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Effects of Sodium Chloride Stress on Growth of Sweet Potato Plantlets in vitro and Ion Content 被引量:13
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作者 高叶 赵术珍 +2 位作者 陈敏 宋晓征 王宝山 《Agricultural Science & Technology》 CAS 2008年第5期27-30,共4页
[Objective] This study aimed to investigate the salt-tolerance mechanism of sweet potato.[Method]Two sweet potato varieties of Xu 25-2(salt-tolerant cultivar)and Triumph 100(salt-sensitive cultivar)were treated by sod... [Objective] This study aimed to investigate the salt-tolerance mechanism of sweet potato.[Method]Two sweet potato varieties of Xu 25-2(salt-tolerant cultivar)and Triumph 100(salt-sensitive cultivar)were treated by sodium chloride with the concentration of 0 mmol/L and 100 mmol/L.After 20 days,Na+ content and Na+/K+ ratio in the roots,shoots and leave were determined by the flame photometer,while dry weight and fresh weight of roots,shoots and leave in different varieties were also studied.[Result]The growth of two sweet potato varieties was inhibited under salt stress,so the plant became shorter,leaf and root became fewer,dry weight of roots and leave decreased,but seedlings of Xu 25-2 were inhibited slightly.Furthermore,Na+ content and Na+/K+ ratio in roots,shoots and leaves of two sweet potato varieties increased.Na+ content of salt-tolerant Xu 25-2 was low in roots,shoots and leaves,while Na+ content of salt-sensitive Triumph 100 was high in shoots and leave of seedlings,but the change range of Xu 25-2 was less than that of Triumph 100.[Conclusion]The lower Na+ content and Na+/K+ ratio in leaves under salt stress were the most important characteristics for salt-tolerance of sweet potato varieties. 展开更多
关键词 SALT STRESS Sweet potato Test-tube PLANTLET GROWTH ion content SALT tolerance
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Effect of salinity on seed germination, growth and ion content in dimorphic seeds of Salicornia europaea L. (Chenopodiaceae) 被引量:7
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作者 Nikolai Orlovsky Ulbasyn Japakova +1 位作者 Huifan Zhang Sergei Volis 《Plant Diversity》 SCIE CAS CSCD 北大核心 2016年第4期183-189,共7页
The halophyte Salicornia europaea L. is a widely distributed salt-tolerant plant species that produces numerous dimorphic seeds. We studied germination and recovery in dimorphic seeds of Central Asian S. europaea unde... The halophyte Salicornia europaea L. is a widely distributed salt-tolerant plant species that produces numerous dimorphic seeds. We studied germination and recovery in dimorphic seeds of Central Asian S. europaea under various salinity conditions. We also tested the effects of various salts on Na+ and K+ accumulation during plant development from germination to anthesis under greenhouse conditions. We found good germination (close to control) of large seeds under