With the increasing demand of high-power and pulsed power electronic devices,environmental-friendly potassium sodium niobate((Na_(0.5)K_(0.5))NbO_(3),KNN)ceramic-based capacitors have attracted much attention in recen...With the increasing demand of high-power and pulsed power electronic devices,environmental-friendly potassium sodium niobate((Na_(0.5)K_(0.5))NbO_(3),KNN)ceramic-based capacitors have attracted much attention in recent years owning to the boosted energy storage density(W_(rec)).Nevertheless,the dielectric loss also increases as the external electric field increases,which will generate much dissipated energy and raise the temperature of ceramic capacitors.Thus,an effective strategy is proposed to enhance the energy storage efficiency(η)via tailoring relaxor behavior and bad gap energy in the ferroelectric 0.9(Na_(0.5)K_(0.5))-NbO_(3)-0.1Bi(Zn_(2/3)(Nb_(x)Ta_(1−x))1/3)O_(3) ceramics.On the one hand,the more diverse ions in the B-sites owing to introducing the Ta could further disturb the long-range ferroelectric polar order to form the short−range polar nanoregions(PNRs),resulting in the highη.On the other hand,the introduction of Ta ions could boost the intrinsic band energy gap and thus improve the Eb.As a result,high Wrec of 3.29 J/cm^(3) and ultrahighηof 90.1%at the high external electric field of 310 kV/cm are achieved in x=0.5 sample.These results reveal that the KNN-based ceramics are promising lead-free candidate for high-power electronic devices.展开更多
Designing dielectric materials with the tremendous energy storage density is fundamentally important for developing pulse power capacitors.An effective approach was proposed to favorably modify the dielectric energy s...Designing dielectric materials with the tremendous energy storage density is fundamentally important for developing pulse power capacitors.An effective approach was proposed to favorably modify the dielectric energy storage properties(ESP)of Bi_(0.5)Na_(0.5)TiO_(3) ceramics using CaTiO_(3) incorporation.The dielectric breakdown strength was effectively enhanced,and simultaneously the relaxor behavior was optimized to lower the remnant polarization,which is resulted from the decreased grains size with the introduction of Ca^(2+)ion.Remarkably,at a CaTiO_(3) doping level of 0.2,a 0.8Bi_(0.5)Na_(0.5)TiO_(3)-0.2CaTiO_(3)(0.8BNT-0.2CT)ceramic obtained both high energy storage density(Wtotal)of~1.38 J/cm^(3) together with excellent efficiency(h)of~91.3%.Furthermore,an ultrafast discharge response speed(t0:9)~94 ns was achieved in 0.8BNT-0.2CT ceramic,as well as tremendous current density(C_(D)~1520 A/cm2)and power density(P_(D)~115 MW/cm^(3)).This study not only revealed the superior ESP mechanism as regards Bi_(0.5)Na_(0.5)TiO_(3) based ceramics but also provided candidate materials in pulse power capacitor devices.展开更多
To obtain the precise calculation method for the peak energy density and energy evolution properties of rocks subjected to uniaxial compression(UC)before the post-peak stage,particularly at s0.9sc(s denotes stress and...To obtain the precise calculation method for the peak energy density and energy evolution properties of rocks subjected to uniaxial compression(UC)before the post-peak stage,particularly at s0.9sc(s denotes stress and sc is the peak strength),extensive UC and uniaxial graded cyclical loading-unloading(GCLU)tests were performed on four rock types.In the GCLU tests,four unloading stress levels were designated when σ<0.9σc and six unloading stress levels were designated forσ≥0.9σc.The variations in the elastic energy density(ue),dissipative energy density(ud),and energy storage efficiency(C)for the four rock types under GCLU tests were analyzed.Based on the variation of ue whenσ≥0:9σc,a method for calculating the peak energy density was proposed.The energy evolution in rock under UC condition before the post-peak stage was examined.The relationship between C0.9(C atσ≥0:9σc)and mechanical behavior of rocks was explored,and the damage evolution of rock was analyzed in view of energy.Compared with that of the three existing methods,the accuracy of the calculation method of peak energy density proposed in this study is higher.These findings could provide a theoretical foundation for more accurately revealing the failure behavior of rock from an energy perspective.展开更多
