无定形Fe-和Mn-羟基氧化物以及硅的沉积体广泛分布于洋中脊(Dekov et al.,2010)、弧后盆地(Hein et al.,2008;Zeng et al.,2012)和海山(Emerson et al.,2002;Edwards et al.,2011)等不同地质背景的海底热液区。热液Fe-羟基氧化物按成因...无定形Fe-和Mn-羟基氧化物以及硅的沉积体广泛分布于洋中脊(Dekov et al.,2010)、弧后盆地(Hein et al.,2008;Zeng et al.,2012)和海山(Emerson et al.,2002;Edwards et al.,2011)等不同地质背景的海底热液区。热液Fe-羟基氧化物按成因可以分为三类:热液硫化物的氧化产物。展开更多
In this paper, some experimental studies on the forms of existenee and conditions for transport and precipitation of rare earth elements (REE) in sea water have been dealt with. The results show that the ions of REE a...In this paper, some experimental studies on the forms of existenee and conditions for transport and precipitation of rare earth elements (REE) in sea water have been dealt with. The results show that the ions of REE and carbonate radicles can be combined into quite stable and soluh|e complex in the medium of weak alkalinity. REE precipitation may result from the decomposition of the REE complex during the transformation of the solution from weak alkalinity to neutrality and to weak acidity and in the presence of REE preeipitating agents, such as P, Ba, Ca, and Mg.This is the reason why REE can concentrate in carbonate formations. Experimental results also show that REE will be precipitated .in the form of phosphate or fluocarhanate, if there exist the anions of [PO4]^3- and F^- in certain quantity in the solution. The experimental results arc consistent with the geologioal characteristics of some REE deposits.展开更多
文摘无定形Fe-和Mn-羟基氧化物以及硅的沉积体广泛分布于洋中脊(Dekov et al.,2010)、弧后盆地(Hein et al.,2008;Zeng et al.,2012)和海山(Emerson et al.,2002;Edwards et al.,2011)等不同地质背景的海底热液区。热液Fe-羟基氧化物按成因可以分为三类:热液硫化物的氧化产物。
文摘In this paper, some experimental studies on the forms of existenee and conditions for transport and precipitation of rare earth elements (REE) in sea water have been dealt with. The results show that the ions of REE and carbonate radicles can be combined into quite stable and soluh|e complex in the medium of weak alkalinity. REE precipitation may result from the decomposition of the REE complex during the transformation of the solution from weak alkalinity to neutrality and to weak acidity and in the presence of REE preeipitating agents, such as P, Ba, Ca, and Mg.This is the reason why REE can concentrate in carbonate formations. Experimental results also show that REE will be precipitated .in the form of phosphate or fluocarhanate, if there exist the anions of [PO4]^3- and F^- in certain quantity in the solution. The experimental results arc consistent with the geologioal characteristics of some REE deposits.