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大气中多环芳烃气/粒分配的不确定性分析 被引量:8
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作者 刘碧莲 吴水平 +2 位作者 杨冰玉 郑桉 王新红 《环境科学》 EI CAS CSCD 北大核心 2011年第9期2794-2799,共6页
于2010年8月10~14日用双层石英膜和双层聚氨酯泡沫(PUF)的方法采集并分析了厦门大学海洋楼顶大气中气态和颗粒态多环芳烃(PAHs),并采用标准误差传递方法对气/粒分配系数(Kp)的不确定度进行了分析.测量结果显示,低分子量PAHs如萘、苊、... 于2010年8月10~14日用双层石英膜和双层聚氨酯泡沫(PUF)的方法采集并分析了厦门大学海洋楼顶大气中气态和颗粒态多环芳烃(PAHs),并采用标准误差传递方法对气/粒分配系数(Kp)的不确定度进行了分析.测量结果显示,低分子量PAHs如萘、苊、二氢苊和芴在PUF吸附体系中的穿透能力最强,穿透率接近50%;如考虑第一层石英滤膜对气态萘、苊和二氢苊的吸附影响,则校正后的Kp值比校正前相应的Kp值低1个数量级以上.采用标准误差传递方法得到PAHs气/粒分配系数Kp的不确定度,介于28.14%~50.37%之间,且表现为易挥发和难挥发性PAHs的Kp值皆具有较高的不确定度,而半挥发性PAHs的Kp值的不确定度则较小.Kp值的不确定度来源分析显示,气态PAHs浓度的不确定度的影响最大(方差贡献均值=77.9%),其次为颗粒态PAHs浓度的不确定度(方差贡献均值=22.0%),大气颗粒物浓度的不确定度影响最小(方差贡献均值=0.1%).因此,选择合适的采样系统以获取更加准确的气态PAHs的浓度,是提高PAHs气/粒分配系数准确度的关键. 展开更多
关键词 多环芳烃 /粒分配 滤膜吸附 穿透率 不确定性分析 误差传递
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大连城区秋季大气中短链氯化石蜡的气/粒相分配行为研究 被引量:1
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作者 白皓 朱秀华 +6 位作者 高媛 陈吉平 王龙星 袁和平 李潇潇 王炜 董学伟 《大连交通大学学报》 CAS 2017年第6期78-84,共7页
研究了大连市城区秋季(10月和11月)大气中SCCPs在气相和颗粒相中的浓度及分布特征,计算了SCCPs的气/粒相分配系数,研究了其与环境温度、SCCPs的过冷液体蒸汽压及正辛醇-空气分配系数的相关性.结果表明,秋季大连大气中SCCPs主要以气态形... 研究了大连市城区秋季(10月和11月)大气中SCCPs在气相和颗粒相中的浓度及分布特征,计算了SCCPs的气/粒相分配系数,研究了其与环境温度、SCCPs的过冷液体蒸汽压及正辛醇-空气分配系数的相关性.结果表明,秋季大连大气中SCCPs主要以气态形式存在.气相中SCCPs浓度10月明显高于11月,但颗粒相中SCCPs浓度11月与10月变化不明显.大气中SCCPs的气/粒相分配系数与其过冷液体蒸汽压和正辛醇-空气分配系数均有较好的线性相关性,对秋季大气中SCCPs的气/粒相分配起主导作用的是颗粒物中的有机质吸收机理,环境温度对其气/粒相分配行为有一定的影响. 展开更多
关键词 大连 大气 短链氯化石蜡 /粒分配
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粒径影响下多溴联苯醚皮肤暴露摄入量预测方法
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作者 胡鹏抟 张子峰 +3 位作者 马万里 刘丽艳 宋维薇 李一凡 《哈尔滨工业大学学报》 EI CAS CSCD 北大核心 2022年第2期67-72,共6页
为改善污染物人体暴露的评估方法,研究了哈尔滨大气环境中多溴联苯醚(PBDEs)的暴露情况,评估各形态PBDEs单体经皮肤每日摄入量,利用多粒径气/粒分配公式与皮肤摄入量公式,实现对粒径影响下颗粒态PBDEs经皮肤每日摄入量的预测。结果表明... 为改善污染物人体暴露的评估方法,研究了哈尔滨大气环境中多溴联苯醚(PBDEs)的暴露情况,评估各形态PBDEs单体经皮肤每日摄入量,利用多粒径气/粒分配公式与皮肤摄入量公式,实现对粒径影响下颗粒态PBDEs经皮肤每日摄入量的预测。结果表明,哈尔滨大气PBDEs经皮肤摄入量为71.6 pg/d,颗粒态和气态PBDEs的经皮肤摄入量相当,分别为32.8和38.8 pg/d,BDE-209是经皮肤摄入的主要单体。受颗粒物质量浓度影响,供暖期的PBDEs经皮肤摄入量高于非供暖期。颗粒态PBDEs的经皮肤摄入量由粗颗粒主导,其中传质系数为主要影响因素。本研究首次提出预测粒径影响下颗粒态PBDEs经皮肤摄入量的方法,并应用哈尔滨、上海和广州的监测数据进行验证,证明之前推导的恒稳态多粒径气/粒分配公式可以很好地预测粒径影响下颗粒态PBDEs的经皮肤摄入量。 展开更多
关键词 多溴联苯醚 皮肤暴露 /粒分配
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Growth mechanism of primary silicon in cast hypoeutectic Al-Si alloys 被引量:10
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作者 王守仁 马茹 +2 位作者 王英姿 王勇 杨丽颖 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第6期1264-1269,共6页
The microstructural features of hypoeutectic AI-10%Si alloy were observed using optical microscopy and electron backscatter diffraction. The results show that primary silicon particles are frequently found in hypoeute... The microstructural features of hypoeutectic AI-10%Si alloy were observed using optical microscopy and electron backscatter diffraction. The results show that primary silicon particles are frequently found in hypoeutectic alloys. Hence, the nucleation and growth mechanisms of the precipitation of primary silicon of hypoeutectic Al-10%Si alloy melts were investigated. It was discovered that Si atoms are easy to segregate and form Si-Si clusters, which results in the formation of primary silicon even in eutectic or hypoeutectic Al-Si alloys. In addition, solute redistribution caused by chemical driving force and large pile-ups or micro-segregation of the solute play an important role in the formation of the primary silicon, and the solute redistribution equations were derived from Jackson-Chalmers equations. Once Si solute concentration exceeds eutectic composition, primary silicon precipitates are formed at the front of solid/liquid interface. 展开更多
关键词 Al-Si alloys SOLIDIFICATION crystal growth primary silicon solute redistribution
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Applicability of Fractal Models in Estimating Soil Water Retention Characteristics from Particle-Size Distribution Data 被引量:8
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作者 LIU JIANLI and XU SHAOHUIInstitute of Soil Science, the Chinese Academy of Sciences, Nanjing 210008 (China) 《Pedosphere》 SCIE CAS CSCD 2002年第4期301-308,共8页
Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics frompartic... Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics fromparticle-size distribution data. Predictive capabilities of three fractal models, i.e, Tyler-Wheatcraft model,Rieu-Sposito model, and Brooks-Corey model, were fully evaluated in this work using experimental datafrom an international database and literature. Particle-size distribution data were firstly interpolated into20 classes using a van Genuchten-type equation. Fractal dimensions of the tortuous pore wall and the poresurface were then calculated from the detailed particle-size distribution and incorporated as a parameter infractal water retention models. Comparisons between measured and model-estimated water retention cha-racteristics indicated that these three models were applicable to relatively different soil textures and pressurehead ranges. Tyler-Wheatcraft and Brooks-Corey models led to reasonable agreements for both coarse- andmedium-textured soils, while the latter showed applicability to a broader texture range. In contrast, Rieu-Sposito model was more suitable for fine-textured soils. Fractal models produced a better estimation of watercontents at low pressure heads than at high pressure heads. 展开更多
关键词 fractal model particle-size distribution soil water retention characteristics
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Multiple objective particle swarm optimization technique for economic load dispatch 被引量:2
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作者 赵波 曹一家 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第5期420-427,共8页
A multi-objective particle swarm optimization (MOPSO) approach for multi-objective economic load dispatch problem in power system is presented in this paper. The economic load dispatch problem is a non-linear constrai... A multi-objective particle swarm optimization (MOPSO) approach for multi-objective economic load dispatch problem in power system is presented in this paper. The economic load dispatch problem is a non-linear constrained multi-objective optimization problem. The proposed MOPSO approach handles the problem as a multi-objective problem with competing and non-commensurable fuel cost, emission and system loss objectives and has a diversity-preserving mechanism using an external memory (call “repository”) and a geographically-based approach to find widely different Pareto-optimal solutions. In addition, fuzzy set theory is employed to extract the best compromise solution. Several optimization runs of the proposed MOPSO approach were carried out on the standard IEEE 30-bus test system. The results revealed the capabilities of the proposed MOPSO approach to generate well-distributed Pareto-optimal non-dominated solutions of multi-objective economic load dispatch. Com- parison with Multi-objective Evolutionary Algorithm (MOEA) showed the superiority of the proposed MOPSO approach and confirmed its potential for solving multi-objective economic load dispatch. 展开更多
关键词 Economic load dispatch Multi-objective optimization Multi-objective particle swarm optimization
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Stereo garage parking space allocation model and simulation analysis 被引量:1
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作者 WANG Xiao-nong LI Jian-guo HE Yun-peng 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2019年第4期369-378,共10页