NaCl between 0.5 and 2%, Na2SO4 and 2NaCl + KCl + CaCl between 0.5 and 3%, and 2Na2SO4 + K2SO4 -- MgSO4 between 0.5 and 5%. For the small seeds, we found stimulating effects of chloride salts (both pure and mixed) under 0.5-1% concentrations, and sulfate salts under 0.5-3%. Both types of seeds showed high germination recovery potential. Salt tolerance limits of the two seed types during germination and at the later stages of development were very similar (4-5%). During plant growth the optimal concentrations of mixed chloride and sulfate salts ranged from 0.5 to 2%. The mechanisms of salt tolerance in the two seed types of S. europaea appear to differ, but complement each other, improving overall adaptation of this species to high salinity. 展开更多
关键词 Dimorphic seeds Germination Salinity Recovery ion content
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Chloride Ion Critical Content in Reinforced Concrete 被引量:1
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作者 李岩 Laura STIRNEMANN 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2007年第4期737-740,共4页
Chloride ion critical content was studied under soaking and cycle of dry and wet conditions, with three electrochemical nondestructive measuring techniques, i e, half-cell potential, A C impedance, and time potential.... Chloride ion critical content was studied under soaking and cycle of dry and wet conditions, with three electrochemical nondestructive measuring techniques, i e, half-cell potential, A C impedance, and time potential. The experimental results show that chloride ion critical content is primarily determined by the water cement ratio, while for the same concrete mixture the chloride ion critical content in soaking conditions is larger than that in a cycle of dry and wet conditions. 展开更多
关键词 chloride ion cycle of dry and wet critical content A C impedance
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Effects of Salinity and Potassium Application on Antioxidant Enzyme Activities and Physiological Parameters in Pearl Millet 被引量:6
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作者 Mostafa Heidari Parisa Jamshidi 《Agricultural Sciences in China》 CAS CSCD 2011年第2期228-237,共10页
A plot culture experiment was conducted in a greenhouse at University of Zabol,Iran,to study the effects of different salinity levels and potassium supply on pearl millet.The experiment was laid out in a completely ra... A plot culture experiment was conducted in a greenhouse at University of Zabol,Iran,to study the effects of different salinity levels and potassium supply on pearl millet.The experiment was laid out in a completely randomized factorial design with three replicates.Potassium sulfate was used as the potassium source.The rates of potassium treatments were 0,100,and 200 kg ha-1.Pearl millet was subjected to different salinity levels(0,4,8,and 12 ds m-1) through