The star-forming clumps in star-bursting dwarf galaxies provide valuable insights into understanding the evolution of dwarf galaxies.In this paper,we focus on five star-bursting dwarf galaxies featuring off-centered c...The star-forming clumps in star-bursting dwarf galaxies provide valuable insights into understanding the evolution of dwarf galaxies.In this paper,we focus on five star-bursting dwarf galaxies featuring off-centered clumps in the Mapping Nearby Galaxies at Apache Point Observatory survey.Using the stellar population synthesis software Fitting Analysis using Differential evolution Optimization,we obtain the spatially resolved distribution of the star formation history,which allows us to construct the g-band images of the five galaxies at different ages.These images can help us to probe the evolution of the morphological structures of these galaxies.While images of a stellar population older than 1 Gyr are typically smooth,images of a stellar population younger than 1 Gyr reveal significant clumps,including multiple clumps which appear at different locations and even different ages.To study the evolutionary connections of these five galaxies to other dwarf galaxies before their star-forming clumps appear,we construct the images of the stellar populations older than three age nodes,and define them to be the images of the"host"galaxies.We find that the properties such as the central surface brightness and the effective radii of the hosts of the five galaxies are in between those of dwarf ellipticals(dEs)and dwarf irregulars(dIrrs),with two clearly more similar to dEs and one more similar to dIrrs.Among the five galaxies,8257-3704 is particularly interesting,as it shows a previous starburst event that is not quite visible from its gri image,but only visible from images of the stellar population at a few hundred million years.The star-forming clump associated with this event may have appeared at around 600 Myr ago and disappeared at around 40 Myr ago.展开更多
We investigated the relationship between the accretion process and jet properties by utilizing very long baseline array （VLBA） and mid-infrared （MIR） data for a sample of 45 3CRR radio galaxies selected with a flu...We investigated the relationship between the accretion process and jet properties by utilizing very long baseline array （VLBA） and mid-infrared （MIR） data for a sample of 45 3CRR radio galaxies selected with a flux density at 178MHz 〉 16.4Jy, 5 GHz very large array （VLA） core flux density ≥7 mJy and MIR observations. The pc-scale radio structure at 5 GHz is presented by using our VLBA observations for 21 sources acquired in February, 2016, the analysis of archival data for 16 objects and directly obtaining measurements for eight radio galaxies available from literatures. The accretion mode is constrained from the Eddington ratio with a dividing value of 0.01, which is estimated from the MIR-based bolometric luminosity and the black hole masses. While most Fanaroff-Riley type II radio galaxies （FRIIs） have higher Eddington ratio than Fanaroff-Riley type I radio galaxies （FRIs）, we found that there is indeed no single correspondence between the FR morphology and accretion mode with eight FRIIs at low accretion rate and two FRIs at high accretion rate. There is a significant correlation between the VLBA core luminosity at 5 GHz and the Eddington ratio. Various morphologies are identi- fied in our sample, including core only, single-sided core-jet and two-sided core-jet structures. We found that the higher accretion rate may be more likely related with the core-jet structure, thus generating a more extended jet. These results imply that the higher accretion rates are likely able to produce more powerful jets. There is a strong correlation between the MIR luminosity at 15 ktm and VLBA 5 GHz core luminosity, in favor of the tight relation between the accretion disk and jets. In our sample, the core brightness temperature ranges from 109 to 101338 K with a median value of 10^11.09K, indicating that systematically the beaming effect may not be significant. The exceptional cases, FRIs at high accretion rates and FRIIs at low accretion rates, are exclusively at the high and low ends, respectively, of the distribution of the flux ratio for VLBA core to 178 MHz flux density. It is not impossible that the locations of these sources are due to the recent shining or weakening of their central engines （i.e., both accretion and jet）.展开更多
Utilizing a BzK-selecfion technique, we obtain 14 550 star-forming galaxies （sBzKs） and 1763 passive galaxies （pBzKs） at z - 2 from the K-selected （KAB 〈 22.5） catalog in the COSMOS/UltraVISTA field. The differ...Utilizing a BzK-selecfion technique, we obtain 14 550 star-forming galaxies （sBzKs） and 1763 passive galaxies （pBzKs） at z - 2 from the K-selected （KAB 〈 22.5） catalog in the COSMOS/UltraVISTA field. The differential number counts of sBzKs and pBzKs are consistent with the results from the literature. Compared to the observed results, semi-analytic models of galaxy formation and evolution provide too few （many） galaxies at the high （low） mass end. Moreover, we find that the star formation rate and stellar mass of sBzKs follow the relation of the main sequence. Based on HST/Wide Field Camera 3 F160W imaging, we find a wide range of morphological diversities for sBzKs, from diffuse to early-type spiral structures, with relatively high M20, large size and low G, while pBzKs have elliptical-like compact morphologies with lower M20, smaller size and higher G, indicating a more concentrated and symmetric spatial extent of stellar population distribution in pBzKs than sBzKs. Furthermore, the sizes of pBzKs （sBzKs） at z - 2 are on average two to three （one to two） times smaller than those of local early-type （late-type） galaxies with similar stellar mass. Our findings imply that the two classes have different evolution models and mass assembly histories.展开更多
Based on the Sloan Digital Sky Survey DR6 （SDSS） and the ＇Millennium Simulation （MS）, we investigate the alignment between galaxies and large-scale structure. For this purpose, we develop two new statistical tool...Based on the Sloan Digital Sky Survey DR6 （SDSS） and the ＇Millennium Simulation （MS）, we investigate the alignment between galaxies and large-scale structure. For this purpose, we develop two new statistical tools, namely the alignment correlation function and the cos（20）-statistic. The former is a two-dimensional extension of the traditional two-point correlation function and the latter is related to the ellipticity correlation function used for cosmic shear measurements. Both are based on the cross correlation between a sample of galaxies with orientations and a reference sample which represents the large-scale structure. We apply the new statistics to the SDSS galaxy catalog. The alignment correlation function reveals an overabundance of reference galaxies along the major axes of red, luminous （L 〉 ～L＊） galaxies out to projected separations of 60 h-lMpc. The signal increases with central galaxy luminosity. No alignment signal is detected for blue galaxies. The cos（2θ）-statistic yields very similar results. Starting from a MS semi-analytic galaxy