Lead-free low melting glasses,ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)system,with fixed contents of 15 mol%CuO and 20 mol%Bi_(2)O_(3),were prepared by using melt cooling method.Structure and thermal properties of the gl...Lead-free low melting glasses,ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)system,with fixed contents of 15 mol%CuO and 20 mol%Bi_(2)O_(3),were prepared by using melt cooling method.Structure and thermal properties of the glasses were studied by using X-ray diffractometer(XRD),infrared spectrometer(FIT-IR),thermal dilatometer and differential thermal analyzer(DTA).Chemical durability of the glasses was studied by using dissolution rate method.Wettability of glasses on substrate was tested by using button sintering experiment.It is found that alkaline resistance of the glass solders is lower than that of plate glass and the water resistance is comparable with that of plate glass.The sealing temperatures are Ts=445-490℃,while the average thermal expansion coefficient from room temperature to 300℃is in the range of(65-82)×10^(−7)℃^(−1).At sealing temperature,the glass solders have good wettability on plate glass or alumina substrate.They are not crystallized even sintered at the sealing temperature for 30 min.The solder glasses are suitable for sealing plate glass,alumina and other inorganic non-metallic materials.展开更多
The influence of hot working on the microstructures of TC11/Ti2 Al Nb dual-alloy joints welded by electron beam welding(EBW) process was investigated. The tensile tests were performed at room temperature for specimens...The influence of hot working on the microstructures of TC11/Ti2 Al Nb dual-alloy joints welded by electron beam welding(EBW) process was investigated. The tensile tests were performed at room temperature for specimens before and after thermal exposure. The results show that the fusion zone of TC11/Ti2 Al Nb dual-alloy joint welded by EBW is mainly composed of β phase. After deformation and heat treatment, the grain boundaries of the as-cast alloy are broken and the fusion zone mainly consists of β, α2and α phases. The fusion zone performs poor property in the tensile test. Specimens before and after thermal exposure all fail in this area under different deformation conditions. The ultimate tensile strength of specimens after heat treatment is up to 1190 MPa at room temperature. The joints by water quenching after deformation have better plasticity with an elongation up to 4.4%. After thermal exposure at 500 °C for 100 h, the tensile strength of the specimen slightly rises while the ductility changes a little. SEM observation shows that the fracture mechanism is predominantly transgranular under different deformation conditions.展开更多
Polyimide matrix composites interpenetrated with foamed copper were prepared via pressure impregnation and vacuum immersion to focus on their thermostability, mechanical and tribological behaviors as sliding electrica...Polyimide matrix composites interpenetrated with foamed copper were prepared via pressure impregnation and vacuum immersion to focus on their thermostability, mechanical and tribological behaviors as sliding electrical contact materials. The results show that the interpenetrating phase composites（IPC） are very heat-resistant and exhibit higher hardness as well as bending strength, when compared with homologous polyimide matrix composites without foamed copper. Sliding electrical contact property of the materials is also remarkably improved, from the point of contact voltage drops. Moreover, it is believed that fatigue wear is the main mechanism involved, along with slight abrasive wear and oxidation wear. The better abrasive resistance of the IPC under different testing conditions was detected, which was mainly attributed to the successful hybrid of foamed copper and polyimide.展开更多
\ According to the analysis of the residual products by thermogravimetric analysis (TGA), the thermal decomposition process of cefazolin sodium (CEZ·Na) was thought to be similar to the degradation in solid sta...\ According to the analysis of the residual products by thermogravimetric analysis (TGA), the thermal decomposition process of cefazolin sodium (CEZ·Na) was thought to be similar to the degradation in solid state in its storage time. This laid a foundation for estimating the relative chemical stability of the drug by determination of its decomposition kinetics using TGA. Although the observed thermal decomposition kinetics of CEZ·Na was complex, a conversion level of 1% was chosen for evaluation of the stability of CEZ·Na crystalline since the mechanism here was more likely to be that of the actual product failure. The evaluation results suggested that the α form of CEZ·Na had the best stability and the amorphous one was the least stable one among α form, dehydrated α form and amorphous form.展开更多