addition of NaCl to irrigation water.Results showed that the increase in the salt concentration from control to 12 ds m-1 decreased grain yield(38.7%) of millet plants.In this study,we found a negative relationship between potassium and proline accumulation at vegetative(r2=-0.75**) and reproductive stage(r2=-0.66**) in millet plants.Salt stress remarkably elevated the activities of CAT and GPX antioxidant enzymes at vegetative and reproductive stages.Furthermore,potassium application had significant effect on grain yield and increased it about 10.6% at the highest salinity treatment(12 ds m-1).Though,potassium treatment increased antioxidant activity in millet plants,it had no significant effect on proline content in leaves.Salinity treatment decreased potassium uptake but application potassium increased potassium content in leaves at two stages. 展开更多
关键词 antioxidants enzymes ion content pearl millet POTASSIUM PROLINE SALINITY
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高效离子排斥色谱法检测复方氨基酸注射液(18AA)中山梨醇含量
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作者 左利民 肖菁 +6 位作者 郭鑫 赵婷 连晓芳 刘惠一 谷永升 周怡 山广志 《中国新药杂志》 北大核心 2025年第3期312-316,共5页
目的:建立高效离子排斥色谱法测定复方氨基酸注射液(18AA)中山梨醇含量。方法:采用Rezex ROA-organic Acid H^(+)(8%)色谱柱(300 mm×7.8 mm,8μm),流动相为12.5×10^(-3)mol·L^(-1)硫酸溶液,等度洗脱,流速为0.5 mL·m... 目的:建立高效离子排斥色谱法测定复方氨基酸注射液(18AA)中山梨醇含量。方法:采用Rezex ROA-organic Acid H^(+)(8%)色谱柱(300 mm×7.8 mm,8μm),流动相为12.5×10^(-3)mol·L^(-1)硫酸溶液,等度洗脱,流速为0.5 mL·min^(-1),柱温为55℃,进样10μL,检测波长200 nm。结果:氨基酸成分不干扰山梨醇测定,山梨醇峰与相邻色谱峰分离度良好,在4.905~19.62 mg·mL^(-1)浓度范围线性良好(r=1.000,n=5),精密度、重复性、稳定性试验的RSD均<1.0%,平均回收率为98.90%,RSD为1.55%(n=9)。3批市售复方氨基酸注射液(18AA)中山梨醇含量分别为标示量的98.54%,97.92%,97.24%。结论:采用该方法能够有效解决氨基酸成分的干扰,不需进行复杂的前处理工作,快速简便、专属性强、准确度高,可用于复方氨基酸注射液(18AA)中山梨醇的含量测定。 展开更多
关键词 高效离子排斥色谱法 复方氨基酸注射液(18AA) 山梨醇 含量测定
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盐胁迫下外源水杨酸对甘蓝幼苗生理特性的影响
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作者 李晶菲 李梦娇 +6 位作者 庞青青 战志鹏 刘杨 郭明慧 李大伟 黄炜 许忠民 《蔬菜》 2025年第3期30-38,共9页
为探究干旱、半干旱地区甘蓝抗盐栽培措施,以甘蓝品种‘秦甘50’为试材,采用水培方法,设置叶面喷施蒸馏水(CK)、叶面喷施100μmol/L水杨酸(SA)、人工模拟150 mmol/L NaCl盐胁迫和150 mmol/L NaCl胁迫下喷施100μmol/L水杨酸(SA+NaCl)4... 为探究干旱、半干旱地区甘蓝抗盐栽培措施,以甘蓝品种‘秦甘50’为试材,采用水培方法,设置叶面喷施蒸馏水(CK)、叶面喷施100μmol/L水杨酸(SA)、人工模拟150 mmol/L NaCl盐胁迫和150 mmol/L NaCl胁迫下喷施100μmol/L水杨酸(SA+NaCl)4组处理,分析处理后幼苗的植株形态、生物量、根系活力、叶绿素含量、矿质元素吸收量、抗氧化酶活性、活性氧积累量和叶片脂膜过氧化等指标,研究水杨酸(SA)对盐胁迫下甘蓝幼苗生理特性的影响。结果表明:在盐胁迫下,喷施100μmol/L SA的甘蓝幼苗株高、茎粗、地上部鲜/干质量、地下部鲜/干质量、根系活力、叶绿素含量分别较NaCl组极显著提高108.02%、74.75%、73.27%、81.82%、138.71%、200.00%、564.68%、43.16%,叶片细胞Na^(+)含量较NaCl组极显著降低了17.74%,K^(+)含量极显著提高41.36%,Na^(+)/K^(+)比值极显著下降41.96%,维持了甘蓝植株体内的离子平衡;组织化学染色结果表明,与CK相比盐胁迫造成了严重的叶片损伤和活性氧(ROS)积累,导致叶片丙二醛(MDA)含量、过氧化氢(H_(2)O_(2))含量和超氧阴离子(O_(2)^(-))含量增高,而喷施100μmol/L SA后,甘蓝幼苗中的过氧化氢酶(CAT)、过氧化物酶(POD)和超氧化物歧化酶(SOD)活性分别较NaCl组极显著提高了36.67%、74.15%和25.73%,MDA含量、H_(2)O_(2)含量、O_(2)^(-)含量分别极显著降低13.48%、24.84%、6.01%,抗氧化酶活性的显著提高减少了盐胁迫下的活性氧累积,维持了甘蓝幼苗细胞内氧化还原稳态,从而提升了甘蓝幼苗的抗氧化能力。SA组与CK相比各指标均无显著变化。由此得出,外源喷施100μmol/L SA对甘蓝幼苗在盐胁迫下的生长具有积极的调控作用。 展开更多
