We explored the potential of the environment and disaster monitoring and forecasting small satellite constellations (HJ-1A/1B satellites) charge-coupled device (CCD) imagery (spatial resolution of 30 m, revisit time o...We explored the potential of the environment and disaster monitoring and forecasting small satellite constellations (HJ-1A/1B satellites) charge-coupled device (CCD) imagery (spatial resolution of 30 m, revisit time of 2 days) in the monitoring of total suspended sediment (TSS) concentrations in dynamic water bodies using Poyang Lake, the largest freshwater lake in China, as an example. Field surveys conducted during October 17-26, 2009 showed a wide range of TSS concentration (3-524 mg/L). Atmospheric correction was implemented using the Fast Line-of-sight Atmospheric Analysis of Spectral Hypercubes (FLAASH) module in ENVI with the aid of aerosol information retrieved from concurrent Terra/Moderate Resolution Imaging Spectroradiometer (MODIS) surveys, which worked well at the CCD bands with relatively high reflectance. A practical exponential retrieval algorithm was created between satellite remote sensing reflectance and in-situ measured TSS concentration. The retrieved results for the whole water area matched the in-situ data well at most stations. The retrieval errors may be related to the problem of scale matching and mixed pixel. In three selected subregions of Poyang Lake, the distribution trend of retrieved TSS was consistent with that of the field investigation. It was shown that HJ-1A/1B CCD imagery can be used to estimate TSS concentrations in Poyang Lake over synoptic scales after applying an appropriate atmospheric correction method and retrieval algorithm.展开更多
As the earliest invented and utilized communication approach, shortwave, known as high frequency(HF) communication now experience the deterioration of HF electromagnetic environment. Finding quality frequency in effic...As the earliest invented and utilized communication approach, shortwave, known as high frequency(HF) communication now experience the deterioration of HF electromagnetic environment. Finding quality frequency in efficient manner becomes one of the key challenges in HF communication. Spectrum prediction infers the future spectrum status from history spectrum data by exploring the inherent correlations and regularities. The investigation of HF electromagnetic environment data reveals the correlations and predictability of HF frequency band in both time and frequency domain. To solve this problem, we develop a Spectrum Prediction-based Frequency Band Pre-selection(SP-FBP) for HF communications. The pre-selection of HF frequency band mainly incorporated in prediction of HF spectrum occupancy and prediction of HF usable frequency, which provide the frequency band ranking of spectrum occupancy and alternative frequency for spectrum sensing, respectively. Performance evaluation via real-world HF spectrum data shows that SP-FBP significantly improves the efficiency of finding quality frequency in HF communications.展开更多
A novel composite charged mosaic membrane(CCMM) was prepared via interfacial polymerization(IP) of polyamine[poly(epichlorohydrin amine) ]and trimesoyl chloride(TMC) on the polyethersulfone(PES) support. Fourier trans...A novel composite charged mosaic membrane(CCMM) was prepared via interfacial polymerization(IP) of polyamine[poly(epichlorohydrin amine) ]and trimesoyl chloride(TMC) on the polyethersulfone(PES) support. Fourier transform infrared spectroscopy(FT-IR) ,environmental scanning electron microscopy(ESEM) ,atomic force microscopy(AFM) and water contact angle analysis were applied to characterize the resulted CCMM.The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine.ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane.The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network.Several factors affecting the IP reaction and the performance of the CCMM,such as monomer concentration,reaction time,pH value of aqueous phase solution and post-treatment,were studied.The pure water flux of the optimized CCMM is 14.73 L·m -2 ·h -1 ·MPa -1 at the operating pressure of 0.4 MPa.The values of separation factorαfor NaCl/PEG1000/water and MgCl2/PEG1000/water are 11.89 and 9.96,respectively.These results demonstrate that CCMM is promising for the separation of low-molecular-weight organics from their salt aqueous solutions.展开更多