In this work,a sponge-like polysulfonamide(PSA)/SiO_2 composite membrane is unprecedentedly prepared by the phase inversion method,and successfully demonstrated as a novel separator of lithium-ion batteries(LIBs).Comp...In this work,a sponge-like polysulfonamide(PSA)/SiO_2 composite membrane is unprecedentedly prepared by the phase inversion method,and successfully demonstrated as a novel separator of lithium-ion batteries(LIBs).Compared to the commercial polypropylene(PP) separator,the sponge-like PSA/SiO_2 composite possesses better physical and electrochemical properties,such as higher porosity,ionic conductivity,thermal stability and flame retarding ability.The LiCoO_2/Li half-cells using the sponge-like composite separator demonstrate superior rate capability and cyclability over those using the commercial PP separator.Moreover,the sponge-like composite separator can ensure the normal operation of LiCoO_2/Li half-cell at an extremely high temperature of 90 °C,while the commercial PP separator cannot.All these encouraging results suggest that this phase inversion based sponge-like PSA/SiO_2 composite separator is really a promising separator for high performance LIBs.展开更多
Thermal stability and thermal decomposition kinetics of 1-butyl-3-methylimidazolium dicyanamide ([bmin+][N(CN) ]2-) were investigated using both isothermal and non-isothermal thermogravimetric analyses (TGA) under hig...Thermal stability and thermal decomposition kinetics of 1-butyl-3-methylimidazolium dicyanamide ([bmin+][N(CN) ]2-) were investigated using both isothermal and non-isothermal thermogravimetric analyses (TGA) under high pure nitrogen as carrier gas. The long-term thermogravimetric studies revealed that the highest temperature used should be 110 °C, at which [bmin+][N(CN)2-] lost less than 10% by mass in 10 hours. The non-isothermal activation energy values determined using Friedman and ASTM methods were (150±13) and (147±2) kJ·mol –1 , respectively. Multivariate non-linear-regression methods showed that expanded Fn and CnB models were the best fit models with highest correlation coefficient of 0.9994, and the apparent activation energies were consistent with iso-conversional methods.展开更多
Multiple direction compression(MDC)was conducted on sintered pure tungsten(99.9%,mass fraction)with different reductions at 1423 K.The microstructure,microhardness and thermal stability of the MDC-processed samples we...Multiple direction compression(MDC)was conducted on sintered pure tungsten(99.9%,mass fraction)with different reductions at 1423 K.The microstructure,microhardness and thermal stability of the MDC-processed samples were studied by X-ray diffraction(XRD),electron backscattered diffraction(EBSD)and differential scanning calorimetry(DSC)compared with those of the initial sintered tungsten.The results show that the dislocation density increases significantly with the reduction of MDC,ranging from 3.08×1014 m-2 for the initial sintered tungsten to 8.08×1014 m-2 for the tungsten after MDC with the reduction of 50%.The average grain size decreases from 83.8 to 14.7μm and the microhardness value increases from HV0.2 417 to HV0.2 521.The recrystallization temperature for the tungsten samples processed by MDC is approximately constant at around 1600 K.The MDC of sintered tungsten results in a decrease of grain size concurrent with an increase of uniformly distributed nucleation sites,which leads to the improvement of the thermal stability.展开更多
We study quantum motion around a classical heteroclinic point of a single trapped ion interacting with a strong laser standing wave. We construct a set of exact coherent states of the quantum system and from the exact...We study quantum motion around a classical heteroclinic point of a single trapped ion interacting with a strong laser standing wave. We construct a set of exact coherent states of the quantum system and from the exact solutions reveal that quantum signatures of chaos can be induced by the adiabatic interaction between the trapped ion and the laser standing wave, where the quantum expectation values of position and momentum correspond to the classically chaotic orbit. The chaotic region on the phase space is illustrated. The energy crossing and quantum resonance in time evolution and the exponentially increased Heisenberg uncertainty are found. The results suggest a theoretical scheme for controlling the unstable regular and chaotic motions.展开更多