关键词 盐胁迫 水杨酸 甘蓝 生理特性 组织化学染色 离子含量 抗氧化酶活性
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Deterioration Mechanisms of Sulfate Attack on Concrete under Alternate Action 被引量:8
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作者 高润东 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第2期355-359,共5页
By micro- and macro-observations, the deterioration mechanisms of concrete under alternate action between repeated sub-high temperature/cooling by water and sodium sulfate solution attack (TW-SA) were studied; meanw... By micro- and macro-observations, the deterioration mechanisms of concrete under alternate action between repeated sub-high temperature/cooling by water and sodium sulfate solution attack (TW-SA) were studied; meanwhile, the single sodium sulfate solution attack (SA) was also done as comparison. Micro-observations included the analysis of attack products by thermal analysis method and the determination of sulfate-ion content from surface to interior by chemical titrating method (modified barium sulfate gravimetric method). Macro-observations mainly included the mechanical behaviors such as compressive strength, splitting strength. The experimental results indicate, in both cases, the main attack product is ettringite, only in the first layer of case SA some gypsum is checked; in case SA, the sulfate ions mainly concentrate in the surface layer, so the attack is relatively mild; but in case TW-SA, the repeated sub-high temperature/cooling by water promotes the sulfate ions diffusing inwards, which leads to obvious strength degradation. 展开更多
关键词 CONCRETE SULFATE repeated sub-high temperature/cooling by water attack product sulfate-ion content strength
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Effects of parasitic plant Cistanche deserticola on chlorophyll a fluorescence and nutrient accumulation of host plant Haloxylon ammodendron in the Taklimakan Desert 被引量:1
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作者 Li LI XinWen XU +2 位作者 YongQiang SUN WeiHAN PengFei TU 《Journal of Arid Land》 SCIE 2012年第3期342-348,共7页
The parasitic plant Cistanche deserticola attaches to Haloxylon ammodendron, a perennial shrub with high tolerance to salinity and drought. However, little was known about the parasite-host relation between the two sp... The parasitic plant Cistanche deserticola attaches to Haloxylon ammodendron, a perennial shrub with high tolerance to salinity and drought. However, little was known about the parasite-host relation between the two species. Effects of the parasite on chlorophyll a fluorescence and nutrient accumulation in the host plant (H. am- modendron) were investigated in the Taklimakan Desert. Some photosynthetic parameters of both host and non-host H. ammodendron plants were measured by in