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近、远场地震作用下深水高墩桥梁水动力效应研究
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作者 李明 开永旺 《中国铁路》 北大核心 2024年第1期57-66,共10页
为研究近、远场地震作用下水动力效应对深水高墩桥梁抗震性能的影响,明确深水高墩桥梁抗震性能分析中考虑动水压力的必要性,以典型的深水高墩大跨连续刚构桥为例,基于OpenSees建立其非线性动力分析模型。通过附加质量法模拟墩-水动力相... 为研究近、远场地震作用下水动力效应对深水高墩桥梁抗震性能的影响,明确深水高墩桥梁抗震性能分析中考虑动水压力的必要性,以典型的深水高墩大跨连续刚构桥为例,基于OpenSees建立其非线性动力分析模型。通过附加质量法模拟墩-水动力相互作用,并在PEER数据库选择代表性的近场和远场地震动记录,对该桥梁进行不同水深下的非线性地震响应分析,对比研究近、远场地震作用下动水压力效应对深水高墩桥梁抗震性能的影响。研究表明:不论近场还是远场地震作用,墩-水相互作用都会显著增大桥梁结构的地震响应,近场地震作用下,对桥墩的墩顶位移和墩底曲率的改变率分别可达到64.77%和156%;与远场地震作用相比,近场地震作用下墩-水相互作用对深水高墩桥梁抗震性能的影响更为显著,在近场地区的深水高墩桥梁抗震性能分析中,应充分考虑近断层地震动和墩-水相互作用的耦合效应;近场地震作用下,墩-水相互作用主要激起桥墩的一阶振型产生基频共振,增大墩底的损伤,而远场地震作用下墩-水相互作用会激起桥墩的高阶振型,不仅增大墩底的损伤而且会加剧墩身中上部的损伤;深水高墩桥梁抗震性能分析不仅需要考虑动水压力效应,还应考虑近场和远场地震动带来的影响。 展开更多
关键词 高墩桥梁 动水效应 抗震性能 近、远场地震
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基于数值分析的动水效应对连续刚构桥抗震性能影响
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作者 黄雯 加攀星 +1 位作者 左光升 张秀成 《数学的实践与认识》 2021年第5期123-130,共8页
为了研究不同水深下,动水效应对连续刚构桥抗震性能的影响,基于一实际工程,利用有限元软件Midas建立全桥模型,采用反应谱数值分析法,并考虑桩土的相互作用,研究了动水效应对连续刚构桥抗震性能的影响.结果表明:考虑动水效应将会减小结... 为了研究不同水深下,动水效应对连续刚构桥抗震性能的影响,基于一实际工程,利用有限元软件Midas建立全桥模型,采用反应谱数值分析法,并考虑桩土的相互作用,研究了动水效应对连续刚构桥抗震性能的影响.结果表明:考虑动水效应将会减小结构的频率,且高阶频率对动水效应更加敏感;另外,动水效应将会放大结构的地震响应,随着水深的增加,地震响应的增大幅度也越大.当水深达到20m以上时,动水效应将使结构的内力增大约10%,此时在抗震设计中应重点考虑动水效应的影响. 展开更多
关键词 动水效应 连续刚构桥 抗震性能 MIDAS
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多层水股射流在水垫塘内的流动特征与动水垫效应分析 被引量:10
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作者 刘沛清 高季章 李永梅 《水利学报》 EI CSCD 北大核心 1999年第3期1-7,共7页
多层水股在水垫塘内的流动特征及其各水股间的干扰、碰撞和动水垫效应等对探明水垫塘的消能机理和体型优化设计具有重要的意义.本文利用激光片光源和荧光染色液技术,对静水和动水垫中的射流进行了流场显示试验,并通过射流在动水中的... 多层水股在水垫塘内的流动特征及其各水股间的干扰、碰撞和动水垫效应等对探明水垫塘的消能机理和体型优化设计具有重要的意义.本文利用激光片光源和荧光染色液技术,对静水和动水垫中的射流进行了流场显示试验,并通过射流在动水中的流动特征和淹没冲击射流理论,分析了多层水股在水垫塘内的流动机理和动水垫效应。 展开更多
关键词 射流 垫塘 效应
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水下桩墩结构体系的动力模型试验研究 被引量:2
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作者 柳春光 孙国帅 韩亮 《地震工程与工程振动》 CSCD 北大核心 2012年第5期97-102,共6页
为了了解动水效应对桩墩结构体系的影响以及完善桥梁结构的抗震设计方法,进行了水下桩墩结构模型体系的动力试验。从模型设计、试验装置和加载工况3个方面介绍了试验的实施过程。通过观察模型破坏形态和分析试验结果,探讨了动水压力对... 为了了解动水效应对桩墩结构体系的影响以及完善桥梁结构的抗震设计方法,进行了水下桩墩结构模型体系的动力试验。从模型设计、试验装置和加载工况3个方面介绍了试验的实施过程。通过观察模型破坏形态和分析试验结果,探讨了动水压力对结构体系动力特性和地震响应的影响并且检验了应用该动力模型试验研究的适用性。试验结果表明:模型在水中的自振频率比无水时有所降低;动水压力的大小与输入的加速度峰值有关并且在相同的峰值加速度下沿模型从上到下依次递增;试验结果满足预期目的,证实了试验方案的有效性。 展开更多
关键词 动水效应 力试验 破坏形态 自振频率 峰值加速度
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近、远场强震下深水桥梁群桩基础的非线性响应及损伤特性 被引量:10
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作者 江辉 王志 +2 位作者 白晓宇 曾聪 王敏 《振动与冲击》 EI CSCD 北大核心 2017年第24期13-22,共10页
以某大型深水桥梁的群桩基础为对象,建立考虑动水效应和桩-土相互作用的非线性计算模型,以近、远场强震记录为输入,分析了不同水深下群桩基础的动力响应及损伤特性。可发现,近场地震下群桩基础的动力响应均大于远场,弯矩、剪力、位移的... 以某大型深水桥梁的群桩基础为对象,建立考虑动水效应和桩-土相互作用的非线性计算模型,以近、远场强震记录为输入,分析了不同水深下群桩基础的动力响应及损伤特性。可发现,近场地震下群桩基础的动力响应均大于远场,弯矩、剪力、位移的最大增幅分别出现在冲刷线以下不同深度处,轴力的最大增幅则出现在桩顶处,弯矩、剪力、位移和轴力的最大增幅分别为150.6%、227.2%、333.4%和64.2%。近场地震下,墩底、桩顶是主要易损部位,当PGA=0.38g和0.6g时,桩顶损伤指数分别为0.19和0.40,损伤水平及范围随地震动强度增加而增大,随水深增加而略有增大;远场地震下,群桩基础主要处于弹性状态。由于桩周土的约束作用,一定深度的土层交界处也可能出现桩基损伤,且损伤程度会随地震动强度的增加而增大,并向两端扩散。对比表明,近场地震下深水群桩基础的动力响应及损伤均明显大于远场,表明脉冲型近断层地震动具有更高的变形和耗能需求,应在深水桥梁的抗震设计尤其是基础延性设计中予以重视。 展开更多
关键词 桥梁群桩基础 非线性模型 动水效应 桩-土相互作用 力时程分析 地震损伤特性 近、远场地震
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考虑桥墩非线性的深水桥梁抗震性能分析 被引量:2