The physicochemical features of phosphorus-modified ZSM-5 zeolites (SiO2/Al2O3 molar ratio is 25) were characterized by XRD(X-ray diffraction), BET(Brunauer, Emmett and Teller spcific surface area measurement), NH3-TP...The physicochemical features of phosphorus-modified ZSM-5 zeolites (SiO2/Al2O3 molar ratio is 25) were characterized by XRD(X-ray diffraction), BET(Brunauer, Emmett and Teller spcific surface area measurement), NH3-TPD(ammonia temperature-programmed desorption) and MASNMR(magic angle spinning nuclear magnetic resonance), and the performance on catalytic pyrolysis to produce ethylene was investigated with a light hydrocarbon fixed bed micro-reactor with n-octane as feed. The results show that the acid site density, acid intensity and hydrothermal stability of ZSM-5 zeolite were improved by phosphorus modification. When P2O5 content in ZSM-5 zeolite is higher than 2.5%, phosphorus modification can prevent ZSM-5 zeolite crystal structure transformation from orthorhombic to monoclinic. In addition, the dealumination of ZSM-5 zeolite framework was moderated by phosphorus modification under high temperature hydrothermal treatment. The results of n-octane pyrolysis on phosphorus-modified ZSM-5 zeolites show that ethylene yields of zeolites with different phosphorus content are almost the same under the same n-octane conversion. However, the modified zeolites with higher pyrolysis activity give lower yield of propene, butene and total olefin than lower pyrolysis activity under the same n-octane conversion.展开更多
The structural properties, heats of formation, elastic properties, and electronic structures of four compositions of binary A1-Li intermetallics, A13Li, A1Li, A12Li3, and A14Li9, are ana- lyzed in detail by using dens...The structural properties, heats of formation, elastic properties, and electronic structures of four compositions of binary A1-Li intermetallics, A13Li, A1Li, A12Li3, and A14Li9, are ana- lyzed in detail by using density functional theory. The calculated formation heats indicate a strong chemical interaction between A1 and Li for all the A1-Li intermetallics. In partic- ular, in the Li-rich A1-Li compounds, the thermodynamic stability of intermetallics linearly decreases with increasing concentration of.Li. According to the computational single crystal elastic constants, all the four A1-Li intermetallic compounds considered here are mechani- cally stable. The polycrystalline elastic modulus and Poisson＇s ratio have been deduced by using Voigt, Reuss, and Hill approximations, and the calculated ratios of bulk modulus to shear modulus indicate that the four compositions of binary A1-Li intermetallics are brittle materials. With the increase of Li concentration, the bulk modulus of A1-Li intermetallics decreases in a linear manner.展开更多
The stability of aggregates in the surface soil is crucial to soil erosion and runoff generation. Thus, to understand the stability and the breakdown mechanisms of soil aggregates as well as the relationship between a...The stability of aggregates in the surface soil is crucial to soil erosion and runoff generation. Thus, to understand the stability and the breakdown mechanisms of soil aggregates as well as the relationship between aggregate stability and selected soil chemical properties, such as different forms of Fe and Al oxides, organic matter, CEC and clay content, the aggregates of slightly and severely eroded red soils derived from Quaternary red clay in subtropical China were analyzed using the routine wet sieving…展开更多
The thermal properties of a thermal barrier coating （TBC） system comprised of BaO-MgO-SiO_2 based glass-ceramic bond coating, 8% （mass fraction） yttria stabilized zirconia （8YSZ） top coating and nimonic alloy su...The thermal properties of a thermal barrier coating （TBC） system comprised of BaO-MgO-SiO_2 based glass-ceramic bond coating, 8% （mass fraction） yttria stabilized zirconia （8YSZ） top coating and nimonic alloy substrate were evaluated. The thermal diffusivity and thermal conductivity of the TBC coated substrate were lower than those of bare substrate and glass-ceramic coated substrate under identical conditions. The specific heat capacity, thermal diffusivity and thermal conductivity of the TBC coated substrate increase with the increase of the temperature. Further, it is observed that the thermal conductivity of the TBC system decreases with the increase in the top coating thickness.展开更多