vivo chlorophyll a fluorescence technology in the field. The assimilating branches of host and non-host plants were collected and nutrient and inorganic ion contents were analyzed. The results from field experiments showed that the infection of C. deserticola reduced the non-photochemical quenching of the variable chlorophyll fluorescence (NPQ) and the potential maximum quantum yield for primary photochemistry (Fv/Fm) of the host. Compared with non-host plants, the host H. ammodendron had low nutrient, low inorganic ion contents (Na~ and K~) and low K~/Na~ ratios in the assimilating branches. It suggested that C. deserticola infection reduced the nutrient acquisition and caused damage to the photoprotection through thermal dissipation of the energy of the photosystem II in the host, resulting in a decrease in the tolerance to salinity and high radiation. It was concluded that the attachment of the parasite plant (C. deserticola) had negative effects on the growth of its host. 展开更多
关键词 parasite-host relation nutrient acquisition inorganic ion content non-photochemical quenching the Taklimakan Desert
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无氰亚铜体系电镀铜−锡合金工艺
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作者 邢希瑞 刘颖 +4 位作者 王亚伟 赵万成 夏方诠 田栋 李宁 《电镀与涂饰》 北大核心 2025年第1期62-68,共7页
[目的]开发了以氧化亚铜和氯化亚锡为主盐的无氰电镀铜−锡(Cu–Sn)合金体系。[方法]通过阴极极化曲线测试,研究了体系中亚锡离子和亚铜离子的电化学还原行为,并通过霍尔槽试验、扫描电子显微镜和能谱仪考察了镀液组成和电流密度对Cu–S... [目的]开发了以氧化亚铜和氯化亚锡为主盐的无氰电镀铜−锡(Cu–Sn)合金体系。[方法]通过阴极极化曲线测试,研究了体系中亚锡离子和亚铜离子的电化学还原行为,并通过霍尔槽试验、扫描电子显微镜和能谱仪考察了镀液组成和电流密度对Cu–Sn合金镀层外观、形貌和元素组成的影响。[结果]在无氰亚铜电镀Cu–Sn合金体系中,亚铜离子的还原电位比亚锡离子的还原电位更负,且锡的电沉积更容易受到传质过程控制。当镀液中含有硫脲(作为亚铜离子配位剂)80 g/L、氧化亚铜16 g/L、酒石酸钾钠(作为锡离子配位剂)20 g/L及无水氯化亚锡8 g/L时,高电流密度和低电流密度下所得的Cu–Sn合金镀层都呈均匀的银灰色,结晶细致,并且Sn的质量分数稳定在35%左右。[结论]采用无氰亚铜体系可以电镀得到成分可控的Cu–Sn合金镀层。 展开更多
关键词 无氰电镀 铜–锡合金 亚铜离子 硫脲 锡含量 霍尔槽试验
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丛枝菌根真菌调控盐碱胁迫下棉花生长及离子平衡的研究
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作者 彭梓程 杜洪力 +2 位作者 王铭 张凤华 杨海昌 《中国农业科技导报(中英文)》 北大核心 2025年第2期33-41,共9页
为探究丛枝菌根真菌(arbuscular mycorrhizal fungi,AMF)对棉花苗期逆境离子吸收和运转的影响,采用盆栽试验,以棉花‘新陆早45号’为材料,接种摩西斗管囊霉,以不接种AMF为对照,待棉花生长至3叶期进行不同水平(0、50、100、150、200 mmol... 为探究丛枝菌根真菌(arbuscular mycorrhizal fungi,AMF)对棉花苗期逆境离子吸收和运转的影响,采用盆栽试验,以棉花‘新陆早45号’为材料,接种摩西斗管囊霉,以不接种AMF为对照,待棉花生长至3叶期进行不同水平(0、50、100、150、200 mmol·L^(−1))盐碱胁迫,分析不同处理下棉花幼苗生长及叶、茎、根离子含量的变化。结果表明,棉花根系侵染率随盐碱胁迫程度的增加而逐渐降低,菌根依赖性随盐碱胁迫程度的增加而增加。随着盐碱胁迫程度的增加,棉花幼苗生物量逐渐降低,而接种AMF可显著促进棉花生长发育。在各盐碱胁迫处理下,接种AMF显著提高了棉花幼苗生物量;显著降低棉花幼苗各器官的Na^(+)含量及Na^(+)/K^(+)、Na^(+)/Ca^(2+)、Na^(+)/Mg^(2+),显著提高棉花幼苗各器官的K^(+)、Ca^(2+)、Mg^(2+)含量;降低了Na^(+)由地下向地上的运输,同时增加K^(+)、Ca^(2+)、Mg^(2+)由地下向地上的运输。综上,盐碱胁迫可抑制K^(+)、Ca^(2+)、Mg^(2+)由地下向地上部的运输,接种AMF能够抑制棉花根系对Na^(+)的吸收及向上运输,促进根系对K^(+)、Ca^(2+)、Mg^(2+)的吸收及向上运输,从而降低Na^(+)/K^(+)、Na^(+)/Ca^(2+)、Na^(+)/Mg^(2+),缓解Na^(+)对棉花植株的伤害,促进棉花幼苗的生长发育。 展开更多
关键词 盐碱含量 离子运输比 侵染 棉花
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高盐石膏提纯工艺研究
