电介质介电响应中所蕴含的信息可以被用于探究电介质的内部微观结构以及电荷的运动特性。Debye模型描述的是没有相互作用的偶极子在黏性介质中发生的极化现象,这很难出现在实际的固体电介质中。基于Debye模型的经验修正模型如Cole-Cole...电介质介电响应中所蕴含的信息可以被用于探究电介质的内部微观结构以及电荷的运动特性。Debye模型描述的是没有相互作用的偶极子在黏性介质中发生的极化现象,这很难出现在实际的固体电介质中。基于Debye模型的经验修正模型如Cole-Cole模型、Davidson-Cole模型以及Havriliak-Negami模型中的参数没有实际的物理意义,使用经验模型分析介电响应测量结果无法获得电介质内部微观结构和电荷运行特性。由Dissado L A与Hill R M提出的具有明确物理意义、涉及微观粒子之间的相互作用的Dissado-Hill介电响应模型是一个更反映介电响应物理实质的理论模型。该文详细阐述了Dissado-Hill介电响应模型的物理意义及该模型中"簇"的概念;Dissado-Hill模型包含2个子模型:一个是用来描述偶极子主导的弛豫峰型介电响应过程的Dissado-Hill loss peak模型;一个是用来描述载流子主导的低频弥散现象的Dissado-Hill QDC模型。文中讨论了低频弥散介电响应现象与电导现象之间的异同及区分方法。结合Dissado-Hill介电响应模型和等效电路模型分析的方法,对电力系统外绝缘领域常用的高温硫化硅橡胶材料的介电响应测量结果进行了深入的分析,结果发现,高温硫化硅橡胶的介电响应中存在明显的低频弥散现象。展开更多
The effect of precipitation on the internal friction(IF)of AZ91 magnesium alloy was investigated by using X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and dynamic mechanical analysis(DMA...The effect of precipitation on the internal friction(IF)of AZ91 magnesium alloy was investigated by using X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and dynamic mechanical analysis(DMA).Six different states of alloy were prepared by applying different heat treatment processes:as-cast,in-complete solid solution,complete solid solution,micro-precipitation,continuous precipitation and continuous-discontinuous precipitation.It was found that the internal friction of in-completely solid-solutionized,completely solid-solutionized and micro-precipitated specimens showed a similar characteristic,and the grain boundary relaxation is completed depressed due to the Al atoms supersaturated in theα-Mg solution.However,a thermal relaxation internal friction peak was observed for continuously precipitated and continuously-discontinuously precipitated specimens at around 438 K and frequency of about 1 Hz,which was attributed to the grain boundaries relaxation.Furthermore,it was found that the relaxation of theβ-Mg17Al12/α-Mg phase interfaces should give its contribution to the background internal friction in the as-cast,continuously precipitated and continuously-discontinuously precipitated specimens.展开更多
文摘电介质介电响应中所蕴含的信息可以被用于探究电介质的内部微观结构以及电荷的运动特性。Debye模型描述的是没有相互作用的偶极子在黏性介质中发生的极化现象,这很难出现在实际的固体电介质中。基于Debye模型的经验修正模型如Cole-Cole模型、Davidson-Cole模型以及Havriliak-Negami模型中的参数没有实际的物理意义,使用经验模型分析介电响应测量结果无法获得电介质内部微观结构和电荷运行特性。由Dissado L A与Hill R M提出的具有明确物理意义、涉及微观粒子之间的相互作用的Dissado-Hill介电响应模型是一个更反映介电响应物理实质的理论模型。该文详细阐述了Dissado-Hill介电响应模型的物理意义及该模型中"簇"的概念;Dissado-Hill模型包含2个子模型:一个是用来描述偶极子主导的弛豫峰型介电响应过程的Dissado-Hill loss peak模型;一个是用来描述载流子主导的低频弥散现象的Dissado-Hill QDC模型。文中讨论了低频弥散介电响应现象与电导现象之间的异同及区分方法。结合Dissado-Hill介电响应模型和等效电路模型分析的方法,对电力系统外绝缘领域常用的高温硫化硅橡胶材料的介电响应测量结果进行了深入的分析,结果发现,高温硫化硅橡胶的介电响应中存在明显的低频弥散现象。
文摘The effect of precipitation on the internal friction(IF)of AZ91 magnesium alloy was investigated by using X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and dynamic mechanical analysis(DMA).Six different states of alloy were prepared by applying different heat treatment processes:as-cast,in-complete solid solution,complete solid solution,micro-precipitation,continuous precipitation and continuous-discontinuous precipitation.It was found that the internal friction of in-completely solid-solutionized,completely solid-solutionized and micro-precipitated specimens showed a similar characteristic,and the grain boundary relaxation is completed depressed due to the Al atoms supersaturated in theα-Mg solution.However,a thermal relaxation internal friction peak was observed for continuously precipitated and continuously-discontinuously precipitated specimens at around 438 K and frequency of about 1 Hz,which was attributed to the grain boundaries relaxation.Furthermore,it was found that the relaxation of theβ-Mg17Al12/α-Mg phase interfaces should give its contribution to the background internal friction in the as-cast,continuously precipitated and continuously-discontinuously precipitated specimens.
基金supported by the National Key R&D Program of China (2018YFA0703600)the National Natural Science Foundation of China (51922102, 52001319, 52271158, 92163108, and 52231006)+2 种基金Zhejiang Provincial Natural Science Foundation (LGF22E010002, LZ22A030001, and LR22E010004)the “Pioneer and Leading Goose” R&D Program of Zhejiang (2022C01023)Ningbo Key Scientific and Technological Project (2019B10051)。