The density,viscosity and refractive index of aqueous solutions of tetrabutylammonium hydroxide(TBAOH),piperazine(PZ) and their aqueous blends are determined at several temperatures(303.15 to 333.15 K).All these measu...The density,viscosity and refractive index of aqueous solutions of tetrabutylammonium hydroxide(TBAOH),piperazine(PZ) and their aqueous blends are determined at several temperatures(303.15 to 333.15 K).All these measured physicochemical properties decreases with an increase in temperature.The density data is used to calculate the coefficient of thermal expansion and excess molar volume of all aqueous binary and ternary solutions.The coefficient of thermal expansion increases with increase in temperatures and concentrations.The negativity of excess molar volume for all the aqueous solution decreased with increase in temperature.Each physical property is correlated with temperature by least square method and the corresponding coefficients for each property are presented.The prediction values from correlations for the physical properties are in good agreement with the experimental values.展开更多
Till now,water based lubricants,especially aqueous solutions,have not been employed in the elastohydrodynamic lubrication(EHL)due to their poor film forming capability or low wear resistance.In this paper,we proposed ...Till now,water based lubricants,especially aqueous solutions,have not been employed in the elastohydrodynamic lubrication(EHL)due to their poor film forming capability or low wear resistance.In this paper,we proposed a method to develop water based lubricant:employing polyalkylene glycol solution as base stock to improve EHL film forming capability and using organic phosphate ester(DPZ)as anti-wear additive to improve wear resistance property.The lubricating properties of the mixed solutions,including load carrying capability,wear resistance property,friction reduction property,EHL film forming behavior,were investigated.The experimental results indicate that the mixed solution presents excellent lubricating properties,which make it a promising candidate in developing water based lubricants.展开更多
基金the CO2 Management (MOR) research group of Universiti TeknologiPETRONAS for providing the financial support and facilities
文摘The density,viscosity and refractive index of aqueous solutions of tetrabutylammonium hydroxide(TBAOH),piperazine(PZ) and their aqueous blends are determined at several temperatures(303.15 to 333.15 K).All these measured physicochemical properties decreases with an increase in temperature.The density data is used to calculate the coefficient of thermal expansion and excess molar volume of all aqueous binary and ternary solutions.The coefficient of thermal expansion increases with increase in temperatures and concentrations.The negativity of excess molar volume for all the aqueous solution decreased with increase in temperature.Each physical property is correlated with temperature by least square method and the corresponding coefficients for each property are presented.The prediction values from correlations for the physical properties are in good agreement with the experimental values.
基金supported by the National Key Basic Research Program of China(Grant No.2013CB934200)the National Natural Science Foundation of China(Grant Nos.51075227,51222507)
文摘Till now,water based lubricants,especially aqueous solutions,have not been employed in the elastohydrodynamic lubrication(EHL)due to their poor film forming capability or low wear resistance.In this paper,we proposed a method to develop water based lubricant:employing polyalkylene glycol solution as base stock to improve EHL film forming capability and using organic phosphate ester(DPZ)as anti-wear additive to improve wear resistance property.The lubricating properties of the mixed solutions,including load carrying capability,wear resistance property,friction reduction property,EHL film forming behavior,were investigated.The experimental results indicate that the mixed solution presents excellent lubricating properties,which make it a promising candidate in developing water based lubricants.