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作者 庞于涛 游科华 +1 位作者 欧阳辉 袁万城 《哈尔滨工程大学学报》 EI CAS CSCD 北大核心 2018年第7期1206-1211,1226,共7页
针对目前深水桥梁抗震流固耦合研究中对桥墩非线性的影响认识的不足,本文基于弥散裂缝混凝土理论,建立了考虑钢筋混凝土桥墩非线性的三维桥梁墩柱实体模型,研究了弥散裂缝混凝土模型对于模拟地震作用下钢筋混凝土结构力学行为的可行性... 针对目前深水桥梁抗震流固耦合研究中对桥墩非线性的影响认识的不足,本文基于弥散裂缝混凝土理论,建立了考虑钢筋混凝土桥墩非线性的三维桥梁墩柱实体模型,研究了弥散裂缝混凝土模型对于模拟地震作用下钢筋混凝土结构力学行为的可行性。在此基础上,采用Φ-U格式的势流体单元模拟桥墩周围水体,建立了考虑桥墩的非线性深水桥梁流固耦合分析模型,研究了不同地震重现期下动水效应对采用非线性桥墩的深水桥梁的影响。研究表明:采用非线性桥墩之后,结构的振动特性将与线弹性结构有所差别,从而导致动水效应对结构的影响不同于动水效应对线弹性结构的影响,桥墩非线性较明显时,动水对桥梁结构的影响较大。 展开更多
关键词 桥梁 地震响应 流固耦合 桥墩非线性 动水效应 混凝土
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不同类型地震动下深水高桩承台群桩基础动力响应对比研究 被引量:6
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作者 江辉 王宝喜 +3 位作者 王志刚 谷琼 王敏 李辰 《建筑结构》 CSCD 北大核心 2018年第S2期818-826,共9页
以某大型深水桥梁工程为背景,引入改进的动水效应简化算法,建立了深水高桩承台群桩基础的数值分析模型。选取成组的近断层脉冲型地震记录及对应的远场记录为输入,开展了不同水深下的动力时程计算,量化对比了近、远场地震下结构动力响应... 以某大型深水桥梁工程为背景,引入改进的动水效应简化算法,建立了深水高桩承台群桩基础的数值分析模型。选取成组的近断层脉冲型地震记录及对应的远场记录为输入,开展了不同水深下的动力时程计算,量化对比了近、远场地震下结构动力响应的差异。结果表明,两种地震动的频谱特性存在明显差异,近断层脉冲型地震下群桩基础的动力响应明显大于远场,在无水、水深10m和20m三种水深下,弯矩响应差异率的中值分别为77. 94%、60. 65%和54. 36%,剪力响应差异率的中值分别为81. 56%、63. 59%和57. 74%,位移响应差异率的中值分别为94. 34%、74. 81%和75. 64%,体现了两种类型地震下的明显差别。三种水深下算例结构地震响应的差别并不明显,这是由于动水效应附加质量在结构总质量中的比重很低,对结构自振周期的影响微小,导致在对应区间内反应谱谱值的差别不显著,表明水中结构地震响应的变化程度也受其自振周期及谱值变化幅度的影响。 展开更多
关键词 桥梁 群桩基础 动水效应简化算法 近断层脉冲型地震 远场地震 力响应
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大跨连续刚构桥地震反应的三维数值模拟研究
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作者 张佳春 《四川建筑》 2014年第3期179-181,184,共4页
文章以黄草乌江特大桥设计为工程背景,考虑了动水作用和竖向地震加速度对桥梁地震反应的影响,采用反应谱分析法对大跨度连续刚构桥进行了三维地震反应分析,分别从主墩的内力反应、主墩的位移以及主梁的内力反应和位移进行分析比较。分... 文章以黄草乌江特大桥设计为工程背景,考虑了动水作用和竖向地震加速度对桥梁地震反应的影响,采用反应谱分析法对大跨度连续刚构桥进行了三维地震反应分析,分别从主墩的内力反应、主墩的位移以及主梁的内力反应和位移进行分析比较。分析结果表明:动水作用对墩的内力影响都比较大,而且增幅较大,对主墩位移影响也比较大,但对主梁影响相对于主墩较小。考虑竖向地震作用时,对主梁的水平向位移、主梁的面外弯矩、主梁的轴力、桥墩的墩顶水平位移以及墩底弯矩均没有太大的影响,而对主梁的面内弯矩以及桥墩的轴力影响比较大,并均有所增大的趋势。 展开更多
关键词 连续刚构桥 大跨度 动水效应 竖向地震加速度三维数值 研究
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Bioturbation Effects of Benthic Fish on the Phosphorus Dynamic in Overlying Water of Paddy Field 被引量:3
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作者 孙刚 房岩 +1 位作者 汪爱武 严永菊 《Agricultural Science & Technology》 CAS 2010年第5期87-89,177,共4页
[Objective]The research aimed to investigate the bioturbation effects of benthic fish Misgurnus anguillicaudatus on phosphorus dynamic in overlying water of paddy field,as well as to explore the bioturbation mechanism... [Objective]The research aimed to investigate the bioturbation effects of benthic fish Misgurnus anguillicaudatus on phosphorus dynamic in overlying water of paddy field,as well as to explore the bioturbation mechanism.[Method]Based on simulation experiment,the phosphorus contents in overlying water were analyzed comparatively with and without Misgurnus anguillicaudatus by the using of ion chromatography and spectrophotometry.[Result]The concentrations of total phosphorus(TP),dissolved total phosphorus(DTP)and particular phosphorus(PP)in bioturbation group had no significant differences with those in control group in initial stage of experiment,and became significantly higher than control group in middle and late stages of experiment(P<0.05). The PP/TP ratios in bioturbation group were bigger than those in control group,the increase of TP concentration in bioturbation group was mainly due to the increase of PP. The ratios of dissolved inorganic phosphorus(DIP) to DTP (DIP/DTP) were significantly bigger than those in control group in middle and late stages of experiment(P<0.05).[Conclusion]The benthic fish had bioturbation effects on phosphorus in overlying water of paddy field,which increased the available phosphorus for rice growth. 展开更多
