The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multip...The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures.展开更多
This paper developed a statistical damage constitutive model for deep rock by considering the effects of external load and thermal treatment temperature based on the distortion energy.The model parameters were determi...This paper developed a statistical damage constitutive model for deep rock by considering the effects of external load and thermal treatment temperature based on the distortion energy.The model parameters were determined through the extremum features of stress−strain curve.Subsequently,the model predictions were compared with experimental results of marble samples.It is found that when the treatment temperature rises,the coupling damage evolution curve shows an S-shape and the slope of ascending branch gradually decreases during the coupling damage evolution process.At a constant temperature,confining pressure can suppress the expansion of micro-fractures.As the confining pressure increases the rock exhibits ductility characteristics,and the shape of coupling damage curve changes from an S-shape into a quasi-parabolic shape.This model can well characterize the influence of high temperature on the mechanical properties of deep rock and its brittleness-ductility transition characteristics under confining pressure.Also,it is suitable for sandstone and granite,especially in predicting the pre-peak stage and peak stress of stress−strain curve under the coupling action of confining pressure and high temperature.The relevant results can provide a reference for further research on the constitutive relationship of rock-like materials and their engineering applications.展开更多
Coupled thermo-mechanical model was used to investigate the effects of the pin diameter, the shoulder diameter and the in conical angle on the heat generations, the material deformations and the energy histories in fr...Coupled thermo-mechanical model was used to investigate the effects of the pin diameter, the shoulder diameter and the in conical angle on the heat generations, the material deformations and the energy histories in friction stir welding（FSW） of AA2024-T3 alloy. Results indicate that the shoulder-plate contact area takes more important contribution to the heat generation than the pin-plate contact area. The increase of the shoulder diameter or the decrease of the pin diameter can lead to the increase of the welding temperature in FSW, but the change of shoulder size is more important. Compared to the cases in FSW of AA6061-T6, the input power is obviously increased in FSW of AA2024-T3 and the ratio of the plastic dissipation to the friction dissipation becomes decreased.展开更多
A thermo-mechanical coupled particle model for simulation of thermally-induced rock damage based on the particle simulation method was proposed.The simulation results of three verification examples,for which the analy...A thermo-mechanical coupled particle model for simulation of thermally-induced rock damage based on the particle simulation method was proposed.The simulation results of three verification examples,for which the analytical solutions are available,demonstrate the correctness and usefulness of the thermo-mechanical coupled particle model.This model is applied to simulating an application example with two cases：one is temperature-independent elastic modulus and strength,while the other is temperature-dependent elastic modulus and strength.The related simulation results demonstrate that microscopic crack initiation and propagation process with consideration of temperature-independent and temperature-dependent elastic modulus and strength are different and therefore,the corresponding macroscopic failure patterns of rock are also different.On the contrary,considering the temperature-dependent elastic modulus and strength has no or little effect on the heating conduction behavior.Numerical results,which are obtained by using the proposed model with temperature-dependent elastic modulus and strength,agree well with the experimental results.This also reveals that the rock subjected to heating experiences much more cracking than the rock subjected to cooling.展开更多
The interfacial heat transfer coefficient between hot profile surface and cooling water was determined by using inverse heat conduction model combined with end quenching experiment. Then, a Deform-3 D thermo-mechanica...The interfacial heat transfer coefficient between hot profile surface and cooling water was determined by using inverse heat conduction model combined with end quenching experiment. Then, a Deform-3 D thermo-mechanical coupling model for simulating the on-line water quenching of extruded profile with unequal and large thicknesses was developed. The temperature field, residual stress field and distortion of profile during quenching were investigated systematically. The results show that heat transfer coefficient increases as water flow rate increases. The peak heat transfer coefficient with higher water flow rates appears at lower interface temperatures. The temperature distribution across the cross-section of profile during quenching is severe nonuniform and the maximum temperature difference is 300 ℃ at quenching time of 3.49 s. The temperature difference through the thickness of different parts of profile first increases sharply to a maximum value, and then gradually decreases. The temperature gradient increases obviously with the increase of thickness of parts. After quenching, there exist large residual stresses on the inner side of joints of profile and the two ends of part with thickness of 10 mm. The profile presents a twisting-type distortion across the cross-section under non-uniform cooling and the maximum twisting angle during quenching is 2.78°.展开更多
