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工艺条件对制备改性脲醛树脂浆料中的甲醛含量的影响 被引量:1
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作者 李敏 陈洲 +2 位作者 徐珊珊 余宏鹏 黄紫洋 《化学工程与技术》 2014年第2期29-35,共7页
本实验采用羟甲基松香与脲醛共聚合,旨在减少脲醛树脂分子结构中可降解或分解生成甲醛的结构单元,从而有效地降低脲醛树脂浆料中甲醛的释放,制得低甲醛环保型改性脲醛树脂浆料。实验中对不同的酸性催化剂、碱性调节剂、甲醛/尿素投料比... 本实验采用羟甲基松香与脲醛共聚合,旨在减少脲醛树脂分子结构中可降解或分解生成甲醛的结构单元,从而有效地降低脲醛树脂浆料中甲醛的释放,制得低甲醛环保型改性脲醛树脂浆料。实验中对不同的酸性催化剂、碱性调节剂、甲醛/尿素投料比、硫脲的添加量等工艺条件下所制得的不同批次的脲醛树脂浆料中甲醛含量和固含量进行测定,筛选出最优工艺条件。实验所制得的脲醛树脂浆料为乳浊液,颜色呈淡黄色,固含量>40%,游离甲醛为1.09%,pH值6.8~7.2,固化时间超过30 d。 展开更多
关键词 脲醛树脂浆料 羟甲基松香 甲醛含量 工艺条件
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New composite grouting materials:Modified urea-formaldehyde resin with cement 被引量:22
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作者 Duan Hongfei Jiang Zhenquan +2 位作者 Zhu Shuyun Yao Pu Sun Qiang 《International Journal of Mining Science and Technology》 2012年第2期195-200,共6页
A new composite two component grout comprised of modified urea-formaldehyde resin and cement was formulated to take account of the advantages and disadvantages of both the cement grout and the chem- ical grout. The ne... A new composite two component grout comprised of modified urea-formaldehyde resin and cement was formulated to take account of the advantages and disadvantages of both the cement grout and the chem- ical grout. The new grout is designed for water blocking by reinforcing as well as seepage control by bore grouting. The A component consists of a modified urea-formaldehyde resin A component, some cement, and some water. The B component is an alkaline coagulant. An orthogonal test of four factors at three lev- els showed that gel time increased with increased water content and with urea-formaldehyde resin con- tent. Gel time decreased at increased levels of alkaline coagulant. The A component of this new composite grout is stable over time. A mixed cross-over test showed that as the volume ratio of A to B increases the gel time falls at first but then increases. The solid strength decreases with increasing levels of the B com- ponent. The solid strength increases over time and becomes stable by the 28th day after mixing. The vis- cosity increases with increasing levels of resin A component. The increase is exponential and may be fit to: μ = 8.162e0.0286x. 展开更多
关键词 Modified urea-formaldehyde resin A liquidGrouting materialsOrthogonal testGel timeSolidification strength
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