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作者 马文浩 张敏 +3 位作者 曹军 郭云云 徐泉 王佩汝 《中国井矿盐》 2025年第1期1-3,共3页
制盐、制碱企业生产过程中产生的石膏含有大量可溶性杂质,需要提纯方可作为产品出售。本文探究了不同提纯工艺下,石膏中可溶性氯离子含量、白度、品位等物性变化,为石膏生产企业生产高纯度二水石膏提供思路。
关键词 石膏 提纯 氯离子含量
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水基钻井液碳酸根离子含量检测失真原因分析及改进方法
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作者 厉明伟 《中国井矿盐》 2025年第1期31-33,39,共4页
通过处理哈山A1井碳酸根离子污染情况,发现碳酸根离子含量检测误差大。分析钻井液各种处理剂对碳酸根离子检测干扰后,提出两种碳酸根离子含量检测方法。两种方法在哈山A2井进行了现场验证,采用方法2计算的碳酸根离子含量来确定加入氧化... 通过处理哈山A1井碳酸根离子污染情况,发现碳酸根离子含量检测误差大。分析钻井液各种处理剂对碳酸根离子检测干扰后,提出两种碳酸根离子含量检测方法。两种方法在哈山A2井进行了现场验证,采用方法2计算的碳酸根离子含量来确定加入氧化钙的量,钻井液流变性恢复,复杂情况完全解决,保证了工程的继续施工。 展开更多
关键词 碳酸根离子 含量分析 含量检测 失真 改进
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反相离子对色谱法测定辅助生殖培养液中庆大霉素含量
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作者 赵丹妹 李柚 +3 位作者 康海华 冷昕洋 刘振齐 柯林楠 《中国药业》 2025年第3期67-70,共4页
目的建立测定辅助生殖培养液中庆大霉素含量的反相离子对色谱法。方法辅助生殖培养液样品采用WCX固相萃取小柱富集、净化法进行前处理。色谱柱为Apollo C_(18)柱(250 mm×4.6 mm,5μm),淋洗液为水(含0.7%三氟乙酸、0.025%五氟丙酸、... 目的建立测定辅助生殖培养液中庆大霉素含量的反相离子对色谱法。方法辅助生殖培养液样品采用WCX固相萃取小柱富集、净化法进行前处理。色谱柱为Apollo C_(18)柱(250 mm×4.6 mm,5μm),淋洗液为水(含0.7%三氟乙酸、0.025%五氟丙酸、0.2%NaOH,pH为2.6)-乙腈(50∶3,V/V),检测器为柱后加碱-脉冲安培检测器,以外标法定量。结果庆大霉素C^(1),C_(1a),C_(2),C_(2a)的质量浓度分别在0.550~10.996μg/mL、0.526~10.512μg/mL、0.584~11.688μg/mL、0.356~7.124μg/mL范围内与峰面积线性关系良好(r>0.9995,n=6);检测限为0.2016μg/mL,定量限为0.6722μg/mL;回收率为92.66%~99.82%,RSD<5%(n=6)。精子冷冻液中未检出庆大霉素,颗粒细胞去除液、玻璃化解冻液、全程培养液、精子密度梯度分离液、精子制动液中庆大霉素的含量分别为17.54,12.60,15.08,9.26,11.12μg/mL(n=6)。结论该方法前处理简单,无须衍生化处理,简便高效,灵敏度高,重复性好,可用于多种辅助生殖培养液中庆大霉素的检测。 展开更多
关键词 反相离子对色谱法 脉冲安培检测法 辅助生殖培养液 庆大霉素 含量测定
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氢氧化钠熔融-氟离子选择电极法测定煤中氟含量
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作者 杨翰枭 刘钢耀 +1 位作者 王宴秋 王嘉 《山西化工》 2025年第1期80-83,共4页
煤燃烧过程中氟元素会转化为挥发性氟化物释放出来,对生物体与环境都会有不良影响。因此,研究一种准确快速检测煤中氟元素含量的方法是非常有必要的。本文采用氢氧化钠作为熔剂,实现了在熔融过程中将煤中的氟元素快速捕获并检测。通过... 煤燃烧过程中氟元素会转化为挥发性氟化物释放出来,对生物体与环境都会有不良影响。因此,研究一种准确快速检测煤中氟元素含量的方法是非常有必要的。本文采用氢氧化钠作为熔剂,实现了在熔融过程中将煤中的氟元素快速捕获并检测。通过研究试样与熔剂比例、反应温度及时间、熔融温度、熔融时间对煤中氟元素含量测定的影响,综合确定了最佳实验条件。后续通过对该方法的检测下限、准确度及精密度进行实验评价,最终建立了一种可以准确、快速、批量测定煤炭中氟元素含量的分析方法。 展开更多
关键词 煤中氟含量 氢氧化钠熔融 氟离子选择电极 标准曲线法
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2D titanium carbide(MXene) electrodes with lower-F surface for high performance lithium-ion batteries 被引量:13
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作者 Ming Lu Haojie Li +9 位作者 Wenjuan Han Junnan Chen Wen Shi Jiaheng Wang Xiang-Min Meng Jingang Qi Haibo Li Bingsen Zhang Wei Zhang Weitao Zheng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第4期148-153,共6页
MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect ... MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect on electrochemical performance. Herein, annealing MXene under hydrogen was employed for removing-F and turning-OH to-O terminations. We demonstrate that it improves the kinetics of Li-ion transport between the electrolyte and electrode. As a result, a lower interfacial charge transfer impedance was obtained. The electrochemical measurement exhibited that a nearly 2-fold increase of specific capacity was achieved for the annealed MXene. 展开更多