Based on grey neural network and particle swarm optimization algorithm,an automated stereo garage decision model is proposed to solve the problems of long waiting queue and low efficiency of automated parking garage.T... Based on grey neural network and particle swarm optimization algorithm,an automated stereo garage decision model is proposed to solve the problems of long waiting queue and low efficiency of automated parking garage.The gray neural network is used to forecast the stay time of the vehicle and particle swarm optimization algorithm is used to allocate the parking spaces in the stereo garage.The proposed stereo garage mathematical model is established on condition that vehicle arrival interval obeys Poisson distribution.The performance of stereo garage is evaluated by the average waiting time,average waiting queue length,average service time and average energy consumption of the customers.By comparing the efficiency indexes of the existing model based on near-distribution principle and the proposed model based on gray neural network and particle swarm algorithm,it is proved that the proposed model based on gray neural network and particle swarm algorithm is effective in improving the efficiency of garage operation and reducing the energy consumption of garage. 展开更多
关键词 stereo garage parking space allocation particle swarm algorithm grey neural network algorithm near-distribution principle
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Global Optimization for the Synthesis of Integrated Water Systems with Particle Swarm Optimization Algorithm 被引量:9
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作者 罗袆青 袁希钢 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2008年第1期11-15,共5页
The problem of optimal synthesis of an integrated water system is addressed in this study, where water using processes and water treatment operations are combined into a single network such that the total cost of fres... The problem of optimal synthesis of an integrated water system is addressed in this study, where water using processes and water treatment operations are combined into a single network such that the total cost of fresh water and wastewater treatment is globally minimized. A superstructure that incorporates all feasible design alterna- tives for wastewater treatment, reuse and recycle, is synthesized with a non-linear programming model. An evolutionary approach--an improved particle swarm optimization is proposed for optimizing such systems. Two simple examples are .Presented.to illustrate the global op.timization of inte.grated water networks using the proposed algorithm. 展开更多
关键词 integrated water network water minimization particle swarm optimization
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Deterministic Quantum Key Distribution Using Two Non-orthogonal Entangled States 被引量:3
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作者 GUO Ying ZENG Gui-Hua 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第3期459-463,共5页
A deterministic quantum key distribution scheme using two non-orthogonal entangled states is proposed. In the proposed scheme, communicators share key information by exchanging one travelling photon with two random an... A deterministic quantum key distribution scheme using two non-orthogonal entangled states is proposed. In the proposed scheme, communicators share key information by exchanging one travelling photon with two random and secret polarization angles. The security of the distributed key is guaranteed by three checking phases in three-way channel and the communicators' secret polarization angles. 展开更多
关键词 quantum key distribution quantum entanglement state
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Investigation of condition-induced bubble size and distribution in electroflotation using a high-speed camera 被引量:2
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作者 Ren Liuyi Zhang Yimin +3 位作者 Qin Wenqing Bao Shenxu Wang Peipei Yang Congren 《International Journal of Mining Science and Technology》 SCIE EI 2014年第1期7-12,共6页