Cement-based materials are the foundation of modern buildings but suffer from intensive energy consumption.Utilizing cement-based materials for efficient energy storage is one of the most promising strategies for real...Cement-based materials are the foundation of modern buildings but suffer from intensive energy consumption.Utilizing cement-based materials for efficient energy storage is one of the most promising strategies for realizing zero-energy buildings.However,cement-based materials encounter challenges in achieving excellent electrochemical performance without compromising mechanical properties.Here,we introduce a biomimetic cement-based solid-state electrolyte(labeled as l-CPSSE)with artificially organized layered microstructures by proposing an in situ ice-templating strategy upon the cement hydration,in which the layered micropores are further filled with fast-ion-conducting hydrogels and serve as ion diffusion highways.With these merits,the obtained l-CPSSE not only presents marked specific bending and compressive strength(2.2 and 1.2 times that of traditional cement,respectively)but also exhibits excellent ionic conductivity(27.8 mS·cm^(-1)),overwhelming most previously reported cement-based and hydrogel-based electrolytes.As a proof-of-concept demonstration,we assemble the l-CPSSE electrolytes with cement-based electrodes to achieve all-cement-based solid-state energy storage devices,delivering an outstanding full-cell specific capacity of 72.2 mF·cm^(-2).More importantly,a 5×5 cm^(2) sized building model is successfully fabricated and operated by connecting 4 l-CPSSE-based full cells in series,showcasing its great potential in self-energy-storage buildings.This work provides a general methodology for preparing revolutionary cement-based electrolytes and may pave the way for achieving zero-carbon buildings.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.52072150)the Young Elite Scientists Sponsorship Program of the Chinese Academy of Space Technology(CAST)and Open Foundation of Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices(EFMD2021002Z).
文摘With the increasing demand of high-power and pulsed power electronic devices,environmental-friendly potassium sodium niobate((Na_(0.5)K_(0.5))NbO_(3),KNN)ceramic-based capacitors have attracted much attention in recent years owning to the boosted energy storage density(W_(rec)).Nevertheless,the dielectric loss also increases as the external electric field increases,which will generate much dissipated energy and raise the temperature of ceramic capacitors.Thus,an effective strategy is proposed to enhance the energy storage efficiency(η)via tailoring relaxor behavior and bad gap energy in the ferroelectric 0.9(Na_(0.5)K_(0.5))-NbO_(3)-0.1Bi(Zn_(2/3)(Nb_(x)Ta_(1−x))1/3)O_(3) ceramics.On the one hand,the more diverse ions in the B-sites owing to introducing the Ta could further disturb the long-range ferroelectric polar order to form the short−range polar nanoregions(PNRs),resulting in the highη.On the other hand,the introduction of Ta ions could boost the intrinsic band energy gap and thus improve the Eb.As a result,high Wrec of 3.29 J/cm^(3) and ultrahighηof 90.1%at the high external electric field of 310 kV/cm are achieved in x=0.5 sample.These results reveal that the KNN-based ceramics are promising lead-free candidate for high-power electronic devices.
基金This work was supported by the National Natural Science Foundation of China(Grant NO 51872177)The authors would also like to thank the Natural Science Basic Research Plan in the Shaanxi Province of China(Grant No.2022JQ-338,2021ZDLSF06-03,2021JM-201)+1 种基金Science and Technology Project of Xian,China(Grant No.2020KJRC0014)the Fundamental Research Funds for the Central Universities(Program No.GK202002014).