关键词 Ti3C2 MXene LI-ion Hydrogen -F content
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离子色谱法测定维格列汀片中基因毒性杂质氯乙酸含量
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作者 母芹 罗誓言 +2 位作者 姚诚 杨俊芸 罗东玲 《中国药业》 2025年第3期76-78,共3页
目的建立测定维格列汀片中氯乙酸含量的离子色谱法。方法分析柱为Dionex IonPac AS11-HC阴离子分离柱(250 mm×4.6 mm),保护柱为Dionex IonPac AG11-HC阴离子保护柱(50 mm×4.0 mm),淋洗液为10 mmol/L氢氧化钾溶液,流速为1.0 mL... 目的建立测定维格列汀片中氯乙酸含量的离子色谱法。方法分析柱为Dionex IonPac AS11-HC阴离子分离柱(250 mm×4.6 mm),保护柱为Dionex IonPac AG11-HC阴离子保护柱(50 mm×4.0 mm),淋洗液为10 mmol/L氢氧化钾溶液,流速为1.0 mL/min,辅助气为99.99%氮气,检测器为抑制电导检测器,检测池温度为35℃,进样量为25μL。结果氯乙酸的质量浓度在0.01~2.00μg/mL范围内与峰面积线性关系良好(r=0.9995,n=7);检测限为11.77 ng/g,定量限为62.77 ng/g;精密度、稳定性试验结果的RSD均小于3.0%;平均加样回收率为101.64%,RSD为4.60%(n=12)。10个厂家的10批样品中,有5批检出氯乙酸杂质,其含量为0.0002%~0.0007%,均低于限度规定的0.0015%。结论该方法操作简便、灵敏度高、专属性强、高效快速,可用于维格列汀片中氯乙酸的含量测定。 展开更多
关键词 离子色谱法 维格列汀片 氯乙酸 基因毒性杂质 含量测定
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不同消解方法对Li_(2)O-Al_(2)O_(3)-SiO_(2)渣系中锂含量测定结果的影响
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作者 彭桢 蒋搏涛 +3 位作者 颜康 方翔 王旭东 邓洪波 《江西冶金》 2025年第1期25-31,共7页
火法冶金是实现短流程回收废旧锂离子电池中有价金属的主要途径,但含锂炉渣中的锂元素难以精准测定。本研究以废旧锂离子电池熔炼所得Li_(2)O-Al_(2)O_(3)-SiO_(2)基含锂炉渣为研究对象,对比分析常规酸溶法、加压酸溶法、碱熔法3种消解... 火法冶金是实现短流程回收废旧锂离子电池中有价金属的主要途径,但含锂炉渣中的锂元素难以精准测定。本研究以废旧锂离子电池熔炼所得Li_(2)O-Al_(2)O_(3)-SiO_(2)基含锂炉渣为研究对象,对比分析常规酸溶法、加压酸溶法、碱熔法3种消解方法对炉渣中锂含量测定结果的影响。结果表明,采用常规酸溶法,在HCl+HF体系下,当加热板温度为200℃、消解时间为2 h时,含锂炉渣中锂含量的测定结果为9.62%;与加压酸溶法和碱熔法相比,常规酸溶法测定便捷,结果准确、稳定且安全性高。本研究可为开发含锂炉渣中高效、便捷、稳定的锂元素定量分析方法提供参考。 展开更多
关键词 废旧锂离子电池 含锂炉渣 锂含量测定 酸溶 碱熔
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掺合料对协同处置水泥混凝土重金属浸出特性的影响
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作者 宋羿昊 《价值工程》 2025年第1期105-107,共3页
将水泥窑协同处置固废技术用于水泥生产是一种环保和资源化利用的有效途径。但固废中的部分重金属会通过熟料进入到水泥中,在水泥产品的使用过程中存在释放或浸出的潜在风险。为了降低碳化作用下水泥混凝土中重金属浸出量,通过外掺矿物... 将水泥窑协同处置固废技术用于水泥生产是一种环保和资源化利用的有效途径。但固废中的部分重金属会通过熟料进入到水泥中,在水泥产品的使用过程中存在释放或浸出的潜在风险。为了降低碳化作用下水泥混凝土中重金属浸出量,通过外掺矿物掺合料研究掺合料对重金属浸出性能的影响。结果表明:粉煤灰和矿渣作为矿物掺合料能够优化混凝土的微观结构,在混凝土内部形成了一种含Cr和Ca的无定形复合氢氧化物沉淀,大幅降低Cr和Cr^(6+)的浸出量,其浸出量小于GB 3838-2002的V类地表水限值。 展开更多
关键词 协同处置水泥混凝土 加速碳化 离子浸出 六价铬
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Influence of Si Content on Properties of Ti1-xSixN Coatings 被引量:3
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作者 WAN Qiang LIU Nian +2 位作者 YANG Bing LIU Huidong CHEN Yanming 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2019年第4期774-780,共7页