In the flotation process, bubble is a key factor in studying bubble-particle interaction and fine particle flo- tation. Knowledge on size distribution of bubbles in a flotation system is highly important. In this stud... In the flotation process, bubble is a key factor in studying bubble-particle interaction and fine particle flo- tation. Knowledge on size distribution of bubbles in a flotation system is highly important. In this study, bubble distributions in different reagent concentrations, electrolyte concentrations, cathode apertures, and current densities in electroflotation are determined using a high-speed camera. Average bubble sizes under different conditions are calculated using Image-Pro@ Plus (Media Cybernetics@, MD, USA) and SigmaScan@ Pro (Systat Software, CA, USA) software. Results indicate that the average sizes of bubbles, which were generated through 38, 50, 74, 150, 250, 420, and 1000 μm cathode apertures, are 20.2, 29.5, 44.6, 59.2, 68.7, 78.5, and 88.8 μm, respectively. The optimal current density in electroflotation is 20 A/m2. Reagent and electrolyte concentrations, current density, and cathode aperture are important factors in controlling bubble size and nucleation. These factors also contribute to the control of fine- Particle flotation. 展开更多
关键词 High-speed camera Bubble Electroflotation Fine particle Bubble production and control
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An algorithm for earthwork allocation considering non-linear factors
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作者 王仁超 刘金飞 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2008年第6期835-840,共6页
For solving the optimization model of earthwork allocation considering non-linear factors,a hybrid algorithm combined with the ant algorithm(AA)and particle swarm optimization(PSO)is proposed in this paper.Then the pr... For solving the optimization model of earthwork allocation considering non-linear factors,a hybrid algorithm combined with the ant algorithm(AA)and particle swarm optimization(PSO)is proposed in this paper.Then the proposed method and the LP method are used respectively in solving a linear allocation model of a high rockfill dam project.Results obtained by these two methods are compared each other.It can be concluded that the solution got by the proposed method is extremely approximate to the analytic solution of LP method.The superiority of the proposed method over the LP method in solving a non-linear allocation model is illustrated by a non-linear case.Moreover,further researches on improvement of the algorithm and the allocation model are addressed. 展开更多
关键词 earthwork allocation linear programming ant algorithm particle swarm optimization optimize
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Hybrid particle swarm optimization with differential evolution and chaotic local search to solve reliability-redundancy allocation problems 被引量:5
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作者 谭跃 谭冠政 邓曙光 《Journal of Central South University》 SCIE EI CAS 2013年第6期1572-1581,共10页
In order to solve reliability-redundancy allocation problems more effectively, a new hybrid algorithm named CDEPSO is proposed in this work, which combines particle swarm optimization (PSO) with differential evoluti... In order to solve reliability-redundancy allocation problems more effectively, a new hybrid algorithm named CDEPSO is proposed in this work, which combines particle swarm optimization (PSO) with differential evolution (DE) and a new chaotic local search. In the CDEPSO algorithm, DE provides its best solution to PSO if the best solution obtained by DE is better than that by PSO, while the best solution in the PSO is performed by chaotic local search. To investigate the performance of CDEPSO, four typical reliability-redundancy allocation problems were solved and the results indicate that the convergence speed and robustness of CDEPSO is better than those of PSO and CPSO (a hybrid algorithm which only combines PSO with chaotic local search). And, compared with the other six improved meta-heuristics, CDEPSO also exhibits more robust performance. In addition, a new performance was proposed to more fairly compare CDEPSO with the same six improved recta-heuristics, and CDEPSO algorithm is the best in solving these problems. 展开更多
关键词 particle swarm optimization differential evolution chaotic local search reliability-redundancy allocation
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AN ITERATIVE PARTICLE FILTER SIGNAL DETECTOR FOR MIMO FAST FADING CHANNELS
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作者 Yang Tao Hu Bo 《Journal of Electronics(China)》 2008年第2期157-165,共9页