关键词 Benthic fish Paddy field Bioturbation Phosphorus Overlying water
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Experiments on Deflecting & Oscillating Waterjet 被引量:2
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作者 卢义玉 《Journal of Chongqing University》 CAS 2002年第1期11-15,共5页
A new type jet, the oscillating & deflecting jet, is put forward and its oscillating and deflecting characteristics are investigated. The nozzle of the self-oscillating & deflecting water jet consists of an up... A new type jet, the oscillating & deflecting jet, is put forward and its oscillating and deflecting characteristics are investigated. The nozzle of the self-oscillating & deflecting water jet consists of an upstream nozzle, a downstream nozzle, an oscillating chamber and two switches. It is experimentally shown that the deflective angle may reach 9.53 degree. The generated pressure fluctuation is very regular and the jet can efficiently increase the ability for breaking and cutting by eliminating the water cushion effect associated with a continuous jet. 展开更多
关键词 Oscillating & deflecting water jet NOZZLE Cushion effect
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Study on hydrodynamic vibration in fluidic flowmeter 被引量:2
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作者 WANG Chi-yu ZOU Jun +1 位作者 FU Xin YANG Hua-yong 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2007年第9期1422-1428,共7页
The characteristics of the fluidic flowmeter,which is a combination of impinged concave wall and bistable fluid amplifier,is investigated by experimental studies and numerical simulations. The numerical approaches are... The characteristics of the fluidic flowmeter,which is a combination of impinged concave wall and bistable fluid amplifier,is investigated by experimental studies and numerical simulations. The numerical approaches are utilized to examine the time dependent flow field and pressure field inside the proposed flowmeter. The effect of varying structural parameters on flow characteristics of the proposed fluidic flowmeter is investigated by computational simulations for the optimization. Both the simulation and experimental results disclose that the hydrodynamic vibration,with the same intensity,frequency and 180° phase shift,occurs at axisymmetric points in the feedback channel of the fluidic flowmeter. Using the structural combination of impinged concave wall and bistable fluid amplifier and differential signal processing technique,a novel fluidic flowmeter with excellent immunity and improved sensibility is developed. 展开更多
关键词 FLOWMETER Fluidic Hydrodynamic vibration Coanda effect
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Interactive Effects of Lead and Bensulfuron-Methyl on Decomposition of ^(14)C-Glucose in Paddy Soils
