Organic inclusions from the Shahejie Formation of the Eogene period in the Bohai Gulf Basin, eastern China, were examined using micro\|FT. IR and fluorescence microscopy in addition to the measurement of their homogen...Organic inclusions from the Shahejie Formation of the Eogene period in the Bohai Gulf Basin, eastern China, were examined using micro\|FT. IR and fluorescence microscopy in addition to the measurement of their homogenization temperatures (T\-h). Two populations of organic inclusions were recognized, the primary and the secondary organic inclusions. The primary organic inclusions contain organic materials with relatively long alkyl chains (the carbon atom number is 15 to 17), whereas the secondary organic inclusions contain a certain amount of H\-2S besides organic materials which have relatively short alkyl chains with the carbon atom number of 5 to 6. The T\-h values of the primary organic inclusions are within the range of 87-91℃, lower than those of the secondary organic inclusions (T\-h=98-105℃), suggesting that the primary organic inclusions experienced a lower degree of thermal evolution than the secondary inclusions. This inference is consistent with the fluorescence spectroscopic characteristics and parameters (T\-\{max\}, Q values) of the organic inclusions. Data from the organic inclusions together with the petroleum geology setting revealed that the primary inclusions resulted from the migration of hydrocarbons generated within the strata they are hosted, whereas the secondary organic inclusions were trapped in the process of secondary hydrocarbons expelled out of the source rocks to the locations where they were accumulated. The thermal properties of the organic inclusions are consistent with the maturation of the oil generated from the Shahejie Formation. The abundance of the organic inclusions and their characteristics indicate that the member Es3 of the Shahejie Formation is highly potential for oil accumulation. The results could provide essential clues to petroleum exploration in the Bohai Gulf Basin.展开更多
Bohaiwan basin is an important oil-bearing basin in east China. The coal-bearing series of Carbonifer ous-Permian in the hasin distributes extensively. The micro-FT-IR analysis of the chief macerals shows that the cut...Bohaiwan basin is an important oil-bearing basin in east China. The coal-bearing series of Carbonifer ous-Permian in the hasin distributes extensively. The micro-FT-IR analysis of the chief macerals shows that the cutinite and resinite are rich in CH3 and CH2, but the sporinite is deficient in that. The desmocollinites in the C-P coals are all rich in CH2, however, the same parameters (ICH3,ICH2,,IA) of coals in Taiyuan Formation (C2t ) are greater than that in Shanxi Formation (P1s), which revealedthat the coals in Taiyuan Formation is more abundant in Hydrogen.展开更多
We investigated bleached human hair by FT-IR microspectroscopy and chemical imaging. The cross sectioned hair is approximately 90 μm in diameter, showed cuticle and cortex in chemical imaging. Differential amide I/II...We investigated bleached human hair by FT-IR microspectroscopy and chemical imaging. The cross sectioned hair is approximately 90 μm in diameter, showed cuticle and cortex in chemical imaging. Differential amide I/II absorbance ratio and broadening amide I band between in the cortex and cuticle were confirmed in FT-IR microspectroscopy and chemical imaging. The cystine monoxide band from the products of disulfide oxidation of the amino acid cystine is associated with hair damaging during bleaching process. With increase bleaching time, the band for cystine monoxide shows more intense and larger area in chemical image. The spatially chemical change was investigated in detail by FT-IR microspectroscopy and chemical imaging during the bleached process.展开更多
基金ThisprojectwassupportedbytheNationalNaturalScienceFoundationofChina (No .496 72 131) .
文摘Organic inclusions from the Shahejie Formation of the Eogene period in the Bohai Gulf Basin, eastern China, were examined using micro\|FT. IR and fluorescence microscopy in addition to the measurement of their homogenization temperatures (T\-h). Two populations of organic inclusions were recognized, the primary and the secondary organic inclusions. The primary organic inclusions contain organic materials with relatively long alkyl chains (the carbon atom number is 15 to 17), whereas the secondary organic inclusions contain a certain amount of H\-2S besides organic materials which have relatively short alkyl chains with the carbon atom number of 5 to 6. The T\-h values of the primary organic inclusions are within the range of 87-91℃, lower than those of the secondary organic inclusions (T\-h=98-105℃), suggesting that the primary organic inclusions experienced a lower degree of thermal evolution than the secondary inclusions. This inference is consistent with the fluorescence spectroscopic characteristics and parameters (T\-\{max\}, Q values) of the organic inclusions. Data from the organic inclusions together with the petroleum geology setting revealed that the primary inclusions resulted from the migration of hydrocarbons generated within the strata they are hosted, whereas the secondary organic inclusions were trapped in the process of secondary hydrocarbons expelled out of the source rocks to the locations where they were accumulated. The thermal properties of the organic inclusions are consistent with the maturation of the oil generated from the Shahejie Formation. The abundance of the organic inclusions and their characteristics indicate that the member Es3 of the Shahejie Formation is highly potential for oil accumulation. The results could provide essential clues to petroleum exploration in the Bohai Gulf Basin.
文摘Bohaiwan basin is an important oil-bearing basin in east China. The coal-bearing series of Carbonifer ous-Permian in the hasin distributes extensively. The micro-FT-IR analysis of the chief macerals shows that the cutinite and resinite are rich in CH3 and CH2, but the sporinite is deficient in that. The desmocollinites in the C-P coals are all rich in CH2, however, the same parameters (ICH3,ICH2,,IA) of coals in Taiyuan Formation (C2t ) are greater than that in Shanxi Formation (P1s), which revealedthat the coals in Taiyuan Formation is more abundant in Hydrogen.
文摘We investigated bleached human hair by FT-IR microspectroscopy and chemical imaging. The cross sectioned hair is approximately 90 μm in diameter, showed cuticle and cortex in chemical imaging. Differential amide I/II absorbance ratio and broadening amide I band between in the cortex and cuticle were confirmed in FT-IR microspectroscopy and chemical imaging. The cystine monoxide band from the products of disulfide oxidation of the amino acid cystine is associated with hair damaging during bleaching process. With increase bleaching time, the band for cystine monoxide shows more intense and larger area in chemical image. The spatially chemical change was investigated in detail by FT-IR microspectroscopy and chemical imaging during the bleached process.