Detection of sulfur-oxidizing bacteria has largely been dependent on targeted gene sequencing technology or traditional cell cultivation, which usually takes from days to months to carry out. This clearly does not mee...Detection of sulfur-oxidizing bacteria has largely been dependent on targeted gene sequencing technology or traditional cell cultivation, which usually takes from days to months to carry out. This clearly does not meet the requirements of analysis for time-sensitive samples and/or complicated environmental samples. Since energy-dispersive X-ray spectrometry(EDS) can be used to simultaneously detect multiple elements in a sample, including sulfur, with minimal sample treatment, this technology was applied to detect sulfur-oxidizing bacteria using their high sulfur content within the cell. This article describes the application of scanning electron microscopy imaging coupled with EDS mapping for quick detection of sulfur oxidizers in contaminated environmental water samples, with minimal sample handling. Scanning electron microscopy imaging revealed the existence of dense granules within the bacterial cells, while EDS identified large amounts of sulfur within them. EDS mapping localized the sulfur to these granules. Subsequent 16S rRNA gene sequencing showed that the bacteria detected in our samples belonged to the genus Chromatium, which are sulfur oxidizers. Thus, EDS mapping made it possible to identify sulfur oxidizers in environmental samples based on localized sulfur within their cells, within a short time(within 24 h of sampling). This technique has wide ranging applications for detection of sulfur bacteria in environmental water samples.展开更多
A novel ambient negative corona discharge ion source with mini line-cylinder electrodes is designed. The diameters of inner and outer electrode are 0.16 and 4 mm respectively. With a special assembly method, a perfect...A novel ambient negative corona discharge ion source with mini line-cylinder electrodes is designed. The diameters of inner and outer electrode are 0.16 and 4 mm respectively. With a special assembly method, a perfect coaxiality of the two electrodes is obtained. An injection system utilizing a temperature control technique, achieves a constant and stable concentration of the sample, which is critical to the experiment. The formulas of the corona onset voltage of line-cylinder electrodes are also introduced. The experiment results show that negative substances such as formic acid and acetic acid can be ionized under ambient conditions. When combined with micro electrical mechanical system fabricationprocess, the volume of the ion source can be reduced dramatically, but there is an undesirable surface discharge. To solve the surface discharge problem, an improved structure was designed and tested. The simplicity of the interface of the ion source makes it suitable for mass spectrometer, micro mass spectrometer, ion mobility spectrometer, and high-field asymmetric waveform ion mobility spectrometer applications.展开更多
A newly developed Deep Ocean Compact Autonomous Raman Spectrometer （DOCARS） system is introduced and used for in-situ detection of acid radical ions in this paper. To evaluate the feasibility and capability of DOCAR...A newly developed Deep Ocean Compact Autonomous Raman Spectrometer （DOCARS） system is introduced and used for in-situ detection of acid radical ions in this paper. To evaluate the feasibility and capability of DOCARS for quantitative analysis of the acid radical ions in the deep ocean, extensive investigations have been carried out both in laboratory and sea trials during the development phase. In the laboratory investigations, Raman spectra of the prepared samples （acid radical ions solutions） were obtained, and analyzed using the method of internal standard normalization in data processing. The Raman signal of acid radical ions was normalized by that of water molecules. The calibration curve showed that the normalized Raman signal intensity of SO4^2-, NO3^-, and HCO^-3 increases linearly as the concentration rises with correlation coefficient R^2 of 0.99, 0.99, and 0.98 respectively. The linear function obtained from the calibration curve was then used for the analysis of the spectra ,data acquired in the sea trial under a simulating chemical field in the deep-sea environment. It was found that the detected concentration of NO3 according to the linear function can reflect the concentration changes of NO~ after the sample was released, and the detection accuracy of the DOCARS system for SO^2-_4 is 8%. All the results showed that the DOCARS system has great potential in quantitative detection of acid radical ions under the deep-sea environment, while the sensitivity of the DOCARS system is expected to be improved.展开更多
In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost ef...In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost effective process to minimize the environmental impacts of oil spills and cleanup these pollutants. In this work, the crude oil sorption capacity was examined with raw sugarcane bagasse and acetylated sugarcane bagasse. Results show that the acetylated bagasse was significantly more oleophilic than the raw bagasse and acetylation reaction can increase bagasse oil sorption ability by about 90%. The maximum sorption capacities of acetylated bagasse were obtained about 11.3 g and 9.1 g in dry system(crude oil sorption) and oil layer sorption, respectively. The physicochemical characteristics of the sorbents such as composition, water solubility, moisture content and density were measured according to ASTM standard methods. Also Fourier transform infrared spectroscopy(FTIR) of raw and acetylated bagasse was performed to investigate the effect of acetylation on sugarcane bagasse structure.展开更多