Powder metallurgy processes are suitable to produce form-stable solid−liquid phase change materials from miscibility gap alloys.They allow to obtain a composite metallic material with good dispersion of low-melting ac...Powder metallurgy processes are suitable to produce form-stable solid−liquid phase change materials from miscibility gap alloys.They allow to obtain a composite metallic material with good dispersion of low-melting active phase particles in a high-melting passive matrix,preventing leakage of the particles during phase transition and,therefore,increasing the stability of thermal response.Also,the matrix provides structural properties.The aim of this work is to combine conventional powder mixing techniques(simple mixing and ball milling)to improve active phase isolation and mechanical properties of an Al−Sn alloy.As matter of fact,ball milling of Sn powder allows to reduce hardness difference with Al powder;moreover,ball milling of the two powders together results in fine microstructure with improved mechanical properties.In addition,different routes applied showed that thermal response depends on the microstructure and,in particular,on the particle size of the active phase.In more detail,coarse active phase particles provide a fast heat release with small undercooling,while small particles solidify more slowly in a wide range of temperature.On the other hand,melting and,consequently,heat storage are independent of the particle size of the active phase.This potentially allows to“tailor”the thermal response by producing alloys with suitable microstructure.展开更多
The ultra-stable zeolite DASY-0.0 was prepared by hydrothermal method in commercial scale. Its structure was further modified via the treatment for cleaning of pores （CP）. The zeolite samples before and after CP tre...The ultra-stable zeolite DASY-0.0 was prepared by hydrothermal method in commercial scale. Its structure was further modified via the treatment for cleaning of pores （CP）. The zeolite samples before and after CP treating were analyzed and characterized by XRF, XRD, NMR, IR, BET and DTA. The results showed that, in comparison with the conventional ultra-stable zeolite DASY-0.0 prepared by the hydrothermal process, the CP-modified zeolite SOY0 exhibited a higher relative crystallinity, a larger surface area and pore volume, a higher thermal stability and contained less amorohous non-framework A1.展开更多
This paper reports the effect of sol size on nanofiltration performances of sol–gel derived microporous zirconia membranes. Microstructure, pure water flux, molecular weight cut-off(MWCO) and salt retention of zircon...This paper reports the effect of sol size on nanofiltration performances of sol–gel derived microporous zirconia membranes. Microstructure, pure water flux, molecular weight cut-off(MWCO) and salt retention of zirconia membranes derived from zirconia sols with different sizes were characterized. Thermal evolution, phase composition, microstructure and chemical stability of unsupported zirconia membranes(powder) were determined by thermogravimetric and differential thermal analysis, X-ray diffraction, nitrogen adsorption–desorption and static solubility measurements. Results show that nanofiltration performance of zirconia membranes is highly dependent on sol size. The sol with an average size of 3.8 nm, which is smaller than the pore size of the γ-Al2O3support(pore size: 5–6 nm), forms a discontinuous zirconia separation layer because of excessive penetration of sol into the support. This zirconia membrane displays a MWCO value towards polyethylene glycol higher than 4000 Da. A smooth and defect-free zirconia membrane with a MWCO value of 1195 Da(pore size: 1.75 nm) and relative high retention rates towards Mg Cl2(76%) and Ca Cl2(64%) was successfully fabricated by dip-coating the sol with an appropriate size of 8.6 nm. Zirconia sol with an average size of 12 nm exhibits colloidal nature and forms a zirconia membrane with a MWCO value of 2332 Da(pore size: 2.47 nm). This promising microporous zirconia membrane presents sufficiently high chemical stability in a wide p H range of 1–12.展开更多
基金National Natural Science Foundation of China(52172070)Jiangxi Provincial Natural Science Foundation(20242BAB25222)Jiangxi Provincial Graduate Innovation Special Fund Project(YC2022-S882 and YC2023-S808).
文摘Lead-free low melting glasses,ZnO-CuO-Bi_(2)O_(3)-B_(2)O_(3)-SiO_(2)system,with fixed contents of 15 mol%CuO and 20 mol%Bi_(2)O_(3),were prepared by using melt cooling method.Structure and thermal properties of the glasses were studied by using X-ray diffractometer(XRD),infrared spectrometer(FIT-IR),thermal dilatometer and differential thermal analyzer(DTA).Chemical durability of the glasses was studied by using dissolution rate method.Wettability of glasses on substrate was tested by using button sintering experiment.It is found that alkaline resistance of the glass solders is lower than that of plate glass and the water resistance is comparable with that of plate glass.The sealing temperatures are Ts=445-490℃,while the average thermal expansion coefficient from room temperature to 300℃is in the range of(65-82)×10^(−7)℃^(−1).At sealing temperature,the glass solders have good wettability on plate glass or alumina substrate.They are not crystallized even sintered at the sealing temperature for 30 min.The solder glasses are suitable for sealing plate glass,alumina and other inorganic non-metallic materials.
