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锂离子电池单层电芯内短路建模与热失控触发特性 被引量:1
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作者 乔亚军 任怡茂 +2 位作者 谭子健 张袆柔 吴伟雄 《储能科学与技术》 CAS CSCD 北大核心 2024年第10期3491-3503,共13页
锂离子电池内短路诱因复杂,为深入研究内短路引起的电池失效问题须构建合适的精细化仿真模型。本工作以NCM/石墨电池为研究对象,围绕电池内短路失效机理,基于电化学-热耦合物理场,建立了考虑热失控放热副反应的三维单层电芯内短路模型,... 锂离子电池内短路诱因复杂,为深入研究内短路引起的电池失效问题须构建合适的精细化仿真模型。本工作以NCM/石墨电池为研究对象,围绕电池内短路失效机理,基于电化学-热耦合物理场,建立了考虑热失控放热副反应的三维单层电芯内短路模型,探究了热失控触发边界,并从内外部特征讨论了单层电芯内短路-热失控的演变过程。首先利用Arrhenius公式得到内短路触发的四种放热副反应产热量与反应速率,探究对电池温升影响最大的副反应类别,结果表明内短路过程放热副反应中负极与电解液反应总热量最大。进一步分析单层电芯内四种典型内短路形式的热失控触发特性,综合考虑组分材料导电性和导热性,得到铝-阳极内短路危险程度最高,其短路电阻值与热失控触发时间呈现正相关趋势,且临界短路电阻的高温热点区域面积值约为30 mm^(2)。模拟结果获得了四种形式内短路临界短路电阻值,并揭示了单层电芯内短路-热失控触发时内部锂离子浓度和温度分布的空间演变规律,相关结果可为研究内短路失效机制和设计安全锂离子电池提供理论指导。 展开更多
关键词 锂离子电池 单层电芯 内短路模型 热失控触发
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Internal short circuit detection method for battery pack based on circuit topology 被引量:8
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作者 ZHANG MingXuan DU JiuYu +4 位作者 LIU LiShuo SIEGEL Jason LU LanGuang HE XiangMing OUYANG MingGao 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2018年第10期1502-1511,共10页
Internal short circuit(ISCr) is one of the major obstacles to the improvement of the battery safety. The ISCr may lead to the battery thermal runaway and is hard to be detected in the early stage. In this work, a new ... Internal short circuit(ISCr) is one of the major obstacles to the improvement of the battery safety. The ISCr may lead to the battery thermal runaway and is hard to be detected in the early stage. In this work, a new ISCr detection method based on the symmetrical loop circuit topology(SLCT) is introduced. The SLCT ensures that every battery has the same priority in the circuit and every battery will contribute the same amount of short-circuit current to the ISCr once the ISCr happens. The ISCr battery could be identified by the combination of the ratio of the short-circuit currents and the sign of the short-circuit currents. The recursive least square method is adopted for the real-time application and the optimized ammeters allocation is derived from the mathematic deduction. The battery pack based on the individual DP(dual polarization) battery model is established to verify the ISCr detection method. The 1–1000 Ω s ISCr(the early stage ISCr) can be effectively detected within 1–125 s. The SLCT provides the possibility of new battery pack designs and new battery management methods. The proposed ISCr detection method shows excellent effectiveness and efficiency on the identification of the ISCr battery in the early stage. 展开更多
关键词 internal short circuit faulty detection lithium battery circuit topology battery pack safety
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