By analyzing the characteristics of development, structural evolution and reservoir beds of the residual carbonate strata, this study shows that the residual carbonate strata in the Yingmaili low uplift are favorable ...By analyzing the characteristics of development, structural evolution and reservoir beds of the residual carbonate strata, this study shows that the residual carbonate strata in the Yingmaili low uplift are favorable oil and gas accumulation series in the Tabei (northern Tarim uplift) uplift. There are different patterns of hydrocarbon accumulation on the northern and southern slopes of the Yingmaili low uplift. The north-south differentiation of oil reservoirs were caused by different lithologies of the residual carbonate strata and the key constraints on the development of the reservoir beds. The Mesozoic terrestrial organic matter in the Kuqa depression and the Palaeozoic marine organic matter in the Manjiaer sag of the Northern depression are the major hydrocarbon source rocks for the northern slope and southern slope respectively. The hydrocarbon accumulation on the northern and southern slopes is controlled by differences in maturity and thermal evolution history of these two kinds of organic matter. On the southern slope, the oil accumulation formed in the early stage was destroyed completely, and the period from the late Hercynian to the Himalayian is the most important time for hydrocarbon accumulation. However, the time of hydrocarbon accumulation on the northern slope began 5 Ma B.P. Carbonate inner buried anticlines reservoirs are present on the southern slope, while weathered crust and paleo-buried hill karst carbonate reservoirs are present on the northern slope. The northern and southern slopes had different controlling factors of hydrocarbon accumulation respectively. Fracture growth in the reservoir beds is the most important controlling factor on the southern slope; while hydrocarbon accumulation on the northern slope is controlled by weathered crust and cap rock.展开更多
针对烃类重整蒸汽制氢工艺转化气能量降级使用、原料气压缩功耗大的问题,提出了一种低碳烃膨胀透平集成制氢工艺。该工艺以炼油厂过剩低碳液态烃为原料,增压功耗较低,在转化炉出口设置膨胀透平,回收转化气的高温高压热能和压力能后再送...针对烃类重整蒸汽制氢工艺转化气能量降级使用、原料气压缩功耗大的问题,提出了一种低碳烃膨胀透平集成制氢工艺。该工艺以炼油厂过剩低碳液态烃为原料,增压功耗较低,在转化炉出口设置膨胀透平,回收转化气的高温高压热能和压力能后再送余热锅炉产汽,同时回收中变气余热以加热液相原料。使用Aspen Plus V11对新工艺进行了全流程模拟,探求其原料组成、反应压力、反应温度、蒸汽碳比对装置热效率、能耗和CO_(2)排放量的影响。基于模拟数据,采用非支配排序遗传算法NSGA-Ⅱ对新工艺进行了多变量多目标优化。计算表明,某液化石油气进料量为8.756 t/h的新工艺,最优操作工况下产氢2636.8 kg/h、发电8870.2 kW·h/h,生产1 t H_(2)综合能耗2892.9 kgoe、装置热效率71.63%、CO_(2)排放29984.6 kg/h,较优化前工况综合能耗降低、产氢量增加。展开更多
Silicate substrates were coated by ion sputtering with nickel,and then used to catalyze the decomposition of low hydrocarbons to prepare the relatively well distributed carbon nanotubes films(CNFs).The effects of sput...Silicate substrates were coated by ion sputtering with nickel,and then used to catalyze the decomposition of low hydrocarbons to prepare the relatively well distributed carbon nanotubes films(CNFs).The effects of sputtering time,etching,and treatment in ammonia water on the morphology of CNFs were investigated,respectively.SEM measurements showed that the morphology of CNFs became more orderly with the increase of sputtering time,and carbon nanotubes of CNFs would not arrange very tightly after the coated nickel films were etched or/and treated in ammonia water for some time.展开更多
基金part of the National Key Fundamental Research Program(No.2005CB422108)the National Natural Science Foundation of China(Grant No.40672092).
文摘By analyzing the characteristics of development, structural evolution and reservoir beds of the residual carbonate strata, this study shows that the residual carbonate strata in the Yingmaili low uplift are favorable oil and gas accumulation series in the Tabei (northern Tarim uplift) uplift. There are different patterns of hydrocarbon accumulation on the northern and southern slopes of the Yingmaili low uplift. The north-south differentiation of oil reservoirs were caused by different lithologies of the residual carbonate strata and the key constraints on the development of the reservoir beds. The Mesozoic terrestrial organic matter in the Kuqa depression and the Palaeozoic marine organic matter in the Manjiaer sag of the Northern depression are the major hydrocarbon source rocks for the northern slope and southern slope respectively. The hydrocarbon accumulation on the northern and southern slopes is controlled by differences in maturity and thermal evolution history of these two kinds of organic matter. On the southern slope, the oil accumulation formed in the early stage was destroyed completely, and the period from the late Hercynian to the Himalayian is the most important time for hydrocarbon accumulation. However, the time of hydrocarbon accumulation on the northern slope began 5 Ma B.P. Carbonate inner buried anticlines reservoirs are present on the southern slope, while weathered crust and paleo-buried hill karst carbonate reservoirs are present on the northern slope. The northern and southern slopes had different controlling factors of hydrocarbon accumulation respectively. Fracture growth in the reservoir beds is the most important controlling factor on the southern slope; while hydrocarbon accumulation on the northern slope is controlled by weathered crust and cap rock.
文摘针对烃类重整蒸汽制氢工艺转化气能量降级使用、原料气压缩功耗大的问题,提出了一种低碳烃膨胀透平集成制氢工艺。该工艺以炼油厂过剩低碳液态烃为原料,增压功耗较低,在转化炉出口设置膨胀透平,回收转化气的高温高压热能和压力能后再送余热锅炉产汽,同时回收中变气余热以加热液相原料。使用Aspen Plus V11对新工艺进行了全流程模拟,探求其原料组成、反应压力、反应温度、蒸汽碳比对装置热效率、能耗和CO_(2)排放量的影响。基于模拟数据,采用非支配排序遗传算法NSGA-Ⅱ对新工艺进行了多变量多目标优化。计算表明,某液化石油气进料量为8.756 t/h的新工艺,最优操作工况下产氢2636.8 kg/h、发电8870.2 kW·h/h,生产1 t H_(2)综合能耗2892.9 kgoe、装置热效率71.63%、CO_(2)排放29984.6 kg/h,较优化前工况综合能耗降低、产氢量增加。
文摘Silicate substrates were coated by ion sputtering with nickel,and then used to catalyze the decomposition of low hydrocarbons to prepare the relatively well distributed carbon nanotubes films(CNFs).The effects of sputtering time,etching,and treatment in ammonia water on the morphology of CNFs were investigated,respectively.SEM measurements showed that the morphology of CNFs became more orderly with the increase of sputtering time,and carbon nanotubes of CNFs would not arrange very tightly after the coated nickel films were etched or/and treated in ammonia water for some time.