A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the see...A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the seepage field and the concentration field were double,and the influences of sets,spaces,angles,continuity ratios,stiffnesses of fractures on the constitutive relationship of the medium were considered.Also,the relative two-dimensional program of finite element method was developed.Taking a hypothetical nuclear waste repository as a calculation example,the case in which the rockmass was unsaturated dual-porosity medium and radioactive nuclide leak was simulated numerically,and the temperatures,negative pore pressures,saturations,flow velocities,nuclide concentrations and principal stresses in the rockmass were investigated.The results show that the negative pore pressures and nuclide concentrations in the porosity and fracture present different changes and distributions.Even though the saturation degree in porosity is only about 1/10 that in fracture,the flow velocity of underground water in fracture is about three times that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity.The value of nuclide concentration in fracture is close to that in porosity.展开更多
Based on twin-roll casting, a cast-rolling force model was proposed to predict the rolling force in the bimetal solid-liquid cast-rolling bonding(SLCRB) process. The solid-liquid bonding zone was assumed to be below t...Based on twin-roll casting, a cast-rolling force model was proposed to predict the rolling force in the bimetal solid-liquid cast-rolling bonding(SLCRB) process. The solid-liquid bonding zone was assumed to be below the kiss point(KP). The deformation resistance of the liquid zone was ignored. Then, the calculation model was derived. A 2D thermal-flow coupled simulation was established to provide a basis for the parameters in the model, and then the rolling forces of the Cu/Al clad strip at different rolling speeds were calculated. Meanwhile, through measurement experiments, the accuracy of the model was verified. The influence of the rolling speed, the substrate strip thickness, and the material on the rolling force was obtained. The results indicate that the rolling force decreases with the increase of the rolling speed and increases with the increase of the thickness and thermal conductivity of the substrate strip. The rolling force is closely related to the KP height. Therefore, the formulation of reasonable process parameters to control the KP height is of great significance to the stability of cast-rolling forming.展开更多
The first wall of the fusion reactor is a plasma-facing component and is a key link to maintain the integrity of structure during thermal shock induced by plasma disruptions. Be and W/Cu functionally graded materials ...The first wall of the fusion reactor is a plasma-facing component and is a key link to maintain the integrity of structure during thermal shock induced by plasma disruptions. Be and W/Cu functionally graded materials are two kinds of important plas- ma-facing materials （PFM） of first wall in fusion reactor currently. Previous researches seldom comparatively evaluated the normal servicing and heat shock resistance performance of first walls with those two kinds of PFMs. And also there lacks cou- pled thermal/mechanical analysis on the heat shock process in consideration of multiple thermal/mechanical phenomena, such as material melting, solidification, evaporation, etc., which is significant to further understand the heat shock damage mecha- nism of the first wall with different PFMs. With the aim of learning more detailed mechanical mechanism of thermal shock damage and then improving the thermal shock resistance performance of different first wall designs, the coupled ther- mal/mechanical response of two typical ITER-like first walls with PFM of Be and functionally graded W-Cu respectively un- der the heat shock of 1 2 GW/m2 are computed by the finite element method. Special considerations of elastic-plastic defor- mation, material melting, and solidification are included in numerical models and methods. The mechanical response behaviors of different structures and materials under the normal servicing operation as well as plasma disruption conditions are analyzed and investigated comparatively. The results reveal that heat is mainly deposited on the PFM layer in thc high energy shock pulse induced by plasma disruptions, resulting in complex thermal stress change as well as mechanical itTeversible damage of thermal elastic and plastic expansion, contraction and yielding. Compared with the first wall with Be PFM, which mitigates the damages from heat shock at most only in the PFM layer with cost of whole PFM layer plastic yielding, the first wall with graded W-Cu PFM is demonstrated to be possessed both of higher heat shock resistance performance and normal servicing performance, provided its material gradient and cooling capacity are well optimized under practical loading conditions.展开更多
基金funded by the National Natural Science Foundation of China(Grant No.12272217)。
文摘The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures.