catalog, we assign an orientation to each red, luminous and central galaxy, based on that of the central region of the host halo （with size similar to that of the stellar galaxy）. As an alternative, we use the orientation of the host halo itself. We find a mean projected misalignment between a halo and its central region of -25°. The misalignment decreases slightly with increasing luminosity of the central galaxy. Using the orientations and luminosities of the semi-analytic galaxies, we repeat our alignment analysis on mock surveys of the MS. Agreement with the SDSS results is good if the central orientations are used. Predictions using the halo orientations as proxies for cen- tral galaxy orientations overestimate the observed alignment by more than a factor of 2. Finally, the large volume of the MS allows us to generate a two-dimensional map of the alignment correlation function, which shows the reference galaxy distribution to be flat- tened parallel to the orientations of red luminous galaxies with axis ratios of -0.5 and ,-0.75 for halo and central orientations, respectively. These ratios are almost independent of scale out to 60 h^-1 Mpc.展开更多
We study the vertical distribution of the highly inclined galaxies from the Continuum Halos in Nearby Galaxies—an EVLA Survey(CHANG-ES).We explore the feasibility of photometrically deriving the HⅠdisk scale heights...We study the vertical distribution of the highly inclined galaxies from the Continuum Halos in Nearby Galaxies—an EVLA Survey(CHANG-ES).We explore the feasibility of photometrically deriving the HⅠdisk scale heights from the moment-0 images of the relatively edge-on galaxies with inclination>80°,by quantifying the systematic broadening effects and thus deriving correction equations for direct measurements.The corrected HⅠdisk scale heights of the relatively edge-on galaxies from the CHANG-ES sample show trends consistent with the quasiequilibrium model of the vertical structure of gas disks.The procedure provides a convenient way to derive the scale heights and can easily be applied to statistical samples in the future.展开更多
On the basis of Poisson＇s equation for the logarithmic perturbation of matter density, we provide improved estimates of scale heights and spiral structures for non-edge-on spiral galaxies by subtracting the surface b...On the basis of Poisson＇s equation for the logarithmic perturbation of matter density, we provide improved estimates of scale heights and spiral structures for non-edge-on spiral galaxies by subtracting the surface brightness distributions from observed images. As examples, the non-edge-on spiral galaxies PGC 24996, which is face-on, and M31, which is inclined, are studied. The scale height, pitch angle and inclination angle of M31, our nearest neighbor, that are presented in this work, agree well with previous research.展开更多
Two-dimensional bulge/disk light decomposition with GIM2D in both the r- and g-bands has been applied to a sample of 129 early-type galaxies brighter than 13.5 magnitude in the r-band, selected from the Sloan Digital ...Two-dimensional bulge/disk light decomposition with GIM2D in both the r- and g-bands has been applied to a sample of 129 early-type galaxies brighter than 13.5 magnitude in the r-band, selected from the Sloan Digital Sky Survey Data Release 2. Intensity-weighted Fourier coefficient （α4/α） was also derived for each sample galaxy. Our analysis shows that there are correlations between bulge-to-total light ratio （B/T） with bulge Sersic index nB and between bulge and disk scale sizes. Isophotal shape parameter （α4/α） is not correlated with BIT and riB. Both bulge and disk components satisfy a color-magnitude relation. The space Fundamental Plane analysis shows that galaxies with larger B/T tend to lie tighter and closer to the line of k1 ＋ k2 = 8 （the so-called ＂zone of avoidance＂） than the galaxies with smaller B/T. It indicates that existence of the disk component may lead to scatter of the distribution on the Fundamental Plane. Our analysis also shows that k1 ＋ k2 correlates with （g-r） color and B/T, but does not correlate with （α4/α） for early-type galaxies. The fitted parameters and other retrieved parameters used in this paper for all sample galaxies are available online.展开更多
The structural parameters of a galaxy can be used to gain insight into its formation and evolution history.In this paper,we strive to compare the Milky Way’s structural parameters to other,primarily edge-on,spiral ga...The structural parameters of a galaxy can be used to gain insight into its formation and evolution history.In this paper,we strive to compare the Milky Way’s structural parameters to other,primarily edge-on,spiral galaxies in order to determine how our Galaxy measures up to the Local Universe.For our comparison,we use the galaxy structural parameters gathered from a variety of literature sources in the optical and near-infrared wave bands.We compare the scale length,scale height,and disk flatness for both the thin and thick disks,the thick-to-thin disk mass ratio,the bulge-to-total luminosity ratio,and the mean pitch angle of the Milky Way’s spiral arms to those in other galaxies.We conclude that many of the Milky Way’s structural parameters are largely ordinary and typical of spiral galaxies in the Local Universe,though the Galaxy’s thick disk appears to be appreciably thinner and less extended than expected from zoom-in cosmological simulations of Milky Way-mass galaxies with a significant contribution of galaxy mergers involving satellite galaxies.展开更多
A corotation radius is a key characteristic of disk galaxies that is essential to determine the angular speed of the spiral structureΩ_p,and therefore understand its nature.In the literature,there are plenty of metho...A corotation radius is a key characteristic of disk galaxies that is essential to determine the angular speed of the spiral structureΩ_p,and therefore understand its nature.In the literature,there are plenty of methods to estimate this value,but do these measurements have any consistency?In this work,we collected a data set of corotation radius measurements for 547 galaxies,300 of which had at least two values.An initial analysis reveals that most objects have rather inconsistent corotation radius positions.Moreover,a significant fraction of galactic disks is distinguished by a large error coverage and almost uniform distribution of measurements.These findings do not have any relation to spiral type,Hubble classification,or presence of a bar.Among other reasons,obtained results could be explained by the transient nature of spirals in a considerable part of galaxies.We have made our collected data sample publicly available,and have demonstrated on one example how it could be useful for future research by investigating a winding time value for a sample of galaxies with possible multiple spiral arm patterns.展开更多