基金Supported by the National Basic Research Program of China(973Program)(No.2011CB707106)the National Natural Science Foundation of China(Nos.41071261,41023001,41021061,40906092,40971193,41101415)+3 种基金the Opening Foundation of Institute of Remote Sensing and Earth Sciences,Hangzhou Normal University(No.PDKF2010YG06)the Fundamental Research Funds for the Central Universities,the China Postdoctoral Science Foundation(No.20100480861)LIESMARS Special Research Funding,the Natural Science Foundation of Hubei Province,China(No.2009CDB107)the Natural Science Foundation of Zhejiang Province,China(No.Y5090143)
文摘We explored the potential of the environment and disaster monitoring and forecasting small satellite constellations (HJ-1A/1B satellites) charge-coupled device (CCD) imagery (spatial resolution of 30 m, revisit time of 2 days) in the monitoring of total suspended sediment (TSS) concentrations in dynamic water bodies using Poyang Lake, the largest freshwater lake in China, as an example. Field surveys conducted during October 17-26, 2009 showed a wide range of TSS concentration (3-524 mg/L). Atmospheric correction was implemented using the Fast Line-of-sight Atmospheric Analysis of Spectral Hypercubes (FLAASH) module in ENVI with the aid of aerosol information retrieved from concurrent Terra/Moderate Resolution Imaging Spectroradiometer (MODIS) surveys, which worked well at the CCD bands with relatively high reflectance. A practical exponential retrieval algorithm was created between satellite remote sensing reflectance and in-situ measured TSS concentration. The retrieved results for the whole water area matched the in-situ data well at most stations. The retrieval errors may be related to the problem of scale matching and mixed pixel. In three selected subregions of Poyang Lake, the distribution trend of retrieved TSS was consistent with that of the field investigation. It was shown that HJ-1A/1B CCD imagery can be used to estimate TSS concentrations in Poyang Lake over synoptic scales after applying an appropriate atmospheric correction method and retrieval algorithm.
基金the Project of National Natural Science Foundation of China (Grant No. 61471395, No. 61301161, and No. 61501510)partly supported by Natural Science Foundation of Jiangsu Province (Grant No. BK20161125 and No. BK20150717)
文摘As the earliest invented and utilized communication approach, shortwave, known as high frequency(HF) communication now experience the deterioration of HF electromagnetic environment. Finding quality frequency in efficient manner becomes one of the key challenges in HF communication. Spectrum prediction infers the future spectrum status from history spectrum data by exploring the inherent correlations and regularities. The investigation of HF electromagnetic environment data reveals the correlations and predictability of HF frequency band in both time and frequency domain. To solve this problem, we develop a Spectrum Prediction-based Frequency Band Pre-selection(SP-FBP) for HF communications. The pre-selection of HF frequency band mainly incorporated in prediction of HF spectrum occupancy and prediction of HF usable frequency, which provide the frequency band ranking of spectrum occupancy and alternative frequency for spectrum sensing, respectively. Performance evaluation via real-world HF spectrum data shows that SP-FBP significantly improves the efficiency of finding quality frequency in HF communications.
基金Supported by the National High Technology Research and Development Program of China（2008AA06Z330） the National Natural Science Foundation of China（20676125） the Technician Service Enterprise Action Program（2009GJD00048）
文摘A novel composite charged mosaic membrane(CCMM) was prepared via interfacial polymerization(IP) of polyamine[poly(epichlorohydrin amine) ]and trimesoyl chloride(TMC) on the polyethersulfone(PES) support. Fourier transform infrared spectroscopy(FT-IR) ,environmental scanning electron microscopy(ESEM) ,atomic force microscopy(AFM) and water contact angle analysis were applied to characterize the resulted CCMM.The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine.ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane.The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network.Several factors affecting the IP reaction and the performance of the CCMM,such as monomer concentration,reaction time,pH value of aqueous phase solution and post-treatment,were studied.The pure water flux of the optimized CCMM is 14.73 L·m -2 ·h -1 ·MPa -1 at the operating pressure of 0.4 MPa.The values of separation factorαfor NaCl/PEG1000/water and MgCl2/PEG1000/water are 11.89 and 9.96,respectively.These results demonstrate that CCMM is promising for the separation of low-molecular-weight organics from their salt aqueous solutions.