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作者 HOU Xian-Wen WU Jian-Jun +1 位作者 XU Jian-Ming TANG Cai-Xian 《Pedosphere》 SCIE CAS CSCD 2009年第5期577-587,共11页
Little information is available on the interactive effects of inorganic and organic pollutants on carbon utilization by soil microorganisms.This study examined the effects of two common soil pollutants,lead(Pb) and be... Little information is available on the interactive effects of inorganic and organic pollutants on carbon utilization by soil microorganisms.This study examined the effects of two common soil pollutants,lead(Pb) and bensulfuron-methyl herbicide(BSM),on decomposition of an adscititious carbon source(14C-glucose).Two contrasting paddy soils,a silty clay soil and a clay loam soil,were incubated with different concentrations and combinations of pollutants for 60 days.Orthogonal rotatable central composite design was adopted to design the combinations of the pollutant concentrations so that rate response curves could be derived.Rapid decomposition of 14C-glucose occurred in the first three days for both soils where no Pb or BSM was added(control).Overall,63%-64% of the added 14C-glucose was decomposed in the control over the 60-day incubation.The addition of Pb or BSM significantly decreased the decomposition of 14C-glucose during the first week but increased the decomposition thereafter;as a result,the percentages of 14C-glucose decomposed(57%-77%) over the 60-day period were similar to or higher than those of the control.Application of the pollutants in combination did not further inhibit decomposition compared with the control.Overall,decomposition rates were lower in the silty clay soil than in the clay loam soil,which was related to the soil texture,cation exchange capacity,and pH.The relationship between the decomposition rates and the pollutants could be well characterized by the quadratic regression orthogonal rotation model.The initial antagonistic effects of the pollutants followed by the synergistic effects on microbial activity might result from changes of the concentrations of the pollutants. 展开更多
关键词 carbon source compound pollution HERBICIDE microbial activity
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Solvent Effect on Conformation of a Cycloheptapeptide,Stylopeptide 1,Evaluated by Molecular Dynamics in Methonal and Aqueous Environments
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作者 LIU Xiao-qing LI Xiao-hui TENG Hu XIU Zhi-long 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2009年第4期560-563,共4页
Stylopeptide 1 synthesized and isolated from different sources exhibits a large activity difference in inhibitory effect on the growth of a cancer cell.Based on the different amounts of methanol and water during synth... Stylopeptide 1 synthesized and isolated from different sources exhibits a large activity difference in inhibitory effect on the growth of a cancer cell.Based on the different amounts of methanol and water during synthesis,isolation and purification of the cyclic peptides,molecular dynamics(MD) was employed to simulate the conformation of stylopeptide 1 in methanol and aqueous environments.The comparative results show that the backbone ring was more rigid in methanol than in water.In methanol,two β-turns and three hydrogen bonds were well conserved throughout the simulation,whereas no hydrogen bonds or turns were preserved in water.The activity difference of stylopeptide 1 seemed to be attributed to the solvent effect on its conformation. 展开更多