Biomass conversion offers an efficient approach to alleviate the energy and environmental issues.Electrochemical oxidation of 5-hydroxymethylfurfural(HMF)has attracted tremendous attention in the latest few years for ...Biomass conversion offers an efficient approach to alleviate the energy and environmental issues.Electrochemical oxidation of 5-hydroxymethylfurfural(HMF)has attracted tremendous attention in the latest few years for the mild synthesis conditions and high conversion efficiency to obtain 2,5-furan dicarboxylic acid(FDCA),but there still remain problems such as limited yield,short cycle life,and ambiguous reaction mechanism.Despite many reviews highlighting a variety of electrocatalysts for electrochemical oxidation of HMF,a detailed discussion of the structural modulation of catalyst and the underlying catalytic mechanism is still lacking.We herein provide a comprehensive summary of the recent development of electrochemical oxidation of HMF to FDCA,particularly focusing on the mechanism studies as well as the advanced strategies developed to regulate the structure and optimize the performance of the electrocatalysts,including heterointerface construction,defect engineering,single-atom engineering,and in situ reconstruction.Experimental characterization techniques and theoretical calculation methods for mechanism and active site studies are elaborated,and challenges and future directions of electrochemical oxidation of HMF are also prospected.This review will provide guidance for designing advanced catalysts and deepening the understanding of the reaction mechanism beneath electrochemical oxidation of HMF to FDCA.展开更多
Three mechanisms for an alternative to the Doppler effect as an explanation for the redshift are reviewed. A fourth mechanism is the attenuation of the light as given by the Beer-Lambert law. The average value of the ...Three mechanisms for an alternative to the Doppler effect as an explanation for the redshift are reviewed. A fourth mechanism is the attenuation of the light as given by the Beer-Lambert law. The average value of the Hubble constant is therefore derived by processing the galaxies of the NED-D catalog in which the distances are independent of the redshift. The observed anisotropy of the Hubble constant is reproduced by adopting a rim model, a chord model, and both 2D and 3D Voronoi diagrams.展开更多
Because of the 3D nature of galaxies, an algorithm for constructing spatial density distribution models of galaxies on the basis of galaxy images has many advan- tages over approximations of the surface density distri...Because of the 3D nature of galaxies, an algorithm for constructing spatial density distribution models of galaxies on the basis of galaxy images has many advan- tages over approximations of the surface density distribution. We present a method for deriving the spatial structure and overall parameters of galaxies from images and estimate its accuracy and derived parameter degeneracies on a sample of idealised model galaxies. The test galaxies consist component with varying proportions and of a disc-like component and a spheroidal properties. Both components are assumed to be axially symmetric and coplanar. We simulate these test galaxies as if they had been observed in the SDSS project through ugriz filters, thus gaining a set of realis- tically imperfect images of galaxies with known intrinsic properties. These artificial SDSS galaxies were thereafter remodelled by approximating the surface brightness distribution with a 2D projection of a bulge＋disc spatial distribution model and the restored parameters were compared to the initial ones. Down to the r-band limiting magnitude of 18, errors in the restored integral luminosities and colour indices re- main within 0.05 mag and errors in the luminosities of individual components within 0.2 mag. Accuracy of the restored bulge-to-disc luminosity ratio （B/D） is within 40% in most cases, and becomes worse for galaxies with low B/D, but the general balance between bulges and discs is not shifted systematically. Assuming that the intrinsic disc axial ratio is ≤ 0.3, then the inclination angles can be estimated with errors 〈 5° for most of the galaxies with B/D 〈 2 and with errors 〈 15° up to B/D = 6. Errors in the recovered sizes of the galactic components are below 10% in most cases. The axial ratios and the shape parameter N of Einasto＇s distribution （similar to the Sersic index） are relatively inaccurate, but can provide statistical estimates for large samples. In general, models of disc components are more accurate than models of spheroidal components for geometrical reasons.展开更多
Recent observations of Dwarf Satellite Galaxies (DSG) show that they have a clear tendency to stay in particular planes. Explanations with standard physics remain controversial. Recently, I proposed a new explanation ...Recent observations of Dwarf Satellite Galaxies (DSG) show that they have a clear tendency to stay in particular planes. Explanations with standard physics remain controversial. Recently, I proposed a new explanation of the galactic flat rotation curves, introducing a new cosmic acceleration due to expansion. In this paper, I apply this new acceleration to the dynamics of DSG’s (without dark matter). I show that this new acceleration implies planar structures for the DSG trajectories. More generally, it is shown that this acceleration produces a space structuration around any massive center. It remains a candidate to explain several cosmic observations without dark matter.展开更多
[Objective] This study aimed to predict the structure of protein OmpH from Pasteurella multocida C47-8 （PmC47-8） strain of yak. [Method] Online BLAST, signal peptide prediction, secondary structure prediction and pr...[Objective] This study aimed to predict the structure of protein OmpH from Pasteurella multocida C47-8 （PmC47-8） strain of yak. [Method] Online BLAST, signal peptide prediction, secondary structure prediction and protein characteristics of sequencing result of gene OmpH from PmC47-8 strain were analyzed. [Result] The similarities of gene OmpH from PmC47-8 with the published 81 OmpH genes were between 84% and 99%; a signal peptide was found with the cleavage sites between 20 and 21 in the polypeptide; secondary structure prediction showed that folding structure accounted for 49.8% and loop structure for 50.2%; it predicted that there were 7 O-glycosylation sites in OmpH protein with the amino acid residual sites of 2, 45, 48, 330, 716, 721, 723, respectively, and 2 N-glycosylation sites with the amino acid residual sites of 15 and 35. [Conclusion] This study lays the foundation for the study on the immunity of OmpH gene from yak.展开更多
An oblique detonation wave for a Mach 7 inlet flow over a long enough wedge of 30 turning angle is simulated numerically using Euler equation and one-step rection model.The fifth-order WENO scheme is adopted to captur...An oblique detonation wave for a Mach 7 inlet flow over a long enough wedge of 30 turning angle is simulated numerically using Euler equation and one-step rection model.The fifth-order WENO scheme is adopted to capture the shock wave.The numerical results show that with the compression of the wedge wall the detonation wave front structure is divided into three sections：the ZND model-like strcuture,single-sided triple point structure and dual-headed triple point strucuture.The first structure is the smooth straight,and the second has the characteristic of the triple points propagating dowanstream only with the same velocity,while the dual-headed triple point structure is very complicated.The detonation waves facing upstream and downstream propagate with different velocities,in which the periodic collisions of the triple points cause the oscillation of the detonation wave front.This oscillation process has temporal and spatial periodicity.In addition,the triple point trace are recorded to obtain different cell structures in three sections.展开更多