基金Project(51175431)supported by the National Natural Science Foundation of China
文摘The influence of hot working on the microstructures of TC11/Ti2 Al Nb dual-alloy joints welded by electron beam welding(EBW) process was investigated. The tensile tests were performed at room temperature for specimens before and after thermal exposure. The results show that the fusion zone of TC11/Ti2 Al Nb dual-alloy joint welded by EBW is mainly composed of β phase. After deformation and heat treatment, the grain boundaries of the as-cast alloy are broken and the fusion zone mainly consists of β, α2and α phases. The fusion zone performs poor property in the tensile test. Specimens before and after thermal exposure all fail in this area under different deformation conditions. The ultimate tensile strength of specimens after heat treatment is up to 1190 MPa at room temperature. The joints by water quenching after deformation have better plasticity with an elongation up to 4.4%. After thermal exposure at 500 °C for 100 h, the tensile strength of the specimen slightly rises while the ductility changes a little. SEM observation shows that the fracture mechanism is predominantly transgranular under different deformation conditions.
文摘Polyimide matrix composites interpenetrated with foamed copper were prepared via pressure impregnation and vacuum immersion to focus on their thermostability, mechanical and tribological behaviors as sliding electrical contact materials. The results show that the interpenetrating phase composites（IPC） are very heat-resistant and exhibit higher hardness as well as bending strength, when compared with homologous polyimide matrix composites without foamed copper. Sliding electrical contact property of the materials is also remarkably improved, from the point of contact voltage drops. Moreover, it is believed that fatigue wear is the main mechanism involved, along with slight abrasive wear and oxidation wear. The better abrasive resistance of the IPC under different testing conditions was detected, which was mainly attributed to the successful hybrid of foamed copper and polyimide.
文摘\ According to the analysis of the residual products by thermogravimetric analysis (TGA), the thermal decomposition process of cefazolin sodium (CEZ·Na) was thought to be similar to the degradation in solid state in its storage time. This laid a foundation for estimating the relative chemical stability of the drug by determination of its decomposition kinetics using TGA. Although the observed thermal decomposition kinetics of CEZ·Na was complex, a conversion level of 1% was chosen for evaluation of the stability of CEZ·Na crystalline since the mechanism here was more likely to be that of the actual product failure. The evaluation results suggested that the α form of CEZ·Na had the best stability and the amorphous one was the least stable one among α form, dehydrated α form and amorphous form.
基金Supported by the funding from "135" Projects Fund of CAS-QIBEBT Director Innovation FoundationThink-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research+3 种基金Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technologythe Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105)National Natural Science Foundation of China(51502319)Shandong Provincial Natural Science Foundation(ZR2016BQ18)
文摘In this work,a sponge-like polysulfonamide(PSA)/SiO_2 composite membrane is unprecedentedly prepared by the phase inversion method,and successfully demonstrated as a novel separator of lithium-ion batteries(LIBs).Compared to the commercial polypropylene(PP) separator,the sponge-like PSA/SiO_2 composite possesses better physical and electrochemical properties,such as higher porosity,ionic conductivity,thermal stability and flame retarding ability.The LiCoO_2/Li half-cells using the sponge-like composite separator demonstrate superior rate capability and cyclability over those using the commercial PP separator.Moreover,the sponge-like composite separator can ensure the normal operation of LiCoO_2/Li half-cell at an extremely high temperature of 90 °C,while the commercial PP separator cannot.All these encouraging results suggest that this phase inversion based sponge-like PSA/SiO_2 composite separator is really a promising separator for high performance LIBs.
基金Supported by the National Natural Science Foundation of China （20703014） the Outstanding Youth Foundation of HenanProvince （074100510005）
文摘Thermal stability and thermal decomposition kinetics of 1-butyl-3-methylimidazolium dicyanamide ([bmin+][N(CN) ]2-) were investigated using both isothermal and non-isothermal thermogravimetric analyses (TGA) under high pure nitrogen as carrier gas. The long-term thermogravimetric studies revealed that the highest temperature used should be 110 °C, at which [bmin+][N(CN)2-] lost less than 10% by mass in 10 hours. The non-isothermal activation energy values determined using Friedman and ASTM methods were (150±13) and (147±2) kJ·mol –1 , respectively. Multivariate non-linear-regression methods showed that expanded Fn and CnB models were the best fit models with highest correlation coefficient of 0.9994, and the apparent activation energies were consistent with iso-conversional methods.