基金Project(11272119)supported by the National Natural Science Foundation of China。
文摘This paper developed a statistical damage constitutive model for deep rock by considering the effects of external load and thermal treatment temperature based on the distortion energy.The model parameters were determined through the extremum features of stress−strain curve.Subsequently,the model predictions were compared with experimental results of marble samples.It is found that when the treatment temperature rises,the coupling damage evolution curve shows an S-shape and the slope of ascending branch gradually decreases during the coupling damage evolution process.At a constant temperature,confining pressure can suppress the expansion of micro-fractures.As the confining pressure increases the rock exhibits ductility characteristics,and the shape of coupling damage curve changes from an S-shape into a quasi-parabolic shape.This model can well characterize the influence of high temperature on the mechanical properties of deep rock and its brittleness-ductility transition characteristics under confining pressure.Also,it is suitable for sandstone and granite,especially in predicting the pre-peak stage and peak stress of stress−strain curve under the coupling action of confining pressure and high temperature.The relevant results can provide a reference for further research on the constitutive relationship of rock-like materials and their engineering applications.
基金Project(NCET-12-0075)supported by the Program for New Century Excellent Talents in University,ChinaProject supported by the Fundamental Research Funds for the Central Universities,China+2 种基金Projects(11172057,11232003)supported by the National Natural Science Foundation of ChinaProject(2011CB013401)supported by the National Basic Research Program of ChinaProject(2012AA050901)supported by the National High-Tech Research and Development Program of China
文摘Coupled thermo-mechanical model was used to investigate the effects of the pin diameter, the shoulder diameter and the in conical angle on the heat generations, the material deformations and the energy histories in friction stir welding（FSW） of AA2024-T3 alloy. Results indicate that the shoulder-plate contact area takes more important contribution to the heat generation than the pin-plate contact area. The increase of the shoulder diameter or the decrease of the pin diameter can lead to the increase of the welding temperature in FSW, but the change of shoulder size is more important. Compared to the cases in FSW of AA6061-T6, the input power is obviously increased in FSW of AA2024-T3 and the ratio of the plastic dissipation to the friction dissipation becomes decreased.
基金Project(41372338)supported by the National Natural Science Foundation of China
文摘A thermo-mechanical coupled particle model for simulation of thermally-induced rock damage based on the particle simulation method was proposed.The simulation results of three verification examples,for which the analytical solutions are available,demonstrate the correctness and usefulness of the thermo-mechanical coupled particle model.This model is applied to simulating an application example with two cases：one is temperature-independent elastic modulus and strength,while the other is temperature-dependent elastic modulus and strength.The related simulation results demonstrate that microscopic crack initiation and propagation process with consideration of temperature-independent and temperature-dependent elastic modulus and strength are different and therefore,the corresponding macroscopic failure patterns of rock are also different.On the contrary,considering the temperature-dependent elastic modulus and strength has no or little effect on the heating conduction behavior.Numerical results,which are obtained by using the proposed model with temperature-dependent elastic modulus and strength,agree well with the experimental results.This also reveals that the rock subjected to heating experiences much more cracking than the rock subjected to cooling.
基金Project(51605234)supported by the National Natural Science Foundation of ChinaProjects(2019JJ50510,2019JJ70077)supported by the Natural Science Foundation of Hunan Province,ChinaProjects(18B285,18B552)supported by Scientific Research Fund of Hunan Provincial Education Department,China。
文摘The interfacial heat transfer coefficient between hot profile surface and cooling water was determined by using inverse heat conduction model combined with end quenching experiment. Then, a Deform-3 D thermo-mechanical coupling model for simulating the on-line water quenching of extruded profile with unequal and large thicknesses was developed. The temperature field, residual stress field and distortion of profile during quenching were investigated systematically. The results show that heat transfer coefficient increases as water flow rate increases. The peak heat transfer coefficient with higher water flow rates appears at lower interface temperatures. The temperature distribution across the cross-section of profile during quenching is severe nonuniform and the maximum temperature difference is 300 ℃ at quenching time of 3.49 s. The temperature difference through the thickness of different parts of profile first increases sharply to a maximum value, and then gradually decreases. The temperature gradient increases obviously with the increase of thickness of parts. After quenching, there exist large residual stresses on the inner side of joints of profile and the two ends of part with thickness of 10 mm. The profile presents a twisting-type distortion across the cross-section under non-uniform cooling and the maximum twisting angle during quenching is 2.78°.