For flat fast fading Multiple-Input Multiple-Output(MIMO) channels,this paper presents a sampling based channel estimation and an iterative Particle Filter(PF) signal detection scheme. The channel estimation is compri... For flat fast fading Multiple-Input Multiple-Output(MIMO) channels,this paper presents a sampling based channel estimation and an iterative Particle Filter(PF) signal detection scheme. The channel estimation is comprised of two parts:the adaptive iterative update on the channel distribution mean and a regular update on the "adaptability" via pilot. In the detection procedure,the PF is employed to produce the optimal decision given the known received signal and the sequence of the channel samples,where an asymptotic optimal importance density is constructed,and in terms of the asymptotic update order,the Parallel Importance Update(PIU) and the Serial Importance Update(SIU) scheme are performed respectively. The simulation results show that for the given fading channel,if an appropriate pilot mode is selected,the proposed scheme is more robust than the conventional Kalman filter based superimposed detection scheme. 展开更多
关键词 Multiple-Input Multiple-Output Update (PIU) Serial Importance Update (SIU) (MIMO) Particle Filter (PF) Parallel Importance
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The influence of discharge style on the separation of coarse coal slime by a hindered fluidized bed
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《Journal of Coal Science & Engineering(China)》 2012年第1期96-100,共5页
Two kinds of liquid distributor, a central discharge or a peripheral discharge, were designed into a hindered fluid- ized bed separator. The beneficiation performance of the fluidized bed was investigated using 0.25-1... Two kinds of liquid distributor, a central discharge or a peripheral discharge, were designed into a hindered fluid- ized bed separator. The beneficiation performance of the fluidized bed was investigated using 0.25-1.00 mm coarse coal slime and the two different distributors. The experimental results show that the heterogeneity of axial particle velocity in the radial direction of the bed can be reduced by a distributor that has a central discharge. The beneficiation performance for this dis- tributor is improved relative to the distributor with the peripheral discharge. This indicates that it is necessary to eliminate or suppress the core-annulus structure within a hindered fluidized bed. Increasing superficial water velocity causes the clean coal ash content, the railings ash content, and the combustible recovery to increase. Additionally, increasing the bed height decreases all of these three indexes. The optimum superficial water velocity and bed height for a 0.25-1.00 mm coal feed were deter- mined to be 3 mm/s and 800 mm, respectively. This work provides a foundation for the scale-up of the bed. 展开更多
关键词 discharge style coarse coal slime hindered fluidized bed liquid distributor
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Dependent task assignment algorithm based on particle swarm optimization and simulated annealing in ad-hoc mobile cloud 被引量:3
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作者 Huang Bonan Xia Weiwei +4 位作者 Zhang Yueyue Zhang Jing Zou Qian Yan Feng Shen Lianfeng 《Journal of Southeast University(English Edition)》 EI CAS 2018年第4期430-438,共9页
In order to solve the problem of efficiently assigning tasks in an ad-hoc mobile cloud( AMC),a task assignment algorithm based on the heuristic algorithm is proposed. The proposed task assignment algorithm based on pa... In order to solve the problem of efficiently assigning tasks in an ad-hoc mobile cloud( AMC),a task assignment algorithm based on the heuristic algorithm is proposed. The proposed task assignment algorithm based on particle swarm optimization and simulated annealing( PSO-SA) transforms the dependencies between tasks into a directed acyclic graph( DAG) model. The number in each node represents the computation workload of each task and the number on each edge