关键词 Cyclic peptide METHANOL WATER Molecular dynamics
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Numerical simulation on turbulent flow field in convergentdiveroent nozzle 被引量:4
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作者 LU Yi-yu LIU Yongc LI Xiao-hong KANG Yong ZHAO Jian-xin 《Journal of Coal Science & Engineering(China)》 2009年第4期434-439,共6页
Because of the complication of turbulence's mechanism and law as well as the jet pressure in nozzle is difficult to test by experiment, five turbulent models were applied to numerically simulate the turbulent flow fi... Because of the complication of turbulence's mechanism and law as well as the jet pressure in nozzle is difficult to test by experiment, five turbulent models were applied to numerically simulate the turbulent flow field in convergent-divergent nozzle. Theory analysis and experiment results of mass flow rates conclude that the RNG k-ε model is the most suitable model. The pressure distribution in the convergent-divergent nozzle was revealed by computational fluid dynamic (CFD) simulating on the turbulent flow field under different pressure conditions. The growing conditions of cavitation bubbles were shown; meanwhile, the phenomena in the experiment could be explained. The differential pres- sure between the upstream and downstream in nozzle throat section can improve the cavitating effect of cavitation water jet. 展开更多
关键词 numerical simulation convergent-divergent nozzle turbulent flow field cavitation water jet cavitating effect
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A nonlinear hydroelastic method considering wave memory effect for ship load responses in irregular waves
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作者 陈占阳 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第9期2058-2070,共13页
Since the amplitude and frequency of irregular waves change with time,great difficulties are brought for solving ship load responses in random waves.To take the effect of various frequencies of irregular waves into co... Since the amplitude and frequency of irregular waves change with time,great difficulties are brought for solving ship load responses in random waves.To take the effect of various frequencies of irregular waves into consideration in load responses of hull,the wave memory effect is necessary.A semi-analytical method is introduced for the time-domain retardation functions,and then a nonlinear hydroelastic method considering memory effect for ships in irregular waves is proposed.Segmented self-propelling model experiments of a container ship were carried out in a towing tank,a ship motion measuring device for self-propelling model test was designed.Whipping responses of the ship in regular and irregular waves are analyzed.Finally,the calculation results are compared with those measured by segmented model experiments,and the result indicates that the memory effect has little effect on load responses of ship in regular waves,but pronounced effect on results in irregular waves.Moreover,the presented method is reasonable for the prediction of ship load responses in irregular waves. 展开更多