The continental margin of Northeast China and its adjacent areas is composed of two tectonic belts. The inner belt is a collage made up of fragments resulting from breakup of an old land with the north part related to...The continental margin of Northeast China and its adjacent areas is composed of two tectonic belts. The inner belt is a collage made up of fragments resulting from breakup of an old land with the north part related to the evolution of the Palaeo-Asian Ocean and the south part to the evolution of the Palaeo - Pacific Ocean. The outer belt is a Mesozoic terrane, which is a melange made up of fragments of the Late Palaeozoic to Early Mesozoic oceanic crust and the Late M esozoic trench accumulations.There existed another ocean-the Palaeo - Pacific Ocean during the period from the closing of the Palaeo-Asian Ocean to the opening of the modern Pacific Ocean or from the Devonian to Jurassic, and the ocean-floor spreading of the Palaeo - Pacific Ocean led to the formation of the above-mentioned tectonic belts. The development of the strike-slip fault system after the Late Jurassic and the formation of an epicontinental volcano -plutonic rock belt in the Late Cretaceous to Early Tertiary are attributed to the interaction between the modern Pacific plate and the Eurasian plate.展开更多
The crystal structure of the title compound, 2-isobutyl-6-(2?4?dichlorophenyl)- imidazo[2,1-b]-1,3,4-thiadiazole (C14H13Cl2N3S, Mr = 326.23), has been synthesized by the treatment of 2-amino-5-isobutyl-1,3,4-thiadiazo...The crystal structure of the title compound, 2-isobutyl-6-(2?4?dichlorophenyl)- imidazo[2,1-b]-1,3,4-thiadiazole (C14H13Cl2N3S, Mr = 326.23), has been synthesized by the treatment of 2-amino-5-isobutyl-1,3,4-thiadiazole with a-chloroaceto-2,4-dichlorophenone and determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 12.483(7), b = 8.420(4), c = 14.998(8) ? b = 105.770(10)? V = 1517.0(14) 3, Z = 4, Dc = 1.428 g/cm3, S = 0.902, m(MoKa) = 0.558 mm-1, F (000) = 672, R = 0.0579 and wR = 0.1186. The X-ray analytic results showed that all ring atoms in the imidazothiadiazole moiety are almost coplanar. The dihedral angel between the phenyl group and hetero-cycle is 16.8(0.2)?展开更多
On the basis of the finite element analysis, the elastic wave propagation in cellular structures is investigated using the symplectic algorithm. The variation principle is first applied to obtain the dual variables an...On the basis of the finite element analysis, the elastic wave propagation in cellular structures is investigated using the symplectic algorithm. The variation principle is first applied to obtain the dual variables and the wave propagation problem is then transformed into two-dimensional （2D） symplectic eigenvalue problems, where the extended Wittrick-Williams algorithm is used to ensure that no phase propagation eigenvalues are missed during computation. Three typical cellular structures, square, triangle and hexagon, are introduced to illustrate the unique feature of the symplectic algorithm in higher-frequency calculation, which is due to the conserved properties of the structure-preserving symplectic algorithm. On the basis of the dispersion relations and phase constant surface analysis, the band structure is shown to be insensitive to the material type at lower frequencies, however, much more related at higher frequencies. This paper also demonstrates how the boundary conditions adopted in the finite element modeling process and the structures＇ configurations affect the band structures. The hexagonal cells are demonstrated to be more efficient for sound insulation at higher frequencies, while the triangular cells are preferred at lower frequencies. No complete band gaps are observed for the square cells with fixed-end boundary conditions. The analysis of phase constant surfaces guides the design of 2D cellular structures where waves at certain frequencies do not propagate in specified directions. The findings from the present study will provide invaluable guidelines for the future application of cellular structures in sound insulation.展开更多
We present an efficient, robust computational method for modeling the Newtonian dynamics for rotation curve analysis of thin-disk galaxies. With appropriate mathematical treatments, the apparent numerical difficulties...We present an efficient, robust computational method for modeling the Newtonian dynamics for rotation curve analysis of thin-disk galaxies. With appropriate mathematical treatments, the apparent numerical difficulties associated with singularities in computing elliptic integrals are completely removed. Using a boundary element discretization procedure, the governing equations are transformed into a linear algebra matrix equation that can be solved by straightforward Gauss elimination in one step without further iterations. The numerical code implemented according to our algorithm can accurately determine the surface mass density distribution in a disk galaxy from a measured rotation curve （or vice versa）. For a disk galaxy with a typical flat rotation curve, our modeling results show that the surface mass density monotonically decreases from the galactic center toward the periphery, according to Newtonian dynamics. In a large portion of the galaxy, the surface mass density follows an approximately exponential law of decay with respect to the galactic radial coordinate. Yet the radial scale length for the surface mass density seems to be generally larger than that of the measured brightness distribution, suggesting an increasing mass-tolight ratio with the radial distance in a disk galaxy. In a nondimensionalized form, our mathematical system contains a dimensionless parameter which we call the ＂galactic rotation number＂ that represents the gross ratio of centrifugal force and gravitational force. The value of this galactic rotation number is determined as part of the numerial solution. Through a systematic computational analysis, we have illustrated that the galactic rotation number remains within 4-10% of 1.70 for a wide variety of rotation curves. This implies that the total mass in a disk galaxy is proportional to V02 Rg, with V0 denoting the characteristic rotation velocity （such as the ＂flat＂ value in a typical ro- tation curve） and Rg the radius of the galactic disk. The predicted total galactic mass of the Milky Way is in good agreement with the star-count data.展开更多
