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纳米TiO_(2)硅氧烷含氟聚醚树脂复合涂料的制备及性能研究 被引量:1
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作者 黎浩劲 卢锡洪 +2 位作者 李厚志 文浩 王荣峰 《化工新型材料》 CAS CSCD 北大核心 2023年第S02期231-236,243,共7页
在丙烯酸酯乳胶涂料中接枝聚全氟甲基异丙基醚、四甲基铵基笼型聚倍半硅氧烷和纳米TiO_(2)制备了纳米TiO_(2)硅氧烷含氟聚醚树脂复合涂料。采用傅里叶变换红外光谱仪、配置能量色散谱仪的场发射扫描电子显微镜、X射线衍射仪、电感耦合... 在丙烯酸酯乳胶涂料中接枝聚全氟甲基异丙基醚、四甲基铵基笼型聚倍半硅氧烷和纳米TiO_(2)制备了纳米TiO_(2)硅氧烷含氟聚醚树脂复合涂料。采用傅里叶变换红外光谱仪、配置能量色散谱仪的场发射扫描电子显微镜、X射线衍射仪、电感耦合等离子体发射光谱仪、X射线荧光波谱仪等对复合涂料的形貌、结构、成分进行表征和测试。通过L_(9)(3^(4))正交试验设计得到最佳的复合涂料配方:80%丙烯酸酯+5g聚全氟甲基异丙基醚(相对分子质量3300)+2.0g四甲基铵基笼型聚倍半硅氧烷+0.8g纳米TiO_(2),纯净水作为100g复合涂料的补充溶剂。采用该配方制备的复合涂料耐强酸腐蚀效果最好。 展开更多
关键词 丙烯酸酯涂料 正交试验设计 强酸腐蚀
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The compressive strength experimental study of cemented soil under H2SO4 corrosive in earlier period
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作者 HAN Peng-ju BAI Xiao-hong HAO Hai-yan 《Journal of Civil Engineering and Architecture》 2009年第3期54-58,共5页
In order to simulate and study the erosion effect process such as the changes of corrosive depth and unconfined compression strength of cemented soil sample in earlier period from 0 day to 60 days, a series of tests i... In order to simulate and study the erosion effect process such as the changes of corrosive depth and unconfined compression strength of cemented soil sample in earlier period from 0 day to 60 days, a series of tests including unconfined compressive tests, measuring the blocks' sizes, and taking photos, are conducted on the cemented soil blocks which were cured in different concentrations of H2SO4 solutions. The results of tests show that the corrosive depth is increasing and the unconfined compression strength is decreasing with the increase of H2SO4 solution concentration at the same erosion time, and the corrosive degree is increasing with the corrosive time. In the earlier state, the corrosive effect is serious, but the effect becomes slow in the later state in the same concentrated H2SO4 solution. After take statistics the date, a coefficient a is put forward to predict the reduction of the compressive strength of cemented soil in various concentration of H2SO4 solution, which could be used in practical design. 展开更多
关键词 cemented soil corrosive depth unconfined compression strength reduced coefficient
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强腐作用下钢板组合梁栓钉退化机理的研究与有限元分析 被引量:3
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作者 朱浩云 乔文靖 +1 位作者 杨帆 张浩 《公路》 北大核心 2022年第1期109-117,共9页
用浓度为36%的工业盐酸对30根钢板组合梁栓钉进行腐蚀,腐蚀时间分别为0 h、0.5 h、1 h、2 h、4 h、8 h、12 h、24 h、48 h和72 h,对腐蚀后栓钉进行拉伸试验,研究强腐蚀对栓钉力学性能的影响,分析不同腐蚀时间的栓钉各项力学性能的退化... 用浓度为36%的工业盐酸对30根钢板组合梁栓钉进行腐蚀,腐蚀时间分别为0 h、0.5 h、1 h、2 h、4 h、8 h、12 h、24 h、48 h和72 h,对腐蚀后栓钉进行拉伸试验,研究强腐蚀对栓钉力学性能的影响,分析不同腐蚀时间的栓钉各项力学性能的退化规律。试验结果表明:强腐蚀对栓钉的各项力学性能有着显著影响;腐蚀时间为0 h、0.5 h、1 h、2 h、4 h、8 h、12 h、24 h、48 h和72 h时,栓钉对应的腐蚀率分别为0%、0.49%、0.59%、0.83%、1.92%、2.87%、3.3%、4.5%、6.06%和7.33%;栓钉经过72 h腐蚀后,名义屈服强度最大下降了11.44%,名义极限强度最大下降了9.94%,弹性模量下降了3.34%,伸长率下降了39.59%;强腐蚀对栓钉的屈强比的影响较小;在腐蚀24 h内,腐蚀对栓钉的各项力学性能影响显著;随着腐蚀率增加,栓钉的颈缩现象逐渐不明显,破坏面从平整变为锯齿状。在试验结果分析的基础上,建立腐蚀后栓钉的力学退化模型和腐蚀后的本构关系模型,并建立ABAQUS拉伸试验有限元模型来验证腐蚀后本构关系模型的可靠性与可行性。本研究结果可为强腐作用下栓钉的工程应用和后续研究提供参考。 展开更多
关键词 钢板组合梁栓钉 强酸腐蚀 力学性能退化 本构关系 有限元模拟
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Cement-and-pebble nanofluidic membranes with stable acid resistance as osmotic energy generators 被引量:1
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作者 Yifei Zhao Weiwen Xin +6 位作者 Yongchao Qian Zhehua Zhang Yadong Wu Xiangbin Lin Xiang-Yu Kong Lei Jiang Liping Wen 《Science China Materials》 SCIE EI CAS CSCD 2022年第10期2729-2736,共8页
Osmotic energy between river water and seawater has attracted interest as a new source of sustainable energy.Nanofluidic membranes in a reverse electrodialysis configuration can capture energy from salinity gradients.... Osmotic energy between river water and seawater has attracted interest as a new source of sustainable energy.Nanofluidic membranes in a reverse electrodialysis configuration can capture energy from salinity gradients.However,current membrane materials suffer from high resistances,low stabilities,and low charge densities,which limit their further application.Here,we designed a high-performance nanofluidic membrane using carboxylic cellulose nanofibers functionalized with graphene oxide nanolamellas with cement-and-pebble microstructures and stable skeletons for enhanced ion transmembrane transport.By mixing artificial river water and seawater,the composite membrane achieved a high output power density up to 5.26 W m^(−2).Additionally,the membrane had an excellent acid resistance,which enabled long-term use with over 67 W m^(−2) of power density.The performance of this composite membrane benefited from the mechanically strong cellulose fibers and the bonding between nanofibers and nanolamellas.In this work,we highlight promising directions in industrial waste treatment using energy extracted from chemical potential gradients. 展开更多
关键词 cement-and-pebble membrane ion transport osmotic energy conversion nanoconfined fluidic channels chargedriven ion diffusion
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