基金Project(51675154)supported by the National Natural Science Foundation of ChinaProject(2014GB121000)supported by the National Magnetic Confinement Fusion Program,China
文摘Multiple direction compression(MDC)was conducted on sintered pure tungsten(99.9%,mass fraction)with different reductions at 1423 K.The microstructure,microhardness and thermal stability of the MDC-processed samples were studied by X-ray diffraction(XRD),electron backscattered diffraction(EBSD)and differential scanning calorimetry(DSC)compared with those of the initial sintered tungsten.The results show that the dislocation density increases significantly with the reduction of MDC,ranging from 3.08×1014 m-2 for the initial sintered tungsten to 8.08×1014 m-2 for the tungsten after MDC with the reduction of 50%.The average grain size decreases from 83.8 to 14.7μm and the microhardness value increases from HV0.2 417 to HV0.2 521.The recrystallization temperature for the tungsten samples processed by MDC is approximately constant at around 1600 K.The MDC of sintered tungsten results in a decrease of grain size concurrent with an increase of uniformly distributed nucleation sites,which leads to the improvement of the thermal stability.
基金The project supported by National Natural Science Foundation of China under Grant No.10575034the Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics of China under Grant No.T152504
文摘We study quantum motion around a classical heteroclinic point of a single trapped ion interacting with a strong laser standing wave. We construct a set of exact coherent states of the quantum system and from the exact solutions reveal that quantum signatures of chaos can be induced by the adiabatic interaction between the trapped ion and the laser standing wave, where the quantum expectation values of position and momentum correspond to the classically chaotic orbit. The chaotic region on the phase space is illustrated. The energy crossing and quantum resonance in time evolution and the exponentially increased Heisenberg uncertainty are found. The results suggest a theoretical scheme for controlling the unstable regular and chaotic motions.
文摘The physicochemical features of phosphorus-modified ZSM-5 zeolites (SiO2/Al2O3 molar ratio is 25) were characterized by XRD(X-ray diffraction), BET(Brunauer, Emmett and Teller spcific surface area measurement), NH3-TPD(ammonia temperature-programmed desorption) and MASNMR(magic angle spinning nuclear magnetic resonance), and the performance on catalytic pyrolysis to produce ethylene was investigated with a light hydrocarbon fixed bed micro-reactor with n-octane as feed. The results show that the acid site density, acid intensity and hydrothermal stability of ZSM-5 zeolite were improved by phosphorus modification. When P2O5 content in ZSM-5 zeolite is higher than 2.5%, phosphorus modification can prevent ZSM-5 zeolite crystal structure transformation from orthorhombic to monoclinic. In addition, the dealumination of ZSM-5 zeolite framework was moderated by phosphorus modification under high temperature hydrothermal treatment. The results of n-octane pyrolysis on phosphorus-modified ZSM-5 zeolites show that ethylene yields of zeolites with different phosphorus content are almost the same under the same n-octane conversion. However, the modified zeolites with higher pyrolysis activity give lower yield of propene, butene and total olefin than lower pyrolysis activity under the same n-octane conversion.
文摘The structural properties, heats of formation, elastic properties, and electronic structures of four compositions of binary A1-Li intermetallics, A13Li, A1Li, A12Li3, and A14Li9, are ana- lyzed in detail by using density functional theory. The calculated formation heats indicate a strong chemical interaction between A1 and Li for all the A1-Li intermetallics. In partic- ular, in the Li-rich A1-Li compounds, the thermodynamic stability of intermetallics linearly decreases with increasing concentration of.Li. According to the computational single crystal elastic constants, all the four A1-Li intermetallic compounds considered here are mechani- cally stable. The polycrystalline elastic modulus and Poisson＇s ratio have been deduced by using Voigt, Reuss, and Hill approximations, and the calculated ratios of bulk modulus to shear modulus indicate that the four compositions of binary A1-Li intermetallics are brittle materials. With the increase of Li concentration, the bulk modulus of A1-Li intermetallics decreases in a linear manner.