基金Supported by the Basic Scientific Fund for National Public Research Institutes of China(Nos.GY02-2011T10,2015P07)the Qingdao Talent Program(No.13-CX-20)+1 种基金the National Natural Science Foundation of China(Nos.31100567,41176061)the National Natural Science Foundation for Creative Groups(No.41521064)
文摘Detection of sulfur-oxidizing bacteria has largely been dependent on targeted gene sequencing technology or traditional cell cultivation, which usually takes from days to months to carry out. This clearly does not meet the requirements of analysis for time-sensitive samples and/or complicated environmental samples. Since energy-dispersive X-ray spectrometry(EDS) can be used to simultaneously detect multiple elements in a sample, including sulfur, with minimal sample treatment, this technology was applied to detect sulfur-oxidizing bacteria using their high sulfur content within the cell. This article describes the application of scanning electron microscopy imaging coupled with EDS mapping for quick detection of sulfur oxidizers in contaminated environmental water samples, with minimal sample handling. Scanning electron microscopy imaging revealed the existence of dense granules within the bacterial cells, while EDS identified large amounts of sulfur within them. EDS mapping localized the sulfur to these granules. Subsequent 16S rRNA gene sequencing showed that the bacteria detected in our samples belonged to the genus Chromatium, which are sulfur oxidizers. Thus, EDS mapping made it possible to identify sulfur oxidizers in environmental samples based on localized sulfur within their cells, within a short time(within 24 h of sampling). This technique has wide ranging applications for detection of sulfur bacteria in environmental water samples.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.60706030 and No.20827007）, the National High Technology Research and Development Plan of China （No.2007AA 04Z337） and the State Key Laboratory Fund （No.9140 C12040506060C12）.
文摘A novel ambient negative corona discharge ion source with mini line-cylinder electrodes is designed. The diameters of inner and outer electrode are 0.16 and 4 mm respectively. With a special assembly method, a perfect coaxiality of the two electrodes is obtained. An injection system utilizing a temperature control technique, achieves a constant and stable concentration of the sample, which is critical to the experiment. The formulas of the corona onset voltage of line-cylinder electrodes are also introduced. The experiment results show that negative substances such as formic acid and acetic acid can be ionized under ambient conditions. When combined with micro electrical mechanical system fabricationprocess, the volume of the ion source can be reduced dramatically, but there is an undesirable surface discharge. To solve the surface discharge problem, an improved structure was designed and tested. The simplicity of the interface of the ion source makes it suitable for mass spectrometer, micro mass spectrometer, ion mobility spectrometer, and high-field asymmetric waveform ion mobility spectrometer applications.
基金Supported by the National High Technology Research and Development Program of China(863 Program)(Nos.2006AA09Z243,2012AA09A405)
文摘A newly developed Deep Ocean Compact Autonomous Raman Spectrometer （DOCARS） system is introduced and used for in-situ detection of acid radical ions in this paper. To evaluate the feasibility and capability of DOCARS for quantitative analysis of the acid radical ions in the deep ocean, extensive investigations have been carried out both in laboratory and sea trials during the development phase. In the laboratory investigations, Raman spectra of the prepared samples （acid radical ions solutions） were obtained, and analyzed using the method of internal standard normalization in data processing. The Raman signal of acid radical ions was normalized by that of water molecules. The calibration curve showed that the normalized Raman signal intensity of SO4^2-, NO3^-, and HCO^-3 increases linearly as the concentration rises with correlation coefficient R^2 of 0.99, 0.99, and 0.98 respectively. The linear function obtained from the calibration curve was then used for the analysis of the spectra ,data acquired in the sea trial under a simulating chemical field in the deep-sea environment. It was found that the detected concentration of NO3 according to the linear function can reflect the concentration changes of NO~ after the sample was released, and the detection accuracy of the DOCARS system for SO^2-_4 is 8%. All the results showed that the DOCARS system has great potential in quantitative detection of acid radical ions under the deep-sea environment, while the sensitivity of the DOCARS system is expected to be improved.
文摘In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost effective process to minimize the environmental impacts of oil spills and cleanup these pollutants. In this work, the crude oil sorption capacity was examined with raw sugarcane bagasse and acetylated sugarcane bagasse. Results show that the acetylated bagasse was significantly more oleophilic than the raw bagasse and acetylation reaction can increase bagasse oil sorption ability by about 90%. The maximum sorption capacities of acetylated bagasse were obtained about 11.3 g and 9.1 g in dry system(crude oil sorption) and oil layer sorption, respectively. The physicochemical characteristics of the sorbents such as composition, water solubility, moisture content and density were measured according to ASTM standard methods. Also Fourier transform infrared spectroscopy(FTIR) of raw and acetylated bagasse was performed to investigate the effect of acetylation on sugarcane bagasse structure.