文摘Designing dielectric materials with the tremendous energy storage density is fundamentally important for developing pulse power capacitors.An effective approach was proposed to favorably modify the dielectric energy storage properties(ESP)of Bi_(0.5)Na_(0.5)TiO_(3) ceramics using CaTiO_(3) incorporation.The dielectric breakdown strength was effectively enhanced,and simultaneously the relaxor behavior was optimized to lower the remnant polarization,which is resulted from the decreased grains size with the introduction of Ca^(2+)ion.Remarkably,at a CaTiO_(3) doping level of 0.2,a 0.8Bi_(0.5)Na_(0.5)TiO_(3)-0.2CaTiO_(3)(0.8BNT-0.2CT)ceramic obtained both high energy storage density(Wtotal)of~1.38 J/cm^(3) together with excellent efficiency(h)of~91.3%.Furthermore,an ultrafast discharge response speed(t0:9)~94 ns was achieved in 0.8BNT-0.2CT ceramic,as well as tremendous current density(C_(D)~1520 A/cm2)and power density(P_(D)~115 MW/cm^(3)).This study not only revealed the superior ESP mechanism as regards Bi_(0.5)Na_(0.5)TiO_(3) based ceramics but also provided candidate materials in pulse power capacitor devices.
基金the National Natural Science Foundation of China(Grant Nos.52104133 and 52304227)the Postdoctoral Foundation of Henan Province(Grant No.HN2022015)are appreciated.
文摘To obtain the precise calculation method for the peak energy density and energy evolution properties of rocks subjected to uniaxial compression(UC)before the post-peak stage,particularly at s0.9sc(s denotes stress and sc is the peak strength),extensive UC and uniaxial graded cyclical loading-unloading(GCLU)tests were performed on four rock types.In the GCLU tests,four unloading stress levels were designated when σ<0.9σc and six unloading stress levels were designated forσ≥0.9σc.The variations in the elastic energy density(ue),dissipative energy density(ud),and energy storage efficiency(C)for the four rock types under GCLU tests were analyzed.Based on the variation of ue whenσ≥0:9σc,a method for calculating the peak energy density was proposed.The energy evolution in rock under UC condition before the post-peak stage was examined.The relationship between C0.9(C atσ≥0:9σc)and mechanical behavior of rocks was explored,and the damage evolution of rock was analyzed in view of energy.Compared with that of the three existing methods,the accuracy of the calculation method of peak energy density proposed in this study is higher.These findings could provide a theoretical foundation for more accurately revealing the failure behavior of rock from an energy perspective.
基金support from the National Natural Science Foundation of China(Grant Nos.:52250010 and 52050128)the Natural Science Foundation of Jiangsu Province(Grant No.:BK20230086)+3 种基金L.P.acknowledges support from the National Natural Science Foundation of China(Grant No.:52201242)the Young Elite Scientists Sponsorship Program by CAST(No.2021QNRC001)the Fund of Key Laboratory of Advanced Materials of Ministry of Education(No.AdvMat-2023-12)Z.M.S.acknowledges support from the National Natural Science Foundation of China(Grant No.:U23A20574).
文摘Cement-based materials are the foundation of modern buildings but suffer from intensive energy consumption.Utilizing cement-based materials for efficient energy storage is one of the most promising strategies for realizing zero-energy buildings.However,cement-based materials encounter challenges in achieving excellent electrochemical performance without compromising mechanical properties.Here,we introduce a biomimetic cement-based solid-state electrolyte(labeled as l-CPSSE)with artificially organized layered microstructures by proposing an in situ ice-templating strategy upon the cement hydration,in which the layered micropores are further filled with fast-ion-conducting hydrogels and serve as ion diffusion highways.With these merits,the obtained l-CPSSE not only presents marked specific bending and compressive strength(2.2 and 1.2 times that of traditional cement,respectively)but also exhibits excellent ionic conductivity(27.8 mS·cm^(-1)),overwhelming most previously reported cement-based and hydrogel-based electrolytes.As a proof-of-concept demonstration,we assemble the l-CPSSE electrolytes with cement-based electrodes to achieve all-cement-based solid-state energy storage devices,delivering an outstanding full-cell specific capacity of 72.2 mF·cm^(-2).More importantly,a 5×5 cm^(2) sized building model is successfully fabricated and operated by connecting 4 l-CPSSE-based full cells in series,showcasing its great potential in self-energy-storage buildings.This work provides a general methodology for preparing revolutionary cement-based electrolytes and may pave the way for achieving zero-carbon buildings.