文摘The stability of aggregates in the surface soil is crucial to soil erosion and runoff generation. Thus, to understand the stability and the breakdown mechanisms of soil aggregates as well as the relationship between aggregate stability and selected soil chemical properties, such as different forms of Fe and Al oxides, organic matter, CEC and clay content, the aggregates of slightly and severely eroded red soils derived from Quaternary red clay in subtropical China were analyzed using the routine wet sieving…
文摘The thermal properties of a thermal barrier coating （TBC） system comprised of BaO-MgO-SiO_2 based glass-ceramic bond coating, 8% （mass fraction） yttria stabilized zirconia （8YSZ） top coating and nimonic alloy substrate were evaluated. The thermal diffusivity and thermal conductivity of the TBC coated substrate were lower than those of bare substrate and glass-ceramic coated substrate under identical conditions. The specific heat capacity, thermal diffusivity and thermal conductivity of the TBC coated substrate increase with the increase of the temperature. Further, it is observed that the thermal conductivity of the TBC system decreases with the increase in the top coating thickness.
文摘Powder metallurgy processes are suitable to produce form-stable solid−liquid phase change materials from miscibility gap alloys.They allow to obtain a composite metallic material with good dispersion of low-melting active phase particles in a high-melting passive matrix,preventing leakage of the particles during phase transition and,therefore,increasing the stability of thermal response.Also,the matrix provides structural properties.The aim of this work is to combine conventional powder mixing techniques(simple mixing and ball milling)to improve active phase isolation and mechanical properties of an Al−Sn alloy.As matter of fact,ball milling of Sn powder allows to reduce hardness difference with Al powder;moreover,ball milling of the two powders together results in fine microstructure with improved mechanical properties.In addition,different routes applied showed that thermal response depends on the microstructure and,in particular,on the particle size of the active phase.In more detail,coarse active phase particles provide a fast heat release with small undercooling,while small particles solidify more slowly in a wide range of temperature.On the other hand,melting and,consequently,heat storage are independent of the particle size of the active phase.This potentially allows to“tailor”the thermal response by producing alloys with suitable microstructure.
文摘The ultra-stable zeolite DASY-0.0 was prepared by hydrothermal method in commercial scale. Its structure was further modified via the treatment for cleaning of pores （CP）. The zeolite samples before and after CP treating were analyzed and characterized by XRF, XRD, NMR, IR, BET and DTA. The results showed that, in comparison with the conventional ultra-stable zeolite DASY-0.0 prepared by the hydrothermal process, the CP-modified zeolite SOY0 exhibited a higher relative crystallinity, a larger surface area and pore volume, a higher thermal stability and contained less amorohous non-framework A1.
基金Supported by the National Natural Science Foundation of China(20906047,21276123)the National High Technology Research and Development Program of China(2012AA03A606)+3 种基金State Key Laboratory of Materials-Oriented Chemical Engineering(ZK201002)the Natural Science Research Plan of Jiangsu Universities(11KJB530006)the"Summit of the Six Top Talents"Program of Jiangsu Provincea Project Funded by the Priority Academic Program development of Jiangsu Higher Education Institutions(PAPD)
文摘This paper reports the effect of sol size on nanofiltration performances of sol–gel derived microporous zirconia membranes. Microstructure, pure water flux, molecular weight cut-off(MWCO) and salt retention of zirconia membranes derived from zirconia sols with different sizes were characterized. Thermal evolution, phase composition, microstructure and chemical stability of unsupported zirconia membranes(powder) were determined by thermogravimetric and differential thermal analysis, X-ray diffraction, nitrogen adsorption–desorption and static solubility measurements. Results show that nanofiltration performance of zirconia membranes is highly dependent on sol size. The sol with an average size of 3.8 nm, which is smaller than the pore size of the γ-Al2O3support(pore size: 5–6 nm), forms a discontinuous zirconia separation layer because of excessive penetration of sol into the support. This zirconia membrane displays a MWCO value towards polyethylene glycol higher than 4000 Da. A smooth and defect-free zirconia membrane with a MWCO value of 1195 Da(pore size: 1.75 nm) and relative high retention rates towards Mg Cl2(76%) and Ca Cl2(64%) was successfully fabricated by dip-coating the sol with an appropriate size of 8.6 nm. Zirconia sol with an average size of 12 nm exhibits colloidal nature and forms a zirconia membrane with a MWCO value of 2332 Da(pore size: 2.47 nm). This promising microporous zirconia membrane presents sufficiently high chemical stability in a wide p H range of 1–12.