A new coordination compound Zn（2,4＇-bpt）2（H2O）（1） based on the versatile ligand 2,4＇-Hbpt（2,4？-Hbpt = 3-（2-pyridyl）-5-（4-pyridyl）-1H-1,2,4-triazole） was prepared by hydrothermal reactions. The structure...A new coordination compound Zn（2,4＇-bpt）2（H2O）（1） based on the versatile ligand 2,4＇-Hbpt（2,4？-Hbpt = 3-（2-pyridyl）-5-（4-pyridyl）-1H-1,2,4-triazole） was prepared by hydrothermal reactions. The structure of complex 1 has been characterized by X-ray single-crystal diffraction, elemental analysis, X-ray powder diffraction, IR spectrum analysis and thermogravimetric analysis. Single-crystal X-ray diffraction analysis indicates that the complex belongs to monoclinic system, space group C2/c with a = 23.877（3）, b = 0.7483（9）, c = 1.2492（2） A, b = 92.681（2）°, V = 2230.6（4） A^3, Z = 4, Dc = 1.572 g/cm^3, m = 1.143 mm^-1, Mr = 527.85 and F（000） = 1080. The final R = 0.0581 and wR = 0.0898 with I 〉 2s（I）. 1 is a 0D motif which is connected by hydrogen bonds to form a corrugated 1D pattern. In addition, 1 shows strong photoluminescent emissions in the solid state at room temperature which can be used as potential optical materials. Theoretical calculations based on density functional theory（DFT） were employed in order to explicate the stability and chemical reactivity of 2,4＇-Hbpt with different conformations. The results indicated that conformation I is more stable and prior to coordination in the reactions.展开更多
基金supported by National Key R&D Program of China(Nos.2019YFA0405501 and 2022YFF0503402)the National Natural Science Foundation of China(NSFC,Nos.12233005 and 12041302)+6 种基金support from the Natural Science Foundation of Shanghai(Project Number:22ZR1473000)the Program of Shanghai Academic Research Leader(No.22XD1404200)supports from the CAS Pioneer Hundred Talents ProgramUSTC Research Funds of the Double First-Class Initiativethe NSFC grant 12273037the NSFC grants 12033004,12333003support from the NSFC through grants 12273091 and U2031139。
文摘The star-forming clumps in star-bursting dwarf galaxies provide valuable insights into understanding the evolution of dwarf galaxies.In this paper,we focus on five star-bursting dwarf galaxies featuring off-centered clumps in the Mapping Nearby Galaxies at Apache Point Observatory survey.Using the stellar population synthesis software Fitting Analysis using Differential evolution Optimization,we obtain the spatially resolved distribution of the star formation history,which allows us to construct the g-band images of the five galaxies at different ages.These images can help us to probe the evolution of the morphological structures of these galaxies.While images of a stellar population older than 1 Gyr are typically smooth,images of a stellar population younger than 1 Gyr reveal significant clumps,including multiple clumps which appear at different locations and even different ages.To study the evolutionary connections of these five galaxies to other dwarf galaxies before their star-forming clumps appear,we construct the images of the stellar populations older than three age nodes,and define them to be the images of the"host"galaxies.We find that the properties such as the central surface brightness and the effective radii of the hosts of the five galaxies are in between those of dwarf ellipticals(dEs)and dwarf irregulars(dIrrs),with two clearly more similar to dEs and one more similar to dIrrs.Among the five galaxies,8257-3704 is particularly interesting,as it shows a previous starburst event that is not quite visible from its gri image,but only visible from images of the stellar population at a few hundred million years.The star-forming clump associated with this event may have appeared at around 600 Myr ago and disappeared at around 40 Myr ago.
基金supported by the National Natural Science Foundation of China(Grant Nos.11473054,U1531245,11763002 and 11590784)
文摘We investigated the relationship between the accretion process and jet properties by utilizing very long baseline array （VLBA） and mid-infrared （MIR） data for a sample of 45 3CRR radio galaxies selected with a flux density at 178MHz 〉 16.4Jy, 5 GHz very large array （VLA） core flux density ≥7 mJy and MIR observations. The pc-scale radio structure at 5 GHz is presented by using our VLBA observations for 21 sources acquired in February, 2016, the analysis of archival data for 16 objects and directly obtaining measurements for eight radio galaxies available from literatures. The accretion mode is constrained from the Eddington ratio with a dividing value of 0.01, which is estimated from the MIR-based bolometric luminosity and the black hole masses. While most Fanaroff-Riley type II radio galaxies （FRIIs） have higher Eddington ratio than Fanaroff-Riley type I radio galaxies （FRIs）, we found that there is indeed no single correspondence between the FR morphology and accretion mode with eight FRIIs at low accretion rate and two FRIs at high accretion rate. There is a significant correlation between the VLBA core luminosity at 5 GHz and the Eddington ratio. Various morphologies are identi- fied in our sample, including core only, single-sided core-jet and two-sided core-jet structures. We found that the higher accretion rate may be more likely related with the core-jet structure, thus generating a more extended jet. These results imply that the higher accretion rates are likely able to produce more powerful jets. There is a strong correlation between the MIR luminosity at 15 ktm and VLBA 5 GHz core luminosity, in favor of the tight relation between the accretion disk and jets. In our sample, the core brightness temperature ranges from 109 to 101338 K with a median value of 10^11.09K, indicating that systematically the beaming effect may not be significant. The exceptional cases, FRIs at high accretion rates and FRIIs at low accretion rates, are exclusively at the high and low ends, respectively, of the distribution of the flux ratio for VLBA core to 178 MHz flux density. It is not impossible that the locations of these sources are due to the recent shining or weakening of their central engines （i.e., both accretion and jet）.
基金Supported by the National Natural Science Foundation of China
文摘Utilizing a BzK-selecfion technique, we obtain 14 550 star-forming galaxies （sBzKs） and 1763 passive galaxies （pBzKs） at z - 2 from the K-selected （KAB 〈 22.5） catalog in the COSMOS/UltraVISTA field. The differential number counts of sBzKs and pBzKs are consistent with the results from the literature. Compared to the observed results, semi-analytic models of galaxy formation and evolution provide too few （many） galaxies at the high （low） mass end. Moreover, we find that the star formation rate and stellar mass of sBzKs follow the relation of the main sequence. Based on HST/Wide Field Camera 3 F160W imaging, we find a wide range of morphological diversities for sBzKs, from diffuse to early-type spiral structures, with relatively high M20, large size and low G, while pBzKs have elliptical-like compact morphologies with lower M20, smaller size and higher G, indicating a more concentrated and symmetric spatial extent of stellar population distribution in pBzKs than sBzKs. Furthermore, the sizes of pBzKs （sBzKs） at z - 2 are on average two to three （one to two） times smaller than those of local early-type （late-type） galaxies with similar stellar mass. Our findings imply that the two classes have different evolution models and mass assembly histories.
基金supported by NSFC (Nos. 10533030, 10821302,10878001)the Knowledge Innovation Program of CAS (No. KJCX2-YW-T05)by 973 Program(No. 2007CB815402).