基金Project(2010CB732101) supported by the National Basic Research Program of ChinaProject(51079145) supported by the National Natural Science Foundation of China
文摘A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the seepage field and the concentration field were double,and the influences of sets,spaces,angles,continuity ratios,stiffnesses of fractures on the constitutive relationship of the medium were considered.Also,the relative two-dimensional program of finite element method was developed.Taking a hypothetical nuclear waste repository as a calculation example,the case in which the rockmass was unsaturated dual-porosity medium and radioactive nuclide leak was simulated numerically,and the temperatures,negative pore pressures,saturations,flow velocities,nuclide concentrations and principal stresses in the rockmass were investigated.The results show that the negative pore pressures and nuclide concentrations in the porosity and fracture present different changes and distributions.Even though the saturation degree in porosity is only about 1/10 that in fracture,the flow velocity of underground water in fracture is about three times that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity.The value of nuclide concentration in fracture is close to that in porosity.
基金The authors are grateful for the financial supports from the National Natural Science Foundation of China(51974278)the Distinguished Young Fund of Natural Science Foundation of Hebei Province,China(E2018203446).
文摘Based on twin-roll casting, a cast-rolling force model was proposed to predict the rolling force in the bimetal solid-liquid cast-rolling bonding(SLCRB) process. The solid-liquid bonding zone was assumed to be below the kiss point(KP). The deformation resistance of the liquid zone was ignored. Then, the calculation model was derived. A 2D thermal-flow coupled simulation was established to provide a basis for the parameters in the model, and then the rolling forces of the Cu/Al clad strip at different rolling speeds were calculated. Meanwhile, through measurement experiments, the accuracy of the model was verified. The influence of the rolling speed, the substrate strip thickness, and the material on the rolling force was obtained. The results indicate that the rolling force decreases with the increase of the rolling speed and increases with the increase of the thickness and thermal conductivity of the substrate strip. The rolling force is closely related to the KP height. Therefore, the formulation of reasonable process parameters to control the KP height is of great significance to the stability of cast-rolling forming.
基金supported by the National Magnetic Confinement Fusion Science Program of China(Grant Nos.2015GB121007&2013GB113004)
文摘The first wall of the fusion reactor is a plasma-facing component and is a key link to maintain the integrity of structure during thermal shock induced by plasma disruptions. Be and W/Cu functionally graded materials are two kinds of important plas- ma-facing materials （PFM） of first wall in fusion reactor currently. Previous researches seldom comparatively evaluated the normal servicing and heat shock resistance performance of first walls with those two kinds of PFMs. And also there lacks cou- pled thermal/mechanical analysis on the heat shock process in consideration of multiple thermal/mechanical phenomena, such as material melting, solidification, evaporation, etc., which is significant to further understand the heat shock damage mecha- nism of the first wall with different PFMs. With the aim of learning more detailed mechanical mechanism of thermal shock damage and then improving the thermal shock resistance performance of different first wall designs, the coupled ther- mal/mechanical response of two typical ITER-like first walls with PFM of Be and functionally graded W-Cu respectively un- der the heat shock of 1 2 GW/m2 are computed by the finite element method. Special considerations of elastic-plastic defor- mation, material melting, and solidification are included in numerical models and methods. The mechanical response behaviors of different structures and materials under the normal servicing operation as well as plasma disruption conditions are analyzed and investigated comparatively. The results reveal that heat is mainly deposited on the PFM layer in thc high energy shock pulse induced by plasma disruptions, resulting in complex thermal stress change as well as mechanical itTeversible damage of thermal elastic and plastic expansion, contraction and yielding. Compared with the first wall with Be PFM, which mitigates the damages from heat shock at most only in the PFM layer with cost of whole PFM layer plastic yielding, the first wall with graded W-Cu PFM is demonstrated to be possessed both of higher heat shock resistance performance and normal servicing performance, provided its material gradient and cooling capacity are well optimized under practical loading conditions.
