution, ultrasonic was adopted to intensify the leaching process. The results show that the Mo leaching rate exceeds 98%, current efficiency increases from 36% to 50% and the Mo concentration in the leaching solution reaches about 60g/L at low mL/mS of 8 and low electric charge of 0.373C.展开更多
文摘Cyclic voltammetric behavior of electrooxidation of Mn(Ⅱ) under ultrasound and without ultrasound were compared. With the ultrasound irradiation the reduction peak potential of Pb(Ⅳ)/ Pb(Ⅱ) was found shifted negatively about 0.14 V, initial electrolytic potential reduced 0.2 V and reduction peak current increased. At the same conditions,the conversion of Mn(Ⅱ) was increased. The optimum conditions for electrooxidation were 0.3 mol/L solution of Mn(Ⅱ), 6 mol/L H 2SO 4, electrolysis potential 2.3 V and 44 W ultrasound.
文摘Sodium hypochlorite was used to treat the standard molybdenum concentrates; the oxidization conditions for sodium hypochlorite were investigated, and the electro-oxidation process was performed. The results indicate that in the suitable conditions, such as temperature around 25℃, NaCl concentration 4.0mol/L, mass ratio of ore slurry liquid to solid （mL/mS） 20, electric charge per gram Mo 0.522C, pH value of original slurry 8, anodic current density 700A·m-2 （cell potential 2.72.9V）, the Mo leaching rate and the current efficiency reach 98% and 36%, respectively. In order to overcome some shortages of the electro-oxidation process, such as low current efficiency, low Mo concentration in the leaching solution, ultrasonic was adopted to intensify the leaching process. The results show that the Mo leaching rate exceeds 98%, current efficiency increases from 36% to 50% and the Mo concentration in the leaching solution reaches about 60g/L at low mL/mS of 8 and low electric charge of 0.373C.