文摘Based on the Sloan Digital Sky Survey DR6 （SDSS） and the ＇Millennium Simulation （MS）, we investigate the alignment between galaxies and large-scale structure. For this purpose, we develop two new statistical tools, namely the alignment correlation function and the cos（20）-statistic. The former is a two-dimensional extension of the traditional two-point correlation function and the latter is related to the ellipticity correlation function used for cosmic shear measurements. Both are based on the cross correlation between a sample of galaxies with orientations and a reference sample which represents the large-scale structure. We apply the new statistics to the SDSS galaxy catalog. The alignment correlation function reveals an overabundance of reference galaxies along the major axes of red, luminous （L 〉 ～L＊） galaxies out to projected separations of 60 h-lMpc. The signal increases with central galaxy luminosity. No alignment signal is detected for blue galaxies. The cos（2θ）-statistic yields very similar results. Starting from a MS semi-analytic galaxy catalog, we assign an orientation to each red, luminous and central galaxy, based on that of the central region of the host halo （with size similar to that of the stellar galaxy）. As an alternative, we use the orientation of the host halo itself. We find a mean projected misalignment between a halo and its central region of -25°. The misalignment decreases slightly with increasing luminosity of the central galaxy. Using the orientations and luminosities of the semi-analytic galaxies, we repeat our alignment analysis on mock surveys of the MS. Agreement with the SDSS results is good if the central orientations are used. Predictions using the halo orientations as proxies for cen- tral galaxy orientations overestimate the observed alignment by more than a factor of 2. Finally, the large volume of the MS allows us to generate a two-dimensional map of the alignment correlation function, which shows the reference galaxy distribution to be flat- tened parallel to the orientations of red luminous galaxies with axis ratios of -0.5 and ,-0.75 for halo and central orientations, respectively. These ratios are almost independent of scale out to 60 h^-1 Mpc.
基金the National Natural Science Foundation of China(NSFC,Grant Nos.12073002 and 11721303)the High-performance Computing Platform of Peking University。
文摘We study the vertical distribution of the highly inclined galaxies from the Continuum Halos in Nearby Galaxies—an EVLA Survey(CHANG-ES).We explore the feasibility of photometrically deriving the HⅠdisk scale heights from the moment-0 images of the relatively edge-on galaxies with inclination>80°,by quantifying the systematic broadening effects and thus deriving correction equations for direct measurements.The corrected HⅠdisk scale heights of the relatively edge-on galaxies from the CHANG-ES sample show trends consistent with the quasiequilibrium model of the vertical structure of gas disks.The procedure provides a convenient way to derive the scale heights and can easily be applied to statistical samples in the future.
基金Supported by the National Natural Science Foundation of China
文摘On the basis of Poisson＇s equation for the logarithmic perturbation of matter density, we provide improved estimates of scale heights and spiral structures for non-edge-on spiral galaxies by subtracting the surface brightness distributions from observed images. As examples, the non-edge-on spiral galaxies PGC 24996, which is face-on, and M31, which is inclined, are studied. The scale height, pitch angle and inclination angle of M31, our nearest neighbor, that are presented in this work, agree well with previous research.
基金the National Natural Science Foundation of China
文摘Two-dimensional bulge/disk light decomposition with GIM2D in both the r- and g-bands has been applied to a sample of 129 early-type galaxies brighter than 13.5 magnitude in the r-band, selected from the Sloan Digital Sky Survey Data Release 2. Intensity-weighted Fourier coefficient （α4/α） was also derived for each sample galaxy. Our analysis shows that there are correlations between bulge-to-total light ratio （B/T） with bulge Sersic index nB and between bulge and disk scale sizes. Isophotal shape parameter （α4/α） is not correlated with BIT and riB. Both bulge and disk components satisfy a color-magnitude relation. The space Fundamental Plane analysis shows that galaxies with larger B/T tend to lie tighter and closer to the line of k1 ＋ k2 = 8 （the so-called ＂zone of avoidance＂） than the galaxies with smaller B/T. It indicates that existence of the disk component may lead to scatter of the distribution on the Fundamental Plane. Our analysis also shows that k1 ＋ k2 correlates with （g-r） color and B/T, but does not correlate with （α4/α） for early-type galaxies. The fitted parameters and other retrieved parameters used in this paper for all sample galaxies are available online.
文摘The structural parameters of a galaxy can be used to gain insight into its formation and evolution history.In this paper,we strive to compare the Milky Way’s structural parameters to other,primarily edge-on,spiral galaxies in order to determine how our Galaxy measures up to the Local Universe.For our comparison,we use the galaxy structural parameters gathered from a variety of literature sources in the optical and near-infrared wave bands.We compare the scale length,scale height,and disk flatness for both the thin and thick disks,the thick-to-thin disk mass ratio,the bulge-to-total luminosity ratio,and the mean pitch angle of the Milky Way’s spiral arms to those in other galaxies.We conclude that many of the Milky Way’s structural parameters are largely ordinary and typical of spiral galaxies in the Local Universe,though the Galaxy’s thick disk appears to be appreciably thinner and less extended than expected from zoom-in cosmological simulations of Milky Way-mass galaxies with a significant contribution of galaxy mergers involving satellite galaxies.
基金support from“BASIS”Foundation for the Development of Theoretical Physics and Mathematics(grant No.23-2-2-6-1)。
文摘A corotation radius is a key characteristic of disk galaxies that is essential to determine the angular speed of the spiral structureΩ_p,and therefore understand its nature.In the literature,there are plenty of methods to estimate this value,but do these measurements have any consistency?In this work,we collected a data set of corotation radius measurements for 547 galaxies,300 of which had at least two values.An initial analysis reveals that most objects have rather inconsistent corotation radius positions.Moreover,a significant fraction of galactic disks is distinguished by a large error coverage and almost uniform distribution of measurements.These findings do not have any relation to spiral type,Hubble classification,or presence of a bar.Among other reasons,obtained results could be explained by the transient nature of spirals in a considerable part of galaxies.We have made our collected data sample publicly available,and have demonstrated on one example how it could be useful for future research by investigating a winding time value for a sample of galaxies with possible multiple spiral arm patterns.