To investigate the evolution of microstructure and wear behavior of TiSiN coatings with the variation of Si in targets and lays the foundation for its controllable mass production, Ti1-xSixN composite coatings were de... To investigate the evolution of microstructure and wear behavior of TiSiN coatings with the variation of Si in targets and lays the foundation for its controllable mass production, Ti1-xSixN composite coatings were deposited onto Si(100) and cemented carbide substrates using TiSi targets with different Si content by cathodic arc ion plating. The influences of Si on the microstructure and mechanical properties were studied. Nano-amorphous composite structure appeared in the Ti1-xSixN coatings when Si content in TiSi target was higher than 5 at%. However, further increase of Si content in TiSi target exhibited a negligible effect on the microstructure of Ti1-xSixN coatings. Hardness and deformation resistance were correlated to the content of Si in TiSi targets. Maximum hardness was obtained as the Si content in target increased up to 20 at%. Friction coefficient and wear rate significantly decreased with addition of Si in TiN coating, and then dually increased with the increase of Si content in targets. 展开更多
关键词 cathodic ARC ion PLATING Ti(1-x)SixN coating silicon content NANOCOMPOSITE mechanical properties WEAR resistance
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Construction and Application of a PVC Membrane Enoxacin Ion-selective Electrode Based on a Needle-shaped Inner Reference Electrode
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作者 HUANG Chao-lun LI Rui-fen XIU Rong 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2003年第4期409-412,共4页
A PVC membrane enoxacin ion-selective electrode based on a needle-shaped inner reference electrode was prepared. A Ag/AgCl wire was used as the substrate of this electrode. It was previously coated with a thin sheet o... A PVC membrane enoxacin ion-selective electrode based on a needle-shaped inner reference electrode was prepared. A Ag/AgCl wire was used as the substrate of this electrode. It was previously coated with a thin sheet of urea-formaldehyde resin containing Cl - ions to form a needle-shaped inner reference electrode, then the inner reference electrode was coated with a thin sheet of a PVC membrane containing an enoxacin tetraphenylborate ion-pair complex. The influences of various ion-pair complexes, concentrations of the active components in the membrane and the plasticizers on the performance of the electrode were studied by orthogonal design. The linear response range of the electrode was 7.9×10 -5 -1.0×10 -2 mol/L. The detection limit was 2.0×10 -5 mol/L. The slope was 30.4 mV/decade(25 ℃). The electrode can be used for the potentiometric determination of enoxacin tablets directly. The average recovery was 100.4%, and the RSD was 0.9%. The results agreed with those determined by the method in Chinese Pharmacopoeia. 展开更多
关键词 Enoxacin PVC membrane-coated-wire electrode ion-selective electrode content determination
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