represents the workload produced by the transmission. In order to simulate the environment of task assignment in AMC,mathematical models are developed to describe the dependencies between tasks and the costs of each task are defined. PSO-SA is used to make the decision for task assignment and for minimizing the cost of all devices,which includes the energy consumption and time delay of all devices.PSO-SA also takes the advantage of both particle swarm optimization and simulated annealing by selecting an optimal solution with a certain probability to avoid falling into local optimal solution and to guarantee the convergence speed. The simulation results show that compared with other existing algorithms,the PSO-SA has a smaller cost and the result of PSO-SA can be very close to the optimal solution. 展开更多
关键词 ad-hoc mobile cloud task assignment algorithm directed acyclic graph particle swarm optimization simulated annealing
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Unsymmetrical Quantum Key Distribution Using Tripartite Entanglement 被引量:1
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作者 XIONG Jin ZHANG Zhe-Shen +2 位作者 ZHOU Nan-Run PENG Jin-Ye ZENG Gui-Hua 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第3期441-445,共5页
An unsymmetrical quantum key distribution protocol is proposed, in which Greenherger-Horne-Zeilinger (GHZ) triplet states are used to obtain the secret key. Except the lost qubits due to the unperfectness of the phy... An unsymmetrical quantum key distribution protocol is proposed, in which Greenherger-Horne-Zeilinger (GHZ) triplet states are used to obtain the secret key. Except the lost qubits due to the unperfectness of the physical devices, the unsymmetrical characteristic makes all transmitted qubits useful. This leads to:an excellent efficiency, which reaches 100% in an ideal case. The 'security is studied from the aspect of information theory. By using the correlation of the GHZ tripartite entanglement state, eavesdropping can be easily checked out, which indicates that the presented protocol is more secure. 展开更多
关键词 unsymmetrical quantum key distribution GHZ triplet states
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A thioether-functionalized pyrene-based covalent organic framework anchoring ultrafine Au nanoparticles for efficient photocatalytic hydrogen generation 被引量:1
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作者 Zhiming Zhou Chuanbiao Bie +2 位作者 Peize Li Bien Tan Yan Shen 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第10期2699-2707,共9页
Covalent organic frameworks(COFs)have lately emerged as a blooming class of potential materials for photocatalytic water splitting because of their high crystallinity,huge surface areas,and structural versatility.Howe... Covalent organic frameworks(COFs)have lately emerged as a blooming class of potential materials for photocatalytic water splitting because of their high crystallinity,huge surface areas,and structural versatility.However,the photocatalytic performance for most pure COFs face some limitations factors,such as the significant recombination of photogenerated carriers and slow charge transfer.Herein,a novel thioether-functionalized pyrene-based COF(S_(4)-COF)was effectively produced and chosen as a support for the immobilization of ultrafine gold nanoparticles(Au NPs).S_(4)-COF photocatalyst with Au as cocatalyst demonstrates remarkable photocatalytic activity with a H_(2) generation rate of 1377μmol g^(−1) h^(−1) under visible light(>420 nm),which is ca.4.5-fold increase comparing to that of pure S_(4)-COF(302μmol g^(−1) h^(−1)).Au NPs anchored on S_(4)-COF possess an ultrafine size distribution ranging from 1.75 to 6.25 nm with an average size centered at 3.8 nm,which benefits from the coordination interaction between thioether groups and Au.Meanwhile,the produced Au@S_(4)-COF can generate a stable photocatalytic H_(2) generation during the four recycles and preserve its crystallinity structure after the stability testing.The Au NPs anchored on the S_(4)-COF photocatalyst can greatly accelerate the separation of photogenerated carriers and increase charge transfer because of the combined function of Au NPs and thioether groups.Such a method can not only prevent the aggregation of Au NPs onto thioether-containing COFs to achieve long-term photostability but also allow uniform dispersion for an ordered structure of photocatalysts.This work provides a rational strategy for designing and preparing COF-based photocatalysts for solar-driven H_(2) production. 展开更多