基金National Natural Science Foundation of China(22272150,22302177)Major Program of Zhejiang Provincial Natural Science Foundation of China(LD22B030002)+2 种基金Zhejiang Provincial Ten Thousand Talent Program(2021R51009)Public Technology Application Project of Jinhua City(2022-4-067)Self Designed Scientific Research of Zhejiang Normal University(2021ZS0604)。
文摘Biomass conversion offers an efficient approach to alleviate the energy and environmental issues.Electrochemical oxidation of 5-hydroxymethylfurfural(HMF)has attracted tremendous attention in the latest few years for the mild synthesis conditions and high conversion efficiency to obtain 2,5-furan dicarboxylic acid(FDCA),but there still remain problems such as limited yield,short cycle life,and ambiguous reaction mechanism.Despite many reviews highlighting a variety of electrocatalysts for electrochemical oxidation of HMF,a detailed discussion of the structural modulation of catalyst and the underlying catalytic mechanism is still lacking.We herein provide a comprehensive summary of the recent development of electrochemical oxidation of HMF to FDCA,particularly focusing on the mechanism studies as well as the advanced strategies developed to regulate the structure and optimize the performance of the electrocatalysts,including heterointerface construction,defect engineering,single-atom engineering,and in situ reconstruction.Experimental characterization techniques and theoretical calculation methods for mechanism and active site studies are elaborated,and challenges and future directions of electrochemical oxidation of HMF are also prospected.This review will provide guidance for designing advanced catalysts and deepening the understanding of the reaction mechanism beneath electrochemical oxidation of HMF to FDCA.
文摘Three mechanisms for an alternative to the Doppler effect as an explanation for the redshift are reviewed. A fourth mechanism is the attenuation of the light as given by the Beer-Lambert law. The average value of the Hubble constant is therefore derived by processing the galaxies of the NED-D catalog in which the distances are independent of the redshift. The observed anisotropy of the Hubble constant is reproduced by adopting a rim model, a chord model, and both 2D and 3D Voronoi diagrams.
基金supported by the Estonian Science Foundationprojects IUT26-2 and IUT40-2support by the Centre of Excellence of Dark Matter in(Astro)particle Physics and Cosmology(TK120)+3 种基金Funding for SDSS-Ⅲ has been provided by the Alfred P.Sloan Foundationthe Participating Institutionsthe National Science Foundationthe U.S.Department of Energy Office of Science
文摘Because of the 3D nature of galaxies, an algorithm for constructing spatial density distribution models of galaxies on the basis of galaxy images has many advan- tages over approximations of the surface density distribution. We present a method for deriving the spatial structure and overall parameters of galaxies from images and estimate its accuracy and derived parameter degeneracies on a sample of idealised model galaxies. The test galaxies consist component with varying proportions and of a disc-like component and a spheroidal properties. Both components are assumed to be axially symmetric and coplanar. We simulate these test galaxies as if they had been observed in the SDSS project through ugriz filters, thus gaining a set of realis- tically imperfect images of galaxies with known intrinsic properties. These artificial SDSS galaxies were thereafter remodelled by approximating the surface brightness distribution with a 2D projection of a bulge＋disc spatial distribution model and the restored parameters were compared to the initial ones. Down to the r-band limiting magnitude of 18, errors in the restored integral luminosities and colour indices re- main within 0.05 mag and errors in the luminosities of individual components within 0.2 mag. Accuracy of the restored bulge-to-disc luminosity ratio （B/D） is within 40% in most cases, and becomes worse for galaxies with low B/D, but the general balance between bulges and discs is not shifted systematically. Assuming that the intrinsic disc axial ratio is ≤ 0.3, then the inclination angles can be estimated with errors 〈 5° for most of the galaxies with B/D 〈 2 and with errors 〈 15° up to B/D = 6. Errors in the recovered sizes of the galactic components are below 10% in most cases. The axial ratios and the shape parameter N of Einasto＇s distribution （similar to the Sersic index） are relatively inaccurate, but can provide statistical estimates for large samples. In general, models of disc components are more accurate than models of spheroidal components for geometrical reasons.
文摘Recent observations of Dwarf Satellite Galaxies (DSG) show that they have a clear tendency to stay in particular planes. Explanations with standard physics remain controversial. Recently, I proposed a new explanation of the galactic flat rotation curves, introducing a new cosmic acceleration due to expansion. In this paper, I apply this new acceleration to the dynamics of DSG’s (without dark matter). I show that this new acceleration implies planar structures for the DSG trajectories. More generally, it is shown that this acceleration produces a space structuration around any massive center. It remains a candidate to explain several cosmic observations without dark matter.
基金Supported by the Project for High-level Talents of Qinghai University (2008-QGC-7)~~
文摘[Objective] This study aimed to predict the structure of protein OmpH from Pasteurella multocida C47-8 （PmC47-8） strain of yak. [Method] Online BLAST, signal peptide prediction, secondary structure prediction and protein characteristics of sequencing result of gene OmpH from PmC47-8 strain were analyzed. [Result] The similarities of gene OmpH from PmC47-8 with the published 81 OmpH genes were between 84% and 99%; a signal peptide was found with the cleavage sites between 20 and 21 in the polypeptide; secondary structure prediction showed that folding structure accounted for 49.8% and loop structure for 50.2%; it predicted that there were 7 O-glycosylation sites in OmpH protein with the amino acid residual sites of 2, 45, 48, 330, 716, 721, 723, respectively, and 2 N-glycosylation sites with the amino acid residual sites of 15 and 35. [Conclusion] This study lays the foundation for the study on the immunity of OmpH gene from yak.
基金supported by the National Natural Science Foundation of China (10872096)the Open Fund of State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology (KFJJ09-13)
文摘An oblique detonation wave for a Mach 7 inlet flow over a long enough wedge of 30 turning angle is simulated numerically using Euler equation and one-step rection model.The fifth-order WENO scheme is adopted to capture the shock wave.The numerical results show that with the compression of the wedge wall the detonation wave front structure is divided into three sections：the ZND model-like strcuture,single-sided triple point structure and dual-headed triple point strucuture.The first structure is the smooth straight,and the second has the characteristic of the triple points propagating dowanstream only with the same velocity,while the dual-headed triple point structure is very complicated.The detonation waves facing upstream and downstream propagate with different velocities,in which the periodic collisions of the triple points cause the oscillation of the detonation wave front.This oscillation process has temporal and spatial periodicity.In addition,the triple point trace are recorded to obtain different cell structures in three sections.