关键词 HYDROELASTICITY memory effect retardation function segmented self-propelling model test irregular waves
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木兰溪下游生态补水设想
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作者 林阗 《水利科技》 2014年第2期5-6,10,共3页
该文通过木兰溪下游河网水环境现状调查和水环境恶化原因分析,针对改善水生态环境中水质因素,提出木兰溪下游河网生态补水的设想,建设宁海闸,疏浚拓宽纵向排水通道,设置湖泊蓄水补水,改造水闸为双向进出水,完善城市截污治污工程,并采用... 该文通过木兰溪下游河网水环境现状调查和水环境恶化原因分析,针对改善水生态环境中水质因素,提出木兰溪下游河网生态补水的设想,建设宁海闸,疏浚拓宽纵向排水通道,设置湖泊蓄水补水,改造水闸为双向进出水,完善城市截污治污工程,并采用河流完全混合模型计算木兰溪下游河网环境需水量,引干流水进入木兰溪下游河网水系,形成"动水效应",以改善木兰溪下游水环境。 展开更多
关键词 资源 生态补 动水效应 木兰溪下游
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Thermoelastohydrodynamic behaviour of inclined-ellipse dimpled gas face seals 被引量:1
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作者 DING ShaoPeng BAI ShaoXian 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第4期529-537,共9页
The thermoelastohydrodynamic performance of an inclined-ellipse dimpled gas face seal is analyzed. The pressure distributions of the gas film and temperature fields of the seal rings and gas film are presented conside... The thermoelastohydrodynamic performance of an inclined-ellipse dimpled gas face seal is analyzed. The pressure distributions of the gas film and temperature fields of the seal rings and gas film are presented considering thermal and elastic distortions.Then, the influences of texturing parameters, including dimple inclination angle and dimple depth, on sealing performance are investigated under different operating parameters such as rotational speeds and seal pressures. The results show that face distortions lead to a decrease in the hydrodynamic effect at high rotational speed. The analysis shows that the opening force can decrease by more than 50% as the rotational speed increases from 0 to 35000 r min^(-1). The influence of face distortion on the seal performance, such as opening force and leakage characteristic, gradually increases with the rotational speed. 展开更多
关键词 thermoelastohydrodynamic effect elastic and thermal distortions inclined-ellipse dimple seal performance
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The gravity field and crustal thickness of Venus 被引量:4
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作者 WEI DaiYun YANG An HUANG JinShui 《Science China Earth Sciences》 SCIE EI CAS 2014年第9期2025-2035,共11页
The gravity and topography of Venus obtained from observations of the Magellan mission, as well as the gravity and topography from our numerical mantle convection model, are discussed in this paper. We used the hypoth... The gravity and topography of Venus obtained from observations of the Magellan mission, as well as the gravity and topography from our numerical mantle convection model, are discussed in this paper. We used the hypothesis that the geoid of degrees 2–40 is produced by sublithospheric mantle density anomalies that are associated with dynamical process within the mantle. We obtained the model dynamical admittance(the geoid topography ratio based on a convection model) by a numerical simulation of the Venusian mantle convection, and used it to correct the dynamical effect in the calculation of crustal thickness. After deducting the