关键词 Photocatalysis Covalent organic framework Thioether functionalization Gold nanoparticle Coordination interaction Photogenerated carrier separation
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Integrating Tabu Search in Particle Swarm Optimization for the Frequency Assignment Problem 被引量:1
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作者 Houssem Eddine Hadji Malika Babes 《China Communications》 SCIE CSCD 2016年第3期137-155,共19页
In this paper, we address one of the issues in the frequency assignment problem for cellular mobile networks in which we intend to minimize the interference levels when assigning frequencies from a limited frequency s... In this paper, we address one of the issues in the frequency assignment problem for cellular mobile networks in which we intend to minimize the interference levels when assigning frequencies from a limited frequency spectrum. In order to satisfy the increasing demand in such cellular mobile networks, we use a hybrid approach consisting of a Particle Swarm Optimization(PSO) combined with a Tabu Search(TS) algorithm. This approach takes both advantages of PSO efficiency in global optimization and TS in avoiding the premature convergence that would lead PSO to stagnate in a local minimum. Moreover, we propose a new efficient, simple, and inexpensive model for storing and evaluating solution's assignment. The purpose of this model reduces the solution's storage volume as well as the computations required to evaluate thesesolutions in comparison with the classical model. Our simulation results on the most known benchmarking instances prove the effectiveness of our proposed algorithm in comparison with previous related works in terms of convergence rate, the number of iterations, the solution storage volume and the running time required to converge to the optimal solution. 展开更多
关键词 frequency assignment problem particle swarm optimization tabu search convergence acceleration
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挥发性和半挥发性有机物向二次有机气溶胶转化的机制 被引量:60
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作者 谢绍东 田晓雪 《化学进展》 SCIE CAS CSCD 北大核心 2010年第4期727-733,共7页
从近20年二次有机气溶胶形成机制的研究成果可发现,挥发性和半挥发性有机物转化为二次有机气溶胶的主要物理化学过程可概述为光化学氧化机制、成核过程、凝结和气/粒分配机制以及非均相反应机制。本文系统总结了这些物理化学反应的发生... 从近20年二次有机气溶胶形成机制的研究成果可发现,挥发性和半挥发性有机物转化为二次有机气溶胶的主要物理化学过程可概述为光化学氧化机制、成核过程、凝结和气/粒分配机制以及非均相反应机制。本文系统总结了这些物理化学反应的发生过程及其影响因素,重点阐述了异戊二烯和甲苯同系物的光氧化机制,总结了二次有机气溶胶气/粒分配的两种理论——吸收机制和吸附机制,评述了发生在颗粒相上的非均相反应对二次有机气溶胶形成的重要作用。最后,对二次有机气溶胶形成机制研究的发展方向进行了展望。 展开更多
关键词 二次有机气溶胶 光化学氧化 挥发性有机物 成核作用 /粒分配 非均相反应
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粤港澳大湾区大气中硝基多环芳烃污染特征与风险评估 被引量:4
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作者 李彦希 谢丹平 +4 位作者 黎玉清 金梦 丁紫荣 闫雅楠 赵波 《环境科学》 EI CAS CSCD 北大核心 2022年第1期93-101,共9页
为探究粤港澳大湾区硝基多环芳烃(NPAHs)污染特征与来源,利用大气主动采样技术采集44个环境空气样品,并使用气相色谱-三重四级杆串联质谱测定NPAHs浓度.结果表明,同时使用滤膜、PUF和XAD-2树脂,可以更高效采集到气态和颗粒态的NPAHs,准... 为探究粤港澳大湾区硝基多环芳烃(NPAHs)污染特征与来源,利用大气主动采样技术采集44个环境空气样品,并使用气相色谱-三重四级杆串联质谱测定NPAHs浓度.结果表明,同时使用滤膜、PUF和XAD-2树脂,可以更高效采集到气态和颗粒态的NPAHs,准确表征环境空气中NPAHs的污染状况.粤港澳大湾区环境空气中(ρ(Σ_(18)NPAHs)范围为162~2094 pg·m^(-3),夏季和冬季的平均(ρ(Σ_(18)NPAHs)分别为(675±430)pg·m^(-3)和(637±349)pg·m^(-3).NPAHs广泛存在于粤港澳大湾区环境空气中,以1-硝基萘(220 pg·m^(-3))、2-硝基萘(146 pg·m^(-3))、9-硝基蒽(105 pg·m^(-3))和2-硝基荧蒽(72 pg·m^(-3))为主,夏季和冬季的族谱特征相似.NPAHs的气/粒分配特征表现为:2环和3环NPAHs倾向于赋存在气相,4环NPAHs倾向于吸附在颗粒相;颗粒相NPAHs在总NPAHs中的占比随分子量增大而增大;冬季NPAHs倾向于吸附在颗粒相中,夏季NPAHs倾向于赋存在气相中.基于特征污染物比值判断,粤港澳大湾区大气中NPAHs在夏季和冬季的主要来源是二次生成,二次生成源以·OH反应生成的贡献为主.呼吸暴露致癌风险值计算结果显示,粤港澳大湾区人群的呼吸暴露致癌风险处于可控范围. 展开更多
关键词 硝基多环芳烃(NPAHs) 粤港澳大湾区(GBA) 大气污染特征 /粒分配 来源分析 致癌风险
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