基金A Project supported by the National Natural Science Foundation of China (Nos.9487001,49173131)
文摘The continental margin of Northeast China and its adjacent areas is composed of two tectonic belts. The inner belt is a collage made up of fragments resulting from breakup of an old land with the north part related to the evolution of the Palaeo-Asian Ocean and the south part to the evolution of the Palaeo - Pacific Ocean. The outer belt is a Mesozoic terrane, which is a melange made up of fragments of the Late Palaeozoic to Early Mesozoic oceanic crust and the Late M esozoic trench accumulations.There existed another ocean-the Palaeo - Pacific Ocean during the period from the closing of the Palaeo-Asian Ocean to the opening of the modern Pacific Ocean or from the Devonian to Jurassic, and the ocean-floor spreading of the Palaeo - Pacific Ocean led to the formation of the above-mentioned tectonic belts. The development of the strike-slip fault system after the Late Jurassic and the formation of an epicontinental volcano -plutonic rock belt in the Late Cretaceous to Early Tertiary are attributed to the interaction between the modern Pacific plate and the Eurasian plate.
基金The project was supported by NNSFC (20172031 29832050) the NSF of shandong province (Y2003B01) and the Fund for the Doctoral Program of Higher Education
文摘The crystal structure of the title compound, 2-isobutyl-6-(2?4?dichlorophenyl)- imidazo[2,1-b]-1,3,4-thiadiazole (C14H13Cl2N3S, Mr = 326.23), has been synthesized by the treatment of 2-amino-5-isobutyl-1,3,4-thiadiazole with a-chloroaceto-2,4-dichlorophenone and determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 12.483(7), b = 8.420(4), c = 14.998(8) ? b = 105.770(10)? V = 1517.0(14) 3, Z = 4, Dc = 1.428 g/cm3, S = 0.902, m(MoKa) = 0.558 mm-1, F (000) = 672, R = 0.0579 and wR = 0.1186. The X-ray analytic results showed that all ring atoms in the imidazothiadiazole moiety are almost coplanar. The dihedral angel between the phenyl group and hetero-cycle is 16.8(0.2)?
基金supported by the National Natural Science Foundation of China (10972182, 10772147, 10632030)the National Basic Research Program of China (2006CB 601202)+3 种基金the Doctorate Foundation of Northwestern Polytechnical University (CX200908)the Graduate Starting Seed Fund of Northwestern Polytechnical University (Z200930)the NPU Foundation for Fundamental Researchthe Open Foundation of State Key Laboratory of Structural Analysis of Industrial Equipment (GZ0802)
文摘On the basis of the finite element analysis, the elastic wave propagation in cellular structures is investigated using the symplectic algorithm. The variation principle is first applied to obtain the dual variables and the wave propagation problem is then transformed into two-dimensional （2D） symplectic eigenvalue problems, where the extended Wittrick-Williams algorithm is used to ensure that no phase propagation eigenvalues are missed during computation. Three typical cellular structures, square, triangle and hexagon, are introduced to illustrate the unique feature of the symplectic algorithm in higher-frequency calculation, which is due to the conserved properties of the structure-preserving symplectic algorithm. On the basis of the dispersion relations and phase constant surface analysis, the band structure is shown to be insensitive to the material type at lower frequencies, however, much more related at higher frequencies. This paper also demonstrates how the boundary conditions adopted in the finite element modeling process and the structures＇ configurations affect the band structures. The hexagonal cells are demonstrated to be more efficient for sound insulation at higher frequencies, while the triangular cells are preferred at lower frequencies. No complete band gaps are observed for the square cells with fixed-end boundary conditions. The analysis of phase constant surfaces guides the design of 2D cellular structures where waves at certain frequencies do not propagate in specified directions. The findings from the present study will provide invaluable guidelines for the future application of cellular structures in sound insulation.
文摘We present an efficient, robust computational method for modeling the Newtonian dynamics for rotation curve analysis of thin-disk galaxies. With appropriate mathematical treatments, the apparent numerical difficulties associated with singularities in computing elliptic integrals are completely removed. Using a boundary element discretization procedure, the governing equations are transformed into a linear algebra matrix equation that can be solved by straightforward Gauss elimination in one step without further iterations. The numerical code implemented according to our algorithm can accurately determine the surface mass density distribution in a disk galaxy from a measured rotation curve （or vice versa）. For a disk galaxy with a typical flat rotation curve, our modeling results show that the surface mass density monotonically decreases from the galactic center toward the periphery, according to Newtonian dynamics. In a large portion of the galaxy, the surface mass density follows an approximately exponential law of decay with respect to the galactic radial coordinate. Yet the radial scale length for the surface mass density seems to be generally larger than that of the measured brightness distribution, suggesting an increasing mass-tolight ratio with the radial distance in a disk galaxy. In a nondimensionalized form, our mathematical system contains a dimensionless parameter which we call the ＂galactic rotation number＂ that represents the gross ratio of centrifugal force and gravitational force. The value of this galactic rotation number is determined as part of the numerial solution. Through a systematic computational analysis, we have illustrated that the galactic rotation number remains within 4-10% of 1.70 for a wide variety of rotation curves. This implies that the total mass in a disk galaxy is proportional to V02 Rg, with V0 denoting the characteristic rotation velocity （such as the ＂flat＂ value in a typical ro- tation curve） and Rg the radius of the galactic disk. The predicted total galactic mass of the Milky Way is in good agreement with the star-count data.
基金Supported by the National Natural Science Foundation of China(Nos.21263019 and 51364038)
文摘A new coordination compound Zn（2,4＇-bpt）2（H2O）（1） based on the versatile ligand 2,4＇-Hbpt（2,4？-Hbpt = 3-（2-pyridyl）-5-（4-pyridyl）-1H-1,2,4-triazole） was prepared by hydrothermal reactions. The structure of complex 1 has been characterized by X-ray single-crystal diffraction, elemental analysis, X-ray powder diffraction, IR spectrum analysis and thermogravimetric analysis. Single-crystal X-ray diffraction analysis indicates that the complex belongs to monoclinic system, space group C2/c with a = 23.877（3）, b = 0.7483（9）, c = 1.2492（2） A, b = 92.681（2）°, V = 2230.6（4） A^3, Z = 4, Dc = 1.572 g/cm^3, m = 1.143 mm^-1, Mr = 527.85 and F（000） = 1080. The final R = 0.0581 and wR = 0.0898 with I 〉 2s（I）. 1 is a 0D motif which is connected by hydrogen bonds to form a corrugated 1D pattern. In addition, 1 shows strong photoluminescent emissions in the solid state at room temperature which can be used as potential optical materials. Theoretical calculations based on density functional theory（DFT） were employed in order to explicate the stability and chemical reactivity of 2,4＇-Hbpt with different conformations. The results indicated that conformation I is more stable and prior to coordination in the reactions.