dynamical effect, the thickness of the Venusian crust is presented. The results show that the gravity and topography are strongly correlated with the Venusian mantle convection and the Venusian crust has a significant influence on the topography. The Venusian crustal thickness varies from 28 to 70 km. Ishtar Terra, and Ovda Regio and Thetis Regio in western Aphrodite Terra have the highest crustal thickness(larger than 50 km). The high topography of these areas is thought to be supported by crustal compensation and our results are consistent with the hypothesis that these areas are remnants of ancient continents. The crustal thickness in the Beta, Themis, Dione, Eistla, Bell, and Lada regiones is thin and shows less correlation with the topography, especially in the Atla and Imdr regiones in the eastern part of Aphrodite Terra. This is consistent with the hypothesis that these highlands are mainly supported by mantle plumes. Compared with the crustal thickness calculated with the dynamical effect, our results are more consistent with the crust evolution and internal dynamical process of Venus. 展开更多
关键词 gravity field of Venus crustal thickness of Venus Venusian mantle dynamics admittance between the geoid and topography
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Structure of water at ionic liquid/Ag interface probed by surface enhanced Raman spectroscopy
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作者 NIU TianChao YUAN YaXian +2 位作者 YAO JianLin LU Feng GU RenAo 《Science China Chemistry》 SCIE EI CAS 2011年第1期200-204,共5页
The potential-dependent adsorption behavior of water and ionic liquid was probed by surface-enhanced Raman spectroscopy (SERS) at the Ag electrode surface in the ionic liquids containing water with different concent... The potential-dependent adsorption behavior of water and ionic liquid was probed by surface-enhanced Raman spectroscopy (SERS) at the Ag electrode surface in the ionic liquids containing water with different concentrations. The configuration of water at the ionic liquid/electrode interface and the relationship between the potential of zero charge (pzc) and the molar frac- tion of water were deduced through the changes in the vibrational frequency of OH stretching mode. A small Stark effect value was determined in the system with lower molar fraction of water. With the increase of the water concentration, the OH stretching vibrational frequency gradually shifted to the high wavenumber region, the pzc was also moved positively, and the Stark effect value of OH stretching vibrational mode increased. It reached about 76 cm-1 V-I in the 1 tool L-1 [BMIM]Br aqueous solution. These differences were mainly contributed by hydrogen bonding and the configuration of water in the ionic liquid solution. In the solution with lower water content, water molecules existed at the interface layer through hydrogen bond- ing with cations, while in the higher content solution, the intermolecular hydrogen bonding between water molecules was strengthened and the possibility of the direct interaction between the water molecule and electrode surface increased. 展开更多
关键词 WATER ionic liquid Ag electrode INTERFACE surface enhanced Raman spectroscopy
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